Neodymium isotopic variations in seawater

New data for the direct measurement of the isotopic composition of neodymium in Atlantic Ocean seawater are compared with previous measurements of Pacific Ocean seawater and ferromanganese sediments from major ocean basins. Data for Atlantic seawater are in excellent agreement with Nd isotopic measurements made on Atlantic ferromanganese sediments and are distinctly different from the observed compositions of Pacific samples. These results clearly demonstrate the existence of distinctive differences in the isotopic composition of Nd in the waters of the major ocean basins and are characteristic of the ocean basin sampled. The average ε_Nd(0) values for the major oceans as determined by data from seawater and ferromanganese sediments are as follows: Atlantic Ocean,ε_Nd(0) ? ?12 ± 2; Indian Ocean,ε_Nd(0) ? ?8 ± 2; Pacific Ocean,ε_Nd(0) ? ?3 ± 2. These values are considerably less than ε_Nd(0) value sources with oceanic mantle affinities indicating that the REE in the oceans are dominated by continental sources. The difference in the absolute abundance of¹⁴³Nd between the Pacific and Atlantic Oceans corresponds to ～10⁶ atoms¹⁴³Nd per gram of seawater. The correspondence between the¹⁴³Nd/¹⁴⁴Nd in seawater and in the associated sediments suggests the possible application of this approach to paleo-oceanography.Distinctive differences in ε_Nd(0) values are observed in the Atlantic Ocean between deep-ocean water associated with North Atlantic Deep Water and near-surface water. This suggests that North Atlantic Deep Water may be relatively well mixed with respect to Nd isotopic composition whereas near-surface water may be quite heterogeneous, reflecting different sources for surface waters relative to deep water. This suggests that it may be possible to distinguish the sources of water masses within an ocean basin on the basis of Nd isotopic composition.The Nd isotopic variations in seawater are used to relate the residence time of Nd and mixing rates between the oceans.     

The oxygen isotopic composition and temperature of Southern Ocean bottom waters during the last glacial maximum

We provide two new determinations of the oxygen isotopic composition of seawater during the last glacial maximum (LGM). High-resolution oxygen isotopic measurements were made on interstitial waters from Ocean Drilling Program (ODP) Sites 1168 and 1170 in the southeast Indian Ocean sector of the Southern Ocean. We use a diffusion-advection numerical model to calculate the glacial-interglacial change in bottom-water δ¹⁸O_sw from the pore water δ¹⁸O profiles; the first such determinations from this part of the oceans. Statistical analyses of the model runs indicate that Circumpolar Deep Water (CDW) δ¹⁸O_sw changed by 1.0-1.1±0.15‰ since the last glacial maximum (LGM). Our results are consistent with a previous calculation from a South Atlantic Southern Ocean location (ODP Site 1093) also situated within CDW. The new values determined in this study, together with previous estimates, are converging on a global average Δδ¹⁸O_sw of 1.0-1.1‰.Using the calculated bottom-water δ¹⁸O_sw, we have extracted the temperature component from the benthic foraminiferal δ¹⁸O record at Sites 1168 and 1170. Since the LGM, bottom waters at these two sites warmed by 2.6 and 1.9°C, respectively. The absolute temperature estimates for the LGM (−0.5°C [Θ=−0.6°C] at Site 1168 and −0.2°C [Θ=−0.4°C] at Site 1170) are slightly warmer than those reported from previous studies using the same technique, but are consistent with more homogenous deep-ocean temperatures during the LGM relative to the modern.     

210Po and210Pb distributions in the central and eastern Indian Ocean

Disequilibrium between²¹⁰Po and²¹⁰Pb and between²¹⁰Pb and²²⁶Ra has been mapped in the eastern and central Indian Ocean based on stations from Legs 3 and 4 of the GEOSECS Indian Ocean expedition.²¹⁰Po/²¹⁰Pb activity ratios are less than 1.0 in the surface mixed layer and indicate a residence time for Po of 0.6 years.²¹⁰Po and²¹⁰Pb are generally in radioactive equilibrium elsewhere in the water column except at depths of 100–500 m, where Po may be returned to solution after removal from the surface water, and in samples taken near the bottom at a few stations.²¹⁰Pb excesses relative to²²⁶Ra are observed in the surface water but these excesses are not as pronounced as in the North Pacific and North Atlantic. The difference is attributable to a lower flux of²¹⁰Pb from the atmosphere to the Indian Ocean. Below the main thermocline,²¹⁰Pb activities increase with depth to a broad maximum before decreasing to lower values near the bottom. Departures from this pattern are especially evident at stations taken in the Bay of Bengal (where²¹⁰Pb/²²⁶Ra activity ratios as low as 0.16 are observed) and near the Mid-Indian Ridge. The data suggest that removal of²¹⁰Pb at oceanic boundaries, coupled with eddy diffusion along isopycnals, can explain gradients in²¹⁰Pb near the boundary. Application of a simple model including isopycnal diffusion, chemical removal, production and radioactive decay produces fits the observed²¹⁰Pb/²²⁶Ra gradients for eddy diffusion coeffients of ～ 10⁷ cm²/s. High productivity in surface waters of the Bay of Bengal makes this region a sink for reactive nuclides in the northern Indian Ocean.     

Pb in the western Indian Ocean: distribution, disequilibrium, and partitioning between dissolved and particulate phases

²²⁶Ra profiles have been measured in the western Indian Ocean as part of the 1977–1978 Indian Ocean GEOSECS program. These profiles show a general increase in deep and bottom water Ra concentration from the Circumpolar region to the Arabian Sea. A deep Ra maximum which originates in the Arabian Sea and in the Somali basin at about 3000 m depth spreads southward into the Mascarene basin and remains discernible in the Madagascar and Crozet basins. In the western Indian Ocean, the cold Antarctic Bottom Water spreads northward under the possibly southward-flowing deep water, forming a clear benthic front along the Crozet basin across the Southwest Indian Ridge into the Madagascar and Mascarene basins. The Antarctic Bottom Water continues to spread farther north to the Somali basin through the Amirante Passage at 10°S as a western boundary current. The benthic front and other characteristic features in the western Indian Ocean are quite similar to those observed in the western Pacific where the benthic front as a distinctive feature was first described by Craig et al. [15]. Across the Mid-Indian Ridge toward the Ceylon abyssal plain near the triple junction, Ra profiles display a layered structure, reflecting the topographic effect of the mid-ocean ridge system on the mixing and circulation of the deep and bottom waters. Both Ra and Si show a deep maximum north of the Madagascar basin. Linear relationships between these two elements are observed in the deep and bottom water with slopes increasing northward. This suggests a preferential input of Ra over Si from the bottom sediments of the Arabian Sea and also from the flank sediments of the Somali basin.     

226Ra distribution in the Antarctic Ocean

²²⁶Ra data on eleven vertical profiles taken during the GEOSECS program from the Antarctic Ocean and its vicinity in both the Atlantic and the Pacific are presented. Replicate measurements were made on each sample using the Rn-emanation method. The precision (1 σ) based on triplicate analyses averages about ±2.5%. Waters all around the Antarctic continent below 2 km depth appear to exhibit a uniform²²⁶Ra concentration of 21.5 ± 1dpm/100kg, except perhaps locally such as the Ross Sea and the Drake Passage where small variations may be present. Higher in the water column, the²²⁶Ra contents decrease toward the surface with gradients which vary as a function of the influence exerted by the Antarctic Convergence. Across this oceanic front, a north-to-south increase of²²⁶Ra occurs (the increase being the largest near the surface: from 8 to 18 dpm/100 kg), reflecting the combining effect of deep-water upwelling and meridional water mixing. The core layer of the Antarctic Intermediate Water contains about 14 dpm/100 kg of²²⁶Ra and that of the Circumpolar Intermediate Water (O₂ minimum and local T maximum) about 18 dpm/100 kg. To a first approximation,²²⁶Ra covaries with Si in the circumpolar waters.     

Changes in the mode of Southern Ocean circulation over the last glacial cycle revealed by foraminiferal stable isotopic variability

Benthic foraminiferal oxygen and carbon isotopic records from Southern Ocean sediment cores show that during the last glacial period, the South Atlantic sector of the deep Southern Ocean filled to roughly 2500 m with water uniformly low in δ¹³C, resulting in the appearance of a strong mid-depth nutricline similar to those observed in glacial northern oceans. Concomitantly, deep water isotopic gradients developed between the Pacific and Atlantic sectors of the Southern Ocean; the δ¹³C of benthic foraminifera in Pacific sediments remained significantly higher than those in the Atlantic during the glacial episode. These two observations help to define the extent of what has become known as the ‘Southern Ocean low δ¹³C problem’. One explanation for this glacial distribution of δ¹³C calls upon surface productivity overprints or changes in the microhabitat of benthic foraminifera to lower glacial age δ¹³C values. We show here, however, that glacial-interglacial δ¹³C shifts are similarly large everywhere in the deep South Atlantic, regardless of productivity regime or sedimentary environment. Furthermore, the degree of isotopic decoupling between the Atlantic and Pacific basins is proportional to the magnitude of δ¹³C change in the Atlantic on all time scales. Thus, we conclude that the profoundly altered distribution of δ¹³C in the glacial Southern Ocean is most likely the result of deep ocean circulation changes. While the characteristics of the Southern Ocean δ¹³C records clearly point to reduced North Atlantic Deep Water input during glacial periods, the basinal differences suggest that the mode of Southern Ocean deep water formation must have been altered as well.     

Interpretation of the 231Pa/230Th paleocirculation proxy: New water-column measurements from the southwest Indian Ocean

Measurements of ²³¹Pa, ²³⁰Th and ²³²Th concentrations have been made on five water-column profiles along the western margin of the Madagascar and Mascarene Basins in the southern Indian Ocean. These measurements help to fill a significant gap in the global coverage of water-column ²³²Th, ²³⁰Th and ²³¹Pa data. ²³²Th concentrations vary, but generally increase with depth, suggesting higher particle loading in deeper waters, and the presence of a significant dissolved fraction of ²³²Th. ²³⁰Th concentrations increase with depth, and profiles are similar to the average of existing data from other regions. ²³¹Pa concentrations, on the other hand, show significant depth structure, apparently reflecting the various water masses sampled at this location. The modified remnants of North Atlantic Deep Water are found at a depth of ≈ 2000 m and exhibit elevated ²³¹Pa concentrations exported from the South Atlantic. Antarctic Intermediate and Bottom Waters have lower ²³¹Pa, probably due to scavenging onto opal particles during transit from the Southern Ocean. The differences between water masses raises a question: which water mass is important in controlling the ²³¹Pa/²³⁰Th ratio in underlying sediments? A simple one-dimensional model is used to demonstrate that the ²³⁰Th and ²³¹Pa exported to sea-floor sediments last equilibrates with waters close to the seafloor (within ≈ 1000 m), rather than averaging the whole water column. These findings suggest that ²³¹Pa_xs/²³⁰Th_xs in sediments provides information primarily about deep-water masses. In this region, sedimentary records will therefore provide information about the past flow of Antarctic Bottom Water into the Indian Ocean. Interpretation of data from other regions, such as the North Atlantic where this proxy has most successfully been applied, requires careful consideration of regional oceanography and knowledge of the composition of the water masses being investigated.     

Robust chronological reconstruction for young speleothems using radiocarbon

We have studied two young speleothems, SC4 from Smiths Cave (Christmas Island, eastern Indian Ocean) and WM7 from Wollondilly Cave (Wombeyan caves, SE Australia). Attempts to date these speleothems by the Th/U method have proved unsuccessful with some age reversals for SC4 due to multiple sources of non-authigenic Th. This method has also resulted in imprecise ages for WM7 because of low U concentrations (<10 ppb) and consequently very low levels of authigenic ²³⁰Th relative even to the very low levels of detrital ²³⁰Th present. Here, we present an alternative method for reliable dating of these young speleothems using radiocarbon. Approximately 100 carbonate samples from SC4 and WM7 were analysed for ¹⁴C by accelerator mass spectrometry (AMS). The AMS results indicate that bomb ¹⁴C was evident in the youngest parts of both stalagmites. Two different approaches were used to estimate dead carbon fraction (DCF) values for these stalagmites for the pre-bomb period. For SC4, the DCF values were estimated based on the timing of ¹⁴C dates for that period determined by high-resolution δ¹⁸O recorded in the speleothem, and the timing of the onset of bomb ¹⁴C. For WM7, a “maximum” range of pre-bomb DCF was determined. Chronologies of these speleothems were built based on a dense sequence of DCF-corrected ages using three different age-depth models: Clam (Classical method), and Bacon and OxCal (Bayesian statistical approach). Good agreement between these age-depth models were observed indicating that the top 170 mm of SC4 and the top 50 mm of WM7 grew during the past 550–750 years and 1360–1740 years, respectively.     

Lower Groundwater 14C Age by Atmospheric CO2 Uptake During Sampling and Analysis

Uptake of atmospheric CO₂ during sample collection and analysis, and consequent lowering of estimated ages, has rarely been considered in radiocarbon dating of groundwater. Using field and laboratory experiments, we show that atmospheric CO₂ can be easily and rapidly absorbed in hyperalkaline solutions used for the extraction of dissolved inorganic carbon, resulting in elevated ¹⁴C measurements. Kinetic isotope fractionation during atmospheric CO₂ uptake may also result in decrease of δ¹³C, leading to insufficient corrections for addition of dead carbon by geochemical processes. Consequently, measured ¹⁴C values of groundwater should not be used for age estimation without corresponding δ¹³C values, and historical ¹⁴C data in the range of 1 to 10% modern Carbon should be re‐evaluated to ensure that samples with atmospheric contamination are recognized appropriately. We recommend that samples for ¹⁴C analysis should be collected and processed in the field and the laboratory without exposure to the atmosphere. These precautions are considered necessary even if ¹⁴C measurements are made with an accelerator mass spectrometer.     

Excess222Rn and the benthic boundary layer in the western and southern Indian Ocean

We present 9 bottom²²²Rn profiles measured from the western and southern Indian Ocean during the 1977–1978 GEOSECS expedition. These profiles can be grouped into three cypes: one-layer, two-layer, and irregular types. The one-layer profiles with quasi-exponential distributions allow one to estimate the apparent vertical eddy diffusivity,K_v, with a simple model. The two-layer profiles show that there is a benthic boundary layer of the order of 50–100 m in which the excess²²²Rn distribution shows a vertical gradient much smaller than that of the layer immediately above. Within the boundary layer, the STD potential temperature (θ) and density(σ₄) profiles are practically constant, and theK_v values are of the order of 1000 cm²/s. The STD profiles for the water column above the boundary layer show gradients of increasing stability, and theK_v values are of the order of 100 cm²/s. Modeling of the Rn data in the water column above the boundary layer indicates that there is a transition layer which effectively reduces the penetration of excess Rn from the benthic boundary layer into the upper layer.Sarmiento et al. [10] have shown that the buoyancy gradient or stability is inversely correlated with the apparent vertical eddy diffusivity, and the resulting buoyancy flux is fairly uniform, ranging from 1 to 14 × 10^?6 cm²/s³ in the Atlantic and Pacific Oceans. However, Sarmiento et al. [11] show that a much higher buoyancy flux is associated with an intensified flow of the bottom water through a passage. In the Indian Ocean basins, we have found that the buoyancy flux has a comparable range (3–14 × 10^?6 cm²/s³), except for a couple of stations where both stability and apparent vertical diffusivity are higher, resulting in a much higher buoyancy flux, probably indicative of rapid bottom water flow.     

A universal approach to alpha-cellulose extraction for radiocarbon analysis of 14C-free to post-bomb ages

In order to expand our in-house capabilities for tree-ring ¹⁴C measurements in support of atmospheric ¹⁴C reconstruction research, we designed a very versatile and inclusive procedure to produce high-quality α-cellulose homogenized extracts. The procedure can be easily scaled up or down (≤10 to 40 samples) and/or modified on demand (chemical steps can be easily adjusted to sample requirements as well, e.g., increased or diminished, according to the amount of available material and/or contaminants to be removed). Procedure setups are straightforward, and all products and instruments required are off-the-shelf. One to three days may be used to extract chipped wood to α-cellulose homogenized fibers that can be further used by high-precision ¹⁴C accelerator mass spectrometry (AMS) analysis. The full procedure, which includes recommendations for wood reduction to chips, chemical treatment, and ¹⁴C-AMS sample processing, measurements and data handling was tested on over 110 wood samples from post-bomb 1950AD to ¹⁴C limit. Radiocarbon results were in the order of 0.29% or better, based on replication and regardless of the age group studied. Best background was in the order of 54 kyrs BP, without any type of background correction. Fourier transform infrared (FTIR) analysis was used as a characterizing tool to confirm the removal of unwanted carbon compounds during the production of α-cellulose extracts. For those analysis, we chose woods that are normally rich in resinous and parenchymatous structures. Results confirmed that our protocol produces pure α-cellulose extracts for ¹⁴C analysis, and therefore this procedure can be safely applied to atmospheric ¹⁴C reconstructions at pantropical regions.     

Sequential radiocarbon measurement of bulk peat for high-precision dating of tsunami deposits

Dates of tsunami deposits have been used to estimate paleotsunami recurrence intervals in areas affected by these natural events. The depositional age of tsunami deposits is commonly constrained by the radiocarbon (¹⁴C) dating of sediments above and below the geological event. However, because of calibration curve fluctuations, the depositional age sometimes has a wide error range. In this study, we conducted millimeter-scale high-resolution radiocarbon measurements of tsunami deposits at Urahoro in southern Hokkaido, Japan. The site faces the Pacific Ocean along the Kuril Trench. Eight event deposits were identified within peat at this site. We took sequential measurements for ¹⁴C dating using bulk peat samples. The results were validated based on comparison with the absolute and radiometric ages of tephra layers. Dating results were further constrained by stratigraphic order using statistical methods. We constrained the depositional age of the paleotsunami deposits better using this method than we did when using conventional methods. We proposed an efficient measurement strategy with respect to the radiocarbon calibration curve. This method is also applicable for other deposits formed by any natural hazard if bulk peat is obtainable so it can contribute to better hazard assessment worldwide.     

Banda Sea surface-layer divergence

Sea-surface temperature (SST) within the Banda Sea varies from a low of 26.5 °C in August to a high of 29.5 °C in December and May. Ekman upwelling reaches a maximum in May and June of approximately 2.5 Sv (Sv=10⁶ m³ s^?1) with Ekman downwelling at a maximum in February of approximately 1.0 Sv. The Ekman pumping annual average is 0.75 Sv upwelling. During the upwelling period, from April through December the average Ekman upwelling velocity is 2.36 × 10^?6 m s^?1 (1.27 Sv). ENSO modulation is generally within 0.5 Sv of the mean Ekman curve, with weaker (stronger) July to October upwelling during El Niño (La Niña). Combined TOPEX/POSEIDON and ERS 1993–1999 altimeter data reveal a 33 cm maximum range of sea level. Steric effects are minor, with well over 80% of the sea level change due to mass divergence (some bias due to unresolved tidal aliasing may still be present). The annual and interannual sea level behavior follows the monsoonal and ENSO phenomena, respectively. Lower (higher) sea level occurs in the southeast (northwest) monsoon and during El Niño (La Niña) events. The surface-layer volume anomaly and the surface-layer divergence, assuming a two-layer ocean, are estimated. Maximum divergence is attained during the transitional monsoon months of October/November: 1.7 Sv gain (convergence), with matching loss (divergence) in the April/May. During the El Niño growth period of 1997 the surface layer is divergent, but in 1998 when the El Niño was on the wane, the average rate of change is convergent. Surface-layer divergence attains values as high as 4 Sv. Banda Sea surface-water divergence correlates reasonably well with the 3-month lagged export of surface (upper 100?m) water into the Indian Ocean as estimated by a shallow pressure gauge array. It is concluded that the Banda Sea surface-layer divergence influences the timing and transport profile of the Indonesian throughflow export into the Indian Ocean, as proposed by Wyrtki in 1958, and that satellite altimetry may serve as an effective means of monitoring this phenomena.     

Carbon isotopic compositions of Recent planktonic foraminifera of the Indian Ocean

Carbon and oxygen isotopic determinations have been made of 29 species of Recent Indian Ocean planktonic foraminifera. Fourteen core-top samples were used and as many as 18 species were chosen from a single core-top sample. The δ¹³C of the foraminifera was compared with that of total dissolved CO₂ (ΣCO₂) and of calcite precipitated in isotopic equilibrium with ΣCO₂. The foraminiferal calcite is always at least 1.2‰ less than the value estimated for equilibrium calcite. This carbon isotopic disequilibrium suggests the partial utilization of¹³C-depleted metabolic CO₂. The calcite tests of several species, however, have δ¹³C values which are similar to the δ¹³C of ΣCO₂ in seawater. This relationship suggests that important paleohydrographic information may be obtained from carbon isotope records based on analyses of several foraminiferal species from single deep-sea sediment samples.     

Distribution of <Superscript>226</Superscript>Ra in the Arctic Ocean and the Bering Sea and its hydrologic implications

Radium-226 (²²⁶Ra) activities were measured in the surface water samples collected from the Arctic Ocean and the Bering Sea during the First Chinese National Arctic Research Expedition. The results showed that ²²⁶Ra concentrations in the surface water ranged from 0.28 to 1.56 Bq/m³ with an average of 0.76 Bq/m³ in the Arctic Ocean, and from 0.25 to 1.26 Bq/m³ with an average of 0.71 Bq/m³ in the Bering Sea. The values were obviously lower than those from open oceans in middle and low latitudes, indicating that the study area may be partly influenced by sea ice meltwater. In the Bering Sea, ²²⁶Ra in the surface water decreased northward, probably as a result of the exchange between the ²²⁶Ra-deficient sea ice meltwater and the ²²⁶Ra-rich Pacific water. In the Arctic Ocean, ²²⁶Ra in the surface water increased northward and eastward. This spatial distribution of ²²⁶Ra reflected the variation of the ²²⁶Ra-enriched river component in the water mass of the Arctic Ocean. The vertical profiles of ²²⁶Ra in the Canadian Basin showed a concentration maximum at 200 m, which could be attributed to the inputs of the Pacific water or/and the bottom shelf water with high ²²⁶Ra concentration. This conclusion was consistent with the results from ²H, ¹⁸O tracers.     

Hydroclimatic influence of large‐scale circulation on the variability of reservoir inflow

In this study, the nature of basin‐scale hydroclimatic association for Indian subcontinent is investigated. It is found that, the large‐scale circulation information from Indian Ocean is also equally important in addition to the El Niño‐Southern Oscillation (ENSO), owing to the geographical location of Indian subcontinent. The hydroclimatic association of the variation of monsoon inflow into the Hirakud reservoir in India is investigated using ENSO and EQUatorial INdian Ocean Oscillation (EQUINOO, the atmospheric part of Indian Ocean Dipole mode) as the large‐scale circulation information from tropical Pacific Ocean and Indian Ocean regions respectively. Individual associations of ENSO & EQUINOO indices with inflow into Hirakud reservoir are also assessed and found to be weak. However, the association of inflows into Hirakud reservoir with the composite index (CI) of ENSO and EQUINOO is quite strong. Thus, the large‐scale circulation information from Indian Ocean is also important apart form the ENSO. The potential of the combined information of ENSO and EQUINOO for predicting the inflows during monsoon is also investigated with promising results. The results of this study will be helpful to water resources managers due to fact that the nature of monsoon inflow is becoming available as an early prediction. Copyright © 2009 John Wiley & Sons, Ltd.     

Air–sea interface fluxes over the Indian Ocean during INDOEX,IFP-99

The Intensive Field Phase of Indian Ocean Experiment (INDOEX, IFP-99) was carried onboard Oceanic Research Vessel Sagar Kanya during January 20–March 12, 1999 over the latitudinal range 15°N–20°S and the longitudinal range 63°E–77°E. The present study deals with the spatial variation of air–sea fluxes over the Indian Ocean during the INDOEX, IFP-99 campaign. Drag coefficient (C_D), and sensible heat (C_H) and water vapor (C_E) exchange coefficients are determined using an iterative scheme. The estimated values of these coefficients are utilized for the computation of air–sea fluxes using the bulk aerodynamic method. The variations of air–sea flux estimates are studied with respect to the variation of wind speed.     

Seasonal radiocarbon reservoir ages for the 17th century James River,Virginia estuary

This study utilizes a combined stable isotope and ¹⁴C dating approach to determine the radiocarbon reservoir age correction, ΔR, for the James River, Virginia estuary from 17th century Crassostrea virginica shells of known collection dates. ΔR, which can vary spatially and temporally, is a locality-specific adjustment applied to the global ocean reservoir, R, to further account for the offset between the atmospheric and marine ¹⁴C calibration curves. To assess the temporal variability in ΔR, continuous δ¹⁸O sampling along the oyster shell hinge provides a seasonal record throughout the oyster's life. This is then used to identify sampling locations for ¹⁴C measurements based on calcite precipitated during the Summer (>19 °C) and Fall through Spring (F-Sp, <15 °C) months. The resulting seasonal ΔR values range from −151 ± 46 to +109 ± 55 ¹⁴C years (260 years) due to changes in the contribution and age of dissolved inorganic carbon (DIC) from marine and freshwater sources in the James River estuary. The F-Sp samples display a larger ΔR range than the Summer samples, as do the shells precipitated during drought conditions (1606–1612) when compared to shells from the remainder of the 17th century. The largest intrashell ΔR variability, 195 ¹⁴C years, is similarly found in a drought shell and is attributed to variability caused by the extreme regional 1606–1612 drought. Early land use changes related to European development and farming practices also altered the age of DIC in the James River estuary. We estimate that the soil inorganic carbon (SIC) contributing to freshwater DIC ranged from 0 to ∼1800 years old and reflected both the drought and land use changes that occurred during the 17th century. Using only the Summer samples, which represent the majority of shell calcite, we obtain a mean ΔR = −32 ± 11 ¹⁴C years (1σ) for 17th century James River estuary ΔR at the very onset of European colonization. Employing a seasonally resolved sampling method will provide the greatest constraint on ¹⁴C measurements in an estuarine environment where multiple carbon sources can fluctuate on seasonal timescales and as a result of large scale environmental change.     

He and Ne isotopes in oceanic crust: implications for noble gas recycling in the mantle

In an attempt to determine the helium and neon isotopic composition of the lower oceanic crust, we report new noble gas measurements on 11 million year old gabbros from Ocean Drilling Program site 735B in the Indian Ocean. The nine whole rock samples analyzed came from 20 to 500 m depth below the seafloor. Helium contents vary from 3.3×10⁻¹⁰ to 2.5×10⁻⁷ ccSTP/g by crushing and from 5.4×10⁻⁸ to 2.4×10⁻⁷ ccSTP/g by melting. ³He/⁴He ratios vary between 2.2 and 8.6 Ra by crushing and between 2.9 and 8.2 by melting. The highest R/Ra ratios are similar to the mean mid-ocean ridge basalt (MORB) ratio of 8±1. The lower values are attributed to radiogenic helium from in situ α-particle production during uranium and thorium decay. Neon isotopic ratios are similar to atmospheric ratios, reflecting a significant seawater circulation in the upper 500 m of exposed crust at this site. MORB-like neon, with elevated ²⁰Ne/²²Ne and ²¹Ne/²²Ne ratios, was found in some high temperature steps of heating experiments, but with very small anomalies compared to air. These first results from the lower oceanic crust indicate that subducted lower oceanic crust has an atmospheric ²⁰Ne/²²Ne ratio. Most of this neon must be removed during the subduction process, if the ocean crust is to be recirculated in the upper mantle, otherwise this atmospheric neon will overwhelm the upper mantle neon budget. Similarly, the high (U+Th)/³He ratio of these crustal gabbros will generate very radiogenic ⁴He/³He ratios on a 100 Ma time scale, so lower oceanic crust cannot be recycled into either MORB or oceanic island basalt without some form of processing.     

The 26 December 2004 Sumatra Tsunami: Analysis of Tide Gauge Data from the World Ocean Part 1. Indian Ocean and South Africa

The M_w = 9.3 megathrust earthquake of December 26, 2004 off the northwest coast of Sumatra in the Indian Ocean generated a catastrophic tsunami that was recorded by a large number of tide gauges throughout the World Ocean. Part 1 of our study of this event examines tide gauge measurements from the Indian Ocean region, at sites located from a few hundred to several thousand kilometers from the source area. Statistical characteristics of the tsunami waves, including wave height, duration, and arrival time, are determined, along with spectral properties of the tsunami records.