Incorporation of U,Pb and Rare Earth Elements in Calcite through Crystallisation from Amorphous Calcium Carbonate: Simple Preparation of Reference Materials for Microanalysis

Uncertainty for elemental and isotopic measurements in calcite by LA‐ICP‐MS is largely controlled by the homogeneity of the reference materials (RMs) used for calibration and validation. In order to produce calcite RMs with homogeneous elemental and isotopic compositions, we incorporated elements including U, Pb and rare earth elements into calcite through heat‐ and pressure‐induced crystallisation from amorphous calcium carbonate that was precipitated from element‐doped reagent solution. X‐ray absorption spectra showed that U was present as U(VI) in the synthesised calcite, probably with a different local structure from that of aqueous uranyl ions. The uptake rate of U by our calcite was higher in comparison with synthetic calcite of previous studies. Variations of element mass fractions in the calcite were better than 12% 2RSD, mostly within 7%. The ²⁰⁷Pb/²⁰⁶Pb ratio in the calcite showed < 1% variations, while the ²³⁸U/²⁰⁶Pb ratio showed 3–24% variations depending on element mass fractions. Using the synthetic calcite as primary RMs, we could date a natural calcite RM, WC‐1, with analytical uncertainty as low as < 3%. The method presented can be useful to produce calcite with controlled and homogeneous element mass fractions and is a promising alternative to natural calcite RMs for U‐Pb geochronology.     

Sequence Stratigraphy of the Jurassic Coal Measures in Northwestern China

The sequence stratigraphy of the Jurassic coal measures of northwestern China has been studied based on data from outcrop and borehole sections. Because of the geological background and the diversity of basin types, such as isochronisms of coal seams and recognition of key sequence boundaries, it is rare to summarize and correlate sequence structure and framework. The types and recognition characteristics of the sequence boundaries of the Jurassic coal measures are revealed by comparing climatic characteristics, structural styles and the base level cycle. A total of five third-order sequences and 15 systems tracts have been subdivided and the sequence stratigraphic framework has been reconstructed confirming that the thick coals accumulated in the late stage of transgression system tracts of sequence I (SQ I) and sequence III (SQ III). This idea is of important academic significance for instructing coal resources exploration, and enhancing geological effects of prospecting engineering. It is also of practical significance for guaranteeing construction of the large-scale coal production base in northwestern China, accelerating the westward development of the coal industry stratagem.     

Zircon U–Pb geochronology of lower crust and quartzo-feldspathic clastic sediments from the Balagne ophiolite (Corsica)

The Balagne ophiolite from central-northern Corsica represents a continent-near paleogeographic domain of the Jurassic Liguria-Piedmont ophiolitic basin. Pillow and massive basalt lavas are primarily associated with Middle–Upper Jurassic pelagic sediments (mostly radiolarites at their base), continental-derived quartzo-feldspathic clastic sediments and ophiolitic breccias containing clasts of gabbros and basalts. The basalt-sedimentary succession is tectonically associated with a slice composed of an intrusive sequence overlain by basalt lavas. A “plagiogranite” from the intrusive sequence was dated by U–Pb zircon geochronology. Although affected by some uncertainty, mainly reflecting common Pb contamination, the U–Pb zircon data suggest a crystallization age of 159 ± 3 Ma (MSWD = 6.3), which is coeval with the formation of oceanic lower crust in the Schistes Lustrés units from Alpine Corsica. The predominance of quartz grains preserving typical volcanic shape, the prevalence of prismatic zircons and the arkose whole-rock composition indicate that the continental-derived quartzo-feldspathic clastic sediments have a low degree of textural maturity. U–Pb zircon geochronology carried out on two distinct levels of quartzo-feldspathic clastic sediments identified the predominance of zircons with within error U–Pb dates at ~280 Ma; minor components at ~457, ~309 and ~262 Ma were also obtained. The U–Pb date distribution is consistent with a source magmatic material mostly developed during the Variscan orogenic collapse.     

Discrimination between wave‐ravinement surfaces and bedset boundaries in Pliocene shallow‐marine deposits,Crotone Basin,southern Italy: An integrated sedimentological,micropalaeontological and mineralogical approach

The lower Pliocene Belvedere Formation, cropping out in the Crotone Basin, southern Italy, exhibits a metre‐scale to decametre‐scale shallow‐marine cyclicity that shares features of both high‐frequency sequences linked to shoreline shifts and controlled by minor relative sea‐level and/or sediment supply changes, and sedimentological cycles unrelated to shoreline shifts. In order to better understand the high‐frequency sequence stratigraphic framework of this succession, an integration of sedimentological, micropalaeontological (micro‐foraminifera assemblages) and mineralogical (heavy mineral abundance) data is used. From a sedimentological/stratigraphic point of view, wave‐ravinement surfaces bounding high‐frequency sequences, and associated substrate‐controlled ichnofacies, are prominent in outcrop and document environmental and water‐depth changes, whereas bedset boundaries separating sedimentological cycles have a more subtle field appearance and are only associated with changes of environmental energy. Moreover, condensed deposits are present only above wave‐ravinement surfaces, and the high‐frequency sequences bounded by these surfaces have a thickness that is an order of magnitude greater than that of the bedsets. Micro‐foraminifera assemblages may change, and the content of heavy minerals usually increases, across wave‐ravinement surfaces, whereas both parameters do not change significantly across bedset boundaries. The abundance of heavy minerals is systematically higher, with respect to the underlying and overlying deposits, in the condensed shell beds that overlie wave‐ravinement surfaces. An integrated sedimentological, micropalaeontological and mineralogical approach represents a powerful tool to discriminate between wave‐ravinement surfaces bounding high‐frequency sequences and bedset boundaries, and in general to investigate at the intra high‐frequency sequence scale. This integrated approach is expected to be very useful in the study of potentially all shallow‐marine successions composed of small‐scale cycles, in order to delineate a detailed sequence stratigraphic framework and understand the factors that controlled the cyclicity.     

浙江丽水地区磨石山群火山岩时代归属

为查明浙江丽水地区中生代磨石山群火山岩的时代,在区域地质调查、火山机构划分的基础上,选择该群代表性火山岩进行锆石年龄测定。结果表明,大爽组底部流纹质晶屑熔结凝灰岩的 SHRIMP 锆石 U‐Pb 年龄为154.9±5.5 Ma 、LA‐ICP‐MS 锆石 U‐Pb 加权平均年龄为152.0±7.0 Ma ,属晚侏罗世基默里奇阶;高坞组流纹质晶屑熔结凝灰岩 SHRIMP 锆石 U‐Pb 年龄为131.6±2.7 Ma ,两个火山机构的西山头组流纹质晶屑凝灰岩 LA‐ICP‐MS 锆石 U‐Pb 加权平均年龄分别为128.6±1.7 Ma 和139.5±2.5 Ma 。认为浙南磨石山群火山岩时代:大爽组为晚侏罗世,高坞组、西山头组、茶湾组和九里坪组为早白垩世。     

宁东煤田中侏罗纪延安组层序地层测井响应特征

以钻井、测井资料为基础,以高分辨率层序地层学为指导,通过层序界面和层序地层的测井响应特征研究,对宁东煤田中侏罗纪延安组含煤岩系进行了精细划分与对比。结果表明,宁东煤田中侏罗纪延安组层序地层界面位于测井曲线基值发生明显改变的转折点上,大型河道冲刷面、湖泛面以及进积（加积）与退积的相互转换面也是层序界面的发育位置;层序地层的测井响应特征中,进积类型测井曲线呈现漏斗型,退积类型测井曲线呈现钟形,加积类型测井曲线呈现箱型：宁夏宁东煤田中侏罗纪延安组可以识别出3个三级层序,共识别出9个层序组,并可进一步详细划分为9个四级层序。     

Detrital zircon geochronology analysis of the Late Mesozoic deposition in the Turpan‐Hami basin: Implications for the uplift history of the Eastern Tian Shan,north‐western China

Analysing the provenance changes of synorogenic sediments in the Turpan‐Hami basin by detrital zircon geochronology is an efficient tool to examine the uplift and erosion history of the easternmost Tian Shan. We present detrital zircon U‐Pb analysis from nine samples that were collected within marginal lacustrine Middle‐Late Jurassic and aeolian‐fluvial Early Cretaceous strata in the basin. Middle‐Early Jurassic (159–172 Ma) zircons deriving from the southern Junggar dominated the Middle Jurassic sample from the western Turpan‐Hami basin, whereas Permian‐Carboniferous (270–330 Ma) zircons from the Bogda mountains were dominant in the Late Jurassic to Early Cretaceous samples. Devonian‐Silurian (400–420 Ma) and Triassic (235–259 Ma) zircons from the Jueluotage and Harlik mountains constituted the subordinate age groups in the Late Jurassic and Early Cretaceous samples from the eastern basin respectively. These provenance transitions provide evidence for uplift of the Bogda mountains in the Late Jurassic and the Harlik mountains since the Early Cretaceous.     

Assessing volcanic origins within detrital zircon populations——A case study from the Mesozoic non-volcanic margin of southern Australia

Detrital zircon U/Pb geochronology is a common tool used to resolve stratigraphic questions,inform basin evolution and constrain regional geological histories.In favourable circumstances,detrital zircon populations can contain a concomitant volcanic contribution that provides constraints on the age of deposition.However,for non-volcanic settings,proving isolated detrital zircon grains are from contemporaneous and potentially remote volcanism is challenging.Here we use same grain(U-Th)/He thermochronology coupled with U/Pb geochronology to identify detrital zircon grains of contemporary volcanic origin.(U-Th)/He ages from Cretaceous zircon grains in southern Australia define a single population with a weighted mean age of 104±6.1 Ma.indistinguishable from zircon U/Pb geochronology and palynology(～104.0-107.5 Ma).Detrital zircon trace-element geochemistry is consistent with a continental signature for parent rocks and coupled with detrital grain ages,supports derivation from a2000 km distant early-to mid-Cretaceous Whitsunday Volcanic Province in eastern Australia.Thus,integration of biostratigraphy,single-grain zircon double-dating(geochronology and thermochronology)and grain geochemistry enhances fingerprinting of zircon source region and transport history.A distal volcanic source and rapid continental-scale transport to southern Australia is supported here.     

Early Paleozoic Magmatism and Gold Mineralization in the Northern Aitun, NW China

Abstract This paper discusses the relationships between granitic magmatism and gold mineralization and the exhumation history of the Dapinggou gold deposit in northern Altun, NW China based on the geochronological data, including zircon U‐Pb ages, Rb‐Sr isochron age and ⁴⁰Ar‐³⁹Ar dating and MDD modeling data. The main granitic magmatism age in this area is attained from the ID TIMS U‐Pb geochronology of zircons from the Kuoshibulak granite, the biggest granite in the northern Altun area, which gives a concordant age of 443±5 Ma in the Late Ordovician. Zircon ID TIMS U‐Pb geochronology of the West Dapinggou biotite granite west of the Dapinggou gold deposit gives concordant ages around 485±10 Ma, representing the early stage of Ordovician magmatism. The Rb‐Sr isochron age (487±21 Ma) of 6 quartz inclusion samples from quartz veins in this gold deposit is very close to that of the West Dapinggou granite. MDD modeling of step heating ⁴⁰Ar‐³⁹Ar data of K‐feldspar from the same West Dapinggou biotite granite gives a rapid cooling history from 300°C to 150°C during 200–185 Ma. According to the age data and the geological setting of this area, we conclude that the Dapinggou gold deposit was formed at the early stage of the Early Paleozoic granitic magmatism in northern Altun, and exhumed in the Early Jurassic due to the normal faulting of the Lapeiquan detachment. The Early Paleozoic magmatism may provide heat source and produce geological fluids, which are very important for gold mineralization. Exhumation in the Mesozoic caused the uplift of the deposit towards the ground surface.     

The complex diagenetic history of discontinuities in shallow‐marine carbonate rocks: New insights from high‐resolution ion microprobe investigation of δ18O and δ13C of early cements

Sedimentary gaps are a major obstacle in the reconstruction of a carbonate platform's history. In order to improve the understanding of the early diagenesis and the succession of events occurring during the formation of discontinuity surfaces in limestones, secondary ion mass spectrometry was used for the first time to measure the δ ¹⁸O and δ ¹³C signatures of 11 early cement and fabric stages in several discontinuity surfaces from the Jurassic carbonate platform of the Paris Basin, France. Pendant cements show a high variability in δ ¹⁸O, which was impossible to detect by the less precise microdrilling method. The morphology of a given cement can be produced in various environments, and dogtooth cements especially can precipitate in marine phreatic and meteoric phreatic to vadose environments. Marine dogtooth cements and micritic microbially induced fabrics precipitated directly as low‐magnesium calcite in marine waters, as attested to by the preservation of their initial δ ¹⁸O and δ ¹³C signals. Five discontinuity types are recognized based on high‐resolution geochemical analyses, and their palaeoenvironmental history can be reconstructed. Two exposure surfaces with non‐ferroan pendant or meniscus cements formed in the oxidizing vadose zone. A hardground displays marine fibrous cements and non‐ferroan dogtooth cements that formed in a subtidal environment in oxidizing water. Two composite surfaces have undergone both marine and subaerial lithification. Composite surface 1 displays non‐luminescent ferroan dogtooth cements that precipitated in reduced conditions in seawater, followed by brown‐luminescent dogtooth cements characteristic of a meteoric phreatic environment. Composite surface 2 exhibits microbially induced fabrics that formed in marine water with abundant organic matter. The latter discontinuity, initially formed in a subtidal environment, was subsequently exposed to meteoric conditions, as evidenced by ferroan geopetal cements. A high‐resolution ion microprobe study is essential to precisely document the successive diagenetic environments that have affected carbonate rocks and discontinuities with a polygenic and intricate history.     

SYN-SEDIMENTARY MARINE LITHIFICATION OF MIDDLE JURASSIC LIMESTONES IN THE PARIS BASIN

SUMMARY
Bored surfaces in Middle Jurassic limestones in northeastern France indicate syn-sedimentary lithification. The sedimentary structures and textures, and age relationships between the bored carbonates and the argillaceous sediments above them suggest that the lithification has occurred in both submarine and intertidal environments. The diagenetic fabrics which have resulted from this early marine lithification include three types of calcite druse, echinoderm overgrowths, and microcrystalline cements. Most of these cements are comparable with those forming today in inter- and subtidal environments of the Persian Gulf.
The localization of bored surfaces ("hard grounds") at the tops of regressive carbonate sequences is interpreted as being the result of slow carbonate sedimentation and lithification of the Jurassic sea-floor prior to the onset of argillaceous colder, or deeper-water sedimentation.     

Stratigraphy and Geochronology of Vertebrate Fossil‐Bearing Jurassic Strata from Linglongta,Jianchang County,Western Liaoning,Northeastern China

Northeastern China contains widely distributed Jurassic terrestrial strata that have yielded many spectacular mammal and pterosaur fossils, in addition to feathered dinosaur fossils and more recent discoveries from Jianchang, particularly from western Liaoning. However, the fossil-bearing stratigraphic succession, regional correlation, and age estimates of the fossils found in Jianchang County and nearby areas have been contentious. Here, we report on the vertebrate fossil-bearing Jurassic stratigraphy from Linglongta, Jianchang County, western Liaoning, including a SHRIMP U-Pb zircon date unambiguously associated with the fossil horizons. The primary goal was to determine the vertebrate fossil-bearing succession. A further aim was to provide age estimations for the fossil-bearing horizon as well as the earliest appearance of feathered dinosaurs, the eutherian–placental clade, and transitional pterosaurs. Field investigations showed that the vertebrate fossil-bearing stratigraphic succession in Jianchang County mainly consists of basal andesites overlain by rhythmic tuffs and tuffaceous lacustrine sediments, with the upper intermediate or acidic lavas interbedded with laminated more or less tuffaceous lacustrine deposits. This sequence correlates well with the Middle Jurassic Lanqi/Tiaojishan Formation in northeastern China. Detailed and accurate field observations showed that the well-preserved vertebrate fossils were buried in either the middle or the upper fine-grained laminated lacustrine deposits. Previous and current SHRIMP U-Pb zircon dates provide an age estimation of 161–159 Myr for the fossil-bearing horizon and vertebrates. This indicates that the earliest appearance of feathered dinosaurs here was more than 159 Myr ago and unquestionably older than Archaeopteryx from Germany, making these the earliest known feathered dinosaurs in the world. Furthermore, the eutherian–placental clade and the known transitional pterosaurs first emerged no later than 161 Myr. The vertebrate assemblage unearthed recently from Linglongta and neighboring areas in Jianchang County belongs to the Daohugou Biota. In addition to feathered dinosaurs, this biota was characterized by mammals, primitive pterosaurs, insects, and plants and was present in Inner Mongolia, western Liaoning, and northern Hebei in northeastern China during the Middle–Late Jurassic.     

The provenance of Western Irish Namurian Basin sedimentary strata inferred using detrital zircon U–Pb LA‐ICP‐MS geochronology

The Western Irish Namurian Basin (WINB) preserves classic examples of basin floor sequences through to slope deposits and deltaic cyclothems. Despite over 50 years of research into the WINB, its sediment provenance remains highly contested. Sedimentological arguments, including palaeocurrent vectors and palaeoslope indicators have been invoked to propose a sediment source from the NW or the west (i.e. from within Laurentia). These same indicators have been subsequently reinterpreted to reflect a southern provenance. It is not clear from sedimentological arguments alone which interpretation more accurately reflects the infilling of the WINB. Regional‐scale constraints on WINB provenance may be obtained with detrital zircon U–Pb geochronology. U–Pb LA‐ICP‐MS detrital zircon analysis was undertaken on samples from three sandstone units at different stratigraphic levels within the WINB siliciclastic sedimentary fill (Ross Formation, Tullig Sandstone, Doonlicky Sandstone). The samples are dominated by 500–700 Ma zircons, which can be correlated with Cadomian–Avalonian orogenic activity within terranes to the south of the WINB (Avalonia/Ganderia, Armorica and Iberia). In contrast, Eastern Laurentia, to the north of the WINB, was devoid of orogenic activity at this time. WINB samples also yield age populations younger than 500 Ma, and older than 700 Ma. These are not diagnostic of a particular source terrane and thus could be derived from terranes north and/or south of the WINB. WINB detrital zircon age spectra can be reconciled by an Avalonian or combined Avalonian–Laurentian provenance for WINB sedimentary strata. Further research is required in order to distinguish between these two possibilities. Copyright © 2011 John Wiley & Sons, Ltd.     

冀北承德盆地九龙山组凝灰岩夹层LA-ICP-MS锆石U-Pb定年及其地质意义

冀北承德盆地中生代侏罗纪地层序列较齐全,但作为关键层位之一的九龙山组一直缺乏高精度年代学的约束。笔者首次对九龙山组凝灰岩夹层进行了LA-ICP-MS锆石U-Pb高精度定年,获得凝灰岩中岩浆锆石²⁰⁶Pb/²³⁸U加权平均年龄164.1±1.3 Ma。综合研究及对比表明,九龙山组的时限为158~164Ma,属中侏罗世晚期至晚侏罗世早期,对应于国际地层表的牛津期至卡洛维期,其沉积时间相对短暂。在此基础上,更新了研究区侏罗系年代地层柱状图,该认识对于深入研究燕山地区中生代侏罗纪地层格架及构造岩浆演化过程具有重要意义。     

Diagenesis in the Middle Jurassic Khatatba Formation sandstones in the Shoushan Basin,northern Western Desert,Egypt

The Middle Jurassic Khatatba Formation acts as a hydrocarbon reservoir in the subsurface in the Western Desert, Egypt. This study, which is based on core samples from two exploration boreholes, describes the lithological and diagenetic characteristics of the Khatatba Formation sandstones. The sandstones are fine‐ to coarse‐grained, moderately to well‐sorted quartz arenites, deposited in fluvial channels and in a shallow‐marine setting. Diagenetic components include mechanical and chemical compaction, cementation (calcite, clay minerals, quartz overgrowths, and a minor amount of pyrite), and dissolution of calcite cements and feldspar grains. The widespread occurrence of an early calcite cement suggests that the Khatatba sandstones lost a significant amount of primary porosity at an early stage of its diagenetic history. In addition to calcite, several different cements including kaolinite and syntaxial quartz overgrowth occur as pore‐filling and pore‐lining cements. Kaolinite (largely vermicular) fills pore spaces and causes reduction in the permeability of the reservoir. Based on framework grain–cement relationships, precipitation of the early calcite cement was either accompanied by or followed the development of part of the pore‐lining and pore‐filling cements. Secondary porosity development occurred due to partial to complete dissolution of early calcite cements and feldspar. Late kaolinite clay cement occurs due to dissolved feldspar and has an impact on the reservoir quality of the Khatatba sandstones. Open hydraulic fractures also generated significant secondary porosity in sandstone reservoirs, where both fractures and dissolution took place in multiple phases during late diagenetic stages. The diagenesis and sedimentary facies help control the reservoir quality of the Khatatba sandstones. Fluvial channel sandstones have the highest porosities and permeabilities, in part because of calcite cementation, which inhibited authigenic clays or was later dissolved, creating intergranular secondary porosity. Fluvial crevasse‐splay and marine sandstones have the lowest reservoir quality because of an abundance of depositional kaolinite matrix and pervasive, shallow‐burial calcite and quartz overgrowth cements, respectively. Copyright © 2013 John Wiley & Sons, Ltd.     

Reactive transport modelling of reflux dolomitization in the Arab‐D reservoir,Ghawar field,Saudi Arabia

It has long been recognized that the Arab‐D reservoir in Ghawar field has been significantly dolomitized and that the distribution of dolomites is highly heterogeneous across this reservoir. Previous studies indicated that dolomite occurs with either a stratigraphic or non‐stratigraphic distribution; when mapped, dolomite tends to form several parallel linear trends across the field. Although stratigraphic dolomite was suggested to be formed early from highly evaporated pore fluids sourced from overlying evaporite deposits, non‐stratigraphic dolomite was thought to be generated primarily from hydrothermal fluids sourced from below. This study focuses primarily on these non‐stratigraphic dolomites, and proposes that: (i) these dolomites initially formed via seepage reflux, but were reinforced by late stage hydrothermal dolomitization; and (ii) reflux is also responsible for the formation of parallel, linear trends of dolomite. The reflux model hypothesizes that an evaporative lagoon (which is the source of dolomitizing fluids) formed during the falling stage systems tract of a depositional sequence, and that with continuing sea‐level fall this lagoon migrated progressively towards deeper parts of an intrashelf basin adjacent to the Ghawar field, leaving behind lines of dolomite bodies along a series of temporary coastlines. Two‐dimensional reactive transport models have been built to test this hypothesis, and have resulted in a predicted pattern of dolomite bodies that agrees with both the observed vertical distribution of non‐stratigraphic dolomite, as well as the mapped lateral distribution of the dolomite trends. In addition, the major ion compositions of Late Jurassic seawater are calculated based on fluid inclusion data in the literature. Using Jurassic seawater in current models leads to the absence of anhydrite cements and less potential of over‐dolomitization than using modern seawater.     

大别造山带北缘中生代地层格架厘定

大别山北麓陆相中生代地层发育 ,由于缺乏可靠生物化石证据 ,地层的划分和对比直到现在仍然存在巨大分歧 ,这制约了造山带研究的深入。根据对发现的火山岩碎屑和 K- Ar同位素年代学数据 (10 3.6— 138.3Ma)研究 ,表明凤凰山组、周公山组和毛坦厂组同属于早白垩世 ,并且可能是同期异相产物 ;覆盖在毛坦厂组之上的黑石渡组亦为早白垩世。根据地层接触关系、同位素年龄数据和岩相对比 ,三尖辅组以中侏罗世为主 ,可能跨早、晚侏罗世 ,与防虎山组和圆筒山组为同期异相。已有的石榴石重矿物分析和孢粉研究支持上述结论。地层接触关系表明白大畈组为早白垩世火山岩。     

An Important Spreading Event of the Neo‐Tethys Ocean during the Late Jurassic and Early Cretaceous: Evidence from Zircon U‐Pb SHRIMP Dating on Diabase in Nagarzê, Southern Tibet

Abstract Widely distributed in Gyangzê‐Chigu area, southern Tibet, NW‐ and nearly E‐W‐trending diabase(gabbro)‐gabbro diorite dykes are regarded as the product of the large‐scale spreading of the late Neo‐Tethys Ocean. In order to constrain the emplacement age of these dykes, zircons of two samples from diabases in Nagarzê were dated by using the U‐Pb SHRIMP method. Two nearly the same weighted mean ²⁰⁶Pb/²³⁸U ages were obtained in this paper, which are 134.9±1.8 Ma (MSWD = 0.65) and 135.5 ± 2.1 Ma (MSWD=1.40), respectively. They not only represent the crystallization age of the diabase, but also documented an important spreading event of the Neo‐Tethys Ocean during the late Jurassic and early Cretaceous. This dating result is of great significance to reconstruct the temporal framework of the late Neo‐Tethys Ocean in the Qinghai‐Tibet Plateau.     

晋东北地区侏罗纪地层划分、时代重新厘定及其地质意义

利用地层序列中火山碎屑岩、凝灰岩及其火山岩锆石U-Pb同位素测年,对晋东北地区侏罗纪地层时代进行了重新厘定。取得了以下主要认识:(1)确认宁武—静乐盆地下侏罗统永定庄组的存在;(2)宁武—静乐盆地天池河组可以与鄂尔多斯盆地安定组相对比,归属于中侏罗统;(3)浑源盆地髫髻山组应归属于中侏罗统上部,该套火山岩地层在整个燕—辽地区具有穿时性;(4)广灵盆地中侏罗统窑坡组底部厚层砾岩的沉积时代可能与燕山造山带的南大岭组相当,应该属于早侏罗世至中侏罗世早期构造运动的产物。通过地层序列的重新厘定,确认了159.0~(152.77±0.63)Ma区域角度不整合的存在,该期构造运动可能与侏罗纪东亚大陆多向汇聚产生的远程效应有关。     

Sequence stratigraphic distribution of diagenetic alterations in coal-bearing, paralic sandstones: evidence from the Rio Bonito Formation (early Permian), southern Brazil

Abstract Linking siliciclastic diagenesis to sequence stratigraphy allows a better understanding of the parameters controlling the spatial and temporal distribution of diagenetic alterations, and hence of reservoir quality. A study of the coal-bearing, alluvial, deltaic, estuarine and shallow-marine sandstones of the Rio Bonito Formation, early Permian, Paraná Basin (southern Brazil), reveals that the distribution of diagenetic alterations and of related reservoir quality evolution can be constrained within a sequence stratigraphic framework. Calcite, dolomite, siderite, kaolinite and pyrite cementation is consistently linked to sequence and parasequence boundaries, transgressive and maximum flooding surfaces and is systematically distributed within lowstand, transgressive and highstand systems tracts. Diagenesis of coal layers at parasequence boundaries has promoted the formation of stratabound calcite (detectable in resistivity wire line logs), concretionary pyrite and kaolinite and of silicate grain dissolution in sandstones located above and below these boundaries, particularly in the transgressive systems tract. Meteoric water diagenesis caused grain dissolution and the formation of kaolinite in sandstones below sequence boundaries and in lowstand systems tract sandstones. Carbonate bioclasts and low sedimentation rates in lag deposits at parasequence boundaries, transgressive and maximum flooding surfaces favoured the formation of grain-rimming siderite. The results of this study are relevant to the exploration of coal-bed methane and other coal-bearing reservoirs, where it is crucial to unravel and predict the distribution and quality of reservoirs and compartments.