A Method for Predicting Chloride Concentrations in Leachate at Natural Attenuation Landfills in the Precambrian Shield Regions of Ontario, Canada

Natural attenuation landfill sites continue to be the preferred method of domestic waste disposal in the Precambrian Shield regions of Ontario due to economic factors. The main challenge in siting these landfills is ensuring that there will be no adverse impact on off-site water resources. Impact risk assessments are generally based on estimated volumes and strengths of chloride in the leachate. While volumes can be estimated using simple water balances, peak chloride concentration predictions are based on judgment and are quite variable. Since design chloride strengths dictate the size of the required attenuation zone, overestimating concentrations will typically make it impossible to find a suitable site, while underestimating concentrations increases the potential for adverse off-site impacts occurring.
Hydrogeological data from active and closed landfills in the Precambrian Shield region were collected to help develop a reliable method of predicting peak chloride concentrations in leachate. This study focused on 21 sites located on relatively permeable sandy soils since landfills underlain by low permeability clayey soils retain leachate similar to lined facilities.
Linear regression analyses were conducted to determine if source chloride concentrations at the "sand" sites are significantly influenced by waste thickness, fill area, waste volume, waste deposition rate, hydraulic conductivity, upgradient flow length, depth to the water table, and moisture surplus.
A strong relationship (R = 0.957) was found to exist between source chloride concentrations and waste volume. This empirical volume versus chloride regression equation can be used as the basis for establishing design chloride concentrations at new natural attenuation landfills developed over sandy soils in the Precambrian Shield regions of Ontario. An alternative risk assessment approach is required for sites developed over clay soils.     

Utilization of Shallow Geophysical Sensing at Two Abandoned Municipal/Industrial Waste Landfills on the Missouri River Floodplain

In the past 30 to 40 years, floodplain areas of large rivers, such as the Missouri River, have been extensively used for large industrial and municipal landfills. Many of these sites are now causing varying degrees of ground water contamination. Rapid geophysical characterization techniques have proven useful for delineation of anomalous areas indicative of potential contaminant plumes. These methods have also resulted in a cost effective approach to the location and number of monitoring wells.
An effective technique to initially characterize ground water contamination at such landfills along the Missouri River in northwestern Missouri involved a combination of electrical resistivity and electromagnetic conductivity methods. Resistivity was used to obtain soundings of the alluvium by using a modified Wenner array and to corroborate shallow electromagnetic conductivity measurements by using short Wenner array electrode spacings.
Upon confirmation of similar measurements of the upper soils for the two methods, numerous electromagnetic conductivity traverses were made at each landfill site. The data generated from these surveys were graphed and contoured to delineate anomalous areas. Based on the geophysical study, a ground water monitoring well network was then designed for each landfill.
As a result, a minimal number of wells were required to initially characterize the ground water quality at these two sites. In general, analysis of water samples from these wells displayed good correlation with the geophysical results.     

Assessing the Hazard of Environmental Pollution by Landfills of Industrial and Municipal Wastes

Water Resources - The environmental effect of landfills of solid municipal wastes is considered, including their effect on groundwater. The accumulation of municipal wastes causes considerable...     

Artificial Sweeteners Identify Spatial Patterns of Historic Landfill Contaminated Groundwater Discharge in an Urban Stream

Leachate-contaminated groundwater from historical municipal landfills, typically lacking engineered liners and leachate collection systems, poses a threat to nearby urban streams, particularly to benthic ecosystems. Effective monitoring and assessment of such sites requires understanding of the spatial patterns (i.e., two-dimensional footprint) of contaminated groundwater discharge and associated controlling factors. However, discharges from groundwater contaminated by modern wastewater can complicate site assessments. The objectives of this study were to (1) demonstrate the use of artificial sweeteners (AS): saccharin (SAC), cyclamate (CYC), acesulfame (ACE), and sucralose (SUC), to distinguish groundwater discharge areas influenced by historic landfill leachate (elevated SAC and sometimes CYC; low ACE and SUC concentrations) from those influenced by wastewater (high ACE and SUC concentrations), and (2) investigate contaminant discharge patterns for two gaining urban stream reaches adjacent historic landfills at base flows. Contaminant discharge patterns revealed by the AS were strongly controlled by hyporheic flow (low AS concentrations), particularly for the straight reach, and stream sinuosity, particularly for the meandering reach. These patterns were different and the contaminant footprint coverage (<25% of streambed area) much less than most past studies (typically >50% coverage), likely due to the homogeneous streambed-aquifer conditions and shallow, narrow landfill plume in this setting.     

Transport of waste leakage in stratified formations

Contaminant transport in a strongly heterogeneous stratified formation whose log hydraulic conductivity distribution has a variance greater than unity is investigated. Four kinds of waste leakage scenario are studied. They are: (1) continuous waste leakage from landfills; (2) temporal waste leakage from landfills; (3) continuous deep-well injection wastes; and (4) temporal deep-well injection wastes. Ensemble average concentrations and variances of concentration distributions are calculated for the four scenarios. The results in this paper show that when heterogeneity of a formation increases, transport in this formation differs significantly from the linear solutions which assume that the variances of log hydraulic conductivity are less than unity.     

Biogeochemical evolution of a landfill leachate plume, Norman, Oklahoma

Leachate from municipal landfills can create groundwater contaminant plumes that may last for decades to centuries. The fate of reactive contaminants in leachate-affected aquifers depends on the sustainability of biogeochemical processes affecting contaminant transport. Temporal variations in the configuration of redox zones downgradient from the Norman Landfill were studied for more than a decade. The leachate plume contained elevated concentrations of nonvolatile dissolved organic carbon (NVDOC) (up to 300 mg/L), methane (16 mg/L), ammonium (650 mg/L as N), iron (23 mg/L), chloride (1030 mg/L), and bicarbonate (4270 mg/L). Chemical and isotopic investigations along a 2D plume transect revealed consumption of solid and aqueous electron acceptors in the aquifer, depleting the natural attenuation capacity. Despite the relative recalcitrance of NVDOC to biodegradation, the center of the plume was depleted in sulfate, which reduces the long-term oxidation capacity of the leachate-affected aquifer. Ammonium and methane were attenuated in the aquifer relative to chloride by different processes: ammonium transport was retarded mainly by physical interaction with aquifer solids, whereas the methane plume was truncated largely by oxidation. Studies near plume boundaries revealed temporal variability in constituent concentrations related in part to hydrologic changes at various time scales. The upper boundary of the plume was a particularly active location where redox reactions responded to recharge events and seasonal water-table fluctuations. Accurately describing the biogeochemical processes that affect the transport of contaminants in this landfill-leachate-affected aquifer required understanding the aquifer's geologic and hydrodynamic framework.     

An integrated 3D constant offset GPR and resistivity survey on a sealed landfill — Ilhavo,NW Portugal

Owing to their nature landfills are challenging targets for high resolution Near Surface Geophysics.Herein it is described an integrated high resolution geophysical survey over the Ilhavo landfill sealed about a decade ago.The first aim of the survey is to investigate the time evolution of the contamination plume of the landfill since operations stopped and sealing took place.The second, and main objective, is the study of the landfill itself, that is, to carry out a high resolution 3D geophysical survey over it in order to investigate the thickness and effectiveness of the top cover, the thickness and sealing conditions of the landfill bottom and, finally, to investigate its internal structure.To fulfill these objectives an integrated 3D constant offset GPR and resistivity survey was designed. The interpretation of the geophysical data was carried out together with local borehole and hydrogeological information, so that, the ambiguity and uncertainty of the interpretation was reduced considerably and the usefulness of the methods were assessed.     

Natural Attenuation: A Feasible Approach to Remediation of Ground Water Pollution at Landfills?

Remediation of ground water pollution at old landfills with no engineered leachate collection system is a demanding and costly operation. It requires control of the landfill body, since the majority of the pollutants are still present in the landfilled waste for decades after the site has been closed. However removing the source is an attractive approach to managing leachate plumes. Natural attenuation has been implemented for petroleum hydrocarbon plumes and chorinated solvent plumes, primarily in the United States. Natural attenuation has not yet gained a foothold with respect to leachate plumes, however. Based on the experience gained from 10 years of research on two Danish landfills, it is suggested that natural attenuation is a feasible approach but is more complicated and demanding than in the case of petroleum hydrocarbons and chlorinated solvent.     

西安北动车段垃圾填埋场地基处理措施研究

随着城市化进程的加快,建筑用地日趋紧张,将垃圾填埋场作为工程场址愈发寻常。为探讨垃圾填埋场各类土的物理力学性质及其作为地基时所应采取的必要处理措施,在西安北动车段垃圾填埋场的地基处理及施工中,采用室内试验及现场原位测试,定量分析杂填土地基的工程特性,提出合理的地基处理方案。工程实践证明,采用挖除换填和强夯处理后地基各参数均满足设计要求,达到预期效果,且创新性地采取掺入生石灰的方法对场区固体废物进行处理,避免二次污染的产生。研究成果可供类似条件下其他垃圾填埋场的地基处理参考和借鉴。     

Emerging Contaminants at a Closed and an Operating Landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty‐eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.     

In-situ assessment of the dynamic properties of municipal solid waste at a landfill in texas

An understanding of dynamic properties of Municipal Solid Waste (MSW) is essential for seismic response analysis of MSW landfills in areas of moderate to high seismicity. A field testing program aimed at characterizing the dynamic properties of MSW was executed at two locations in a Subtitle D landfill in Austin, Texas. Shear and primary wave velocities were measured using small-scale crosshole and downhole seismic tests. The combination of these seismic methods allowed an assessment of the effect of waste composition on dynamic properties, anisotropy, and Poisson׳s ratio of the MSW. In addition, steady-state dynamic testing was performed using two mobile vibroseis shakers to evaluate in-situ the nonlinear relationship between shear modulus and shearing strain. Horizontal steady-state shaking at increasing stress level generated shearing strains from 0.001% to 0.2% allowing evaluation of shear modulus reduction curves over a wide shearing strain range. The effect of confining stress on the dynamic properties of the MSW was also evaluated using the substantial weight of the vibroseis as reaction to apply surcharge vertical loads at the surface of the MSW.     

The use of reference models from a priori data to guide 2D inversion of electrical resistivity tomography data

Clay-rich till plains cover much of the UK. Such sites are attractive locations for landfills, since clay aquitards lower the risk of landfill leachate entering groundwater. However, such tills often contain sand and gravel bodies that can act as leachate flow routes. Such bodies may not be detected by conventional site investigation techniques such as drilling boreholes and trial pitting. A method of guided inversion, where a priori data are used to construct structural reference models for use in inverting electrical resistivity tomography data, was proposed as a tool to improve the detection of sand and gravel bodies within clay-rich till sequences.
Following a successful 2D guided inversion synthetic modelling study, a field study was undertaken. Wenner 2D electrical resistivity tomography lines, resistivity cone penetrometry bores and electromagnetic induction ground resistivity data were collected over a site on the East Yorkshire coast, England, where sand and gravel lenses were known to exist from cliff exposures. A number of equally valid geoelectrical models were constructed using the electromagnetic and resistivity cone data. These were used as structural reference models in the inversion of the resistivity tomography data. Blind inversion using an homogenous reference model was also carried out for comparison.
It was shown for the first time that the best solution model produced by 2D inversion of one data set with a range of structural reference models could be determined by using the l ₂ model misfit between the solution models and associated reference models (reference misfit) as a proxy for the l ₂ misfit between the solution models and the synthetic model or 'best-guess' geoelectrical model (true misfit). The 2D methodology developed here is applicable in clay-rich till plains containing sand and gravel bodies throughout the UK.     

Understanding the dynamics and contamination of an urban aquifer system using groundwater age (14C, 3H,CFCs) and chemistry

The quality of the groundwater supplying drinking water to the Guadalajara metropolitan area has deteriorated due to both endogenic and exogenic processes. Previous studies of this complex neotectonic volcanic environment suggest that the sources of contamination here are underground fluids derived from an active volcanic center and surface wastewater derived from regional land‐use intensification. This study uses isotopic, gaseous, and chemical signatures to more comprehensively characterize this groundwater flow and its contamination paths. Groundwater is mainly recharged at the La Primavera Caldera to the west and is discharged into the Santiago River to the east. The exception to this trend is the Toluquilla area, where groundwater most likely represents rainfall originating from outside the basin limits. Evaporation affects groundwater in these areas, especially waters that have been affected by recycling below urban areas in the Atejamac area and by intensive agricultural activity in the Toluquilla area. Additionally, we present evidence that groundwater flow through alluvial sediments and tuffs in deeper wells mixes with a lower aquifer unit in basaltic‐andesitic rocks, which are in contact with hydrothermal fluids. Groundwater ages range from postbomb in the western and northwestern regions of the study area (i.e., the Atemajac aquifer unit) to Late Pleistocene in the southern and southeastern regions (i.e., the Toluquilla aquifer unit). Recently recharged water records little mixing and is located mostly in or near the La Primavera volcanic system. As groundwater undergoes gravitational flow towards discharge areas, it mixes with older water components. Chloride and sodium concentrations above natural background levels are primarily related to volcanic activity, nitrate is associated with human activities, and sulfate originates from both anthropogenic sources and water–rock interactions. Nitrate originating from land‐use activities (such as sewers, septic tanks, landfills, and agricultural fields) that is introduced into the deeper part of the groundwater system is expected to travel with the groundwater to the discharge areas because oxidizing conditions will prevent microbial reduction. See Supplementary Information.     

Detection of Contaminant Plumes by Borehole Geophysical Logging

Two borehole geophysical methods—electromagnetic induction and natural gamma radiation logs—were used to vertically delineate landfill leachate plumes in a glacial aquifer. Geophysical logs of monitoring wells near two land-fills in a glacial aquifer in west-central Vermont show that borehole geophysical methods can aid in interpretation of geologic logs and placement of monitoring well screens to sample landfill leachate plumes.
Zones of high electrical conductance were delineated from the electromagnetic log in wells near two landfills. Some of these zones were found to correlate with silt and clay units on the basis of drilling and gamma logs. Monitoring wells were screened specifically in zones of high electrical conductivity that did not correlate to a silt or clay unit. Zones of high electrical conductivity that did not correlate to a silt or clay unit were caused by the presence of ground water with a high specific conductance, generally from 1000 to 2370 μS/cm (microsiemens per centimeter at 25 degrees Celsius). Ambient ground water in the study area has a specific conductance of approximately 200 to 400 μS/cm. Landfill leachate plumes were found to be approximately 5 to 20 feet thick and to be near the water table surface.     

Evaluation of an active variable-damping structure

We present a numerical evaluation of the potential improvements in seismic disturbance rejection to be obtained by using active variable damping control in a structure. Using the responses to seismic excitation of an optimally controlled variable structure and of a minimax-optimal designed fixed structure, we obtain an upper bound on the achievable performance and a lower bound on the acceptable performance of a control system for a variable-damping structure. Both of these bounds are relative to an energy-function criterion. Our numerical experiments lead to the following conclusions:

• (i) The gap between the upper and lower bounds is rather small, which makes designing a feedback law, that results in performance superior to that of a minimax-optimal designed structure, very difficult. The best choice for a feedback law appears to be continuous moving horizon control, whose implementation requires ground motion prediction up to 0.2 sec ahead, possibly using sensors located a small distance away from the site.
• (ii) A minimax-optimal designed structure gives very good seismic disturbance suppression, not only for the earthquakes used in its design, but also for other earthquakes of similar intensity. Controlled variable structures are likely to offer advantages when earthquakes are moderate to severe, particularly at sites, such as landfills and dry lake beds, where resonances can be expected, but the resonance frequency cannot be estimated in advance.

     

Attenuation relation of Arias intensity for Zagros Mountains region (Iran)

Arias intensity is considered as a shaking parameter suitable for characterizing earthquake impact on ground stability. Within the framework of a study aimed at providing tools for the assessment of hazards related to earthquake-induced slope failures, Arias intensity attenuation relations were determined for the Zagros Mountains region, an active tectonic belt elongated NW–SE in the western and south-western part of Iran. The calculation of relation coefficients was based on strong-motion data of earthquakes located in the Zagros area and recorded by Iranian stations managed by the Building and Housing Research Center of Iran (BHRC). Five models of attenuation relation were considered and their coefficients were estimated through a least-square regression analysis. The relations obtained were then applied to a data sample different from that used for regression and the root mean square (RMS) of residuals was examined in order to compare effectiveness of different relations in probabilistic estimates. Furthermore a comparison made with attenuation relations obtained for Alborz and the central part of Iran showed significant differences possibly related to structural differences.     

Discovery of a recurrent lava lake on Saunders Island (South Sandwich Islands) using AVHRR imagery

Monitoring of the remote South Sandwich Islands volcanic arc, using advanced very high resolution radiometer (AVHRR) data, has identified a radiant pixel on channels 3 (3.55–3.93 μm) and (rarely) 4 (10.3–11.3 μm). The position of the pixel is coincident with Mount Michael, Saunders Island, the active summit crater of a snow-covered basaltic stratovolcano with a persistent steam plume. The radiant pixel was continuously present in successive AVHRR images acquired during intervals of several months in the period examined (March 1995–February 1998), although apparently disappearing for similar time intervals. More than 5000 images were examined during this study. The radiant pixel is interpreted to indicate that the crater has contained a lava lake, the first to be recorded in the South Sandwich Islands. The lake appears to persist in the crater for several months at a time, at least. It may have drained completely at times and was probably absent when the crater was viewed briefly during an overflight in January 1997. Persistent or recurring lava lakes are very uncommon world-wide and that at Mount Michael is one of only two recorded in the Antarctic region.     

Assessing the Transport of Pharmaceutical Compounds in a Layered Aquifer Discharging to a Stream

A groundwater plume containing high concentrations of pharmaceutical compounds, mainly sulfonamides, barbiturates, and ethyl urethane, in addition to chlorinated ethenes and benzene was investigated. The contamination originating from a former pharmaceutical industry discharges into a multilayered aquifer system and a downgradient stream. In this study, geological and hydrogeological data were integrated into a numerical flow model to examine identified trends using statistical approaches, including principal component analysis and hierarchal cluster analysis. A joint interpretation of the groundwater flow paths and contaminant concentrations in the different compartments (i.e., groundwater and hyporheic zone) provided insight on the transport processes of the different contaminant plumes to the stream. The analysis of historical groundwater concentrations of pharmaceutical compounds at the site suggested these compounds are slowly degrading. The pharmaceutical compounds migrate in both a deep semiconfined aquifer, as well as in the shallow unconfined aquifer, and enter the stream along a 2-km stretch. This contrasted with the chlorinated ethenes, which mainly discharge to the stream as a focused plume from the unconfined aquifer. The integrated approach developed here, combining groundwater flow modeling and statistical analyses of the contaminant concentration data collected in groundwater and the hyporheic zone, lead to an improved understanding of the observed distribution of contaminants in the unconfined and semiconfined aquifers, and thus to their discharge to the stream. This approach is particularly relevant for large and long-lasting contaminant sources and plumes, such as abandoned landfills and industrial production sites, where field investigations may be very expensive.     

An experimental study on active control of in-plane cable vibration by axial support motion

Active control of slightly sagged cables using the axial motion at the cable support is studied experimentally and analytically. Non-linear modal equations of a cable are presented, and two control schemes are identified, i.e. active stiffness control and active sag-induced force control. In this study, emphasis is placed on the active sag-induced force control. Additional damping is analytically expressed when a velocity feedback control is used. Although the active sag-induced force control can be applicable only for in-plane symmetric modes, it is shown that it is very efficient for the first mode. An experiment is conducted using a scaled cable model of 2 m length. First, it is shown by the experiment that the analytical model can predict well the non-linear cable motion. Next, sag-induced force control is examined using free vibration and harmonic excitations. The results agree well with the analytical predictions and confirm that additional damping can be obtained efficiently from the axial support motion.     

Experimental verification of a wireless sensing and control system for structural control using MR dampers

The performance aspects of a wireless ‘active’ sensor, including the reliability of the wireless communication channel for real‐time data delivery and its application to feedback structural control, are explored in this study. First, the control of magnetorheological (MR) dampers using wireless sensors is examined. Second, the application of the MR‐damper to actively control a half‐scale three‐storey steel building excited at its base by shaking table is studied using a wireless control system assembled from wireless active sensors. With an MR damper installed on each floor (three dampers total), structural responses during seismic excitation are measured by the system's wireless active sensors and wirelessly communicated to each other; upon receipt of response data, the wireless sensor interfaced to each MR damper calculates a desired control action using an LQG controller implemented in the wireless sensor's computational core. In this system, the wireless active sensor is responsible for the reception of response data, determination of optimal control forces, and the issuing of command signals to the MR damper. Various control solutions are formulated in this study and embedded in the wireless control system including centralized and decentralized control algorithms. Copyright © 2007 John Wiley & Sons, Ltd.