Benzo[a]pyrene modulates the biotransformation,DNA damage and cortisol level of red sea bream challenged with lipopolysaccharide

In animals, biotransformation and the immune system interact with each other, however, knowledge of the toxic mechanism of benzo[a]pyrene (BaP) on these two systems is not well known. The present study investigated the toxic effects of BaP on the biotransformation system, cortisol level and DNA integrity of red sea bream (Pagrus major). The results showed that cortisol level was induced under the challenge of lipopolysaccharide (LPS). Short-term exposure (96 h) of BaP at environmental concentration significantly increased the cortisol level, hepatic EROD activity and CYP1A1 mRNA expression. When P. major was exposed to BaP for 14 d followed by LPS challenge this increased the cortisol level, EROD activity and hepatic DNA damage except CYP1A1 mRNA expression. Combined with our previous data, which showed that BaP exposure can modulate the immunologic response in P. major challenged with LPS, a hypothetical adverse outcome pathway of BaP on fish was suggested.     

Chemical characterization of naturally weathered oil residues in the sediment from Yellow River Delta, China

With its close proximity to Shengli Oilfield, China’s second largest oilfield, the Yellow River Delta is at high risk for crude oil contamination. The massive oil discharge in oilfield may offer a chance for a natural experiment to investigate compositional changes of oil residues and study the stability of source- and weathering-dependent molecular parameters in oil residues after spills. The results demonstrate that the conventional diagnostic ratios, such as C₂₉20S/(20S + 20R), C₂₉/C₃₀H, C₃₀βα/αβ, C₃₁22S/(22S + 22R), C₂-DBTs/C₂-PHENs, C₃-DBTs/C₃-PHENs, DBT/MCHRY, CHRY/PHENs, are also valid for oil source identification even after extensive weathering of spilled oils in terrestrial environment, although some exceptions were encountered for extensively weathered sample. Moreover, the ratios of selected specific biomarkers (the oleanane index, the gammacerane index) have been developed and assessed as source indicators. Finally, we find that some maturity parameters based on alkyl naphthalenes and methyl phenanthrenes in petroleum geochemistry, such as the methylnaphthalene ratios (TMNr, TeMNr, PMNr), the methylphenanthrene ratios (MPI-1, MPDF), can be applied for the source identification and correlation at their lightly to moderately weathered stage.     

Distribution,sources and potential toxicological significance of polycyclic aromatic hydrocarbons (PAHs) in surface soils of the Yellow River Delta,China

PAH concentrations of 61 surface soil samples collected from the Yellow River Delta (YRD), China were measured to determine occurrence levels, sources, and potential toxicological significance of PAHs. The total concentrations of ∑PAHs ranged from 27 to 753 ng/g d.w., with a mean of 118 ± 132 ng/g. The highest concentrations was found in the mid-southern part of the YRD (753 ng/g), which was associated with the oil exploration. The ratios indicated that the PAHs throughout the YRD were mostly of pyrogenic origin; while various sites in mid-southern part in the region were derived mainly from the petrogenic sources. Multivariate statistical analyses supported that the PAHs in surface soils of the YRD were principally from the coal and biomass combustion, petroleum spills, and/or vehicular emissions. The toxic assessment suggested that the PAHs in soils were at low potential of ecotoxicological contamination level for the YRD.     

基于底栖动物生物完整性指数的黄河干流生态健康评价

黄河为世界上最长的多沙河流,全河段水沙异质性及其生态健康的空间差异明显。本文基于黄河干流全河段44个断面春秋两季(2019年)底栖动物的系统调查数据,构建黄河底栖动物生物完整性评价体系。该体系融入指示水沙过程变化的ASPT指数及EPT分类单元个体相对丰度,且参照点与受损点得分差异显著,适用于多沙河流生态健康评价。评价结果显示:黄河干流亚健康及以上状态的断面占比为秋季(75.0%)高于春季(54.5%);自源区沿河而下,底栖动物生物完整性指数值呈下降趋势;库区断面底栖动物生物完整性指数低于临近自然河段。回归分析表明,黄河干流底栖动物生物完整性指数与盐度、总氮、城镇及农田用地占比呈显著负相关,与林地及草地占比呈显著正相关。本研究结果可为黄河生态保护与管理提供科学依据。     

Geospatial-temporal analysis of land-use changes in the Yellow River Delta during the last 40 years

Research on land use/land cover changes (LUCC)has been the core project of the Global EnvironmentalChanges since the 1990s[1—6]. Scientists at home andabroad have been laying emphasis on integrationstudies on land-use change by “space and process”features[7—10] as researches on LUCC are in a greatdeal. It is of paramount important for us to studyLUCC at various spatial-temporal scales and build aquantitative assessment of land-use conversion by in-tegrated spatial-temporal features. …     

南四湖表层底泥重金属污染及其风险性评价

通过对南四湖表层底泥中的重金属元素浓度分析,揭示出南四湖不同湖区重金属污染物空间分布特征.利用潜在生态风险指数(RI)和地质积累指数(Igeo)两种指标相结合的方法对表层底泥中重金属污染程度进行评价.结果表明,南四湖上级湖的重金属污染主要以汞为主,并依据潜在生态风险指数将南四湖上级湖分为三个生态风险功能区: 昭阳湖轻污染区;独山湖中等污染区和南阳湖重污染区.     

Geomorphic evolution of the Qingshuigou channel of the Yellow River Delta in response to changing water and sediment regimes and human interventions

Delta channels are important landforms at the interface of sediment transfer from terrestrial to oceanic realms and affect large, and often vulnerable, human populations. Understanding these dynamics is pressing because delta processes are sensitive to climate change and human activity via adjustments in, for example, mean sea level and water/sediment regimes. Data collected over a 40-year period along a 110-km distributary channel of the Yellow River Delta offer an ideal opportunity to investigate morphological responses to changing water and sediment regimes and intensive human activity. Complementary data from the delta front provide an opportunity to explore the interaction between delta channel geomorphology and delta-front erosion–accretion patterns. Cross-section dimensions and shape, longitudinal gradation and a sediment budget are used to quantify spatial and temporal morphological change along the Qingshuigou channel. Distinctive periods of channel change are identified, and analysis provides a detailed understanding of the temporal and spatial adjustments of the channel to specific human interventions, including two artificial channel diversions and changes in water and sediment supply driven by river management, and downstream delta-front development. Adjustments to the diversions included a short-lived period of erosion upstream and significant erosion in the newly activated channel, which progressed downstream. Channel geomorphology widened and deepened during periods when management increased water yield and decreased sediment supply, and narrowed and shallowed during periods when management reduced water yield and the sediment load. Changes along the channel are driven by both upstream and downstream forcing. Finally, there is some evidence that changing delta-front erosion–accretion patterns played an important role in the geomorphic evolution of the deltaic channel; an area that requires further investigation. © 2020 John Wiley & Sons, Ltd.     

Levels and distribution of tris-(2,3-dibromopropyl) isocyanurate and hexabromocyclododecanes in surface sediments from the Yellow River Delta wetland of China

The levels and distribution of tris-(2,3-dibromopropyl) isocyanurate (TBC) and hexabromocyclododecanes (HBCDs) of surface sediments in the Yellow River Delta wetland had been investigated. The concentrations of TBC and ∑ HBCDs ranged from 0.20 to 29.03 ng·g^? 1 dw and below limits of detections (LODs) to 20.25 ng·g^? 1 dw. The average composition profile of three HBCDs isomers were 10.1%, 6.1% and 83.8% for α-, β- and γ-HBCD, respectively. Moreover, correlation analysis indicated there are similar sources among three isomers and positive correlations between total organic carbon (TOC) content and concentrations of TBC and HBCDs. The mass inventory of TBC,α-, β-, γ-HBCD, ΣHBCDs in surface sediments of Yellow River Delta wetland were estimated about 725.50, 72.76, 44.29, 548.34, 665.39 kg. Therefore, further investigations on potential human health and environmental risk assessments of TBC and HBCDs were needed.