Persistent organochlorine residues in sediments from the Black Sea

The extent of contamination of the Black Sea by selected organochlorine compounds has been assessed through the analysis of surficial sediments taken from throughout the region. Concentrations of HCHs at sites influenced by the Danube delta are among the highest recorded on a global basis (up to 40 ng g(-1) dry wt). The ratio between the alpha- and gamma-isomers was relatively low indicating contamination through the use of lindane. Concentrations of DDTs (0.06-72 ng g(-1) dry wt) and PCBs (0.06-72 ng g(-1) dry wt) were not especially high in comparison to levels reported from throughout the world. The DDE/DDT ratio was, however, low indicating fresh inputs and hence current usage of DDT within the Black Sea region.     

Structure of the crust in the Black Sea and adjoining regions from surface wave data

Group velocities of Rayleigh and Love waves along the paths across the Black Sea and partly Asia Minor and the Balkan Peninsula are used to estimate lateral variations of the crustal structure in the region. As a first step, lateral variations of group velocities for periods in the range 10–20 s are determined using a 2D tomography method. Since the paths are oriented predominantly in NE–SW or N–S direction, the resolution is estimated as a function of azimuth. The local dispersion curves are actually averaged over the extended areas stretched in the predominant direction of the paths. The size of the averaging area in the direction of the best resolution is approximately 200 km. As a second step, the local averaged dispersion curves are inverted to vertical sections of S-wave velocities. Since the dispersion curves in the 10–20 s period range are mostly affected by the upper crustal structure, the velocities are estimated to a depth of approximately 25 km. Velocity sections along 43° N latitude are determined separately from Rayleigh and Love wave data. It is shown that the crust under the sea contains a low-velocity sedimentary layer of 2–3 km thickness, localized in the eastern and western deeps, as found earlier from DSS data. Beneath the sedimentary layer, two layers are present with velocity values lying between those of granite and consolidated sediments. Velocities in these layers are slightly lower in the deeps, and the boundaries of the layers are lowered. S-wave velocities obtained from Love wave data are found to be larger than those from Rayleigh wave data, the difference being most pronounced in the basaltic layer. If this difference is attributed to anisotropy, the anisotropy coefficient = (SH - SV)/Smean is reasonable (2–3%) in the upper layers, and exceeds 9% in the basaltic layer.     

Hydrodynamic modelling of mesoscale eddies in the Black Sea

A three dimensional structure of mesoscale circulation in the Black Sea is simulated using the Proudman Oceanographic Laboratory Coastal Ocean Modelling System. A number of sensitivity tests reveal the response of the model to changes in the horizontal resolution, time steps, and diffusion coefficients. Three numerical grids are examined with x-fine (3.2 km), fine (6.7 km) and coarse (25 km) resolution. It is found that the coarse grid significantly overestimates the energy of the currents and is not adequate even for the study of basin-scale circulation. The x-fine grid, on the other hand, does not give significant advantages compared to the fine grid, and the latter is used for the bulk of simulations. The most adequate parameters are chosen from the sensitivity study and used to model both the basin-scale circulation and day-to-day variability of mesoscale currents for the months of May and June of 2000. The model is forced with actual wind data every 6 h and monthly climatic data for evaporation, precipitation, heat fluxes and river run-off. The results of the fine grid model are compared favourably against the satellite imagery. The model adequately reproduces the general circulation and many mesoscale features including cyclonic and anticyclonic eddies, jets and filaments in different parts of the Black Sea. The model gives a realistic geographical distribution and parameters of mesoscale currents, such as size, shape and evolution of the eddies.     

Removal of the Azo Dye Congo Red from Aqueous Solutions by the Marine Alga Porphyra yezoensis Ueda

Batch adsorption experiments were carried out using nonliving biomass of Porphyra yezoensis Ueda (red alga) for the removal of Congo red from aqueous solutions at 25°C. The effects of process parameters such as contact time, adsorbent concentration and ionic strength were investigated. The raw biomass and Congo red loaded biomass were characterized by Fourier transform infrared spectroscopy (FTIR). The pseudo first order, pseudo second order and intraparticle diffusion models were tested. The results showed that adsorption of Congo red followed pseudo second order kinetics very well. Langmuir and Freundlich equations were applied to the data related to the adsorption isotherms, and the observed maximum adsorption capacities (q_m) were 71.46 mg/g at 25°C. Adsorbent concentration and ionic strength had a marked effect on Congo red adsorption.     

Thermochronological data from Sudan in the frame of the denudational history of the Nubian Red Sea margin

Low‐temperature thermochronology provides information on the timing of rifting and denudation of passive margins, and the Red Sea with its well‐exposed, young rift margins is a suitable setting for its application. Here we present new apatite fission‐track (AFT) data from Sudan northern hinterland and Red Sea coastal areas. From the former region we obtained ages between 270 ± 2 Ma ad 253 ± 53 Ma, and from the coastal belt between 83 ± 8 Ma and 39 ± 7 Ma. These data prompted a review and comparison with low‐temperature thermochronological data from the whole Nubian Red Sea Margin, and a discussion on their implication in assessing the margin evolutionary style. AFT data are available for Egypt and Eritrea as well as apatite (U‐Th)/He (AHe) ages for two transects transversal to the margin in Eritrea. Both in Egypt and Eritrea AFT data record a cooling event at about 20–25 Ma (Early Miocene) and an earlier, more local, cooling event in Egypt at about 34 Ma (Early Oligocene). The thermal modeling of the Sudan samples provides an indication of a rapid cooling in Miocene times, but does not support nor rules out an Early Oligocene cooling phase. The re‐assessment of new and existing thermochronological data within the known geological framework of the Nubian and conjugate Arabian margins favours the hypothesis that early rifting stages were affecting the whole Gulf of Suez–Red Sea–Gulf of Aden system since the Oligocene. These precocious, more attenuated, phases were followed by major extension in Miocene times. As to the mode of margin evolution, AFT age patterns both in Egypt and Eritrea are incompatible with a downwarp model. The distribution of AHe ages across the Eritrean coastal plain suggests that there the escarpment was evolving predominantly by plateau degradation. Copyright © 2009 John Wiley & Sons, Ltd.     

Signature of ENSO Signals in the Coral Growth Rate Record of Arabian Sea and Indian Monsoons

We examine here three sets of recently published data: (1) Updated Indian Rainfall (IRF) time series of the entire country covering the time span of 1826–1994, (2) coral growth rate time series for a period of 42 years spanning 1948–1990 from the Arabian Sea, and (iii) NINO3 temperature records to investigate the signature of ENSO response of the Indian monsoon. Multiple spectral techniques (e.g., multi-taper method (MTM), maximum entropy method (MEM), wavelet and cross spectra) are used to identify the coherent cyclic and nonstationary modes in these records. MTM analysis of IRF time series resolves statistically significant variability (>90% C.I) (i) at multi-decadal (66–70 years) scales related to the well-known global temperature variability of internal atmospheric-ocean origin, (ii) relatively weak signals at 13 and 22 years (solar cycles) and (iii) the 2.5 to 7.5-year cycles associated with the ENSO frequency band. The MTM spectra of the coral growth rate record also reveal statistically significant periodicities (>90% C.I.) within 1.8–4.2 ENSO frequency band, and a relatively weak signal at 12.8 years. MEM analysis confirms the stability of above spectral peaks. Wavelet spectral analyses of the above time series reveal nonstationary localized modes of ENSO evolution corresponding to 2–7 years and higher order terms. Although matching periodicities are present in these records, cross-spectral analysis of IRF and NINO3 temperature records exhibits significant coherency (>80% CI) only at periods 5.4 years and 2.7 years, suggesting the significant role of ENSO dynamics in organizing the subtle Indian monsoon at these frequencies. These results may provide significant implication for the modeling of Indian monsoon.     

Vertical Crustal Motion along the Mediterranean and Black Sea Coast Derived from Ocean Altimetry and Tide Gauge Data

Tide gauge (TG) data along the northern Mediterranean and Black Sea coasts are compared to the sea-surface height (SSH) anomaly obtained from ocean altimetry (TOPEX/Poseidon and ERS-1/2) for a period of nine years (1993–2001). The TG measures the SSH relative to the ground whereas the altimetry does so with respect to the geocentric reference frame; therefore their difference would be in principle a vertical ground motion of the TG sites, though there are different error sources for this estimate as is discussed in the paper. In this study we estimate such vertical ground motion, for each TG site, from the slope of the SSH time series of the (non-seasonal) difference between the TG record and the altimetry measurement at a point closest to the TG. Where possible, these estimates are further compared with those derived from nearby continuous Global Positioning System (GPS) data series. These results on vertical ground motion along the Mediterranean and Black Sea coasts provide useful source data for studying, contrasting, and constraining tectonic models of the region. For example, in the eastern coast of the Adriatic Sea and in the western coast of Greece, a general subsidence is observed which may be related to the Adriatic lithosphere subducting beneath the Eurasian plate along the Dinarides fault.     

Physical mechanisms of submesoscale eddies generation: evidences from laboratory modeling and satellite data in the Black Sea

Ocean Dynamics - The observed evidence of the implementation of three different mechanisms of the submesoscale eddies generation in the Black Sea previously studied by the field research and...     

Gravity Anomaly Map over The Black Sea Using Corrected Sea Surface Heights from ERS1, ERS2 and Topex/Poseidon Satellite Altimetry Missions

Approximately nine-year data from ERS1, ERS2 and TOPEX/POSEIDON (T/P) satellite altimetry missions have been used for the recovery of gravity anomalies over the Black Sea. The Corrected Sea Surface Height product of Aviso/Altimetry has been proven to be homogeneous after a cross-over adjustment. The Least Squares Collocation method was applied in a so-called remove-restore procedure. The residual geoid heights, obtained by subtracting EGM96 geoid heights from cross-over adjusted sea surface heights, were inverted to recover residual gravity anomalies in a grid structure over the Black Sea. Finally, EGM96 free air gravity anomalies were added to the predicted residual gravity anomalies to obtain the free air gravity anomalies. In order to check the consistency with respect to an external source, these computed free air gravity anomalies were compared to ship gravity observations, and to alternative satellite altimetry derived gravity anomalies. Comparisons with the observed gravity data yielded that external consistency of the gravity anomalies computed in this study is about 3 mGal for individual ship tracks. Overall external consistency in the test area is 4.8 mGal. Comparison with other satellite altimetry derived gravity anomalies presented a good agreement.     

Sea Surface Salinity Observations from Space with the SMOS Satellite: A New Means to Monitor the Marine Branch of the Water Cycle

While it is well known that the ocean is one of the most important component of the climate system, with a heat capacity 1,100 times greater than the atmosphere, the ocean is also the primary reservoir for freshwater transport to the atmosphere and largest component of the global water cycle. Two new satellite sensors, the ESA Soil Moisture and Ocean Salinity (SMOS) and the NASA Aquarius SAC-D missions, are now providing the first space-borne measurements of the sea surface salinity (SSS). In this paper, we present examples demonstrating how SMOS-derived SSS data are being used to better characterize key land–ocean and atmosphere–ocean interaction processes that occur within the marine hydrological cycle. In particular, SMOS with its ocean mapping capability provides observations across the world’s largest tropical ocean fresh pool regions, and we discuss from intraseasonal to interannual precipitation impacts as well as large-scale river runoff from the Amazon–Orinoco and Congo rivers and its offshore advection. Synergistic multi-satellite analyses of these new surface salinity data sets combined with sea surface temperature, dynamical height and currents from altimetry, surface wind, ocean color, rainfall estimates, and in situ observations are shown to yield new freshwater budget insight. Finally, SSS observations from the SMOS and Aquarius/SAC-D sensors are combined to examine the response of the upper ocean to tropical cyclone passage including the potential role that a freshwater-induced upper ocean barrier layer may play in modulating surface cooling and enthalpy flux in tropical cyclone track regions.     

Contribution of satellite altimetry data in the geophysical investigation of the Red Sea Region, Egypt

Successful development of geodetic satellite missions has aroused new interest in determining global and regional gravity field based on satellite data. Satellite altimetry data enable direct determination of the geoid over sea regions. In Egypt, where land and marine geophysical data are inadequate because of rough topography and economic reasons, the use of satellite altimetry data is of special importance. The northern Red Sea region has been selected as a site for case study of the current research, after applying spectral analysis to reveal near-surface structure, the residual geoid of the studied region shows a good correlation with the known geologic features. Moreover, satellite-based gravity data enhance small-scale features and agrees well with land and marine gravity data. Thus, geoid undulation and satellite gravity data can be a complementary source of data to determine near-surface and deep structures.     

Geochronological reconstruction of Cs transport from the Coruh river to the SE Black Sea: comparative assessment of radionuclide retention in the mountainous catchment area

The deposition record of ¹³⁷Cs was traced in the SE Black Sea sediments adjacent to the Coruh river mouth in comparison with the earlier studied chronology of ¹³⁷Cs deposition in front of the Danube delta (NW Black Sea). In both cases, the ¹³⁷Cs profiles showed two subsurface peaks attributable to maximum fallout of ‘bomb’ and Chernobyl radionuclides. The Coruh profile revealed a larger contribution of ‘bomb’ ¹³⁷Cs in comparison with the Chernobyl input, suggesting different coverage of NW and SE Black Sea regions with the Chernobyl fallout. The ¹³⁷Cs-derived dating showed that maximum deposition of particulate bound ¹³⁷Cs in sediments adjacent to the Coruh river mouth was delayed for 14 yr relative to date of Chernobyl accident, reflecting a buffer effect of the watershed soils. This transit time is 3 times longer than in the Danube catchment area, indicating a difference in retention processes in these mountainous (Coruh) and lowland (Danube) river basins. The ¹³⁷Cs profile in Coruh sediments showed penetration of ¹³⁷Cs to much greater depth than would be expected from ¹³⁷Cs fallout chronology, suggesting the sediment mixing rate of 1.3 cm² yr⁻¹. This value was used to evaluate deposition chronology of ¹³⁷Cs, applying the model developed for pulse fallout case. Comparing the measured and modelled data has allowed differentiation of the flood-induced discharge of the ¹³⁷Cs-containing suspended matter and the slower transit of eroded soil particles from the contaminated catchment areas. The obtained results may be used for the prediction of period when the pollutants, deposited over the river basins, can reach the Black Sea.     

Estimation of evaporation from the Dead Sea

A project to link the Dead Sea to the Red Sea via a canal is undergoing extensive study. As part of this study, a method to estimate evaporation from the Dead Sea is required as it is a hypersaline lake in which standard methods cannot be applied. Two methods based on Penman and Dalton formulae were examined. The method derived here is a modified Penman model that estimates the evaporation as a function of salinity, humidity, air temperature and wind speed. Other parameters such as water temperature are included implicitly in the model. The results obtained were verified as satisfactory agreement was achieved by comparison with previous measurements. A short‐cut relationship to estimate evaporation as a function of salinity only was also derived. Copyright © 1999 John Wiley & Sons, Ltd.     

Mass-induced sea level variations in the Red Sea from GRACE,steric-corrected altimetry,in situ bottom pressure records,and hydrographic observations

An annual amplitude of ∼18 cm mass-induced sea level variations (SLV) in the Red Sea is detected from the Gravity Recovery and Climate Experiment (GRACE) satellites and steric-corrected altimetry from 2003 to 2011. The annual mass variations in the region dominate the mean SLV, and generally reach maximum in late January/early February. The annual steric component of the mean SLV is relatively small (<3 cm) and out of phase of the mass-induced SLV. In situ bottom pressure records at the eastern coast of the Red Sea validate the high mass variability observed by steric-corrected altimetry and GRACE. In addition, the horizontal water mass flux of the Red Sea estimated from GRACE and steric-corrected altimetry is validated by hydrographic observations.     

Formation and Evolution of the Anaerobic Zone in the Black Sea from the Most Recent Salinization to the Present State: Retrospective Estimation Based on Mathematical Modeling

It is established that the formation and evolution of the anaerobic zone of the Black Sea are associated with the beginning and development of the most recent salinization of the sea and the formation of pycnocline at intermediate depths; a deterioration of deep-water aeration and the formation of anaerobic conditions in deeper layers; the rate of sulfate-reduction first in the near-bed layer and later, as oxygen is depleted, in the water mass. Formalization of these processes based on refined present-day data on water balance enabled the reproduction of profiles of water salinity and vertical-exchange coefficient for different formation stages of salinity regime in the Black Sea. The vertical distribution of oxygen and hydrogen sulfide is reconstructed, and the rates of oxygen consumption in water column and sulfate reduction in the near-bed layer and at the upper boundary of the anaerobic zone are evaluated in numerical experiments. The obtained data show the transformation of the vertical distribution of oxygen and hydrogen sulfide in the Black Sea from the beginning of its most recent salinization to the present-day state. It is shown that the anaerobic zone rises from 2000 to 200 m within 500–600 years (in the period 3.9–4.5 Ka from the beginning of water exchange through the Bosphorus), and next the upper boundary of the anaerobic zone slowly ascends up to its present-day position (130–180 m). Mathematical modeling was used to evaluate the fluxes of oxygen and hydrogen sulfide at different formation stages of the anaerobic zone in the sea.__________Translated from Vodnye Resursy, Vol. 32, No. 3, 2005, pp. 307–321.Original Russian Text Copyright © 2005 by Leonov, Shaporenko.     

Wave Energy from the North Sea: Experiences from the Lysekil Research Site

This paper provides a status update on the development of the Swedish wave energy research area located close to Lysekil on the Swedish West coast. The Lysekil project is run by the Centre for Renewable Electric Energy Conversion at Uppsala University. The project was started in 2004 and currently has permission to run until the end of 2013. During this time period 10 grid-connected wave energy converters, 30 buoys for studies on environmental impact, and a surveillance tower for monitoring the interaction between waves and converters will be installed and studied. To date the research area holds one complete wave energy converter connected to a measuring station on shore via a sea cable, a Wave Rider? buoy for wave measurements, 25 buoys for studies on environmental impact, and a surveillance tower. The wave energy converter is based on a linear synchronous generator which is placed on the sea bed and driven by a heaving point absorber at the ocean surface. The converter is directly driven, i.e. it has no gearbox or other mechanical or hydraulic conversion system. This results in a simple and robust mechanical system, but also in a somewhat more complicated electrical system.