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1.
The properties and transformation of dissolved organic matter (DOM) extracted (10 L water per kilogram compost) from municipal solid waste (MSW) compost at five stages (days 47, 77, 105, 126, and 187) of composting were investigated. The DOM was fractionated into hydrophobic or hydrophilic neutrals, acids, and bases. The unfractionated DOM, the hydrophobic acids and neutrals (HoA and HoN, respectively), and the hydrophilic neutrals (HiN) fractions were studied using solid-state 13C-NMR, FTIR, and DRIFT spectroscopy. The HoA fraction was found to be the dominant (percentage of total DOM) hydrophobic fraction, exhibiting a moderate increase during composting. The HoN fraction increased sharply from less than 1% to 18% of the total DOM during 187 days of composting, while the hydrophobic bases (HoB) exhibited the opposite trend. The HiN represented the major fraction of the hydrophiles up to 120 days of composting, decreasing thereafter by 38%. The relative concentration of the hydrophilic acids and bases (HiA and HiB, respectively) exhibited no consistent trend during composting. DRIFT spectra of the unfractionated DOM taken from the composting MSW revealed a decreasing level of polysaccharide structures with time. The 13C-NMR and FTIR spectra of the HoA fraction exhibited a polyphenol-humic structure, whereas the HoN spectra exhibited strong aliphatic features. The spectra of the HiN fraction confirmed its polysaccharide nature. During the final stage of composting, the DOM concentration was steady, while a relative decrease of HiN concomitant with an increase of HoA and HoN fractions was observed. These indicate that the DOM contained a low concentration of biodegradable organic matter and a higher content of macromolecules related to humic substances. The biological significance and heavy metal binding of these fractions are being studied based on earlier observations showing enhanced plant growth in the presence of DOM extracted from mature as opposed to immature compost.  相似文献   

2.
The scope of this study was to investigate the effects of natural zeolite and expanded perlite on the quality of municipal solid waste compost. Various ratios of the materials were added as supplements to the organic fraction of municipal solid waste. These applications were periodically compared with an untreated control process. The results obtained from experimental studies clearly showed that municipal solid waste collected from the metropolitan city center of Samsun, Turkey could not be composted without any additions due to the very high moisture content, which reached up to 75–80%. In the untreated control process, thermophilic temperatures were not supported during the composting. In this system, ammonia and other odors became a problem because of the high pH levels, and the electrical conductivity was too high for aged compost. However, the addition of natural zeolite and expanded perlite had a positive affect on the quality of the final compost. Natural zeolite trapped ammonium and reduced nitrogen losses from the compost. Expanded perlite held excess moisture and supported improved aeration. The results also indicated that the use of natural zeolite together with expanded perlite in municipal solid waste composting processes produced mature and stable compost.  相似文献   

3.
Ng QY  Chan AH  Ma SW 《Marine pollution bulletin》2008,57(6-12):381-391
Composting is one of the waste disposal methods adopted for disposal of livestock waste in Hong Kong. The composting livestock waste normally undergoes 6-8 weeks fermentation, followed by 16-20 weeks maturation. The matured compost is sold as soil conditioner in the local market. In 2006, feedstock material and a time-series of compost samples were collected throughout the fermentation and maturation process from the Sha Ling Composting Plant in the New Territories. The feedstock material and compost samples were analyzed for contents of three unintentional persistent organic pollutants (POPs), i.e. dioxins/furans, dioxin-like PCBs and total PCBs. These POPs are unintentionally produced by-products of chemical industrial processes and combustion processes. Selected heavy metals were also analyzed, which served as conservative tracers to determine potential mass loss during the composting process. Levels of contamination by these POPs were found to be low in the matured compost for sale. The mean concentrations (lower-upper bound) of total dioxins/furans, total dioxin-like PCBs and total PCBs were 2.01-2.05 ng I-TEQ/kg dw, 0.04-0.05 ng WHO-TEQ/kg dw and 1.55-1.55 microg/kg dw, respectively. Progressively elevated levels of these POPs were observed in the compost samples during the fermentation process. Analysis of the congener profiles revealed that the heptaCDD and octaCDD were the main contributors to the observed increase in dioxin/furan content. The possible sources of dioxins/furans in the compost were discussed. The study results established a local dioxins/furans emission factor specific to the trade and provided a better estimate of the annual dioxins/furans emission for the livestock waste composting activity in Hong Kong.  相似文献   

4.
Composting is one of the waste disposal methods adopted for disposal of livestock waste in Hong Kong. The composting livestock waste normally undergoes 6–8 weeks fermentation, followed by 16–20 weeks maturation. The matured compost is sold as soil conditioner in the local market. In 2006, feedstock material and a time-series of compost samples were collected throughout the fermentation and maturation process from the Sha Ling Composting Plant in the New Territories. The feedstock material and compost samples were analyzed for contents of three unintentional persistent organic pollutants (POPs), i.e. dioxins/furans, dioxin-like PCBs and total PCBs. These POPs are unintentionally produced by-products of chemical industrial processes and combustion processes. Selected heavy metals were also analyzed, which served as conservative tracers to determine potential mass loss during the composting process. Levels of contamination by these POPs were found to be low in the matured compost for sale. The mean concentrations (lower–upper bound) of total dioxins/furans, total dioxin-like PCBs and total PCBs were 2.01–2.05 ng I-TEQ/kg dw, 0.04–0.05 ng WHO-TEQ/kg dw and 1.55–1.55 μg/kg dw, respectively. Progressively elevated levels of these POPs were observed in the compost samples during the fermentation process. Analysis of the congener profiles revealed that the heptaCDD and octaCDD were the main contributors to the observed increase in dioxin/furan content. The possible sources of dioxins/furans in the compost were discussed. The study results established a local dioxins/furans emission factor specific to the trade and provided a better estimate of the annual dioxins/furans emission for the livestock waste composting activity in Hong Kong.  相似文献   

5.
《Marine pollution bulletin》2009,58(6-12):381-391
Composting is one of the waste disposal methods adopted for disposal of livestock waste in Hong Kong. The composting livestock waste normally undergoes 6–8 weeks fermentation, followed by 16–20 weeks maturation. The matured compost is sold as soil conditioner in the local market. In 2006, feedstock material and a time-series of compost samples were collected throughout the fermentation and maturation process from the Sha Ling Composting Plant in the New Territories. The feedstock material and compost samples were analyzed for contents of three unintentional persistent organic pollutants (POPs), i.e. dioxins/furans, dioxin-like PCBs and total PCBs. These POPs are unintentionally produced by-products of chemical industrial processes and combustion processes. Selected heavy metals were also analyzed, which served as conservative tracers to determine potential mass loss during the composting process. Levels of contamination by these POPs were found to be low in the matured compost for sale. The mean concentrations (lower–upper bound) of total dioxins/furans, total dioxin-like PCBs and total PCBs were 2.01–2.05 ng I-TEQ/kg dw, 0.04–0.05 ng WHO-TEQ/kg dw and 1.55–1.55 μg/kg dw, respectively. Progressively elevated levels of these POPs were observed in the compost samples during the fermentation process. Analysis of the congener profiles revealed that the heptaCDD and octaCDD were the main contributors to the observed increase in dioxin/furan content. The possible sources of dioxins/furans in the compost were discussed. The study results established a local dioxins/furans emission factor specific to the trade and provided a better estimate of the annual dioxins/furans emission for the livestock waste composting activity in Hong Kong.  相似文献   

6.
In this study, it was aimed to determine the effect of various aeration rates on composting to supply the optimum aeration rate for a successful and economic composting. For this aim, vegetable–fruit wastes (VFW) were composted at various aeration rates (0.37, 0.49, 0.62, 0.74, 0.86, and 0.99 L/min kg VS) and moisture, temperature, pH, electrical conductivity, C/N, and cellulose were investigated. Moistures of the reactor that had the highest aeration were generally lower than those of the others. Reactor that had the lowest aeration reached thermophilic phase earlier than the others and stayed more days. This situation was opposite for the reactor that had the highest aeration. pH variations with aeration rates were not significant. Although electrical conductivity did not differ significantly with aeration rates, at the beginning of the thermophilic phase it generally increased with the increase in aeration. The highest C/N reduction was observed in the reactor that had an aeration of 0.62 L/min kg VS. The final cellulose contents were close to each other. It could be said that aeration rates used were efficient on composting of VFW. Taking the C/N into account which is the parameter of the indicator of the stabilization in composting, it could be said that the optimum aeration rate for forced aerobic composting of VFW was 0.62 L/min kg VS.  相似文献   

7.
Composts with five different ratios of agricultural wastes, viz. rice straw (RS), wheat straw (WS), potato plant (PP), and mustard stover (MS) were prepared with or without fish pond bottom sediment to investigate the compost maturity and their suitability for field application. The composting process was monitored through the changes in physico‐chemical parameters and germination index (GI) at every 7 days interval of the composting process. All the composts were dark brown and smelled like forest soil within 56 days of composting, which reflected its matured status. On the basis of the physico‐chemical parameters (bulk density: 0.84 g/cm3; pH 7.05; electrical conductivity: 3.52 mS/cm; cation exchange capacity:82.4 cmol/kg; total carbon:321.4 g/kg; total nitrogen: 16.9 g/kg; As: 6.8 mg/kg; Cd: 2.96 mg/kg; Cr: 29.6 mg/kg, Cu: 243.6 mg/kg; Hg: 0.019 mg/kg; Ni: 24.3 mg/kg; Pb: 62.1 mg/kg and Zn: 812 mg/kg) and GI (89–96%), it could be concluded that RS/WS/PP/MS, 1:1:2:1 v/v/v/v with fish pond sediment produced better compost in accordance with the Indian compost standard. Application of a combined randomized block design analysis revealed that there is a significant difference in the responses of the five composts, in relation to the time of composting. Hierarchical clustering algorithm was applied with a view to form homogeneous groups of five different composts on the basis of different physico‐chemical parameters. Therefore, the ratio of waste incorporation is an important decision for composting and addition of pond sediment can improve the quality of compost.  相似文献   

8.
New methods for obtaining and quantifying spatially distributed subsurface moisture are a high research priority in process hydrology. We use simple linear regression analyses to compare terrain electrical conductivity measurements (EC) derived from multiple electromagnetic induction (EMI) frequencies to a distributed grid of water‐table depth and soil‐moisture measurements in a highly instrumented 50 by 50 m hillslope in Putnam County, New York. Two null hypotheses were tested: H0(1), there is no relationship between water table depth and EC; H0(2), there is no relationship between soil moisture levels and EC. We reject both these hypotheses. Regression analysis indicates that EC measurements from the low frequency EM31 meter with a vertical dipole orientation could explain over 80% of the variation in water‐table depth across the test hillslope. Despite zeroing and sensitivity problems encountered with the high frequency EM38, EC measurements could explain over 70% of the gravimetrically determined soil‐moisture variance. The use of simple moisture retrieval algorithms, which combined EC measurements from the EM31 and EM38 meters in both their vertical and horizontal orientations, helped increase the r2 coefficients slightly. This first hillslope hydrological analysis of EMI technology in this way suggests that it may be a promising method for the collection of a large number of distributed soilwater and groundwater depth measurements with a reasonable degree of accuracy. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

9.
Anaerobically stabilized sludge from wastewater treatment is always a challenge from the environmental aspect of management. The agrarian environmental surroundings present a possibility for swift and efficient utilization of compost from anaerobically stabilized sludge in order to increase the quality of the biological product. With intensification of the composting procedure by means of the microbiological consortium Geocell‐1 (Cellvibrio sp., Pseudomonas fluorescens with the addition of micro‐ and macro‐elements), the results show that the compost obtained from stabilized sludge after inoculation is significantly improved in terms of moisture reduction (39–43%), while in the control compost, this value is significantly higher with 61%. The results of the pathogenic effect show a significant reduction in the number of fecal coliform (<1 × 103) and Enterococcus bacteria (<1 × 104) in the inoculated (treated) compost. With a slight decrease in the concentration of limiting factors such as As, Cd, Cu, a quality biological product can be achieved, which can be safely deposited on soil. The phytotoxicological germination test with white mustard (Sinapis alba) shows a higher number of sprouting plants with a mixture of treated compost and standard soil for flowers 1:1 and 1:4 compared to the control group.  相似文献   

10.
Treatment of nitrogen in landfill leachate has received considerable attention recently because of the relatively low levels at which some nitrogen species (i.e., NH3) can be toxic to aquatic life forms. This study reports on the results of a three-year, pilot-scale field trial demonstrating the use of infiltration bed and nitrate barrier technology to achieve nitrogen removal in landfill leachate. The infiltration bed comprises an unsaturated sand layer overlying a saturated layer of waste cellulose solids (sawdust), which acts as a carbon source for heterotrophic denitrification. When loaded at a rate of 1 to 3 cm/day, the infiltration bed was successful at lowering leachate inorganic nitrogen (NH4++ NO3-) levels averaging 24.8 mg/L N by 89%, including 96% in the third year of operation. The surface water discharge criteria for un-ionized ammonia (NH3) were met on all occasions in the treated leachate during the second and third years of operation. Nitrogen attenuation is presumed to occur by a two-step process in which leachate NH4+ is first oxidized to NO3- in the unsaturated sand layer and then is converted to nitrogen gas (N2) by denitrification occurring in the underlying sawdust layer. Mass balance calculations suggest that the sawdust layer has sufficient carbon to allow denitrification to proceed for long periods (1.0 to 30 years) without replenishment. Because this technology is simple to construct and is relatively maintenance free, it should be attractive for use at smaller landfills where the installation of conventional treatment plants may not be feasible.  相似文献   

11.
Spectroscopic Characterization of Compost at Different Maturity Stages   总被引:1,自引:0,他引:1  
We studied the physicochemical and molecular changes of compost during its maturation within 60, 90, and 150 days after the composting process. Moreover, the changes were also studied in compost residues after sequential removal of lipidic compounds. Infrared DRIFT spectrometry and 13C‐CPMAS‐NMR spectroscopy indicate that the molecular composition of compost changes dramatically during the stabilization period. The most decomposable components, mainly represented by bioavailable lipidic and peptidic structures, were progressively mineralized passing from 60 days to longer periods of compost stabilization. At increasing maturity stages, the composition of organic matter underwent a progressive enrichment in stable hydrophobic and ligno‐cellulosic material. The sequential extraction of lipidic compounds allowed an improved characterization of substrates and confirmed the outlined progressive transformation of compost. Compost may well be chosen on the basis of selected characteristics for environmental applications.  相似文献   

12.
In this study, an inexact inventory-theory-based chance-constrained programming (IICP) model is proposed for planning waste management systems. The IICP model is derived through introducing inventory theory model into a general inexact chance-constrained programming framework. It can not only tackle uncertainties presented as both probability distributions and discrete intervals, but also reflect the influence of inventory problem in decision-making problems. The developed method is applied to a case study of long-term municipal solid waste (MSW) management planning. Solutions of total waste allocation, waste allocation batch and waste transferring period associated different risk levels of constraint violation are obtained. The results can be used to identify inventory-based MSW management planning with minimum system cost under various constraint-violation risks. Compared with the ICP model, the developed IICP model can more actually reflect the complexity of MSW management systems and provide more useful information for decision makers.  相似文献   

13.
An understanding of dynamic properties of Municipal Solid Waste (MSW) is essential for seismic response analysis of MSW landfills in areas of moderate to high seismicity. A field testing program aimed at characterizing the dynamic properties of MSW was executed at two locations in a Subtitle D landfill in Austin, Texas. Shear and primary wave velocities were measured using small-scale crosshole and downhole seismic tests. The combination of these seismic methods allowed an assessment of the effect of waste composition on dynamic properties, anisotropy, and Poisson׳s ratio of the MSW. In addition, steady-state dynamic testing was performed using two mobile vibroseis shakers to evaluate in-situ the nonlinear relationship between shear modulus and shearing strain. Horizontal steady-state shaking at increasing stress level generated shearing strains from 0.001% to 0.2% allowing evaluation of shear modulus reduction curves over a wide shearing strain range. The effect of confining stress on the dynamic properties of the MSW was also evaluated using the substantial weight of the vibroseis as reaction to apply surcharge vertical loads at the surface of the MSW.  相似文献   

14.
Egypt is located in the Northeast of Africa where oil and gas (O&G) are produced offshore from the Gulf of Suez and the Southeast part of the Mediterranean. The O&G production in Egypt is distributed as follows: 70% from Gulf of Suez, 16% from Western desert, 8% from the Sinai Peninsula and 6% from Eastern desert. Past O&G activities, refining and transport have resulted in chronic pollution in Egyptian offshore and numerous environmental programs have been initiated to protect new development areas from the environmental impacts. The offshore drilling process uses drilling fluids (mud) and generates waste fluids and cuttings, which could be the largest discharges going into the receiving water bodies. There are several options to manage offshore drilling wastes: offshore discharge, offshore down-hole injection and onshore disposal. Water-based drilling fluids (WBF) are commonly employed for drilling in Egyptian offshore because of their expected environmental benign behavior. The main objective of this paper is to develop a methodology to determine the fate of heavy metals associated with WBF drilling waste in the marine environment and estimate the associated ecological risks. Proposed contaminant fate model is based on an aquivalence approach, which has been integrated with fuzzy-based analysis to study the uncertainties. This research concluded that the impacts of heavy metals associated with the drilling waste discharges in the receiving waters are minimal.  相似文献   

15.
The nature and rates of fluvial and slope processes change over time and space as urbanized areas replace forested land in Singapore. Storm-based and time-based data, from undisturbed rainforests, heavily disturbed construction sites, urban grass-covered slopes and an experimental plot, are collected to observe the impact of rainwater on the soil moisture conditions, surface microtopography, runoff generation, sediment movement, and ground lowering in the three different categories of land use. The undisturbed forested environment is characterized by high throughfall (58% of total rainfall) and frequent negative soil moisture suctions. The slow and unconcentrated overland flow during heavy storms is restricted by the forest floor microtopography. No rills develop. Ground lowering is recorded as 3·2–3·4 mm a?1. But sediment movement is episodic and suspended sediment concentrations in overland flow are 172–222 mg l?1. During urban construction, gully development is rapid on the bare slopes, runoff generation, voluminous, and sediment-laden discharges (5200–75498 mg l?1) lead to sediment plumes at channel mouths. Ground lowering rates are measured at 132·4 mm a?1. Once grass-covered, runoff carries less suspended sediment (800 mg l?1) and ground lowering rates are reduced, but depend on the condition of the cover, ranging from 0·2 to 8·2 mm a?1. As urban development continues, environments are altered both in time as well as spatially.  相似文献   

16.
Surface mining in the Elk Valley, British Columbia, involves removing vegetation, soil, and rock to access underlying metallurgical coal. Subsequent waste rock is placed into adjacent valleys, frequently burying headwater streams. Due to their coarse texture, waste rock piles increase infiltration and percolation, increasing solute transport and concentration of geochemicals in downstream surface waters. Previous research suggests that weathering solutes are transport limited, and it is hypothesized that revegetation will enhance evapotranspiration (ET) and reduce percolation through the waste rock, potentially reducing loading. This study examined the surface‐atmosphere water and energy exchanges using the eddy covariance technique for three waste rock surfaces with different levels of reclamation: (a) an ~25‐year‐old mixed coniferous forest, (b) a grass site, and (c) bare waste rock. Measurements were taken from May to October in 2013 and 2014. Soil moisture and matric suction were measured to 1‐m depth. Sap flow at the forested site was measured to partition transpiration from total ET. In all years, ET rates were greatest at the forested site, followed by the grass cover and lowest at the bare waste rock site. Growing season ET rates at the forest were 56% higher than grass in 2013 and 35% higher in 2014. At the vegetated sites, climate was the main driver of ET, with high radiation, and warm and dry conditions enhancing fluxes. Maximum ET at these sites corresponded with peak growing season, with vegetation increasing both transpiration and rainfall interception. At the bare rock site, ET was weakly related to atmospheric conditions, and ET rates briefly increased during periods following rainfall when near‐surface soil moisture was enhanced. Transpiration comprised 29% of overall ET at the forest site from late July to early October. Results suggest that vegetation establishment can be incorporated into mine reclamation plans to enhance ET rates and limit percolation, potentially reducing downstream geochemical loads.  相似文献   

17.
An inexact stochastic mixed integer linear semi-infinite programming (ISMISIP) model is developed for municipal solid waste (MSW) management under uncertainty. By incorporating stochastic programming (SP), integer programming and interval semi-infinite programming (ISIP) within a general waste management problem, the model can simultaneously handle programming problems with coefficients expressed as probability distribution functions, intervals and functional intervals. Compared with those inexact programming models without introducing functional interval coefficients, the ISMISIP model has the following advantages that: (1) since parameters are represented as functional intervals, the parameter’s dynamic feature (i.e., the constraint should be satisfied under all possible levels within its range) can be reflected, and (2) it is applicable to practical problems as the solution method does not generate more complicated intermediate models (He and Huang, Technical Report, 2004; He et al. J Air Waste Manage Assoc, 2007). Moreover, the ISMISIP model is proposed upon the previous inexact mixed integer linear semi-infinite programming (IMISIP) model by assuming capacities of the landfill, WTE and composting facilities to be stochastic. Thus it has the improved capabilities in (1) identifying schemes regarding to the waste allocation and facility expansions with a minimized system cost and (2) addressing tradeoffs among environmental, economic and system reliability level.  相似文献   

18.
This paper describes a quasi-static test program featuring lateral cyclic loading on single piles in sandy soil. The tests were conducted on 18 aluminum model piles with different cross sections and lateral load eccentricity ratios, e/d, (e is the lateral load eccentricity and d is the diameter of pile) of 0, 4 and 8, embedded in sand with a relative density of 30% and 70%. The experimental results include lateral load-displacement hysteresis loops, skeleton curves and energy dissipation curves. Lateral cap...  相似文献   

19.
通过对鱼苗时期鄱阳湖网箱养殖区沉积物、饵料及鱼粪等样品总有机碳(TOC)含量、总氮(TN)含量、碳氮比(C/N)、δ^13 C及δ^15 N的测定,分析探讨了鄱阳湖网箱养殖区沉积物有机质来源,量化了网箱养殖废物对养殖区沉积物有机质的贡献.结果表明,网箱养殖区沉积物的δ^13 C和δ^15 N值分别为-27.67‰~-25.65‰和5.19‰~7.27‰,饵料的δ^13 C和δ^15 N值分别为-24.73‰和10.28‰,鱼粪的δ^13 C和δ^15 N值分别为-26.30‰和15.54‰.网箱养殖区沉积物有机质来源主要有残饵、浮游生物及其他来源,其贡献率分别为48.3%±11.4%、25.6%±11.3%及26.0%±5.8%,而鱼粪的贡献几乎可以忽略不计.在水动力平流引起的扩散及沉积物的再悬浮的影响下,网箱养殖源有机质的扩散距离达1500 m.在鱼苗时期,鱼类网箱养殖的残饵是鄱阳湖网箱养殖区沉积物有机质的主要来源.  相似文献   

20.
Dynamic properties of municipal solid waste (MSW) from two dump sites located at Delhi, India are evaluated from field and large scale laboratory tests. Shear wave velocity (Vs) profiles of MSW, measured at these two sites using surface wave techniques, are in range of Vs data reported for MSW landfills worldwide. Representative bulk MSW samples were collected from large test pits excavated at the two dump sites to determine the near surface unit weight. Large scale undrained cyclic triaxial (CTX) tests were conducted on reconstituted MSW specimens to investigate the effect of various parameters such as composition, confining pressure, number of loading cycles, loading frequency and saturation on the dynamic properties. Undrained CTX tests, conducted on the specimens with and without fibrous materials demonstrated the effect of fibrous waste constituents on the stiffness and damping behavior of MSW. Specimens consisting of fibrous waste constituents such as plastics and textiles exhibited significantly less modulus reduction compared to specimens with negligible amount of fibrous content. The modulus reduction (G/Gmax) and material damping ratio curves derived from the present study are in the range reported for MSW in the literature. The G/Gmax curves from present study are in good agreement with curves recommended for MSW at Tri-Cities landfill in USA and Tianziling landfill in China. Dynamic properties evaluated from the present study add to the growing database of the worldwide dataset and can be useful for evaluating the seismic stability and associated permanent deformations of the existing dumps in and around Delhi.  相似文献   

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