Projecting climate change impacts on stream flow regimes with tracer‐aided runoff models ‐ preliminary assessment of heterogeneity at the mesoscale

The northern mid‐high latitudes form a region that is sensitive to climate change, and many areas already have seen – or are projected to see – marked changes in hydroclimatic drivers on catchment hydrological function. In this paper, we use tracer‐aided conceptual runoff models to investigate such impacts in a mesoscale (749 km²) catchment in northern Scotland. The catchment encompasses both sub‐arctic montane sub‐catchments with high precipitation and significant snow influence and drier, warmer lowland sub‐catchments. We used downscaled HadCM3 General Circulation Model outputs through the UKCP09 stochastic weather generator to project the future climate. This was based on synthetic precipitation and temperature time series generated from three climate change scenarios under low, medium and high greenhouse gas emissions. Within an uncertainty framework, we examined the impact of climate change at the monthly, seasonal and annual scales and projected impacts on flow regimes in upland and lowland sub‐catchments using hydrological models with appropriate process conceptualization for each landscape unit. The results reveal landscape‐specific sensitivity to climate change. In the uplands, higher temperatures result in diminishing snow influence which increases winter flows, with a concomitant decline in spring flows as melt reduces. In the lowlands, increases in air temperatures and re‐distribution of precipitation towards autumn and winter lead to strongly reduced summer flows despite increasing annual precipitation. The integration at the catchment outlet moderates these seasonal extremes expected in the headwaters. This highlights the intimate connection between hydrological dynamics and catchment characteristics which reflect landscape evolution. It also indicates that spatial variability of changes in climatic forcing combined with differential landscape sensitivity in large heterogeneous catchments can lead to higher resilience of the integrated runoff response. Copyright © 2012 John Wiley & Sons, Ltd.     

Evolution of the spatial and temporal characteristics of the isotope hydrology of a montane river basin

Abstract

Precipitation and streamwater were analysed weekly for δ¹⁸O in seven tributaries and five main stem sites of a 2100 km² catchment; >60% of it is upland in character. Precipitation δ¹⁸O followed seasonal patterns ranging from –20‰ in winter to –4‰ in summer. Seasonality was also evident in stream waters, though much more damped. Mean transit times (MTTs) were estimated using δ¹⁸O input–output relationships in a convolution integral with a gamma distribution. The MTTs were relatively similar (528–830 days): tributaries exhibited a greater range, being shorter in catchments with montane topography and hydrologically responsive soils, and longer where catchments have significant water storage. Along the main stem, MTTs increased modestly from 621 to 741 days. This indicates that montane headwaters are the dominant sources of runoff along the main stem of the river system. Models suggest that around 10% of runoff has transit times of less than two weeks during higher flows whilst older (>10-year old) water sustains low flows contributing around 5% of runoff.

Citation Speed, M., Tetzlaff, D., Hrachowitz, M. & Soulsby, C. (2011) Evolution of the spatial and temporal characteristics of the isotope hydrology of a montane river basin. Hydrol. Sci. J. 56(3), 426–442     

Influence of lowland aquifers and anthropogenic impacts on the isotope hydrology of contrasting mesoscale catchments

We examined the isotope hydrology of eight, contrasting mesoscale (104–488 km²) catchments characterized by a systematic change in the relative importance of upland and lowland areas that reflects the relative distribution of metamorphic and sedimentary rocks. Precipitation and stream water were monitored over a 12‐month period, and stable isotopes were used to examine spatial variations in the hydrometric and tracer dynamics of the catchments. Isotopic tracers were used to examine the temporal dynamics of different runoff sources, and geochemical tracers (alkalinity) were used to identify the geographic sources of runoff. Input–output relationships of isotopic tracers were explored using a gamma function to fit a transit time distribution, which was used to test the hypothesis that the length of mean transit times increased systematically with the cover of sandstone aquifers in the catchments. However, in three catchments, the increased influence of anthropogenic factors, notably reservoir storage, urban runoff and agricultural abstraction for irrigation, prevented reliable transit time estimation. For sites where tentative mean transit time estimates were possible, these varied from around 1.6 years in upland catchments dominated by metamorphic rocks (>75%) and responsive soils to around 4 years in catchments with 34% sandstone cover and freely draining soils. These preliminary results were consistent with inferences of geochemical tracers on the increased role of sedimentary aquifers as runoff sources in lowland areas, but observation from a larger number of sites is needed to confirm this. Copyright © 2012 John Wiley & Sons, Ltd.     

Stream water chemistry and quality along an upland–lowland rural land-use continuum, south west England

This study examined stream water quality across a range of catchments which are representative of the key environments and land uses of rural south-west England. These catchments included: (a) an acidic upland headwater catchment, rising on the moorlands of Dartmoor, with low-intensity sheep rearing; (b) a headwater catchment rising on the weathered granite lower slopes of Dartmoor, with cattle farming; (c) a lowland headwater clay catchment with sub-surface drainage and high intensity livestock farming, fodder crop cultivation, and hard-standing/slurry storage; and (d) the main River Taw, a lowland river system receiving drainage from a range of tributaries, exemplified by the above catchment types. Variations in water chemistry and quality were observed along an upland–lowland transition, from headwater streams to the main river channel. Within the livestock-dominated headwater streams, total phosphorus (TP) was dominated by particulate phosphorus (PP). These PP concentrations appeared to be mainly linked to two sets of processes: (1) in-stream sediment precipitation with sorption/co-precipitation of phosphate and/or localised in-channel mobilisation of sediment (by cattle or channel-clearing operations) under low flow conditions, and (2) sediment erosion and transportation associated with near-surface runoff during storm events. Under baseflow conditions, in-stream and/or riparian processes played a significant role in controlling general nutrient chemistry, particularly in the headwater streams which were heavily impacted by livestock.     

Isotopic and geochemical tracers reveal similarities in transit times in contrasting mesoscale catchments

There is a need for more isotopic tracer studies at the mesoscale to extend our understanding of catchment transit times and their associated controls beyond smaller experimental sites (typically < 10 km²). This paper, therefore, examines the isotope hydrology of six mesoscale (10¹–10² km²) sub‐catchments of the 2000 km² basin of the River Dee in northern Scotland. All the catchments were upland in character (mean altitude > 400 m) with similar suites of soil coverage (predominantly regosols, gleys, peats and podzols), although the relative distribution varied, as did the presence of other landscape features such as aquifers in Quaternary drifts and lakes. Input–output relationships of δ¹⁸O in precipitation and runoff revealed contrasting responses and differential damping which were broadly consistent with catchment characteristics. The mean transit times (MTTs) were estimated using a convolution integral with a Gamma distribution as the transfer function. These varied from 528 days in the most responsive catchments to > 800 days in catchments where the tracer signature was most damped. Shorter MTTs were found in sub‐catchments with a higher percentage cover of responsive soils (i.e. regosols, gleys and peats), whilst sub‐catchments with longest MTTs had a higher coverage of free‐draining podzolic and alluvial soils, as well as significant amount of stored water either in fluvio‐glacial aquifers or large lakes. The MTT of all six catchments had the same order of magnitude; this contrasts with studies in the Scottish Highlands with smaller (<10 km²) catchments where MTT has been shown to vary between 60 and 1200 days. Copyright © 2010 John Wiley & Sons, Ltd.     

Influence of sea salt on stream water chemistry in an upland afforested catchment

The chemistry of bulk precipitation and stream water was monitored in an acidic afforested catchment at Llyn Brianne in upland Wales between 1985 and 1990. Throughfall, stemflow and soil water chemistry were also monitored between 1988 and 1989. Marine-derived solutes dominated the ionic composition of precipitation and stream water, which had mean Cl concentrations of 113 μequiv. 1^?1 and 245 μequiv. 1^?1, respectively. The higher concentrations in stream water reflect occult and dry deposition on the forest canopy and the effect of interception and transpiration losses. Chloride variations in stream water (112-454μequiv. 1^?1) were damped compared with bulk precipitation (28-762μequiv. 1^?1) due to the mixing of event (‘new’) water with pre-event (‘old’) water in the catchment soils. A storm episode monitored in the catchment in April 1989 was associated with high sea salt inputs and Cl concentrations in throughfall (1466μequiv. 1^?1) and storm runoff were exceptionally high (392μequiv. 1^?1). The Cl signal in stream water during the episode was consistent with an event (‘new’) water contribution to the storm response. However, a short-term hydrochemical budget estimated that although Cl outputs from the catchment during the event (1.17 kg ha^?1) were equivalent to 8% of inputs in throughfall and stemflow, the storm runoff was equivalent to 32% of effective precipitation. This indicates that pre-event (‘old’) water was the dominant source (> 75%) of storm runoff. Although sea salt inputs during the event had a marked impact on stream water chemistry, the anomalously high levels of acidity sometimes associated with sea salt events were not observed in this particular study.     

A tracer‐based assessment of hydrological pathways at different spatial scales in a mesoscale Scottish catchment

Geochemically based hydrograph separation techniques were used in a preliminary assessment to infer how runoff processes change with landscape characteristics and spatial scale (1–233 km²) within a mesoscale catchment in upland Scotland. A two‐component end‐member mixing analysis (EMMA) used Gran alkalinity as an assumed conservative tracer. Analysis indicated that, at all scales investigated, acidic overland flow and shallow subsurface storm flows from the peaty soils covering the catchment headwaters dominated storm runoff generation. The estimated groundwater contribution to annual runoff varied from 30% in the smallest (ca 1 km²) peat‐dominated headwater catchment with limited groundwater storage, to >60% in larger catchments (>30 km²) with greater coverage of more freely draining soils and more extensive aquifers in alluvium and other drift. This simple approach offers a useful, integrated conceptualization of the hydrological functioning in a mesoscale catchment, which can be tested and further refined by focused modelling and process‐based research. However, even as it stands, the simple conceptualization of system behaviour will have significant utility as a tool for communicating hydrological issues in a range of planning and management decisions. Copyright © 2002 John Wiley & Sons, Ltd.     

Groundwater isoscapes in a montane headwater catchment show dominance of well‐mixed storage

We conducted an integrated groundwater–surface water monitoring programme in a 3.2‐km² experimental catchment in the Scottish Highlands by sampling all springs, seepages, and wells in six, spatially extensive synoptic surveys over a 2‐year period. The catchment has been glaciated, with steep hillslopes and a flat valley bottom. There is around 70% glacial drift cover in lower areas. The solid geology, which outcrops at higher elevations, is granite and metamorphic schist. The springs and seepages generally occur at the contact between the solid geology and drift or at breaks of slopes in the valley bottom. Samples were analysed for stable isotopes, Gran alkalinity and electrical conductivity. Despite the surveys encompassing markedly different antecedent conditions, the isotopic composition of groundwater at each location exhibited limited temporal variability, resulting in a remarkable persistence of spatial patterns indicating well‐mixed shallow, groundwater stores. Moreover, line‐conditioned excess values derived from the isotope data indicated no evidence of fractionation affecting the groundwater, which suggests that most recharge occurs in winter. The alkalinity and electrical conductivity of groundwater reflected geological differences in the catchment, being highest where more weatherable calcareous rocks outcrop at higher altitudes in the catchment. Springs draining these areas also had the most variable isotope composition, which indicated that they have shorter residence times than the drift covered part of the catchment. The study showed that even in geologically heterogeneous upland catchments, groundwater can be characterized by a consistent isotopic composition, reflecting rapid mixing in the recharge zone. Our work, thus, emphasizes the critical role of groundwater in upland catchments and provides tracer data that can help constrain quantitative groundwater models.     

Process controls on the statistical flood moments ‐ a data based analysis

In this paper, the controls of different indicators on the statistical moments (i.e. mean annual flood (MAF), coefficient of variation (CV) and skewness (CS)) of the maximum annual flood records of 459 Austrian catchments are analysed. The process controls are analysed in terms of the correlation of the flood moments within five hydrologically homogeneous regions to two different types of indicators. Indicators of the first type are static catchment attributes, which are associated with long‐term observations such as mean annual precipitation, the base flow index, and the percentage of catchment area covered by a geological unit or soil type. Indicators of the second type are dynamic catchment attributes that are associated with the event scale. Indicators of this type used in the study are event runoff coefficients and antecedent rainfall. The results indicate that MAF and CV are strongly correlated with indicators characterising the hydro‐climatic conditions of the catchments, such as mean annual precipitation, long‐term evaporation and the base flow index. For the catchments analysed, the flood moments are not significantly correlated with static catchment attributes representing runoff generation, such as geology, soil types, land use and the SCS curve number. Indicators of runoff generation that do have significant predictive power for flood moments are dynamic catchment attributes such as the mean event runoff coefficients and mean antecedent rainfall. The correlation analysis indicates that flood runoff is, on average, more strongly controlled by the catchment moisture state than by event rainfall. Copyright © 2008 John Wiley & Sons, Ltd.     

Stable isotope tracers as diagnostic tools in upscaling flow path understanding and residence time estimates in a mountainous mesoscale catchment

δ¹⁸O measurements of precipitation and stream waters were used as a natural tracer to investigate hydrological pathways and residence times in the River Feshie, a complex mesoscale (231 km²) catchment in the Cairngorm Mountains of Scotland. Precipitation δ¹⁸O exhibited strong seasonal variation over the 2001–02 hydrological year, ranging from −6·9‰ in the summer, to −12·0‰ during winter snowfalls (mean δ¹⁸O −9·59‰). Although damped, this seasonality was reflected in stream water outputs at seven sampling sites in the catchment, allowing δ¹⁸O variations to be used to infer hydrological source areas. Thus, stream water δ¹⁸O was generally controlled by a seasonally variable storm flow end member, mixing with groundwater of more constant isotopic composition. Periodic regression analysis allowed the differences in this mixing process between monitoring subcatchments to be assessed more quantitatively to provide a preliminary estimate of mean stream water residence time. This demonstrated the importance of responsive hydrological pathways associated with peat and shallow alpine soils in the headwater subcatchments in producing seasonally variable runoff with short mean residence times (33–113 days). In contrast, other tributaries with more freely draining soils and larger groundwater storage in shallow aquifers provided more effective mixing of variable precipitation inputs, resulting in longer residence time estimates (178–445 days). The mean residence time of runoff leaving the Feshie catchment reflected an integration of these contrasting influences (110–200 days). These insights from δ¹⁸O measurements extend the hydrological understanding of the Feshie catchment gained from other hydrochemical tracers, and demonstrate the utility of isotope tracers in investigating hydrological processes at the mesoscale. Copyright © 2005 John Wiley & Sons, Ltd.     

Pathways of runoff and sediment transfer in small agricultural catchments

Simultaneous field monitoring of runoff and suspended sediment loads from a 30 ha, artificially‐drained, mixed‐agricultural catchment in Herefordshire, UK indicates field drains are the dominant pathway for the transfer of runoff and sediment to the stream. Surface runoff pathways draining 6·2% of the catchment area transported around 1% of the catchment sediment load, while subsurface runoff in field drains draining 26·5% of the catchment transported around 24% of the sediment load. The explanations offered here for the dominance of drainflow—the spatial limitation of surface runoff generation and low hillslope‐stream connectivity of surface runoff compared with subsurface runoff—are also likely to apply to other artificially‐drained lowland agricultural catchments in the UK. These catchments are usually on poorly‐drained soils, and land management can have a considerable effect on the operation of runoff pathways and the transfer of sediment from hillslope to stream. As a result, subsurface inputs may also dominate sediment transfers in other underdrained catchments. The focus on sediment and pollutant losses via surface runoff pathways means that pollution inputs from subsurface, preferential pathways have been unfairly neglected, and it may be more important to focus on subsurface sediment and sediment‐associated pollution inputs for mitigation rather than inputs from surface pathways. Copyright © 2009 John Wiley & Sons, Ltd.     

Controls on event runoff coefficients in the eastern Italian Alps

Analyses of event runoff coefficients provide essential insight on catchment response, particularly if a range of catchments and a range of events are compared by a single indicator. In this study we examine the effect of climate, geology, land use, flood types and initial soil moisture conditions on the distribution functions of the event runoff coefficients for a set of 14 mountainous catchments located in the eastern Italian Alps, ranging in size from 7.3 to 608.4 km². Runoff coefficients were computed from hourly precipitation, runoff data and estimates of snowmelt. A total of 535 events were analysed over the period 1989–2004. We classified each basin using a “permeability index” which was inferred from a geologic map and ranged from “low” to “high permeability”. A continuous soil moisture accounting model was applied to each catchment to classify ‘wet’ and ‘dry’ initial soil moisture conditions. The results indicate that the spatial distribution of runoff coefficients is highly correlated with mean annual precipitation, with the mean runoff coefficient increasing with mean annual precipitation. Geology, through the ‘permeability index’, is another important control on runoff coefficients for catchments with mean annual precipitation less than 1200 mm. Land use, as indexed by the SCS curve number, influences runoff coefficient distribution to a lesser degree. An analysis of the runoff coefficients by flood type indicates that runoff coefficients increase with event snowmelt. Results show that there exists an intermediate region of subsurface water storage capacity, as indexed by a flow–duration curve-based index, which maximises the impact of initial wetness conditions on the runoff coefficient. This means that the difference between runoff coefficients characterised by wet and dry initial conditions is negligible both for basins with very large storage capacity and for basins with small storage capacity. For basins with intermediate storage capacities, the impact of the initial wetness conditions may be relatively large.     

Landscape influence on small‐scale water temperature variations in a moorland catchment

We monitored temperatures in stream water, groundwater and riparian wetland surface water over 18 months in a 3.2‐km² moorland catchment in the Scottish Highlands. The stream occupies a glaciated valley, aligned east–west. It has three main headwater tributaries with a large north facing catchment, a south facing catchment and the smallest east facing headwater. The lower catchment sampling locations begin after the convalescence of all three headwaters. Much of the stream network is fringed by riparian peatlands. Stream temperatures are mainly regulated by energy exchanges at the air–water interface. However, they are also influenced by inflows from the saturated riparian zone, where surface water source areas are strongly connected with the stream network. Consequently, the spatial distribution of stream temperatures exhibits limited variability. Nevertheless, there are significant summer differences between the headwaters, despite their close proximity to each other. This is consistent with aspect (and incident radiation), given the south and east facing headwaters having higher temperatures. The largest, north‐facing sub‐catchment shows lower summer diurnal temperature variability, suggesting that lower radiation inputs dampen temperature extremes. Whilst stream water temperature regimes in the lower catchment exhibit little change along a 1‐km reach, they are similar to those in the largest headwater; probably reflecting size and comparable catchment aspect and hydrological flow paths. Our results suggest that different parts of the channel network and its connected wetlands have contrasting sensitivity to higher summer temperatures. This may be important in land management strategies designed to mitigate the impacts of projected climatic warming. Copyright © 2015 John Wiley & Sons, Ltd.     

A case study in catchment hydrochemistry: Conflicting interpretations from hydrological and chemical observations

Soil water, stream water, groundwater and rain water were sampled through a storm event in a moorland catchment. Samples were analysed for major ions and deuterium. Chloride and deuterium are used as tracers to enable separation of the stream runoff hydrograph into three components: rain, soil and groundwater. The results indicate that rain water arrives in the stream quickly during the event and contributes a significant volume to the runoff peak. The chemical signal in the rain water is, however, significantly damped, apparently due to mixing with soil water held in the catchment before the event. This is further modified before reaching the stream, apparently through mixing with a deeper groundwater component. Interpretation of tracer, chemistry and hydrological data to present an integrated picture of catchment hydrochemical response is difficult due to problems in the chemical and conceptual definition of the flow components.     

Comparative analysis of the response of various land covers to an exceptional rainfall event in the central Spanish Pyrenees,October 2012

The hydrological and geomorphological effects of an exceptional rainstorm event that occurred in the central Spanish Pyrenees during 19–21 October 2012 were studied in five experimental catchments under various land covers: (i) subhumid badlands; (ii) dense forest; (iii) an abandoned farmland area recolonized by shrubs and forest patches; and (iv) subalpine grasslands. Hydrographs and sedigraphs demonstrated that vegetation cover is a major factor affecting the control of floods even during exceptional rainstorms, at least at the spatial scale at which the phenomenon was studied (catchment sizes: 0.3–2.8 km2) and under dry catchment conditions. The combined precipitation over the two days (c. 250 mm) was the greatest for any two‐day event recorded since 1950 in the central‐western Pyrenees for all but one of the stations in the study. Five pulses of most intense rainfall were recorded. The forested catchment did not react to the two most intense rainfall pulses, because of the very low antecedent level of the water table. The main peak flow occurred only when at least a part of the catchment was saturated. The abandoned farmland catchment had two small peak discharges at the beginning of the event, which were produced by infiltration excess overland flow from eroded areas close to the main stream. During the third most intense rainfall period a large part of this catchment contributed to runoff and a relatively high peak discharge was produced. The badland catchment reacted immediately from the beginning of the rainstorm, yielding very high discharges accompanied by high suspended sediment concentrations. The subalpine catchment showed a hydrograph mirroring the hyetograph, with brief but intense hydrological responses to increased precipitation, because of the marked gradients and the presence of bare rock in the headwaters. A high volume of bedload was carried during the peak discharge. Copyright © 2013 John Wiley & Sons, Ltd.     

Isotope hydrological study of mean transit times in an alpine basin (Wimbachtal, Germany)

Measurements of tritium and ¹⁸O concentrations in precipitation and runoff were used to provide further insight into the groundwater storage properties of the Wimbachtal Valley, a catchment area of 33.4 km², extending between 636 and 2713 m a.s.l. in the Berchtesgaden Alps. The catchment includes three aquifer types: a dominant porous aquifer; a fractured dolomite; a karstic limestone aquifer. Employing a simple hydrological model, information about mean transit times of environmental tracers is derived for the groundwater runoff component and several karst springs from the application of the exponential and dispersion flow models to the isotopic input and output data. The mean transit times calculated from a dispersion model with transit times of 4.1 years for ¹⁸O and 4.2 years for tritium, which agree well, allow calculation of total (mobile + stagnant) groundwater storage volume, which is equivalent to 6.6 m of water depth. Direct runoff appears negligible as in many other cases.     

Temporal patterns and controls on runoff magnitude and solution chemistry of urban catchments in the semiarid southwestern United States

Urban expansion and the scarcity of water supplies in arid and semiarid regions have increased the importance of urban runoff to localized water resources. However, urban catchment responses to precipitation are poorly understood in semiarid regions where intense rainfall often results in large runoff events during the short summer monsoon season. To evaluate how urban runoff quantity and quality respond to rainfall magnitude and timing, we collected stream stage data and runoff samples throughout the 2007 and 2008 summer monsoons from four ephemeral drainages in Tucson, Arizona. Antecedent rainfall explained 20% to 30% of discharge (mm) and runoff ratio in the least impervious (22%) catchment but was not statistically related to hydrologic responses at more impervious sites. Regression models indicated that rainfall depth, imperviousness and their combined effect control discharge and runoff ratios (p < 0.01, r² = 0.91 and 0.75, respectively). In contrast, runoff quality did not vary with imperviousness or catchment size. Rainfall depth and duration, time since antecedent rainfall and event and cumulative discharge controlled runoff hydrochemistry and resulted in five specific solute response patterns: (i) strong event and seasonal solute mobilization (solute flush), (ii) event chemostasis and strong seasonal flush, (iii) event chemostasis and weak seasonal flush, (iv) event and seasonal chemostasis and (v) late seasonal flush. Our results indicate that hydrologic responses of semiarid catchments are controlled by rainfall partitioning at the event scale, whereas wetting magnitude, frequency and timing alter solute stores readily available for transport and control temporal runoff quality. Copyright © 2012 John Wiley & Sons, Ltd.     

A comparison of gauge and radar precipitation data for simulating an extreme hydrological event in the Severn Uplands,UK

This paper provides a comparison of gauge and radar precipitation data sources during an extreme hydrological event. November–December 2006 was selected as a time period of intense rainfall and large river flows for the Severn Uplands, an upland catchment in the United Kingdom. A comparison between gauge and radar precipitation time‐series records for the event indicated discrepancies between data sources, particularly in areas of higher elevation. The HEC‐HMS rainfall‐runoff model was selected to assess the accuracy of the precipitation to simulate river flows for the extreme event. Gauge, radar and gauge‐corrected radar rainfall were used as model inputs. Universal cokriging was used to geostatistically interpolate gauge data with radar and elevation data as covariates. This interpolated layer was used to calculate the mean‐field bias and correct the radar composites. Results indicated that gauge‐ and gauge‐corrected radar‐driven models replicated flows adequately for the extreme event. Gauge‐corrected flow predictions produced an increase in flow prediction accuracy when compared with the raw radar, yet predictions were comparative in accuracy to those using the interpolated gauge network. Subsequent investigations suggested this was due to an adequate spatial and temporal resolution of the precipitation gauge network within the Severn Uplands. Results suggested that the six rain gauges could adequately represent precipitation variability of the Severn Uplands to predict flows at an approximately equal accuracy to that obtained by radar. Temporally, radar produced an increase in flow prediction accuracy in mountainous reaches once the gauge time step was in excessive of an hourly interval. Copyright © 2010 John Wiley & Sons, Ltd.     

Spatial delineation of groundwater–surface water interactions through intensive in‐stream profiling

The dominance of ‘old’ pre‐event water in headwater storm runoff has been recorded in numerous upland catchment studies; however, the mechanisms by which this pre‐event water enters the stream channel are poorly understood. Understanding these processes is fundamental to determining the controls on surface water quality and associated impacts on stream ecology. Previous studies in the upland forested catchment of the Afon Hafren (River Severn) at Plynlimon, mid‐Wales, identified an active bedrock groundwater system that was discharging into the stream channel during storm response. Detailed analysis showed that these discharges were small and could not account for the majority of pre‐event storm water response identified at this site; pre‐event storm runoff had to be sourced predominantly from further upstream. An intensive stream survey was used to determine the spatial nature of groundwater–surface water (GW–SW) interactions in the Hafren Catchment. Detailed physico‐chemical in‐stream profiling identified a marked change in water quality indicating a significant discrete point of bedrock groundwater discharge upstream of the Hafren Transect study site. The in‐stream profiling showed the importance of high spatial resolution sampling as a key to understanding processes of GW–SW interaction and how quick and cost‐effective measurements of specific electrical conductance of stream waters could be used to highlight in‐stream heterogeneity. This approach is recommended for use in headwater catchments for initial characterisation of the stream channel in order to better locate instrumentation and to determine more effective targeted sampling protocols in upland catchment research. Copyright © 2012 John Wiley & Sons, Ltd.     

Release of dissolved organic carbon from upland peat

This study examines the release of dissolved organic carbon (DOC) from upland peat during the period of the autumn flushing. Hydroclimatic conditions were monitored in conjunction with measurements of absorbance and the E4/E6 ratio of the stream draining an 11·4 km² upland peat catchment in northern England. During two months of monitoring the effects of 67 separate rainfall events were examined showing that:

• The peat behaves hydrologically as if it were a two end‐member system consisting of old, interevent, and new, event, water. Runoff is initiated by percolation excess of new water at the acrotelm–catotelm interface.
• The discharge of dissolved organic matter behaves like a three end‐member system with the between‐event water being low in DOC and storm events being characterized by two types of water. Initial runoff being characterized by new water rich in DOC that gives way to new water depleted in DOC. This transition can be ascribed to the runoff progressing from throughflow within the acrotelm progressing to saturation‐excess overland flow.
• Depletion of DOC during storm events is accompanied by a change in the character of the DOC as the E4/E6 ratio changes. This suggests that the decrease in DOC during events is the result of exhaustion of reserves rather than changes in the flowpaths being utilized by runoff.
• The amount of carbon released in any event is critically dependent upon the time between events during which oxidation processes generate a reservoir of available carbon. Production of available carbon in the catchment is as high as 4·5 g C per day per m³ of peat, suggesting a turnover rate of peat of the order of 42 years. Copyright © 2002 John Wiley & Sons, Ltd.