Characteristics and Health Risk Assessment of Potentially Toxic Metals in Urban Topsoil in Shenyang City,Northeast China

Soil samples are collected from 74 sites in Shenyang city, northeast China, and the concentrations, spatial distribution, enrichment factors (EF), and potential ecological and human health risk (E_r) of potentially toxic metals (Sr, Zn, Cr, Pb, Cu, Ni, and As) are investigated. The mean concentrations of potentially toxic metals in topsoil follow the order Sr > Zn > Cr > Pb > Cu > Ni > As. Compared with 2011, the contamination magnitude has improved in 2017, but the pollution status still exists, especially for As and Cr. EF and the mean E_r of potentially toxic metals decrease following the order As > Pb > Cu > Ni > Zn > Cr > Sr and As > Cu > Zn > Pb > Sr > Ni > Cr, suggesting that the potentially toxic metals in the topsoil of Shenyang city mainly come from natural sources, and the potential ecological risk for potentially toxic metals is low. There are potentially non‐carcinogenic and carcinogenic health risks, but they are not considered significant. For non‐carcinogenic health risks, oral ingestion is the main exposure pathway, and Cr and Pb are the major pollutants. Finally, As is found to be the main carcinogenic contamination metal.     

Assessment of heavy metal contamination in the surficial sediments from the lower Meghna River estuary,Noakhali coast,Bangladesh

Sediment samples were collected from ten selected sites of the lower Meghna River estuary,and six heavy metals were analyzed with Atomic Absorption Spectrophotometry(AAS)to assess the contamination level and the metals’association with sediment grain size.The current results revealed that the mean concentrations of the studied metals were ranked in descending order of iron(Fe)(1.29×103 mg/kg)>zinc(Zn)(42.41 mg/kg)>lead(Pb)(12.48 mg/kg)>chromium(Cr)(10.59 mg/kg)>copper(Cu)(6.22 mg/kg)>cadmium(Cd)(0.28 mg/kg).The geo-accumulation,contamination,and pollution load indexes suggested that the lower Meghna river estuary was not contaminated by Fe,Zn,Pb,Cr,and Cu.The mean size of the sediment ranged from 28.92 to 126.2 mm,and the Pearson correlation coefficient showed a significant association between Fe and Pb(coefficient of determination,r2=0.836;p<0.05),and no significant correlation was found between individual metals and grain size,indicating no or low influence on the metals distribution.     

Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Does heavy oil pollution induce bacterial diseases in Japanese flounder Paralichthys olivaceus?

As basic research for the effect of heavy oil on the fish immune system, in this study, the number of leukocyte was counted in Japanese flounder Paralichthys olivaceus, after exposure to heavy oil at a concentration of 30 g/8 L for 3 days. To compare the numbers of bacteria in the skin mucus between oil-exposed and control fish, viable bacteria were enumerated by counting colony forming unit (CFU). Compared with 5.79 ± 1.88 × 10⁷ leukocytes/mL in the controls, the exposed fish demonstrated higher counts, averaging 1.45 ± 0.45 × 10⁸ cells/mL. The bacterial numbers of control fish were 4.27 ± 3.68 × 10⁴ CFU/g, whereas they were 4.58 ± 1.63 × 10⁵ CFU/g in the exposed fish. The results suggest that immune suppression of the fish occurred due to heavy oil stressor, and bacteria could invade in the mucus, resulting in the increasing leukocyte number to prevent infectious disease.     

New marine ΔR values for Arctic Canada

For more than four decades, the reporting of ¹⁴C dates on marine molluscs from Arctic Canada has been notable for the lack of consistently applied marine reservoir corrections. We propose that the common approach of reporting Canadian Arctic marine ¹⁴C dates using presumed time-invariant reservoir corrections be abandoned in favour of calibration of ¹⁴C dates, using the current standard protocol. This approach best facilitates inter- and intra-regional correlation, and correlation with other geochronometers. In order to enable the consistent calibration of marine ¹⁴C dates from Arctic Canada, we analysed a ¹⁴C database of 108 marine mollusc samples collected live between 1894 and 1956, and determined regional reservoir offset values (ΔR) for eight oceanographically distinct regions. The following new ΔR values should be used for ¹⁴C calibration: NW Canadian Arctic Archipelago, 335 ± 85 yrs; Foxe Basin, 310 ± 90 yrs; NE Baffin Island, 220 ± 20 yrs; SE Baffin Island, 150 ± 60 yrs; Hudson Strait, 65 ± 60 yrs; Ungava Bay, 145 ± 95 yrs; Hudson Bay, 110 ± 65 yrs; and James Bay, 365 ± 115 yrs.     

230Th/U chronology of a paleolithic site at Xinglong Cave in the three-Gorge region of south China

Xinglong Cave, containing four human teeth, numerous mammalian fossils, stone artifacts and a Stegodon tusk with intentional and seemingly grouped engravings, is one of the most significant archaic Homo sapiens sites in south China, located 95 km south of Fengjie County, in Chongqing. In an attempt to constrain the age of the human relics, calcitic flowstone deposits with a significant detrital component were dated by U–Th methods using a leachate scheme. Total sample digestion MC-ICPMS dating was used to assess the reliability of the leachate technique. Six calcite samples from horizons beneath and above the fossil-bearing layer were dated. We obtained ages of 130 ± 9.1, 124 ± 11, 135 ± 12 and 127 ± 11 ka for the flowstones above the fossil layer with a weighted mean of 128.9 ± 5.2 ka. Two flowstone samples gave MC-ICPMS dates between 128.3 ± 3.3 and 152.4 ± 25.3 ka with an assumed detrital component to correct for the initial ²³⁰Th, which are consistent with results obtained using the L/L regression data from layer U-4 within uncertainty. All errors herein quoted at the 2σ level. Ages determined for the flowstone underlying the fossil-bearing layer were 221 ± 29 to 189 ± 19 ka with a weighted mean age of 199 ± 16 ka. These results are stratigraphically consistent within error limits and show that the cave was occupied by Fengjie Man within the time range of ∼200 to ∼130 ka. These new U-series ages of flowstones in association with human teeth and an engraved stegodon tusk at the Xinglong Cave site provide valuable geochronologic information for the study of the origin of modern humans in East Asia and earliest human art.     

Imposex levels and concentrations of organotin compounds (TBT and its metabolites) in Nassarius nitidus from the Lagoon of Venice

Specimens of Nassarius nitidus were collected in seven stations of the Venice Lagoon to assess the levels of tributyltin (TBT) and its metabolites monobutyltin and dibutyltin in the tissues and monitor their effect on organisms, in particular the phenomenon of imposex (superimposition of male sexual characteristics on females). The following values of population indices were found: vas deferens sequence: 1.2 ± 0.7–4.0 ± 0.5; relative penis length: 6–47%. The least impacted station was situated in the northern part of the Lagoon, where females without imposex were found and Butyltin (BuTs) concentrations in the organisms (average sum of BuTs = 43 ± 14 ng Sn g⁻¹ w.) were significantly lower than in the other stations (range of average sum of BuTs: 101 ± 22–217 ± 27 ng Sn g⁻¹ d.w.). Population indices were found to be related to the TBT content in the tissues. In particular VDSI had a significant logarithmic correlation: r = 0.95, n = 8, p < 0.05.     

Coupled ESR and U-series dating of early Pleistocene Gigantopithecus faunas at Mohui and Sanhe Caves,Guangxi, southern China

Several caves of the Guangxi Zhuang Autonomous Region, southern China, have delivered Gigantopithecus blacki remains, an extinct Pleistocene giant ape, in association with abundant mammalian faunas. To determine their geological ages, fossil teeth from Mohui and Sanhe Caves were dated using the coupled ESR/U-series method. The teeth from Mohui Cave gave age estimates of 1.69 ± 0.22 Ma and 1.29 ± 0.11 Ma. The Sanhe Cave samples had age estimates ranging from 910 ± 200 ka to 600 ± 150 ka with error weighted mean ages of 890 ± 130 ka and 720 ± 90 ka for the layers 5 and 4, respectively. Our results and previous paleomagnestism data place the Gigantopithecus fauna at Mohui Cave between Olduvai and Jaramillo subchrons and suggest that it was coeval with Chuifeng, Longgupo and Liucheng assemblages. The Sanhe fauna is younger, of late early Pleistocene age, and can be dated to the period between Jaramillo subchron and B/M boundary.     

Comparative assessment of water treatment using polymeric and inorganic coagulants

Portable water plays a vital role in improving human life, particularly in controlling the spread of diseases. However, problems associated with lack of potable water are still common especially in developing countries including Malawi. Until now little information exists on the effectiveness of available commercial coagulants used by national water boards in Malawi. Therefore, this study was undertaken in Southern Region Water Board (SRWB) to investigate the efficiency of polymeric coagulants (sufdfloc 3850 and algaefloc 19s) in turbidity reduction comparative with inorganic coagulant (aluminium sulphate) at Zomba, Liwonde, Mangochi, Chikwawa and Mulanje Treatment plants. The jar test method was used to determine the effectiveness of the water coagulants. The results revealed that sudfloc 3850 was most effective in reducing turbidity at Mangochi (99.4 ± 0.06%) and Liwonde (97.2 ± 0.04%) using 0.4 mg L⁻¹ flocculant dose. The Zomba, Mulanje and Chikwawa plants gave 19.56 ± 0.03%, 29.23 ± 0.02% and 9.43 ± 0.02% total reductions respectively. Algaefloc 19s afforded the highest turbidity reduction at Liwonde and Mangochi plants (98.66 ± 0.06 and 97.48 ± 0.05% at a dose of 0.4 and 0.6 mg L⁻¹ respectively), while Chikwawa provided the lowest (9.52 ± 0.01%). At the Zomba and Mulanje plants 20.5 ± 0.03% and 28.4 ± 0.04% reductions were obtained respectively. The inorganic flocculant, alum provided a 99.0 ± 0.05% and 98.6 ± 0.04% reduction at a dose of 4.0 mg L⁻¹ and 6.0 mg L⁻¹ at Zomba and Liwonde plants respectively. The lowest reductions in turbidity were achieved at Chikwawa (7.50 ± 0.01%), Mangochi (12.97 ± 0.02%) and Mulanje (25.00 ± 0.02). The best and optimum pH ranges for polymeric and inorganic coagulants were 7.20–7.80 and 7.35 to 7.57 respectively. The results further revealed that sudfloc 3850 and algaefloc 19s achieved faster formation of heavy flocs than alum. At 0.4 mg L⁻¹ flocculant dosage sudfloc 3850 and algaefloc 19s required ten times lower dosages than alum. Therefore, the polymeric coagulants could be used instead of alum, the choice dependant on the type of water.     

A new Scandinavian reference 10Be production rate

An important constraint on the reliability of cosmogenic nuclide exposure dating is the rigorous determination of production rates. We present a new dataset for ¹⁰Be production rate calibration from Mount Billingen, southern Sweden, the site of the final drainage of the Baltic Ice Lake, an event dated to 11,620 ± 100 cal yr BP. Five samples of flood-scoured bedrock surfaces (58.5°N, 13.7°E, 105–120 m a.s.l.) unambiguously connected to the drainage event yield a reference ¹⁰Be production rate of 4.19 ± 0.20 atoms g⁻¹ yr⁻¹ for the CRONUS-Earth online calculator Lm scaling and 4.02 ± 0.18 atoms g⁻¹ yr⁻¹ for the nuclide specific LSD_n scaling. We also recalibrate the reference ¹⁰Be production rates for four sites in Norway and combine three of these with the Billingen results to derive a tightly clustered Scandinavian reference ¹⁰Be production rate of 4.13 ± 0.11 atoms g⁻¹ yr⁻¹ for the CRONUS Lm scaling and 3.95 ± 0.10 atoms g⁻¹ yr⁻¹ for the LSD_n scaling scheme.     

Lavini di Marco (Trentino,Italy): 36Cl exposure dating of a polyphase rock avalanche

The Lavini di Marco rock avalanche deposit (“Marocca di Marco”) is located along the left side of the middle Adige Valley, south of the town of Rovereto (NE Italy). The deposit is estimated to have a volume of ∼2 × 10⁸ m³ and cover an area of ∼6.8 km². It comprises Jurassic Calcari Grigi limestones that detached from the western slope of Mt. Zugna Torta. The Lavini di Marco is composed of at least two different rock avalanche bodies, the main deposit known as Lavini di Marco (the principal) and the much smaller Costa Stenda deposit. Costa Stenda deposits overlie Lavini di Marco deposits. Samples for ³⁶Cl exposure dating were collected from boulders within the deposits, from sliding plane bedrock and from the bedrock wall at the head scarp. Exposure ages range from 800 ± 210 to 21310 ± 1000 years. The latter age stands as a notable outlier suggesting that that Costa Stenda boulder was exposed for a considerable amount of time in the pre-slide bedrock. Lavini di Marco and Costa Stenda boulder ages are 2600 ± 200, 2700 ± 200, 3100 ± 300, 3300 ± 300, 3400 ± 300, 4400 ± 290, 5300 ± 300, and 5400 ± 300 years. The latter three are Costa Stenda boulders which we also interpret to contain inherited nuclide concentrations. The five remaining boulder ages cluster around 3000 years. We calculate a mean age for the Lavini di Marco and Costa Stenda rockslides of 3000 ± 400 years. Within the uncertainties of our data the two slides were simultaneous. For the bedrock sliding plane we obtained significantly younger ages, 1600 ± 100 and 1400 ± 100 years, and for the head scarp 800 ± 200 years. The sliding plane ages record small-scale reactivation which seems to overlap in time with a catastrophic flood event of the Adige River in Verona, as reported in the Fulda Annales, in 883 AD. Only the single age of 800 ± 210 years suggests activity at Lavini di Marco coincident with the well-known Verona earthquake (1117 AD).     

Geodynamic implications of flattened tabular equigranular textured peridotites from the Bakony-Balaton Highland Volcanic Field (Western Hungary)

Peridotite xenoliths showing unusual tabular equigranular textures (addressed as flattened tabular equigranular) were found in Neogene alkali basalts from the Bakony-Balaton Highland Volcanic Field (Western Hungary), Carpathian-Pannonian Region. The olivines have a characteristic crystallographic preferred orientation (CPO) with [0 1 0]-axes perpendicular to the foliation and the [1 0 0]- and [0 0 1]-axes forming a continuous girdle in the foliation plane. Contrarily, the CPO pattern of orthopyroxene is much more scattered, although a single maximum can be observed in [0 0 1] axes subparallel to the plane of foliation. In case of olivine, the activation of (0 1 0)[1 0 0] and also probably (0 1 0)[0 0 1] is suggested. The deformation micro-mechanisms of orthopyroxenes are suggested to be a combination of intracrystalline glide on the (1 0 0)[0 0 1] system and some kind of other mechanism resulting in quite scattered patterns.We suggest that the unusual orientation patterns of olivines and orthopyroxenes are the result of the complex tectonic evolution of the region. The flattened tabular equigranular xenoliths represent a structural domain within the subcontinental lithospheric mantle beneath the volcanic field with particular seismic characteristics. The occurrence of flattened domains in the upper mantle may considerably influence the percolation and residence time of the mantle melts and fluids, which could promote or prevent melt/wall-rock interaction.     

Refining the Quaternary Geomagnetic Instability Time Scale (GITS): Lava flow recordings of the Blake and Post-Blake excursions

The Blake excursion was among the first recognized with directional and intensity behavior known mainly from marine sediment and Chinese loess. Age estimates for the directional shifts in sediments are poorly constrained to about 118−100 ka, i.e., at the marine isotope stage (MIS) 5e/5d boundary. Moreover, sediments at Lac du Bouchet maar, France and along the Portuguese margin reveal what may be a "post-Blake" excursion at about 105−95 ka. The excursional directions are associated with a prominent paleointensity minimum between about 125 and 95 ka in global stacked records. Lava flow recordings of the Blake excursion(s) have, however, been questionable because precise ages required for correlation with these sediment records are lacking. To establish new, independent records of the Blake excursion, and link these into a larger Quaternary GITS, we have undertaken ⁴⁰Ar/³⁹Ar incremental heating and unspiked K-Ar experiments on groundmass from the transitionally magnetized Inzolfato flow on Lipari Island. We also obtained ⁴⁰Ar/³⁹Ar incremental heating results for a lava flow on Amsterdam Island originally thought to record the Mono Lake excursion and from the transitionally magnetized El Calderon basalt flow, New Mexico that was K-Ar dated by Champion et al. (1988) at 128 ± 66 ka.Unspiked K-Ar ages of four samples from the Inzolfato flow are 102.5 ± 4.7, 101.3 ± 3.3, 97.1 ± 2.6, and 96.8 ± 3.1 ka and thus indistinguishable from one another. ⁴⁰Ar/³⁹Ar results are more complex, with three samples yielding discordant age spectra. Based on incremental heating data obtained in both the UW-Madison and Gif-sur-Yvette ⁴⁰Ar/³⁹Ar laboratories, a fourth sample yields six concordant age plateaus and a weighted mean age of 105.2 ± 1.4 ka that we take as the best estimate of time since the flow erupted. Five ⁴⁰Ar/³⁹Ar incremental heating experiments on the Amsterdam Island lava yield a plateau age of 120 ± 12 ka, whereas ages from two sites in the Calderon flow are 112 ± 23 and 101 ± 14 ka, together giving a weighted mean of 104 ± 12 ka. The age of 120 ± 12 ka from Amsterdam Island, though imprecise, correlates with the Blake excursion. In contrast, the 104–105 ka age obtained from both Lipari and New Mexico indicates that these lavas record a younger period of dynamo instability, most probably associated with the post-Blake excursion. These radioisotopic ages are consistent with the astronomical ages of two paleointensity minima in the PISO-1500 global stack. Our findings indicate that the Blake and post-Blake excursions are both global features of past geodynamo behavior and support the hypothesis that Brunhes chron excursions are temporally clustered into two groups of at least a half-dozen each spanning over 220 to 30 ka and 720 to 520 ka.     

Effect of iron salt counter ion in dose–response curves for inactivation of Fusarium solani in water through solar driven Fenton-like processes

The inactivation of Fusarium solani in water was assessed by solar driven Fenton-like processes using three different iron salts: ferric acetylacetonate (Fe(acac)₃), ferric chloride (FeCl₃) and ferrous sulfate (FeSO₄). The experimental conditions tested were [Fe] ≈ 5 mg L⁻¹, [H₂O₂] ≈ 10 mg L⁻¹ and [Fe] ≈ 10 mg L⁻¹; [H₂O₂] ≈ 20 mg L⁻¹ mild and high, respectively, and pH 3.0 and 5.0, under solar radiation. The highest inactivation rates were observed at high reaction conditions for the three iron salts tested at pH 5.0 with less than 3.0 kJ L⁻¹ of accumulate energy (Q_UV) to achieve over 99.9% of F. solani inactivation. Fe(acac)₃ was the best iron salt to accomplishing F. solani inactivation. The modified Fermi equation was used to fix the experimental inactivation, data showed it was helpful for modeling the process, adequately describing dose–response curves. Inactivation process using FeSO₄ at pH 3.0 was modeled fairly with r² = 0.98 and 0.99 (mild and high concentration, respectively). Fe(acac)₃, FeCl₃ and FeSO₄ at high concentration (i.e. [Fe] ≈ 10 mg L⁻¹; [H₂O₂] ≈ 20 mg L⁻¹) and pH 5.0 showed the highest fitting values (r² = 0.99). Iron salt type showed a remarkable influence on the Fenton-like inactivation process.     

Paleomagnetic dating of Phanerozoic kimberlites in Siberia

Diamond bearing kimberlite pipes are exposed across the north-central part of the Siberian platform. Three main time intervals are considered to be the age of emplacement: the Devonian–Early Carboniferous, Triassic, and Cretaceous. However, isotopic age data from of the pipes are scattered and provide a very broad age interval for the magmatic activity. New paleomagnetic poles from four kimberlite pipes (Eastern Udachnaya, Western Udachnaya, International and Obnazhennaya) are obtained to estimate their paleomagnetic age. The mean primary magnetization directions for the pipes are as follows: D = 4.3°, I = − 44.5° (k = 29.4, α₉₅ = 7.4°, N = 14); D = 340.5°, I = − 65.6° (k = 12.9, α₉₅ = 19.4°, N = 6); D = 291.1°, I = − 78.1° (k = 27.5, α₉₅ = 14.9°, N = 5); and D = 306.7°, I = − 82.6° (k = 38.4, α₉₅ = 5.8°, N = 17), respectively. On the basis of a comparison with the Siberian apparent polar wander path (APWP) we estimate the age of kimberlite magmatism, assuming primary magnetizations in these rocks. The paleomagnetic ages are as follows: 428 ± 13 Ma for Eastern Udachnaya; 251 ± 30 Ma for International pipe; and 168 ± 11 Ma for Obnazhennaya pipe. The Western Udachnaya pipe was remagnetized and no clear paleomagnetic age could be determined. The ages of magmatic activity span the Early Silurian to Middle Late Jurassic. Early Silurian magmatism could be associated with the formation of the Viluy rift. Middle to Late Jurassic magmatic activity is most likely related to subduction related to the accretion of surrounding terranes to Siberia.     

Net autotrophy in a fluvial lake: the relative role of phytoplankton and floating-leaved macrophytes

This study combined water- and sediment flux measurements with mass balances of dissolved gas and inorganic matter to determine the importance of pelagic and benthic processes for whole-system metabolism in a eutrophic fluvial lake. Mass balances of dissolved O₂, inorganic carbon (DIC), nitrogen (DIN), phosphorous (SRP), particulate N (PN) and P (PP) and Chl a were calculated at a nearly monthly frequency by means of repeated sampling at the lake inlet and outlet. Simultaneously, benthic fluxes of gas and nutrients, including denitrification rates, and the biomass of the dominant pleustophyte (Trapa natans) were measured, and fluxes of O₂ and CO₂ across the water–atmosphere interface were estimated from diel changes in outlet concentrations. On an annual scale, Middle Lake exhibited CO₂ supersaturation, averaging 313% (range 86–562%), but was autotrophic with a net O₂ production (6.35 ± 2.05 mol m⁻² y⁻¹), DIC consumption (−31.18 ± 18.77 mol m⁻² y⁻¹) and net export of Chl a downstream (8.38 ± 0.95 mol C m⁻² y⁻¹). Phytoplankton was the main driver of Middle Lake metabolism, with a net primary production estimated at 33.24 mol O₂ m⁻² y⁻¹, corresponding to a sequestration of 4.18 and 0.26 mol m⁻² y⁻¹ of N and P, respectively. At peak biomass, T. natans covered about 18% of Middle Lake’s surface and fixed 2.46, 0.17 and 0.02 mol m⁻² of C, N and P, respectively. Surficial sediments were a sink for O₂ (−14.47 ± 0.65 mol O₂ m⁻² y⁻¹) and a source of DIC and NH₄ ⁺ (18.84 ± 2.80 mol DIC m⁻² y⁻¹ and 0.83 ± 0.16 mol NH₄ ⁺ m⁻² y⁻¹), and dissipated nitrate via denitrification (1.44 ± 0.11 mol NO₃ ⁻ m⁻² y⁻¹). Overall, nutrient uptake by primary producers and regeneration from sediments were a minor fraction of external loads. This work suggests that the creation of fluvial lakes can produce net autotrophic systems, with elevated rates of phytoplanktonic primary production, largely sustained by allochtonous nutrient inputs. These hypereutrophic aquatic bodies are net C sinks, although they simultaneously release CO₂ to the atmosphere.     

Establishment of a sediment transport capacity equation on loessal slope via experimental investigation

Areliable sediment transport capacity function provides response against challenges of soil erosion prediction on the Loess Plateau of China. The popular sediment transport capacity functions are questionable on loess slopes because the experimental conditions from which they were derived, like bed materials, gentle slopes,and surface roughness, are different from soil erosion processes on the loess slopes. Due to the foregoing uncertainty, a suitable sediment transport capacity function was dev...     

Radiogenic heat production in the lithosphere of Sulu ultrahigh-pressure metamorphic belt

The Chinese Continental Scientific Drilling (CCSD) project is located at the Sulu ultrahigh-pressure metamorphic (UHPM) belt. It offers a unique opportunity for studying the radiogenic heat production of both shallower and deeper rocks. Based on the concentrations of radiogenic elements U, Th and K on 349 samples from main hole of CCSD (CCSD MH), pilot holes and exposures, we determined radiogenic heat productions of all major rock types in the Sulu UHPM belt. Results show the mean values of orthogneiss and paragneiss are respectively 1.65 ± 0.81 and 1.24 ± 0.61 µW m^? 3. Due to different composition and grade of retrogressive metamorphism, the eclogites display significant scatter in radiogenic heat production, ranging from 0.01 to 2.85 µW m^? 3, with a mean of 0.44 ± 0.55 µW m^? 3. The radiogenic heat production in ultramafic rocks also varies within a large range of 0.02 to 1.76 µW m^? 3, and the average turns out to be 0.18 ± 0.31 µW m^? 3. Based on the measurements and crustal petrologic model, the vertical distribution model of heat production in Sulu crust is established. The resulting mean heat production (0.76 µW m^? 3) contributes 24 mW m^? 2 to the surface heat flow. 1-D thermal model indicates that the temperature at the Moho reaches above 750 °C, and the thermal thickness of the lithosphere is ~ 75 km, in good agreement with the geophysical results. The high teat flow (~ 75 mW m^? 2) together with thin lithosphere presents strong support for the extension events during the late Cretaceous and Cenozoic.     

Evaluation of uncalibrated energy balance model (BAITSSS) for estimating evapotranspiration in a semiarid,advective climate

The backward‐averaged iterative two‐source surface temperature and energy balance solution (BAITSSS) model was developed to calculate evapotranspiration (ET) at point to regional scales. The BAITSSS model is driven by micrometeorological data and vegetation indices and simulates the water and energy balance of the soil and canopy sources separately, using the Jarvis model to calculate canopy resistance. The BAITSSS model has undergone limited testing in Idaho, United States. We conducted a blind test of the BAITSSS model without prior calibration for ET against weighing lysimeter measurements, net radiation, and surface temperature of drought‐tolerant corn (Zea mays L. cv. PIO 1151) in a semiarid, advective climate (Bushland, Texas, United States) in 2016. Later in the season (20 days), BAITSSS consistently overestimated ET by up to 3 mm d^?1. For the entire growing season (127 days), simulated versus measured ET resulted in a 7% error in cumulative ET, RMSE = 0.13 mm h^?1, and 1.70 mm d^?1; r² = 0.66 (daily) and r² = 0.84 (hourly); MAE = 0.08 mm h^?1 and 1.24 mm d^?1; and MBE = 0.02 mm h^?1 and 0.58 mm d^?1. The results were comparable with thermally driven instantaneous ET models that required some calibration. Next, the initial soil water boundary condition was reduced, and model revisions were made to resistance terms related to incomplete cover and assumption of canopy senescence. The revisions reduced discrepancies between measured and modelled ET resulting in <1% error in cumulative ET, RMSE = 0.1 mm h^?1, and 1.09 mm d^?1; r² = 0.86 (daily) and r² = 0.90 (hourly); MAE = 0.06 mm h^?1 and 0.79 mm d^?1; and MBE = 0.0 mm h^?1 and 0.17 mm d^?1 and generally mitigated the previous overestimation. The advancement in ET modelling with BAITSSS assists to minimize uncertainties in crop ET modelling in a time series.     

Determination of vertical displacements over the coastal area of Korea due to the ocean tide loading using GPS observations

This paper describes the GPS applicability for detecting the vertical displacements of ground stations caused by ocean tide loading effects. An experiment was carried out using 12 permanent GPS stations located in the coastal area of Korea using data in the period 1 July until 26 August 2003. The relative height differences were calculated from hourly DGPS data processing based on the carrier-phase observation. The power spectra of the M₂ and N₂ constituents of ocean tide loading were derived using the CLEAN algorithm. The differential vertical displacements generated by the ocean tide loading effect are typically 3–25 mm in coastal area of the Korea. We compared the results from GPS with those of the ocean tide models, NAO.99Jb regional model and GOT00.2, FES99 global models. The M₂ (N₂) amplitude differences of vertical displacements between GPS and GOT00.2 is 1.22 ± 3.61 mm (1.01 ± 1.48 mm), and that of the M₂ (N₂) amplitude difference between GPS and FES99 is 0.04 ± 4.64 mm (0.64 ± 1.75 mm), whereas the M₂ (N₂) amplitude difference between GPS and NAO.99Jb are 0.05 ± 1.03 mm (0.86 ± 1.18 mm). The highest vertical displacements at the PALM station are found for 24.5 ± 0.7 mm from GPS observation, and 22.9 mm from the regional model NAO.99Jb and 13.17 and 10.00 mm from the global models GOT00.2 and FES99, respectively. These values show that the vertical displacements derived from GPS are in good agreement with those of the regional model NAO.99Jb around Korea, more than with the global models. This result indicated that GPS is an effective tool to measure the vertical displacement caused by the ocean tide loading effect in the coastal area, and we need to use the NAO.99Jb ocean tide model rather than the global ocean tide models in and around the Korean peninsula for position determination with permanent GPS installations. This work demonstrates that vertical displacement caused by the M₂ and N₂ constituents of ocean tide loading can be measured by carrier-phase DGPS.