Pectin–cerium (IV) tungstate nanocomposite and its adsorptional activity for removal of methylene blue dye

Pectin–cerium (IV) tungstate composite (Pc/CT) has been prepared by sol gel method at room temperature. The composite ion exchanger has been characterized using X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy and Fourier infrared spectroscopy. The ion exchange capacity, pH titrations, thermal stability and distribution coefficient of composite ion exchanger were investigated. The Na⁺ ions exchange capacity of the Pc/CT has been observed higher (1.4 meq g^?1) as compared to its inorganic counterpart (0.8 meq g^?1). Pc/CT composite ion exchanger was thermally stable and retained about 60 % of its ion exchange capacity up to 400 °C. The distribution study has inferred more selective the Pc/CT for Zn²⁺ as compared to other metal ions. The adsorption efficiency of Pc/CT was tested for methylene blue removal dye from aqueous phase. The removal of dye followed pseudo-second-order kinetics.     

Observation of surface and atmospheric parameters using “NOAA 18” satellite: a study on earthquakes of Sumatra and Nicobar Is regions for the year 2014 (M ≥ 6.0)

Analysing pre-earthquake signals using satellite technology are getting importance among the scientific community, since round-the-clock survey for the wider region is possible compared to ground-based monitoring techniques. Several scientists are involved in various satellites and ground-based technologies to decode the complex physical mechanism of the earthquake process since 1980. They involved in measuring anomalous variations using space-based methodologies like EM signals, SAR interferometry, GPS for ionospheric sounding, satellite gravimetry, atmospheric sounding, Outgoing Longwave Radiation (OLR), radon gas and seismo-tectonic clouds. In this paper, the authors have considered surface latent heat flux (SLHF) and OLR satellite data for detailed analysis of earthquakes took place during the year 2014 in Sumatra and Nicobar Is regions. At the surface and atmospheric interface, the anomalous variations in SLHF were observed prior to the occurrence of the earthquake. Similarly, anomalous variations in OLR have been observed 3–30 days prior to the big earthquakes and it is measured above the cloud level. From the analysis, the author has found that variations in the SLHF and OLR flux can be utilized as efficient tools to identify the impending big earthquakes. SLHF and OLR variation level can give us a clue about the probable magnitude of earthquakes and also about earthquake preparation zones. Hence, by correlating the above-mentioned parameters, it is potential to key out the impending earthquakes with reasonable accuracy.

     

Human alteration of groundwater–surface water interactions (Sagittario River,Central Italy): implication for flow regime,contaminant fate and invertebrate response

Many rivers worldwide are undergoing severe man-induced alterations which are reflected also in changes of the degree of connectivity between surface waters and groundwater. Pollution, irrigation withdrawal, alteration of freshwater flows, road construction, surface water diversion, soil erosion in agriculture, deforestation and dam building have led to some irreversible species losses and severe changes in community composition of freshwater ecosystems. Taking into account the impact of damming and flow diversion on natural river discharge, the present study is aimed at (i) evaluating the effects of anthropogenic changes on groundwater/surface water interactions; (ii) analyzing the fate of nitrogenous pollutants at the floodplain scale; and (iii) describing the overall response of invertebrate assemblages to such changes. Hydrogeological, geochemical and isotopic data revealed short- and long-term changes in hydrology, allowing the assessment of the hydrogeological setting and the evaluation of potential contamination by nitrogen compounds. Water isotopes allowed distinguishing a shallow aquifer locally fed by zenithal recharge and river losses, and a deeper aquifer/aquitard system fed by surrounding carbonate aquifers. This system was found to retain ammonium and, through the shallow aquifer, release it in surface running waters via the hyporheic zone of the riverbed. All these factors influence river ecosystem health. As many environmental drivers entered in action offering a multiple-component artificial environment, a clear relationship between river flow alteration and benthic and hyporheic invertebrate diversity was not found, being species response driven by the combination of three main stressors: ammonium pollution, man-induced changes in river morphology and altered discharge regime.     

A distributed water–heat coupled model for mountainous watershed of an inland river basin in Northwest China (II) using meteorological and hydrological data

A distributed water–heat coupled model (DWHC) is calibrated by using daily precipitation data from 26 hydrological and meteorological stations: daily averaged air temperature data from the 11 stations and daily pan evaporation data (E601) from the 15 stations in 2000. Six tests by using different spatial interpolation methods to calculate the above daily meteorological data in each 1 km × 1 km grid, are designed to simulate the mean daily runoff generated from the research Heihe mountainous watershed in 2000. Due to spatial sparseness and asymmetry of the hydrological and meteorological stations, the results of the six tests have little differences. The interpolation method in 3-D mode considering altitude is not better than those taking no account of altitude, nor are the model results when the daily meteorological data at the two stations far from the research watershed are complemented. At last, a nearest neighbor interpolation method in 2-D mode is used to calibrate the DWHC model, in which the revised Nash-Sutcliffe Efficiency NSE, balance error B, determinate coefficient R ², root mean square error RMSE and average absolute error MAE is about 0.61, 0.08%, 0.73, 25.0 and 15.8 m³s⁻¹, respectively. However, by using the daily data in 1999 to validate the model, the NSE, B, R ², RMSE and MAE are, respectively, 0.63, −2.98%, 0.77, 34.9 and 20.3 m³s⁻¹. The reason that the model result is not favorable is mainly because of the lack of detailed soil information, meteorological data and vegetation data; even worse, the basic equations for runoff generation processes are mainly derived from the research results in other regions and meanwhile, its flow concentration method should be improved too. The water balance of the research watershed in 2000 is also discussed in this paper. Though the runoff simulation results are not favorable, the estimated evapotranspiration and runoff components are in accordance with the usual knowledge qualitatively, parts of which meet with the field measurements. According to the model results, the runoff is mainly generated from the land surfaces and shallow soil layers in this cold mountainous watershed. The alpine meadow has evident water conservation function based on the model results, field investigation and field observation results. The DWHC model also reproduces the formation processes of the thick-layered ground ice to some extent, though it is suppositional due to lack of detailed soil, vegetation and meteorological information.     

Major and trace element compositions (including REE) of mineral,thermal, mine and surface waters in SW Germany and implications for water–rock interaction

The near-surface water cycle in a geologically complex area comprises very different sources including meteoric, metamorphic and magmatic ones. Fluids from these sources can react with sedimentary, magmatic and/or metamorphic rocks at various depths. The current study reports a large number of major, minor and trace element analyses of meteoric, mineral, thermal and mine waters from a geologically well-known and variable area of about 200 × 150 km in SW Germany. The geology of this area comprises a Variscan granitic and gneissic basement overlain in parts by Triassic and Jurassic shales, sandstones and limestones. In both the basement and the sedimentary rocks, hydrothermal mineralization occurs (including Pb, Cu, As, Zn, U, Co and many others) which were mined in former times. Mineral waters, thermal waters and meteoric waters flowing through abandoned mines (mine waters) are distributed throughout the area, although the mine waters concentrate in and around the Schwarzwald.The present analyses show, that the major element composition of a particular water is determined by the type of surrounding rock (e.g., crystalline or sedimentary rocks) and the depth from which the water originates. For waters from crystalline rocks it is the origin of the water that determines whether the sample is Na–Cl dominant (deeper origin) or Ca–HCO₃ dominant (shallow origin). In contrast, compositions of waters from sedimentary rocks are determined by the availability of easily soluble minerals like calcite (Ca–HCO₃ dominant), halite (Na–Cl dominant) or gypsum (Ca–SO₄ dominant). Major element data alone cannot, therefore, be used to trace the origin of a water. However, the combination of major element composition with trace element data can provide further information with respect to flow paths and fluid–rock interaction processes. Accordingly, trace element analyses showed, that:

• −Ce anomalies can be used as an indicator for the origin of a water. Whereas surface waters have negative or strongly negative Ce anomalies, waters originating from greater depths show no or only weak negative Ce anomalies.
• −Eu anomalies can be used to differentiate between host rocks. Waters from gneisses display positive Eu anomalies, whereas waters from granites have negative ones. Waters from sedimentary rocks do not display any Eu anomalies.
• −Rb and Cs can also be indicators for the rock with which the fluid interacted: Rb and Cs correlate positively in most waters with Rb/Cs ratios of ∼2, which suggests that these waters are in equilibrium with the clay minerals in the rocks. Rb/Cs ratios >5 indicate reaction of a water with existing clay minerals, whereas Rb/Cs ratios <2 are probably related to host rock alteration and clay mineral formation.

The chemical compositions of carbonate precipitates from thermal waters indicate that rare earth elements (REEs), Rb and Cs concentrations in the minerals are controlled by the incorporation of clay particles that adsorb these elements.     

Detecting the footprint of a longwall mine panel claimed to infringe on a permit boundary at the Soma–Darkale coalfield (Manisa, Turkey) using surface fractures and microgravity measurements

A coal mine panel claimed to infringe on a permit boundary, or to create an hazard after subsidence has been the subject of lawsuits. We study at the Soma–Darkale coalfield (Manisa, Turkey), the footprint of a lignite coal mine panel at a depth of about 150–200 m by mapping all of the surface fractures we could observe, and by developing a post-subsidence density model that we verified through gravity measurements with positive Bouguer anomaly. With the analysis of the fracture map and the gravity data, we were able to identify the footprint of a mine panel from the effect of the anomalous mass due to denser overburden material filling up the space after the extraction of less-dense lignite. Whereas, using empirical methods like the so-called “limit line approach” to evaluate the extent of the area where mining can have subsidence-induced surface fracturing, one could not recognize for certain infringement of permit boundaries. The orientations of the fractures we mapped at the ground surface, the Bouguer gravity map, and a test borehole indicated the presence and dimensions of a coal panel in dispute. The presented approach based on gravity method and fracture observations may be an example to help settle conflicts related to the position of the longwall mine panel.     

S patio-temporal pattern of land use and land cover and its effects on land surface temperature using remote sensing and GIS techniques: a case study of Bhubaneswar city,Eastern India (1991–2021)

Urbanization produces substantial land use changes by causing the construction of different urban infrastructures in the city region for habitation, transportation, industry, and other reasons. As a result, it has a significant impact on Land Surface Temperature (LST) by disrupting the surface energy balance. The objective of this paper is to assess the impact of land-use/land-cover (LU/LC) dynamics on urban land surface temperature (LST) of Bhubaneswar City in Eastern India during 30 years (1991–2021) using Landsat data (TM, ETM + , and OLI/TIRS) and machine learning algorithms (MLA). The finding reveals that the mean LST over the entire study domain grows significantly between 1991 and, 2021due to urbanization (β coefficient 0.400, 0.195, 0.07, and 0.06 in 1991, 2001, 2011, and 2021 respectively) and loss of green space (β coefficient − 0.295, − 0.025, − 0.125 and − 0.065 in 1991, 2001, 2011 and 2021 respectively). The highest class recorded for agricultural land (49.60 km², accounting for 33.94% of the total land area) was in 1991 followed by vegetation (41.27 km², 28.19% of the total land area), and built-up land (27.59 km², 18.84% of the total land area). The sharp decline of vegetation cover will continue until 2021 due to increasing built-up areas (r = − 0.531, − 0.329, − 0.538, and − 0.063 in the 1991, 2001, 2011 and 2021 respectively). Built-up land (62.60 km², accounting for 42.76% of the total land area, an increase of 35.01 km² from 1991) as the highest class followed by water bodies (21.57%, 32.60 km² of the land area), and agricultural land (31.57 km², 21.57% of the land area) in 2021. Remote sensing techniques proved to be an important tool to urban planners and policymakers to take adequate steps to promote sustainable development and minimize urbanization influence on LST. Urban green space (UGS) can help improve the overall liveability and environmental sustainability of Bhubaneswar city.

     

Contents,seasonal variations,and forms of migration of major and minor elements in surface waters in the area of the Tyrnyauz Tungsten–Molybdenum Combine (TTMC) and adjacent areas (Kabardino-Balkarian Republic,Russian Federation) and actions for recovery of the ecological environment

Anomalous concentrations of numerous major and minor elements significantly exceeding the threshold limit values (TLV) for drinking water were registered in the area of the Tyrnyauz Tungsten–Molybdenum Combine (TTMC). The maximal excess of the TLV (by one or two orders of magnitude) were obtained for Mo (up to 11 mg/L), W (4.4 mg/L), As (1.5 mg/L), Mn (8.4 mg/L), and Tl (up to 3.3 μg/L) in water of the Bolshoi Mukulan Brook flowing through the mines and three brooks flowing out from the base of the embankment of the tailing store no. 1. They are the major pollutants for water of the Baksan River. Upon flowing out to the plain, water of the Baksan River shows significant excess of the TLVs (in summer) for Al, Fe, Mn, Be, Si, Ti, Tl, and Hg.     

Response to the paper by H. Zia,B. Lecampion “Explicit versus implicit front advancing schemes for the simulation of hydraulic fracture growth” (Int. J. Numer. Anal. Methods Geomech., 2019, 43 (6), 1300–1315)

The response presents three comments, which (i) explain theoretical background for the success of the explicit front advancing scheme by Zia and Lecampion (comment 1), (ii) suggest possible extensions (comment 2), and (iii) pay attention on expected limitations of the scheme to be checked by the authors in numerical experiments (comment 3). The response does not intend to present novel results: it is entirely based on known results published in the references cited.