Bacterial and Virus‐Like Particle Abundances in Purged and Unpurged Groundwater Depth Profiles

Bacteria and viruses are ubiquitous in subterranean aquatic habitats. Bacterial abundance is known to vary with depth in aquifers; however, whether viral abundance varies with depth is less well known. Here we use flow cytometry (FCM) to enumerate bacteria and virus‐like particles (VLP) from groundwater depth profiles. Groundwater samples were obtained from a set of nested piezometers from depths of 15, 30, 45, 60, 80, and 90 m and bacteria and VLP abundances were determined in purged aquifer water and unpurged water at each slot depth. Mean bacterial abundance (cells / mL) was not significantly different in unpurged water (3.2 × 10⁵) compared to purged water (1.4 × 10⁵); however, mean VLP abundance (particles / mL) was significantly greater in unpurged water (4.4 × 10⁵) compared to purged water (2.3 × 10⁵). Purged water was used to investigate the aquifer depth profile and bacterial and VLP abundances were observed to vary significantly between depths. The virus‐bacteria ratio was determined and was observed to steadily increase with depth. Overall, our data indicate the dynamic nature of bacterial and viral abundances in subsurface environments which should be considered when designing groundwater microbial sampling methodologies.     

Forced oscillation measurements of seismic attenuation in fluid saturated sandstone

Adopting the method of forced oscillation, attenuation was studied in Fontainebleau sandstone (porosity 10%, permeability 10 mD) at seismic frequencies (1–100 Hz). Confining pressures of 5, 10, and 15 MPa were chosen to simulate reservoir conditions. First, the strain effect on attenuation was investigated in the dry sample for 11 different strains across the range 1 × 10^?6–8 × 10^?6, at the confining pressure of 5 MPa. The comparison showed that a strain of at least 5 × 10^?6 is necessary to obtain a good signal to noise ratio. These results also indicate that nonlinear effects are absent for strains up to 8 × 10^?6. For all the confining pressures, attenuation in the dry rock was low, while partial (90%) and full (100%) saturation with water yielded a higher magnitude and frequency dependence of attenuation. The observed high and frequency dependent attenuation was interpreted as being caused by squirt flow.     

Spatial and Temporal Dependence of Temperature Variations Induced by Atmospheric Pressure Variations in Shallow Underground Cavities

Pressure-induced temperature (PIT) variations are systematically observed in the atmosphere of underground cavities. Such PIT variations are due to the compressibility of the air, damped by heat exchange with the rock surface. It is important to characterize such processes for numerous applications, such as the preservation of painted caves or the assessment of the long-term stability of underground laboratories and underground waste repositories. In this paper we thoroughly study the spatiotemporal dependence of the PIT response versus frequency using vertical and horizontal profiles of temperature installed in an abandoned underground quarry located in Vincennes, near Paris. The PIT response varies from about 20 × 10^?3°C hPa^?1 at a frequency of 2 × 10^?4 Hz to 2–3 × 10^?3°C hPa^?1 at a frequency of one cycle per day. An analytical expression based on a simple heat exchange model accounts for the observed features of the PIT response and allows for correcting the measured time series, having standard deviations of about 10^?2°C, to residual variations with a standard deviation of about 2 × 10^?3°C. However, a frequency-dependent attenuation of the response, corresponding to a reduction in amplitude with a factor varying from 2 to 3, is observed near the walls. This effect is not included in the simple analytical expression, but it can be accounted for by a one-dimensional differential equation, solved numerically, where temperature variations in the atmosphere are damped by an effective radiative coupling with the rock surface, complemented by a diffusive coupling near the walls. The TIP response is observed to remain stable over several years, but a large transient enhancement of about a factor of two is observed near the roof at one location from July to October 2005. In a cavity located below the Paris Observatory, an additional contribution is identified in the PIT response function versus frequency for frequencies smaller than 2 × 10^?5 Hz. This contribution can be described using a modified analytical expression that includes the effect of heat diffusion into the surrounding rock. Using this expression, in this case also, the temperature time series can then be corrected, giving a residual standard deviation smaller than 1.6 × 10^?3°C. Transient temporal variations of the PIT response are observed in all sites, with possible nonlinear components in the PIT. Such effects are not properly understood at this stage, and limit the reduction of time series to standard deviations of the order of 2 × 10^?3°C, and consequently limit the search for new transient or seasonal temperature signals, for example due to the presence of tiny heat sources in the cavity or to geodynamical effects.     

Modification of the deep salinity-maximum in the Southern Ocean by circulation in the Antarctic Circumpolar Current and the Weddell Gyre

The evolution of the deep salinity-maximum associated with the Lower Circumpolar Deep Water (LCDW) is assessed using a set of 37 hydrographic sections collected over a 20-year period in the Southern Ocean as part of the WOCE/CLIVAR programme. A circumpolar decrease in the value of the salinity-maximum is observed eastwards from the North Atlantic Deep Water (NADW) in the Atlantic sector of the Southern Ocean through the Indian and Pacific sectors to Drake Passage. Isopycnal mixing processes are limited by circumpolar fronts, and in the Atlantic sector, this acts to limit the direct poleward propagation of the salinity signal. Limited entrainment occurs into the Weddell Gyre, with LCDW entering primarily through the eddy-dominated eastern limb. A vertical mixing coefficient, κ_V of (2.86 ± 1.06) × 10^?4 m² s^?1 and an isopycnal mixing coefficient, κ_I of (8.97 ± 1.67) × 10² m² s^?1 are calculated for the eastern Indian and Pacific sectors of the Antarctic Circumpolar Current (ACC). A κ_V of (2.39 ± 2.83) × 10^?5 m² s^?1, an order of magnitude smaller, and a κ_I of (2.47 ± 0.63) × 10² m² s^?1, three times smaller, are calculated for the southern and eastern Weddell Gyre reflecting a more turbulent regime in the ACC and a less turbulent regime in the Weddell Gyre. In agreement with other studies, we conclude that the ACC acts as a barrier to direct meridional transport and mixing in the Atlantic sector evidenced by the eastward propagation of the deep salinity-maximum signal, insulating the Weddell Gyre from short-term changes in NADW characteristics.     

Seasonal dynamics of microbial sulfate reduction in temperate intertidal surface sediments: controls by temperature and organic matter

The role of microbial sulfate reduction on organic matter oxidation was studied quantitatively in temperate intertidal surface sediments of the German Wadden Sea (southern North Sea) on a seasonal base in the years 1998–2007. The sampling sites represent the range of sediments found in the back-barrier tidal area of Spiekeroog Island: sands, mixed and muddy flats. The correspondingly different contents in organic matter, metals, and porosities lead to significant differences in the activity of sulfate-reducing bacteria with volumetric sulfate reduction rates (SRR) in the top 15 cm of up to 1.4 μmol cm^?3 day^?1. Depth-integrated areal SRR ranged between 0.9 and 106 mmol m^?2 day^?1, with the highest values found in the mudflat sediments and lower rates measured in sands at the same time, demonstrating the impact of both temperature and organic matter load. According to a modeling approach for a 154-km² large tidal area, about 39, 122, and 285 tons of sulfate are reduced per day, during winter, spring/autumn, and summer, respectively. Hence, the importance of areal benthic organic matter mineralization by microbial sulfate reduction increases during spring/autumn and summer by factors of about 2 and 7, respectively, when compared to winter time. The combined results correspond to an estimated benthic organic carbon mineralization rate via sulfate reduction of 78 g C m^?2 year^?1.     

Cancer risk estimation from dietary arsenic,a new approach from longitudinal cohort study

Inorganic arsenic is a carcinogen and consumption in low dose may lead to cancer. We estimated the cancer risk of the participants from arsenic endemic regions of West Bengal, India. The probable cancer risk was estimated following the assessment of daily inorganic arsenic intake through drinking water and diets of 20 participants for three consecutive years who had been using low arsenic water in the Indian context (median arsenic concentration in the study Years-I, II and III were 22, 16, 13 µg/l respectively). Probable cancer risk of the population was 2.80 × 10^?4, 2.94 × 10^?4, 3.12 × 10^?4 in the three respective study years (Year-I, II and III); just higher than the US EPA risk level of concern. The arsenic species content of the paired raw, cooked rice and urine was estimated in the as is taken basis. The major diet component, rice contained 72–86% inorganic arsenic whereas urine contains 70% organic arsenic on an average. The cancer risk assessment has been proposed to be modified by inclusion of urine arsenic release, considering the fact of arsenic release through urine. The risk became 1.28 × 10^?5, 1.13 × 10^?5, 1.01 × 10^?5 in the study Year-I, II and III respectively, considering urinary arsenic release, attributed the consideration of urine arsenic release into probable cancer risk estimation.     

Application of wavelet-artificial intelligence hybrid models for water quality prediction: a case study in Aji-Chay River,Iran

The accuracy of Artificial Neural Network (ANN), Adaptive Neuro-Fuzzy Inference System (ANFIS), wavelet-ANN and wavelet-ANFIS in predicting monthly water salinity levels of northwest Iran’s Aji-Chay River was assessed. The models were calibrated, validated and tested using different subsets of monthly records (October 1983 to September 2011) of individual solute (Ca²⁺, Mg²⁺, Na⁺, SO₄ ^2? and Cl^?) concentrations (input parameters, meq L^?1), and electrical conductivity-based salinity levels (output parameter, µS cm^?1), collected by the East Azarbaijan regional water authority. Based on the statistical criteria of coefficient of determination (R²), normalized root mean square error (NRMSE), Nash–Sutcliffe efficiency coefficient (NSC) and threshold statistics (TS) the ANFIS model was found to outperform the ANN model. To develop coupled wavelet-AI models, the original observed data series was decomposed into sub-time series using Daubechies, Symlet or Haar mother wavelets of different lengths (order), each implemented at three levels. To predict salinity input parameter series were used as input variables in different wavelet order/level-AI model combinations. Hybrid wavelet-ANFIS (R² = 0.9967, NRMSE = 2.9 × 10^?5 and NSC = 0.9951) and wavelet-ANN (R² = 0.996, NRMSE = 3.77 × 10^?5 and NSC = 0.9946) models implementing the db4 mother wavelet decomposition outperformed the ANFIS (R² = 0.9954, NRMSE = 3.77 × 10^?5 and NSC = 0.9914) and ANN (R² = 0.9936, NRMSE = 3.99 × 10^?5 and NSC = 0.9903) models.     

Source parameters and scaling relations for small earthquakes in Kumaon Himalaya, India

We investigate the scaling relationships among earthquake source parameters using more than 300 good quality broad band seismograms from 30 small earthquakes in the Kumaon Himalaya from the spectral analysis of P and S waves. The average ratio of P/S wave corner frequency is found to be 1.13, which is suggestive of shift in the corner frequency. The estimated seismic moment range from 1.6?×?10¹³–5.8?×?10¹⁵ N?m, while the stress drop varies from 0.6 to 16 bars with 80 % of the events below 10 bars. An analysis of stress drop and apparent stress drop indicates the partial stress drop mechanism in the region. The source radii are between 0.17 and 0.88 km. The total seismic energy varies from 1.79?×?10⁸ to 7.30?×?10¹¹ J. We also observe the variation in seismic energy for a given seismic moment. The scaling relation between the seismic moment and stress drop suggests the breakdown of constant stress drop scaling for the range of seismic moments obtained here for the region. This shows the anomalous behavior of small earthquakes in the region. The study indicates that the stress drop is the dominant scaling factor for the moments studied here.     

Initiation and Propagation of Compaction Bands in Dry and Wet Bentheim Sandstone

We investigated initiation and propagation of compaction bands (CB) in six wet and four dry Bentheim sandstone samples deformed in axial compression tests with strain rates ranging from 3.2 × 10^?8 s^?1 to 3.2 × 10^?4 s^?1. Circumferential notches with 0.8-mm width and 5-mm depth served to initiate CB at mid-sample length. Wet samples were saturated with distilled water and deformed at 195 MPa confining pressure and 10 MPa pore pressure. Dry samples were deformed at 185 MPa confining pressure. Twelve P-wave sensors, eight S-wave sensors and two pairs of orthogonally oriented strain-gages were glued to the sample surface to monitor acoustic emission (AE), velocities and local strain during the loading process. Nucleation of compaction bands is indicated by AE clusters close to the notch tips. With progressive loading, AE activity increased and AE hypocenters indicated propagation of a single CB normal to the sample axis. CB propagation from the sample periphery towards the centre was monitored. Microstructural analysis of deformed samples shows excellent agreement between location of AE clusters and CBs. In both dry and wet samples the lateral propagation of CBs was about 100 times faster than axial shortening rates. At the slowest displacement rate, AE activity during band propagation was reduced and CB nucleation in wet samples occurred at 20% lower stresses. This may indicate an increasing contribution of stress corrosion processes to the formation of the compaction bands. In dry and wet samples inelastic compaction energy per area ranged between 16 and 80 kJ m^?2. This is in good agreement with previous estimates from laboratory and field studies.     

Benthic respiration and stoichiometry of regenerated nutrients in lake sediments with Dreissena polymorpha

The effect of patchy colonies of the invasive zebra mussel (Dreissena polymorpha) on sedimentary processes was investigated in a mesotrophic lake (Plateliai Lake, Lithuania). Benthic fluxes of O₂, TCO₂, CH₄, Mn²⁺, Fe²⁺, N₂, the inorganic forms of N, Si and P and dissolved organic C and N were quantified by dark incubations of sediments cores, with and without D. polymorpha. Individual mussels also were incubated for metabolic measurements. Sediments with D. polymorpha had significantly higher O₂ and TCO₂ fluxes and displayed higher rates of denitrification. The presence of mussels also resulted in higher regeneration of P and N (mostly as ammonium) while the effect on Si was not significant. However, likely due to the low zebra mussel biomass (57.2 ± 25.3 g_SFDW m^?2), biodeposition has not changed the ratio between anaerobic and total respiration. Methane and reduced metals fluxes were in fact similar in the presence and absence of D. polymorpha. Incubations of mussels without sediments confirmed that bivalve metabolism was the main driver of benthic respiration and nutrient recycling. Nitrate production suggested the presence of nitrifiers associated with the molluscs. The main outcome of this study was that zebra mussels alter the quantity and the stoichiometry of nutrients regenerated by the benthic compartment. The enhancement of nitrogen loss via denitrification, by a factor of 1.5, was much less pronounced than the increase in ammonium recycling rate, stimulated by a factor of 33. Negligible PO₄ ^3? fluxes in bare sediments (?3.4 ± 6.8 μmol m^?2 h^?1) increased in the presence of mussels and considerable amounts of this nutrient (69.6 ± 29.4 μmol m^?2 h^?1) were mobilized to the water column. Further research should address other nutrient sources to the lake to verify whether altered rates and stoichiometry of benthic regeneration can affect primary producer community composition and activity.     

Condensation and the composition of iron meteorites

The pressure-temperature conditions in the primordial nebula which could produce the observed Ni, Ga and Ge abundances in the major iron meteorite groups have been calculated assuming equilibrium condensation. Included in these calculations are the effect on the metal composition of Fe oxidation and sulphide formation during accretion, GeS and GaCl in the nebula gases and pressure variations in the nebula. It was found that the IIAB irons had their abundances of these elements fixed at the low-pressure extreme of the range which gives the IAB irons, but at 50 ± 10K higher temperatures. IIIAB and IVA formed over the same temperature range as IAB (600–670_?40⁺⁶⁰ K) in regions where the pressure was lower by a factor of 20 and 10⁴ respectively. Group IVB accreted soon after condensation of the metal and at pressures of less than 10^?3 atmosphere. The distribution of sulphur and carbon are consistent with this. The abundance of carbon in group IAB suggests that this and group IIAB accreted at about 10^?4 atmosphere, so that IIIAB and IVA accreted where the pressure was 5 × 10^?6 and 10^?8 atmosphere, respectively.     

Constraining tephra dispersion and deposition from three subplinian explosions in 2011 at Shinmoedake volcano,Kyushu, Japan

Constraining physical parameters of tephra dispersion and deposition from explosive volcanic eruptions is a significant challenge, because of both the complexity of the relationship between tephra distribution and distance from the vent and the difficulties associated with direct and comprehensive real-time observations. Three andesitic subplinian explosions in January 2011 at Shinmoedake volcano, Japan, are used as a case study to validate selected empirical and theoretical models using observations and field data. Tephra volumes are estimated using relationships between dispersal area and tephra thickness or mass/area. A new cubic B-spline interpolation method is also examined. Magma discharge rate is estimated using theoretical plume models incorporating the effect of wind. Results are consistent with observed plume heights (6.4–7.3 km above the vent) and eruption durations. Estimated tephra volumes were 15–34?×?10⁶ m³ for explosions on the afternoon of 26 January and morning of 27 January, and 5.0–7.6?×?10⁶ m³ for the afternoon of 27 January; magma discharge rates were in the range 1–2?×?10⁶ kg/s for all three explosions. Clast dispersal models estimated plume height at 7.1?±?1 km above the vent for each explosion. The three subplinian explosions occurred with approximately 12-h reposes and had similar mass discharge rates and plume heights but decreasing erupted magma volumes and durations.     

Effectiveness of subsurface pressure monitoring for brine leakage detection in an uncertain CO2 sequestration system

This work evaluates the detection sensitivity of deep subsurface pressure monitoring within an uncertain carbon dioxide sequestration system by linking the output of an analytical reduced-order model and first-order uncertainty analysis. A baseline (non-leaky) modeling run was compared against 10 different leakage scenarios, where the cap rock permeability was increased by factors of 2–100 (cap rock permeability from 10^?3 to 10^?1 millidarcy). The uncertainty variance outputs were used to develop percentile estimates and detection sensitivity for pressure throughout the deep subsurface as a function of space (lateral distance from the injection wells and vertical orientation within the reservoir) and time (years since injection), or P(x, z, t). Conditional probabilities were computed for combinations of x, z, and t, which were then used to generate power curves for detecting leakage scenarios. The results suggest that measurements of the absolute change in pressure within the target injection aquifer would not be able to distinguish small leakage rates (i.e., less than 50 × baseline) from baseline conditions, and that only large leakage rates (i.e., >100 × baseline) would be discriminated with sufficient statistical power (>99 %). Combining measurements, for example by taking the ratio of formation pressure in Aquifer 2/Aquifer 1, provides better statistical power for distinguishing smaller leakage rates at earlier times in the injection program. Detection sensitivity for pressure is a function of space and time. Therefore, design of an adequate monitoring network for subsurface pressure should account for this space–time variability to ensure that the monitoring system performs to the necessary design criteria, e.g., specific false-negative and false-positive rates.     

Bayesian network-based risk assessment for hazmat transportation on the Middle Route of the South-to-North Water Transfer Project in China

A Bayesian network-based risk assessment (BN-RA) model was developed to assess the risk of hazmat transportation by identifying, modeling, and quantitatively calculating the risk on the Middle Route of the South-to-North Water Transfer Project (MRSNWTP) in China. First, we selected seven parameters from five categories of impact factors (i.e., human, vehicle, tank, weather, and road environment) as quintessential risk factors for accidents. Second, we used the developed BN-RA model to predict the probability of accidents. Third, using bidirectional inference in the BN approach, we analyzed and ranked the importance of the effects of these factors. The developed model was subsequently applied to assess the risks of major bridges crossing canals with different pavement grades and traffic flow levels both at present and in the future for the Beijing-Shijiazhuang Section of the MRSNWTP. The results indicated the following: (1) Although the overall potential risk of hazmat transportation accidents on all bridges in the Beijing-Shijiazhuang Section was fairly low (e.g., 0.08 %), the impacts cannot be ignored because of the potential for huge losses. (2) According to the analysis of many factors that may affect accidents, the driving patterns of drivers exerted the strongest influence on the probability of an accident, followed by vehicle conditions and lighting conditions. (3) If a vehicle were to fail, the highest probability (0.17 %) of an accident would arise if it were traveling on a road with no street lighting and poor road conditions at night. (4) Assuming that a vehicle was in good condition, the highest probability (0.12 %) of an accident arised when the vehicle suddenly encountered poor road conditions with no lights on a foggy night. (5) The predicted probabilities of accidents on Bridge TCWRR (short for the Tang County West Ring Road Bridge) in the short (i.e., the year 2017), medium (i.e., the year 2022) and long terms (i.e., the year 2027) were 3.25 × 10^?4, 5.37 × 10^?4, and 8.89 × 10^?4, respectively. For Bridge DNR (short for the Dian Bridge on the North Road), these values were 8.64 × 10^?6, 1.02 × 10^?5, and 1.21 × 10^?5, respectively. Based on the risk assessment results, to lower the accident probability and avoid the serious consequences resulting from hazmat transportation accidents, we developed an appropriate emergency response program to reduce potential hazards. This research resolved the problems of randomness and uncertainty associated with hazmat transportation in the MRSNWTP and can provide a reference for the effective prevention of hazmat transportation accidents and scientific decision-making in risk management.     

Export and degassing of terrestrial carbon through watercourses draining a temperate podzolized catchment

We measured spatial and temporal variations in carbon concentrations, isotopic compositions and exports during a complete hydrological cycle in nine watercourses draining a lowland forested podzolized catchment, flowing into the Arcachon lagoon (France). In addition, integrated fluxes of CO₂ across the water-atmosphere interface were estimated to assess the relative importance of CO₂ evasion versus lateral carbon transport at the catchment scale. Watercourse similarities and specificities linked to the local catchment characteristics are discussed and compared with other riverine systems. Low concentrations of suspended particulate matter and particulate organic carbon (POC) were generally measured in all the watercourses (8.4 ± 3.4 and 1.6 ± 0.6 mg L^?1, respectively), reflecting limited mechanical soil erosion. The generally high POC content in the suspended matter (20 %), low Chl a concentrations (1.3 ± 1.4 μg L^?1) and the relatively constant δ¹³C-POC value (near ?28 ‰) throughout the year reveal this POC originates from terrestrial C₃ plant and soil detritus. The presence of podzols leads to high levels of dissolved organic carbon (DOC; 6.6 ± 2.2 mg L^?1). Similarly, high dissolved inorganic carbon (DIC) concentrations were measured in the Arcachon lagoon catchment (5.9 ± 2.2 mg L^?1). The δ¹³C-DIC value around ?20 ‰ throughout the year in many small watercourses reveals the predominance of terrestrial carbon mineralisation and silicate rock weathering in soils as the major DIC source. With pCO₂ between 1,000 and 10,000 ppmv, all watercourses were a source of CO₂ to the atmosphere, particularly during the low river stage. Organic carbon parameters remained relatively stable throughout the year, whereas DIC parameters showed strong seasonal contrasts closely linked to the hydrological regime and hyporheic flows. In total, the carbon export from the Arcachon watershed was estimated at 15,870 t C year^?1 or 6 t C km^?2 year^?1, mostly exported to the lagoon as DOC (35 %), DIC (24 %) and lost as CO₂ degassing to the atmosphere (34 %).     

Influences of temperature and nutrients on Synechococcus abundance and biomass in the southern Mid-Atlantic Bight

Synechococci are small (<1 μm) coccoid prokaryotes that play a significant ecological role in microbial food webs and are important contributors to carbon and nitrogen biogeochemical cycles. Under funding from NOAA and NASA, we developed a time series observatory to understand the seasonal variability of Synechococcus and other phytoplankton. Our goal is to understand the distribution and relative contribution of Synechococcus to the carbon cycle and how they relate to nutrients and temperature. Synechococcus in the southern Mid-Atlantic Bight exhibited a clear seasonal abundance pattern in both inshore and offshore waters—peaking in abundance (11×10⁴ cells ml⁻¹) during warm periods of summer. Synechococci were numerically important during periods of stratification when waters were warm and macronutrients were low. Using a simple algorithm to convert cellular volume to cellular carbon using image analysis, we estimated that Synechococcus cellular carbon ranged from 0.1 to 1.5 pg C per cell and was most significant compared to total particulate carbon in the summer peaking at ∼25% of the total carbon available. No direct correlations were found between Synechococcus abundance and nitrate, nitrite, ammonium, phosphate, and silicate. However, inshore Synechococcus abundance peaked at 10⁴ cells ml⁻¹ when nitrogen concentrations were lowest. Our results suggest that Synechococcus is adapted to warm temperatures and are capable of demonstrating rapid growth during summer when macronutrients are limiting. The ability of Synechococcus to take advantage of high summer temperatures, low nutrient concentrations and low light levels allows them to maintain a picoplankton community during periods of low detritus and nanophytoplankton is nutrient limited. Temperature-dependence is important in altering the size spectrum of the phytoplankton community and affects the carbon cycle on the Mid Atlantic Bight.     

Source parameters of seismic events potentially associated with damage in block 33/34 of the Kiirunavaara mine (Sweden)

Forty-six mining-induced seismic events with moment magnitude between ?1.2 and 2.1 that possibly caused damage were studied. The events occurred between 2008 and 2013 at mining level 850–1350 m in the Kiirunavaara Mine (Sweden). Hypocenter locations were refined using from 6 to 130 sensors at distances of up to 1400 m. The source parameters of the events were re-estimated using spectral analysis with a standard Brune model (slope ?2). The radiated energy for the studied events varied from 4.7 × 10^?1 to 3.8 × 10⁷ J, the source radii from 4 to 110 m, the apparent stress from 6.2 × 10² to 1.1 × 10⁶ Pa, energy ratio (E _s/E _p) from 1.2 to 126, and apparent volume from 1.8 × 10³ to 1.1 × 10⁷ m³. 90% of the events were located in the footwall, close to the ore contact. The events were classified as shear/fault slip (FS) or non-shear (NS) based on the E _s/E _p ratio (>10 or <10). Out of 46 events 15 events were classified as NS located almost in the whole range between 840 and 1360 m, including many events below the production. The rest 31 FS events were concentrated mostly around the production levels and slightly below them. The relationships between some source parameters and seismic moment/moment magnitude showed dependence on the type of the source mechanism. The energy and the apparent stress were found to be three times larger for FS events than for NS events.     

Carbon sinks/sources in the Yellow and East China Seas—Air-sea interface exchange,dissolution in seawater,and burial in sediments

The sinks/sources of carbon in the Yellow Sea(YS) and East China Sea(ECS), which are important continental shelf seas in China, could exert a great influence on coastal ecosystem dynamics and the regional climate change process. The CO_2 exchange process across the seawater-air interface, dissolved and particulate carbon in seawater, and carbon burial in sediments were studied to understand the sinks/sources of carbon in the continental shelf seas of China. The YS and the ECS generally have different patterns of seasonal air-sea CO_2 exchange. In the YS, regions west of 124°E can absorb CO_2 from the atmosphere during spring and winter, and release CO_2 to the atmosphere during summer and autumn. The entire YS is considered as a CO_2 source throughout the year with respect to the atmosphere, but there are still uncertainties regarding the exact air-sea CO_2 exchange flux. Surface temperature and phytoplankton production were the key controlling factors of the air-sea CO_2 exchange flux in the offshore region and nearshore region of the YS, respectively. The ECS can absorb CO_2 during spring, summer, and winter and release CO_2 to the atmosphere during autumn. The annual average exchange rate in the ECS was-4.2±3.2 mmol m~(-2) d~(-1) and it served as an obvious sink for atmospheric CO_2 with an air-sea exchange flux of 13.7×10~6 t. The controlling factors of the air-sea CO_2 exchange in the ECS varied significantly seasonally. Storage of dissolved inorganic carbon(DIC) and dissolved organic carbon(DOC) in the YS and the ECS were 425×10~6 t and 1364×10~6 t, and 28.2×10~6 t and 54.1×10~6 t,respectively. Long-term observation showed that the DOC content in the YS had a decreasing trend, indicating that the "practical carbon sink" in the YS was decreasing. The total amount of particulate organic carbon(POC) stored in the YS and ECS was10.6×10~6 t, which was comparable to the air-sea CO_2 flux in these two continental shelf seas. The amounts of carbon sequestered by phytoplankton in the YS and the ECS were 60.42×10~6 t and 153.41×10~6 t, respectively. Artificial breeding of macroalgae could effectively enhance blue carbon sequestration, which could fix 0.36×10~6–0.45×10~6 t of carbon annually. Organic carbon(OC) buried in the sediments of the YS was estimated to be 4.75×10~6 t, and OC of marine origin was 3.03×10~6 t, accounting for5.0% of the TOC fixed by phytoplankton primary production. In the ECS, the corresponding depositional flux of OC in the sediment was estimated to be 7.4×10~6 t yr~(-1), and the marine-origin OC was 5.5×10~6 t, accounting for 5.4% of the phytoplankton primary production. Due to the relatively high average depositional flux of OC in the sediment, the YS and ECS have considerable potential to store a vast amount of "blue carbon."     

Bacterial growth and the decomposition of particulate organic carbon collected in sediment traps

We have studied bacterial abundance and production in samples from sediment traps deployed for 1 and 100 days in several areas of the shelf and slope regions of the Middle Atlantic Bight, U.S.A. By making a series of assumptions about bacterial growth at the expense of POC in traps, we have estimated that the turnover time of organic particles collected in traps during long deployments is slow (mean 1500 ± 300 days), if only bacterial activity is considered. However the abundance and biomass of bacteria in traps is very high, ranging from 3 to 30 × 10¹¹ cells gC^?1, i.e., 0.3 to 3% of the POC is bacterial carbon. Fifteen to 88% of the particles in traps were colonized by bacteria, but usually about half the particles had only 0 to 1 cell attached. Growth of bacteria was observed at all scales relevant to these trap deployments; over periods ranging from hours to weeks, at rates of 0.01 to 0.3 d^?1. In spite of slow growth, bacteria appeared to be physiologically active in that [³H]adenine and [³H]thymidine were incorporated more rapidly into RNA and protein than into DNA. Total incorporation rates were high. We conclude that even relatively old (ca. 1 y) POC in sediment traps supports high levels of active bacterial biomass, but that POC decomposition is slow, so that bacteria may not be the principal agents of POC turnover following collection.