煅烧改性净水厂污泥对底泥内源磷释放的控制效果

以自主研发的煅烧改性净水厂污泥（C-WTPS）作为污染底泥活性覆盖材料,室内静态模拟实验研究C-WTPS覆盖强度对控制底泥磷释放效果的影响,分析C-WTPS和底泥中不同形态磷含量变化,探讨C-WTPS薄层覆盖对上覆水体中pH、DO和ORP的影响.结果表明,实验历时40天,在底泥TP释放强度为6.25~10.87 mg/（m²·d）时,覆盖强度为0.25、0.50、1.00、1.50和2.00 kg/m²的C-WTPS对TP平均削减率分别为59.68%、75.71%、88.75%、92.42%和96.28%,可见覆盖强度为1.00 kg/m²以上的C-WTPS能控制底泥中90%以上TP释放.C-WTPS吸附的磷主要以无机磷（IP）中的铁铝结合态磷（NAIP）形式存在,有机磷（OP）和钙磷（AP）形式较少.C-WTPS促进了底泥中易释放形态磷迁移到C-WTPS中,并转化较为稳定的形态磷,可见C-WTP覆盖不仅控制了底泥磷释放,而且也削减了底泥磷释放风险.C-WTPS覆盖后,上覆水体中pH开始呈现下降趋势,最终维持在pH=7范围波动;C-WTPS覆盖强度越大,上覆水体pH下降也明显;C-WTPS覆盖改善上覆水体中DO和ORP环境的效果不明显.     

人工湖滨湿地磷素汇-源功能转换及理论解释

采用水动力弥散和吸附理论建立了表流湿地水-土界面磷通量模型,定义了湿地汇-源转换的临界水体磷浓度值.模型揭示,湿地对磷的截留是水动力弥散和吸附共同作用的结果.在湿地建成运行初期,吸附作用明显,临界浓度值较低,湿地较好地发挥截磷功能.随着湿地的运行,土壤吸附趋于饱和,吸附作用减弱,水动力弥散变为主导因素,临界浓度值增大,使湿地除磷功能减弱,在一定条件下,反而可能释放磷.本文建立的磷通量模型具有明确的物理基础,能解释湿地对磷去除功能退化的机理和汇-源转换条件.应用模型对抚仙湖马料河湿地的观测数据作了初步解释,该湿地运行两年后,临界磷浓度值为0.58 mg/L,湿地除磷功能明显衰退.     

Modelling sediment and total phosphorus export from a lowland catchment: comparing sediment routing methods

Bank erosion is the main source of suspended sediment (SS) and diffuse total phosphorus (TP) in many lowland catchments. This study compared a physically based sediment routing method (Physical method), which distinguishes between stream bed and bank erosion, with the original sediment routing method (Original method) within the Soil and Water Assessment Tool (SWAT) version 2009, for simulating SS and TP losses from a lowland catchment. A SWAT model was set up for the lowland River Odense catchment in Denmark and calibrated against observed stream flow and phosphate (PO₄) loads. On the basis of an initial calibration of hydrological and PO₄ parameters, the SWAT model with the Original method (Original model) and the SWAT model with the Physical method (Physical model) were calibrated separately against observed SS and TP loads. The SWAT model simulated daily stream flow well but underestimated PO₄ loads. The Physical model simulated daily SS and TP better than the Original model. The simulated contribution of bank erosion to SS in the Physical model (99%) was close to the estimated contribution from in situ erosion measurements (90–94%). Compared with the Original method, the Physical method is not only more conceptually correct but also improves model performance. Copyright © 2014 John Wiley & Sons, Ltd.     

镧改性膨润土对浅水湖泊水体磷浓度和沉积物磷形态的影响

分析湖泊沉积物磷形态的变化是揭示控制沉积物磷释放机理的关键.本研究分析了暨南大学南湖加镧改性膨润土前后水体磷浓度和沉积物磷形态变化,以探讨镧改性膨润土对削减水体磷浓度的效果.结果显示,镧改性膨润土添加后,上覆水磷浓度波动较大,总体呈下降趋势;至60 d时,水体总磷、颗粒态磷、总溶解磷和溶解性反应磷分别比添加前下降了45.1%、44.1%、48.2%和85.3%;沉积物中的弱结合态磷和氧化还原敏感性磷含量减少,更稳定的磷灰石结合态磷和残渣磷含量增加,而金属氧化物磷和有机磷含量变化较小.本研究表明镧改性膨润土能改变沉积物磷形态,使活性磷转化为稳定的磷形态,从而提高沉积物对磷的滞留能力、降低湖水磷含量,改善水质.     

磷素在湖滨湿地基质-上覆水界面中的迁移过程

以抚仙湖流域马料河湖滨湿地基质为研究对象,进行了低浓度(P≤3.0mg/L)负荷条件的吸附动力学试验;以及低、高浓度磷的吸附等温线试验,结果表明,在初始磷浓度为0.02mg/L、0.03mg/L时,基质存在磷释放现象,当初始浓度增加到0.05mg/L时,基质开始吸附磷,24h后吸附趋于平衡状态,以一元线性回归法对上述基质的吸附等温线进行了Freundlich模型和Langmuir模型的回归分析,在此基础上,进行了高初始浓度下上覆水与基质振荡24h后基质对磷的吸附试验,结果表明在高浓度下,基质样品可在24h内释放原来吸附的大部分磷量.     

氧化还原条件对红枫湖沉积物磷释放影响的微尺度分析

选取贵州红枫湖为研究对象,在实验室条件下模拟了自然、好氧和厌氧条件下沉积物内源磷的释放过程,联合应用微电极技术和沉积物磷形态分析对沉积物—水界面开展了微尺度观测与研究.结果表明,厌氧条件下红枫湖沉积物总磷含量显著降低,且主要是NaOH提取态磷(NaOH-P)和残渣态磷(rest-P)含量降低所致,厌氧条件下沉积物孔隙水中磷酸盐浓度明显升高,而好氧条件下沉积物孔隙水磷酸盐浓度显著降低,反映厌氧条件显著促进了红枫湖沉积物磷释放.厌氧条件下沉积物内部溶解氧浓度下降、硫还原活动增强可能是导致NaOH-P释放的主要原因.O_2浓度的降低加速了沉积物还原作用并产生大量H2S,进而与二价铁离子形成硫化亚铁沉淀,最终导致NaOH-P(Fe-P)释放到孔隙水中.好氧条件向厌氧条件的转换可通过改变沉积物内部pH值分布和微生物活动促使rest-P释放:厌氧条件下,厌氧微生物不仅可以消耗硫酸根产生H_2S,导致pH值降低,还可消耗有机质,将有机磷转变为无机磷.上述研究结果表明,沉积物—水界面氧化还原环境可影响沉积物氧渗透深度、pH值分布、微生物活动、硫循环以及有机质降解过程,进而控制沉积物磷的形态转化与释放.联合应用微电极技术和沉积物磷形态分析对湖泊沉积物—水界面开展微尺度观测研究是揭示沉积物内源磷释放机制与控制因素的有效途径.     

动、静水条件下苦草(Vallisneria natans L.)对沉积物磷释放的影响

在浅水湖泊中,沉降在沉积物中的营养盐易受到水流的扰动再释放出来,而沉水植物可以在一定程度减少营养盐的释放.借助自主开发的生态水槽,在40 d的实验周期内检测动、静水条件下有、无苦草(Vallisneria natans L.)时沉积物、上覆水中磷含量变化,旨在为沉水植物对湖泊沉积物营养盐释放量的影响估算及水环境质量评价提供科学依据.结果表明:动水条件下,沉积物在没有苦草的保护下总磷含量下降21.8%,而有苦草的保护下总磷含量下降17.7%.苦草根系从周围沉积物中吸收磷,1~4 cm沉积物层的吸收量高于4~8 cm沉积物层.动水槽的上覆水中总溶解态磷浓度和总颗粒态磷浓度均大量增加,并且总颗粒态磷浓度相对于总溶解态磷浓度占较大比例.苦草减少了沉积物中磷的释放,并对上覆水中正磷酸盐有明显的吸收作用.     

Economic valuation of suspended sediment and phosphorus filtration services by four different wetland types: A preliminary assessment for southern Ontario,Canada

Wetlands are known for their water filtration (or purification) function. Although different wetland types differ in their filtration capacity, they are usually aggregated together in economic valuation studies. Here, we explicitly separate the valuation of the suspended sediment and phosphorus (P) filtration services of the four major wetland types—bogs, fens, marshes and swamps—found in southern Ontario, Canada. The areal extents of the four wetland types are derived from the Canadian Wetland Inventory (CWI) progress map, while the sediment accretion rate is used as the key variable regulating the suspended sediment and P filtration functions. Based on available literature data, we assess the relationship of the sediment accretion rate to wetland size. Because only weak positive correlations are found, we assign a mean (average) sediment accretion rate to each wetland type. The sediment accretion rates are combined with mean soil P concentrations to estimate Pretention rates by the wetlands. The replacement cost method is then applied to valuate the sediment and P filtration services. The unit values for both sediment and P retention decrease in the order: marshes > bogs ≈ swamps > fens. The total value of sediment plus phosphorus removal by all wetlands in southern Ontario amounts to $4.2 ± 2.9 billion per year, of which about 80% is accounted for by swamps. We further assess the costs of different options to offset the additional P loading generated in a hypothetical scenario whereby all wetlands are converted to agriculture. The results demonstrate that replacing the P filtration function of existing wetlands with conventional land management and water treatment solutions is not cost-effective, hence reinforcing the importance of protecting existing wetlands.     

沉水植物生长对沉积物间隙水中的氮磷分布及界面释放的影响

采集未破坏沉积物结构的柱状沉积物样品,通过室内41 d的培养实验,研究了沉水植物生长过程对间隙水中NH_4~ -N和PO_4~(3-)-P的浓度的动态影响,分析了沉水植物生物量与沉积物中氮磷释放通量的对应关系．结果表明：随沉水植物生长和生物量增加,上部0-5 cm沉积物垂向各层间隙水中NH_4~ -N含量呈逐步降低,表现出沉积物-水界面氮的释放通量与沉水植物生物量存在负相关性;而间隙水PO_4~(3 )-P含量则随沉水植物生长呈单峰型变化,磷释放通量与生物量相关性不明显．初步反映沉水植物在沉积物的生长过程中对氮磷吸收的生物地球化学机制是不同的．     

Relationship between texture and fractions of inorganic phosphorus in the surface sediment of a reservoir

Inorganic P was fractionated into three categories (NaOH-, BD- and HCI-extractable) for 30 surface sediment samples in La Minilla Reservoir (Sevilla, Spain). The amount of reactive P extracted with NaOH (NaOH-RP) and with HCI (HCI-RP) correlated in a multivariate regression with the clay and sand content of the sediment. This multivariate function should aid in predicting the amount of phosphorus available to the sediment organisms, and it can also contribute to the knowledge of the phosphorus budget of the reservoir.Supported by a Grant from CSIC-CONICET.     

Hydrodynamics of floodplain wetlands in a chalk catchment: The River Lambourn, UK

Variations in floodplain channel water levels and valley floor groundwater levels (measured in piezometers and boreholes) are examined at selected points along the course of the River Lambourn, a chalk river in southern England. A local alluvial gravel aquifer in the valley bottom is associated with numerous small wetlands that extend over much of the river's perennial profile. Variations in hydraulic gradient between local borehole levels and/or floodplain channel water levels are described for three sites in the seasonal section of the channel at Bockhampton, East Garston and West Shefford. The results indicate that observed groundwater levels are closely associated with flows from discrete springs at the margins of the channel and floodplain. However, as the floodplain widens and the alluvial gravel aquifer increases in size, the gravel aquifer accounts for a substantial down-valley component of groundwater flow with a diffuse vertical water flux. In the lower catchment, the exchange of flows between the gravel aquifer and the river enables some attenuation of floodplain water-table variability, providing a stable hydrological regime for valley-bottom wetlands. Catchment controls upon the local, valley-bottom, wetland regime are demonstrated with the application of a simple groundwater model developed using MODFLOW. The model is used to simulate groundwater discharge to the river in the upper and lower catchment, in addition to the water level regime at selected points in the valley bottom in the lower catchment. The results demonstrate the importance of taking catchment-scale water flow into account when managing isolated wetlands in a permeable catchment.     

南四湖消落带底泥有机磷赋存形态及分布特征

研究南四湖消落带底泥有机磷赋存形态及分布特征,有利于全面揭示湖区各形态磷迁移转化规律,对南四湖富营养化防控及南水北调东线调水水质保障具有重要的科学意义。以南四湖消落带底泥为研究对象,采用改进Hedley连续分级提取法测定底泥中各形态有机磷含量,通过紫外可见分光光谱与三维荧光光谱技术表征底泥有机分子结构特征及稳定性,反映消落带有机磷结构及稳定性差异,运用Pearson相关性分析及主成分分析解析底泥各形态磷与其他理化指标的相关性。研究结果表明,南四湖消落带底泥总磷含量均值为679.90 mg/kg,其中有机磷(OP)占比20.03%~45.69%。各赋存形态有机磷含量及相对比例大小依次为:残渣态有机磷(67.58%)＞钙结合态有机磷(16.61%)＞铁/铝结合态有机磷(7.62%)＞碳酸氢钠提取态有机磷(5.97%)＞水提取态有机磷(2.22%)。南四湖消落带底泥OP含量及形态主要受内源影响,主要来自内源性微生物代谢。南四湖消落带西岸底泥磷释放风险高于东岸和南岸消落带。相关性分析发现,消落带底泥pH与磷含量显著负相关,表明随着底泥碱性的增强可能导致底泥磷向水体中释放的风险更高;底泥有机质与OP显著正相关,表明有机质可能是OP的重要载体;主成分分析发现底泥各形态磷呈正相关性,表明消落带底泥各形态磷具有同源性。研究结果可为南四湖湖区内源磷释放控制及富营养化风险防控提供科学依据。     

Experimental study on phosphorus release from sediments of shallow lake in wave flume

Influence of wave on sediment resuspension and nutrients release from sediments, collected from Lake Taihu and Lake Chaohu, was studied in flume experiments. Under strong-wave conditions, concentrations of suspended solids (SS), total phosphorus (TP) and dissolved total phosphorus (DTP) in overlying water were increased significantly following the sediments re-suspension. During the experiments on sediments of Lake Taihu and Lake Chaohu, TP concentrations increased 6 times and 3 times, and DTP concentration increased 100% and 70% more than it in presuspension, respectively. Concentration of soluble reactive phosphorus (SRP) of experiment on sediment of Lake Taihu increased 25%. During the massive sediment suspension, the dissolved phosphorus in pore water and much of the phosphorus adsorbed by the sediment particles were released into overlying water. The phenomena in this wave flume experiment are quite similar to the situation observed in situ of Lake Taihu. The critical wave stresses of sediment re-suspension are nearly equal. The change of concentrations of SS, TP, and SRP was the same as that in situ situation. This study showed that concentrations of TP and SRP in lake water could be increased significantly by wave disturbance. Phosphorus release was significantly enhanced by wave disturbance at the beginning of massive sediment re-suspension, but decreased later.     

贵州草海湿地不同水位梯度沉积物中汞、砷形态分布及风险评价

通过改进Tessier连续提取法对贵州草海黑颈鹤栖息地不同水位梯度下沉积物汞(Hg)、砷(As)形态及生态风险进行了研究.结果表明,草海湿地沉积物中Hg含量在0.45～1.51-mg/kg之间,超过国家土壤环境质量农用地土壤风险管控标准;形态组成上,残渣态汞(Res-Hg)>有机结合态汞(Org-Hg)>碳酸盐结合态(Car-Hg)>铁锰氧化态(Fe-O-Hg)>可交换态(Ex-Hg),不同水位梯度下含量和赋存形态在不同区域不一致.As含量在16.4～23.8-mg/kg之间,形态依次为残渣态砷(Res-As)>有机结合态砷(Org-As)>铁锰氧化态砷(Fe-O-As)>碳酸盐结合态砷(Car-As)>可交换态砷(Ex-As).-As含量与贵州省土壤背景值持平,随着水位梯度的抬升,其总量呈增加趋势,残渣态占比逐步增多,性质逐渐稳定.采用地积累指数(I_geo)、潜在生态风险指数(E_rⁱ)、风险评价编码法(RAC)对Hg、As的危害程度进行分析表明,基于草海较高Hg环境背景值...     

Major element chemistry of sediments from the Darling–Barwon river and its tributaries: implications for sediment and phosphorus sources

In 1991, one of Australia's longest rivers, the Darling–Barwon, experienced one of the world's largest recorded algal blooms. Nearly 1000 km of river were affected. At the time of the bloom phosphorus originating from anthropogenic sources was believed to be the principal cause. In this study we have used major element chemistry to examine the sources of sediment and sediment‐associated phosphorus delivered to the Darling–Barwon River. We show that the sediments are derived primarily from the sedimentary and granitic bedrock areas of the catchment, not the intensively farmed basalt areas. We also show that the sediment currently in transport in the Darling–Barwon does not originate from contemporary upland erosion, but is probably derived from lowland areas of the catchment that contain more weathered material. Phosphorus concentrations in the sediments are consistent with those in natural soils of the region, and evidence from two sediment cores indicates that phosphorus concentrations have not changed significantly in the last 200 years. The implications of these findings for algal growth control strategies are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

Estimation on dynamic release of phosphorus from wind-induced suspended particulate matter in Lake Taihu

The internal source, especially resuspension process of the sediments in lakes and its environ- mental effect has been paid shining attention in the West as well as in China[1—6] although the influence of external source is important to water environment[7]. S鴑dergaard et al. compared the releases of soluble reactive phosphorus (SRP) in the surface sediments of Lake Arres before and after disturbance and they found that disturbing can increase the release by 20—30 times[3]. Robarts and ot…     

Influence of external loading and halocline on phosphorus release from sediment in an artificial tidal lake

Many of the dams built in estuaries in the last century have difficulty with water quality management.Numerous factors have affected the estuary lake water,most importantly external loadings,tidal currents,and increases in the phosphorus(P) release from sediment,so that most water quality characteristics in the estuary are highly interactive and dynamic.In the current study,water quality measurements were made in the laboratory and field,and a series of phosphorus release experiments was done to understand the behavior of P in an estuary lake.The concentrations of chemical oxygen demand(COD),chlorophyll-a(Chl-a),and total P(TP) showed an increasing trend when the pollutant loading of the influent stream water was high.The measurements showed increasing trends,which indicates the constituents are produced in the internal environment of the lake.When a large amount of freshwater flowed in from the upper watershed,density stratification was observed,which forms strongly because of the salinity of seawater.During the period of stratification,a hypoxic layer formed,which can accelerate P release.Comparing the open and dosed conditions of the release experiments,the P release rate was much higher under the closed condition than under the open condition.The maximum P release rates from the sediment collected from the five main sites of the lake were more than 2.5 times the P loading from the inflowing streams in April.Spatially,the release rate was higher mid-reservoir than down-reservoir where a halocline was evident The pollutant load discharged from the tributary watershed was deposited on the bottom mid-reservoir,whereas it was washed out downreservoir because of the density stratification and strong tide in that area.To sustainably manage water quality and decrease lake eutrophication in brackish environments formed by freshwater from streams mixing with seawater entering through sluice dikes,different measures than those applied in strictly freshwater environments are required.Considering the spatial characteristics of an estuary lake,these measures include 1) blocking settleable particles discharged from the rivers upstream,2) controlling hypoxia to avoid P release from the sediment and inhibiting algae growth mid-reservoir,and 3)decreasing stratification caused by the halocline down-reservoir.     

The effects of eight years aeration and isolation from polluting discharges on sewage‐ and metal‐contaminated sediments

The Manchester Ship Canal (MSC) has been the recipient of domestic and trade effluent since 1895, it continues to be grossly polluted. In 1985 the dock basins, now known as Salford Quays were isolated from the canal inorder to improve water quality and encourage redevelopment. Subsequent to isolation the dock basins received no effluent or drainage and Helixor pumps were installed to improve circulation, thereby preventing stratification and bottom water anoxia. Analysis of solid material, pore waters and phospholipid fatty acids (PLFA) in cores taken from Salford Quays and the MSC was carried out to assess changes in sediment characteristics that might affect water quality. Loss of carbon was apparent in the upper sediment of Salford Quays, as was a greater proportion of reducible Fe, Mn, Zn and Cd compared with the MSC. In Salford Quays a superficial peak in Fe and Zn concentration appeared to be attributable to migration of metals in the pore water and precipitation of Fe oxyhydroxide at the oxic sediment water interface. Despite these differences, NHSOconcentration pore water profiles were similar in both sediments if the MSC sediments were considered from a point below their top layers, which appeared to be composed of freshly deposited sewage. Bacterial biomass extrapolated from PLFA concentration also suggested that the upper sediment of the MSC was largely faecal. PLFA analyses to characterize changes in the microbial community, however, did not reveal any systematic changes. That this may have been because of an absence of vertical zonation was supported by pore water analyses. It was also apparent that the lack of systematic change might be due at least in part to an artefact of vestigial PLFA signatures, resulting from deposition and burial, and the need for finer vertical resolution in the sampling procedure. Despite incomplete and some contradictory findings it appears that although metal mobilization may result from the development of an oxic sediment water interface, the extremely high original organic content of the sediment ensures that even after 10 years it exerts a high oxygen demand. Consequently, sediment management is likely to be a long‐term commitment and as remediation proceeds the importance of continuity in management will increase. Copyright © 1999 John Wiley & Sons, Ltd.     

三峡水库出水断面磷通量及形态研究(1998-2019年)

总磷是长江流域备受关注的污染物。来自长江上游的物质输送对长江中下游、对入海口水域水生态都具有重要影响。研究了1998—2019时期长江上游和中下游之间的衔接断面暨三峡水库出水断面的磷通量及形态变化。整个研究时段分为3个阶段:1998—2002(阶段Ⅰ,三峡水库运行之前),2003—2013(阶段Ⅱ,作为过渡时期)及2014—2019(阶段Ⅲ,三峡水库实现175m正常蓄水位且金沙江下游段向家坝和溪洛渡水库运行后),以阶段Ⅰ、Ⅲ为重点时段进行对比分析。研究表明,2014—2019年总磷年通量平均为5.67万t/a,比1998—2002年减少了38.0%;溶解态磷年通量为4.02万t/a,增加了60.0%;颗粒态磷年通量为1.67万t/a,减少了74.9%。磷的主导形态由颗粒态变为溶解态,溶解态磷通量占比由27.5%上升为70.9%;相应地,颗粒态磷通量占比由72.5%下降为29.1%。总磷、溶解态磷和颗粒态磷通量均表现为丰水期>平水期>枯水期。近20年来,水沙关系发生了巨大变化,含沙量(SS)与水量(Q)正相关性大幅下降,其拟合方程的斜率由1.44下降为0.10,R^2...     

云南阳宗海表层沉积物有机质组成结构对磷赋存形态特征的影响

利用连续提取分级的方法定量分析阳宗海表层沉积物磷赋存形态,阐明了沉积物C、N、H和O组成及溶解有机质(DOM)紫外-可见光谱特征,探讨沉积物元素组成及DOM组成结构对不同形态磷含量的影响.结果表明:(1)沉积物潜在可移动磷含量在68.67~124.70 mg/kg之间变化,平均占总磷含量的9.81%,表现为BD-PNa OH-nr PNH_4Cl-P;沉积物稳定磷含量在496.73~908.28 mg/kg之间变化,平均占总磷含量的60.86%.(2)沉积物C、N含量和疏水性DOM光谱参数A_(240-400)表现出北部高、南部低的变化趋势,但H/C、O/C和(N+O)/C摩尔比和亲水性DOM光谱参数A_(240-400)变化趋势则与之恰好相反.(3)沉积物NH4Cl-P含量与C、N和H含量之间呈显著正相关,但与H/C、O/C、(N+O)/C摩尔比和亲水性DOM光谱参数E_2/E_3值之间呈显著负相关;NaOH-rP和BD-P+NaOH-rP含量均与O含量及O/H摩尔比呈显著负相关;NaOH-rP、BD-P+NaOH-rP和HCl-P均与疏水性DOM光谱参数A_(240-400)值之间呈显著正相关.因此,天然有机质元素组成及官能团结构是影响沉积物磷赋存形态的重要因素.