Biosorption of rhenium from industrial effluents by a new strain of Bacillus sp. GT-83: New biosorbent for biotechnology applications

Bioremediation of industrial effluents containing heavy metals has been demonstrated in recent years. In contrast to other metals, the recover of oxyanions particularly rhenium via biosorption by microorganisms has not been investigated yet and there is n…     

Nettle ash as a low cost adsorbent for the removal of nickel and cadmium from wastewater

This study was focused on nettle ash as an alternative adsorbent for the removal of nickel (II) and cadmium (II) from wastewater. Batch experiments were conducted to determine the factors affecting adsorption of nickel (II) and cadmium (II). The adsorption process is affected by various parameters such as contact time, solution pH and adsorbent dose. The optimum pH required for maximum adsorption was found to be 6. The experimental data were tested using Langmuir, Freundlich and Tempkin equations. The data were fitted well to the Langmuir isotherm with monolayer adsorption capacity of 192.3 and 142.8 mg/g for nickel and cadmium, respectively. The adsorption kinetics were best described by the pseudo second order model. The cost of removal is expected to be quite low, as the adsorbent is cheap and easily available in large quantities. The present study showed that nettle ash was capable of removing nickel and cadmium ions from aqueous solution.     

Two-stage reverse flotation process for removal of carbonates and silicates from phosphate ore using anionic and cationic collectors

Phosphate rock contains various gangue minerals including silicates and carbonates which need to be reduced in content in order to meet the requirements of the phosphate industry. Froth flotation has become an integral part of phosphate concentration process. In this study, double reverse flotation was applied to recover apatite from phosphate ore. H₃PO₄ and CaO were used as phosphate depressants, in acidic and alkaline conditions. Fatty acids and amines were added as carbonate and silicate collectors respectively. An experimental protocol devised to optimize the grade and recovery of phosphate using anionic–cationic method was found effective. Consequently, a required high quality of phosphate concentrate containing 30.1% P₂O₅ was obtained, with a recovery of 94%. X-ray diffraction and optical microscopy studies were performed to define the main minerals.     

TG/plus—a pyrolysis method for following maturation of oil and gas generation zones using Tmax of methane

Thermogravimetric Fourier transform infrared spectroscopy (TG-FTIR) analyses were carried out on two sets of isolated kerogens covering a wide maturity range from low mature (0.46% R_o) through the end of oil and gas generation (maximum R_{o = 5.32%}). Data onweight percent and T_max for evolution of methane, volatile tars, ethylene, SO₂, NH₃, CO₂, and CO are reported. The T_max of methane shows the most consistent response to increasing maturation in both sets of samples. Results are comparable to those of whole rocks from an Alaskan North Slope well analyzed previously. The collective data for both whole rocks and isolated kerogens shows a generally linear correlation between %R_o and T_max of methane, with the exception of R_o of about 2.0% where a dip in the curve occurs. The slope of the correlation line was steeper for the predominantly terrigenous Wilcox kerogen than for more marine Colorado kerogen or for the Alaskan North Slope whole rock samples, probably reflecting differences in the chemical nature of various kerogen sets, which is also reflected by differences in the shapes of the pyrolysis curves of SO₂, CO₂, CO, H₂O, and ethylene. These preliminary data indicate that T_max of methane is a good maturation indicator for whole rocks and isolated kerogens up to an R_o of about 4%, which includes all of the wet gas and a considerable portion of the dry gas generation zones. This correlation was also observed for samples containing migrated bitumen, where it was not possible to obtain a reliable T_max for the volatile tar (S2) peak. The more terrigenous Wilcox kerogens also showed a good correlation of the T_max of ethylene with %R_o. T_max of ammonia evolution did not correlate with maturity and occurred 100–200°C lower than previously found for whole rocks, consistent with a whole-rock source of pyrolytic ammonia for Alaskan whole rock samples. HI and OI indices were calculated in several ways and plotted to reflect kerogen type as well as both the residual oil and gas generation potential. The ratio of pyrolyzable to combustible sulfur (evolved as SO₂) was independent of maturity and showed a clear difference between the more terrigenous Wilcox kerogens and the more marine Colorado kerogens.     

Experimental study of the stability of sudoite and magnesiocarpholite and calculation of a new petrogenetic grid for the system FeO–MgO–Al2O3–SiO2–H2O

The solid-solid reaction magnesiocarpholite = sudoite + quartz has been bracketed between 350 and 500°C, 6.3 and 7.8 kbar. Because it is impossible to synthesize end-member sudoite, all experiments were carried out using natural minerals as starting materials. Although mineral compositions were very close to those of the end-members, the effect of the fluorine content in carpholite was significant. Particularly in those experiments where sudoite grows at the expense of carpholite, electron microprobe analysis of the run products shows that a more stable F-rich carpholite crystallizes too, and consumes the fluorine released in solution by the breakdown of the original carpholite.
Our experimental results are combined, through a thermodynamic analysis, with a previous data set and with previous experimental data concerning the relative stability of chlorite, talc and magnesiocarpholite with excess of quartz and water as a function of P–T and AlAl(SiMg)_-1 substitutions in phyllosilicates. This allows us to constrain the feasible thermodynamic parameters (H°_f, sud; S ° sud) and (H°_f,car; S °_car) for the Mg end-members. Using the partition coefficients calculated from natural parageneses, we have computed a petrogenetic grid for the system FeO–MgO–Al₂O₃–SiO₂–H₂O. It demonstrates that parageneses involving sudoite and carpholite can be used as indicators of P–T conditions, up to 600° C, 8 kbar for sudoite, and at higher pressure for carpholite.     

Sediment yield and soil erosion assessment by using empirical models for Shazand watershed,a semi-arid area in center of Iran

Natural Hazards - In Kuwait, the transport sector is facing a daily traffic congestion pandemic. The traffic congestion is significantly influencing the economy and obstructing the development and...     

A new method for identification of protocatagenesis, mesocatagenesis, and apocatagenesis zones in a terrigenous sedimentary cover by applying layer seismic velocities

This method pertains to oil and gas geology and to geology of sedimentary basins prospective for oil and gas. It includes identifying catagenesis zones in drilled areas within the sedimentary cover of the basin based on assay results for drill cores and cuttings using the standard methods. Analysis is primarily made in order to determine rock catagenesis based on the optical characteristics of vitrinite. A correlation between catagenesis zones and layer seismic velocities obtained from regional and exploration seismic data is made for a drilled area. Both the layer seismic velocities and the degree of rock catagenesis increase with depth under the influence of increasing rock density. Correlations between layer velocities and the degree of rock catagenesis have been established. The following ratios have been determined for the Scotian shelf, Canada, and the Barents shelf, Russia: a protocatagenesis zone (the cap) corresponds to layer seismic velocities (V _lay) of 1.5–3.3 km/s, a mesocatagenesis zone (the principal hydrocarbon generation area) corresponds to V _lay of 3.3–5.0 km/s, and an apocatagenesis zone (an area with a very low hydrocarbon potential) corresponds to V _lay of over 5.0 km/s. An advantage of the new method of identification of catagenesis zones is that it can be used prior to drilling. Its conceptual originality and cost efficiency lie precisely in this.     

Determination of earthquake-risky areas in Yalova City Center (Marmara region,Turkey) using GIS-based multicriteria decision-making techniques (analytical hierarchy process and technique for order preference by similarity to ideal solution)

Disaster mitigation as a pre-disaster measure within the scope of disaster risk management is significant in the sense of reducing the adverse effects of earthquakes in the context of earthquake-sensitive risk planning. In the urban planning context, the existence of numerous decision makers and alternatives, which are depending on many criteria, makes decision-making process difficult. This difficulty was overcomed through geographical information systems (GIS). In the context of GIS-based multicriteria decision-making (MCDM) analysis, we used analytic hierarchy process (AHP) and technique for order preference by similarity to ideal solution (TOPSIS) to determine earthquake-risky areas in Yalova City Center. First, AHP analysis related to geological and superstructure/infrastructure criteria was conducted and two separate AHP maps were obtained. Then, we conducted TOPSIS analysis to consider both criteria in the sense of earthquake risk-sensitive planning. Then, overall earthquake risk map obtained which could be used as an input for disaster mitigation processes.

     

A virtual voyage through 3D structures generated by chaotic mixing of magmas and numerical simulations: a new approach for understanding spatial and temporal complexity of magma dynamics

In this contribution, we present a virtual voyage through 3D structures generated by chaotic mixing of magmas and numerical simulations with the aim to highlight the power of 3D representations in the understanding of this geological phenomenon. In particular, samples of mixed juveniles from Salina island (Southern Italy) are reconstructed in 3D by serial lapping and digital montage and numerical simulations are performed by using a 3D chaotic dynamical system. Natural and simulated magma mixing structures are visualized by using several multimedia tools including animations and “virtual reality” models. It is shown that magma interaction processes can generate large spatial and temporal compositional heterogeneities in magmatic systems. The same topological structures are observed in both 3D reconstructed rock samples and chaotic numerical simulations, indicating that the mixing of magmas is governed by chaotic dynamics. The use of 3D multimedia models gives the opportunity to penetrate into magma mixing structures and to understand their significance in the context of magma dynamics. Such an approach is very powerful since multimedia tools can strongly capture the attention of the reader bringing him/her into an interactive and memorable geological experience. Electronic supplementary material  enclosed:     

Rare earth elements in three fluorites: graphical comparison of data and model Comment to “Mathematical analysis of rare earth element patterns of fluorites from the Ehrenfriedersdorf tin deposit, Germany: evidence for a hydrothermal mixing process of lanthanides from two different sources” by T. Monecke et al.

Summary A graphical method is proposed for comparing the data reported by Monecke et al. (2000) with their mathematical model. Received August 9, 2001; accepted October 25, 2001     

Numerical well model for non-Darcy flow through isotropic porous media[*]This work was supported in part by the EPA under grant # R 825207-01-1, by the State of Texas under ARP/ATP grant # 010366-168 and by a gift grant from Mobil Oil Corp.

Numerical simulation of fluid flow in a hydrocarbon reservoir has to account for the presence of wells. The pressure of a grid cell containing a well is different from the average pressure in that cell and different from the bottom-hole pressure for the well [17]. This paper presents a study of grid pressures obtained from the simulation of single phase flow through an isotropic porous medium using different numerical methods. Well equations are proposed for Darcy flow with Galerkin finite elements and mixed finite elements. Furthermore, high velocity (non-Darcy) flow well equations are developed for cell-centered finite difference, Galerkin finite element and mixed finite element techniques.