Effects of medium and pore‐fluid compressibility on chemical‐dissolution front instability in fluid‐saturated porous media

Theoretical analysis and computational simulations have been carried out to investigate how medium and pore‐fluid compressibility affects the chemical‐dissolution front propagation, which is associated with a fully‐coupled nonlinear problem between porosity, pore‐fluid pressure, pore‐fluid density and reactive chemical‐species transport within a deformable and fluid‐saturated porous medium. When the fully‐coupled nonlinear system is in a subcritical state, some analytical solutions have been derived for a special case, in which the ratio of the equilibrium concentration to the solid molar density of the chemical species is approaching zero. To investigate the effect of either medium compressibility or pore‐fluid compressibility on the evolutions of chemical dissolution fronts in supercritical chemical dissolution systems, numerical algorithms and procedures have been also proposed. The related theoretical and numerical results have demonstrated that: (i) not only can pore‐fluid compressibility affect the propagating speeds of chemical dissolution fronts in both subcritical and supercritical systems, but also it can affect the growth and amplitudes of irregular chemical dissolution fronts in supercritical systems; (ii) medium compressibility may have a little influence on the propagating speeds of chemical dissolution fronts, but it can have significant effects on the growth and amplitudes of irregular chemical dissolution fronts in supercritical systems; and (iii) both medium and pore‐fluid compressibility may stabilize irregular chemical‐dissolution‐fronts in supercritical chemical dissolution systems. Copyright © 2011 John Wiley & Sons, Ltd.     

Theoretical analyses of acidization dissolution front instability in fluid‐saturated carbonate rocks

This paper presents an instability theory that can be used to understand the fundamental behavior of an acidization dissolution front when it propagates in fluid‐saturated carbonate rocks. The proposed theory includes two fundamental concepts, namely the intrinsic time and length of an acidization dissolution system, and a theoretical criterion that involves the comparison of the Zhao number and its critical value of the acidization dissolution system. The intrinsic time is used to determine the time scale at which the acidization dissolution front is formed, while the intrinsic length is used to determine the length scale at which the instability of the acidization dissolution front can be initiated. Under the assumption that the acidization dissolution reaction is a fast process, the critical Zhao number, which is used to assess the instability likelihood of an acidization dissolution front propagating in fluid‐saturated carbonate rocks, has been derived in a strictly mathematical manner. Based on the proposed instability theory of a propagating acidization dissolution front, it has been theoretically recognized that: (i) the increase of the mineral dissolution ratio can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (ii) the increase of the final porosity of the carbonate rock can destabilize the acidization dissolution front, while the increase of the initial porosity can stabilize the acidization dissolution front in fluid‐saturated carbonate rocks; (iii) the increase of the mineral dissolution ratio can cause an increase in the dimensionless propagation speed of the acidization dissolution front; (iv) the increase of the initial porosity can enable the acidization dissolution front to propagate faster, while the increase of the final porosity can enable the acidization dissolution front to propagate slower in the acidization dissolution system. Copyright © 2012 John Wiley & Sons, Ltd.     

Theoretical analyses of chemical dissolution‐front instability in fluid‐saturated porous media under non‐isothermal conditions

This paper mainly deals with the theoretical aspects of chemical dissolution‐front instability problems in two‐dimensional fluid‐saturated porous media under non‐isothermal conditions. In the case of the mineral dissolution ratio (that is defined as the ratio of the dissolved‐mineral equilibrium concentration in the pore fluid to the molar concentration of the dissolvable mineral in the solid matrix of the fluid‐saturated porous medium) approaching zero, the corresponding critical condition has been mathematically derived when temperature variation effects are considered. As a complementary tool, the computational simulation method is used to simulate the morphological evolution of chemical dissolution fronts in two‐dimensional fluid‐saturated porous media under non‐isothermal conditions. The related theoretical and numerical results have demonstrated that: (i) a temperature increase in a non‐isothermal chemical dissolution system can have some influence on the propagation speed of the planar chemical dissolution front in the system. Generally, the chemical dissolution front in the non‐isothermal chemical dissolution system propagates slower than that in the counterpart isothermal chemical dissolution system when the temperature of the non‐isothermal chemical dissolution system is higher than that of the counterpart isothermal chemical dissolution system; (ii) a temperature increase in the non‐isothermal chemical dissolution system can stabilize the chemical dissolution front propagating in the system, because it can cause a decrease in the Zhao number of the system but does not affect the critical Zhao number of the system; and (iii) the temperature gradient in the upstream direction of a chemical dissolution front is smaller than that in the downstream direction of the chemical dissolution front when the non‐isothermal chemical dissolution system is supercritical. Copyright © 2014 John Wiley & Sons, Ltd.     

Theoretical analyses of nonaqueous phase liquid dissolution‐induced instability in two‐dimensional fluid‐saturated porous media

This paper deals with the theoretical aspects of nonaqueous phase liquid (NAPL)‐dissolution‐induced instability in two‐dimensional fluid‐saturated porous media including solute dispersion effects.After some weaknesses associated with the previous work are analyzed and overcome, a comprehensive dimensionless number, known as the Zhao number, is proposed to represent the main driving force and three controlling mechanisms of an NAPL‐dissolution system that has a finite domain. The linear stability analysis is carried out to derive the critical value of the comprehensive dimensionless number of the NAPL‐dissolution system in a limit case as the ratio of the equilibrium concentration to the density of the NAPL approaches zero. As a result, a theoretical criterion that can be used to assess the instability of planar NAPL‐dissolution fronts in two‐dimensional fluid‐saturated porous media of finite domains has been established. Not only can the present theoretical results be used for the theoretical understanding of the effect of solute dispersion on the instability of an NAPL‐dissolution front in the fluid‐saturated porous medium of either a finite domain or an infinite domain, but also they can be used as benchmark solutions for verifying numerical methods employed to simulate detailed morphological evolution processes of NAPL‐dissolution fronts in two‐dimensional fluid‐saturated porous media. Copyright © 2009 John Wiley & Sons, Ltd.     

Exact solutions for one‐dimensional transient response of fluid‐saturated porous media

Based on the Biot theory, the exact solutions for one‐dimensional transient response of single layer of fluid‐saturated porous media and semi‐infinite media are developed, in which the fluid and solid particles are assumed to be compressible and the inertial, viscous and mechanical couplings are taken into account. First, the control equations in terms of the solid displacement u and a relative displacement w are expressed in matrix form. For problems of single layer under homogeneous boundary conditions, the eigen‐values and the eigen‐functions are obtained by means of the variable separation method, and the displacement vector u is put forward using the searching method. In the case of nonhomogeneous boundary conditions, the boundary conditions are first homogenized, and the displacement field is constructed basing upon the eigen‐functions. Making use of the orthogonality of eigen‐functions, a series of ordinary differential equations with respect to dimensionless time and their corresponding initial conditions are obtained. Those differential equations are solved by the state‐space method, and the series solutions for three typical nonhomogeneous boundary conditions are developed. For semi‐infinite media, the exact solutions in integral form for two kinds of nonhomogeneous boundary conditions are presented by applying the cosine and sine transforms to the basic equations. Finally, three examples are studied to illustrate the validity of the solutions, and to assess the influence of the dynamic permeability coefficient and the fluid inertia to the transient response of porous media. Copyright © 2010 John Wiley & Sons, Ltd.     

Theoretical and numerical study of the steady‐state flow through finite fractured porous media

This paper investigates the two‐dimensional flow problem through an anisotropic porous medium containing several intersecting curved fractures. First, the governing equations of steady‐state fluid flow in a fractured porous body are summarized. The flow follows Darcy's law in matrix and Poiseuille's law in fractures. An infinite transversal permeability is considered for the fractures. A multi‐region boundary element method is used to derive a general pressure solution as a function of discharge through the fractures and the pressure and the normal flux on the domain boundary. The obtained solution fully accounts for the interaction and the intersection between fractures. A numerical procedure based on collocation method is presented to compute the unknowns on the boundaries and on the fractures. The numerical solution is validated by comparing with finite element solution or the results obtained for an infinite matrix. Pressure fields in the matrix are illustrated for domains containing several interconnected fractures, and mass balance at the intersection points is also checked. Copyright © 2013 John Wiley & Sons, Ltd.     

Theoretical and numerical analyses of convective instability in porous media with upward throughflow

Exact analytical solutions have been obtained for a hydrothermal system consisting of a horizontal porous layer with upward throughflow. The boundary conditions considered are constant temperature, constant pressure at the top, and constant vertical temperature gradient, constant Darcy velocity at the bottom of the layer. After deriving the exact analytical solutions, we examine the stability of the solutions using linear stability theory and the Galerkin method. It has been found that the exact solutions for such a hydrothermal system become unstable when the Rayleigh number of the system is equal to or greater than the corresponding critical Rayleigh number. For small and moderate Peclet numbers (Pe ⩽ 6), an increase in upward throughflow destabilizes the convective flow in the horizontal layer. To confirm these findings, the finite element method with the progressive asymptotic approach procedure is used to compute the convective cells in such a hydrothermal system. Copyright © 1999 John Wiley & Sons, Ltd.     

An interface-condition substitution strategy for theoretical study of dissolution-timescale reactive infiltration instability in fluid-saturated porous rocks

A theoretical study of reactive infiltration instability is conducted on the dissolution timescale. In the present theoretical study, the transient behavior of a dissolution-timescale reactive infiltration system needs to be considered, so that the upstream region of the chemical dissolution front should be finite. In addition, the chemical dissolution front of finite thickness should be considered on the dissolution timescale. Owing to these different considerations, it is very difficult, even in some special cases, to derive the first-order perturbation solutions of the reactive infiltration system on the dissolution timescale. To overcome this difficulty, an interface-condition substitution strategy is proposed in this paper. The basic idea behind the proposed strategy is that although the first-order perturbation equations in the downstream region cannot be directly solved in a purely mathematical manner, they should hold at the planar reference front, which is the interface between the upstream region and the downstream region. This can lead to two new equations at the interface. The main advantage of using the proposed interface-condition substitution strategy is that through using the original interface conditions as a bridge, the perturbation solutions for the dimensionless acid concentration, dimensionless Darcy velocity, and their derivatives involved in the two new equations at the interface can be evaluated just by using the obtained analytical solutions in the upstream region. The proposed strategy has been successfully used to derive the dimensionless growth rate, which is the key issue associated with the theoretical study of dissolution-timescale reactive infiltration instability in fluid-saturated porous rocks.     

A semianalytical approach for solving first-order perturbation equations of dissolution-timescale reactive infiltration instability problems in fluid-saturated rocks

This paper presents a semianalytical approach for solving first-order perturbation (FOP) equations, which are used to describe dissolution-timescale reactive infiltration instability (RII) problems in fluid-saturated rocks. The proposed approach contains two parts because the chemical dissolution reaction divides the whole problem domain into two subdomains. In the first part, the interface-condition substitution strategy is used to derive the analytical expressions of purely mathematical solutions for the FOP equations in the upstream subdomain, where the dissolution chemical reaction is ceased and the FOP equations are weakly coupled. In the second part, the finite element method (FEM) is used to derive the analytical expressions of numerical solutions for the FOP equations in the downstream subdomain, where the dissolution chemical reaction needs to be considered and the FOP equations are strongly coupled so that it is impossible to derive purely mathematical solutions for them. Particular attention is paid to the development of the element-by-element forward marching strategy, which is associated with the use of the FEM for solving this new kind of scientific problem. The related analytical results demonstrated that (1) both the dynamic characteristic of a reactive infiltration system and the dimensionless wavenumber can have pronounced influences on the distribution of the FOP dimensionless acid concentration within the entire domain of the dissolution-timescale RII problems in fluid-saturated rocks and (2) the FOP dimensionless acid concentration distribution exhibits two significantly different patterns in the upstream and downstream subdomains of the dissolution-timescale RII system.     

Modeling of dynamic cohesive fracture propagation in porous saturated media

In this paper, a mathematical model is presented for the analysis of dynamic fracture propagation in the saturated porous media. The solid behavior incorporates a discrete cohesive fracture model, coupled with the flow in porous media through the fracture network. The double‐nodded zero‐thickness cohesive interface element is employed for the mixed mode fracture behavior in tension and contact behavior in compression. The crack is automatically detected and propagated perpendicular to the maximum effective stress. The spatial discretization is continuously updated during the crack propagation. Numerical examples from the hydraulic fracturing test and the concrete gravity dam show the capability of the model to simulate dynamic fracture propagation. The comparison is performed between the quasi‐static and fully dynamic solutions, and the performance of two analyses is investigated on the values of crack length and crack mouth opening. Copyright © 2010 John Wiley & Sons, Ltd.     

Assessment of acceleration modelling for fluid‐filled porous media subjected to dynamic loading

The purpose of this paper is to examine the importance of different possible simplifying approximations when performing numerical simulations of fluid‐filled porous media subjected to dynamic loading. In particular, the relative importance of the various acceleration terms for both the solid and the fluid, especially the convective contribution, is assessed. The porous medium is modelled as a binary mixture of a solid phase, in the sense of a porous skeleton, and a fluid phase that represents both liquid and air in the pores. The solid particles are assumed to be intrinsically incompressible, whereas the fluid is assigned a finite intrinsic compressibility. Finite element (FE) simulations are carried out while assuming material properties and loading conditions representative for a road structure. The results show that, for the range of the material data used in the simulations, omitting the relative acceleration gives differences in the solution of the seepage velocity field, whereas omitting only the convective term does not lead to significant differences. Copyright © 2007 John Wiley & Sons, Ltd.     

A fully coupled element‐free Galerkin model for hydro‐mechanical analysis of advancement of fluid‐driven fractures in porous media

Hydraulic fracturing (HF) of underground formations has widely been used in different fields of engineering. Despite the technological advances in techniques of in situ HF, the industry uses semi‐analytical tools to design HF treatment. This is due to the complex interaction among various mechanisms involved in this process, so that for thorough simulations of HF operations a fully coupled numerical model is required. In this study, using element‐free Galerkin (EFG) mesh‐less method, a new formulation for numerical modeling of hydraulic fracture propagation in porous media is developed. This numerical approach, which is based on the simultaneous solution of equilibrium and continuity equations, considers the hydro‐mechanical coupling between the crack and its surrounding porous medium. Therefore, the developed EFG model is capable of simulating fluid leak‐off and fluid lag phenomena. To create the discrete equation system, the Galerkin technique is applied, and the essential boundary conditions are imposed via penalty method. Then, the resultant constrained integral equations are discretized in space using EFG shape functions. For temporal discretization, a fully implicit scheme is employed. The final set of algebraic equations that forms a non‐linear equation system is solved using the direct iterative procedure. Modeling of cracks is performed on the basis of linear elastic fracture mechanics, and for this purpose, the so‐called diffraction method is employed. For verification of the model, a number of problems are solved. According to the obtained results, the developed EFG computer program can successfully be applied for simulating the complex process of hydraulic fracture propagation in porous media. Copyright © 2016 John Wiley & Sons, Ltd.     

悬浮颗粒的浓度对其在饱和多孔介质中迁移和沉积特性的影响

多孔介质中悬浮颗粒迁移和沉积特性的研究对地下污染物净化、石油开采、核废料处置、水土保持等有很重要的意义。对4种不同浓度的悬浮颗粒在3种不同的渗流速度下进行室内试验,研究悬浮颗粒的浓度对其迁移和沉积特性的影响。结果表明,在一定的悬浮颗粒浓度下,随着渗流速度的增加,穿透曲线中的悬浮颗粒的相对浓度也增大。同时,渗流速度一定时,悬浮颗粒的浓度存在一个临界值,小于该临界值,穿透曲线中的相对浓度随悬浮颗粒的浓度增大而增大;大于该临界值时,相对浓度随悬浮颗粒的浓度增大而减小。另外,悬浮颗粒的临界浓度是与渗流速度相关的,随着渗流速度增加,悬浮颗粒的临界浓度也逐渐增大     

General coupling extended multiscale FEM for elasto‐plastic consolidation analysis of heterogeneous saturated porous media

This paper presents a general coupling extended multiscale FEM (GCEMs) for solving the coupling problem of elasto‐plastic consolidation of heterogeneous saturated porous media. In the GCEMs, the numerical multiscale base functions for the solid skeleton and fluid phase of the coupling system are all constructed on the basis of the equivalent stiffness matrix of the unit cell, which not only contain the interaction between the solid and fluid phases but also consider the time effect. Furthermore, in order to improve the computational accuracy for two‐dimensional problems, a multi‐node coarse element strategy for the GCEMs is proposed, and a two‐scale iteration algorithm for the elasto‐plastic consolidation analysis is developed. Some one‐dimensional and two‐dimensional homogeneous and heterogeneous numerical examples are carried out to validate the proposed method through the comparison with the coupling multiscale FEM and standard FEM. Numerical results show that the newly developed GCEMs can almost preserve the same convergent property as the standard FEM and also possesses the advantages of high computational efficiency. In addition, the GCEMs can be easily applied to other coupling multifield and multiphase transient problems. Copyright © 2014 John Wiley & Sons, Ltd.     

On computation of strain‐dependent permeability of rocks and rock‐like porous media

Determination of transport properties of geomaterials is an important issue in many fields of engineering analysis and design. For example, in petroleum engineering, in situ permeability of an oil reservoir may be crucial in establishing its viability for exploitation, whilst prevention of leakage from underground storage facilities for oil and gas, nuclear waste as well as viability of CO₂ sequestration projects crucially depends on its long‐term values. Permeability is indirectly related to the porosity, pore‐size distribution and pore architecture of the porous media. These parameters evolve when a strain field is imposed. Physical measurement of permeability under a strain field in laboratory conditions is difficult, expensive and prone to a number of uncertainties. In the past, pore network models have been used to compute permeability of materials under stress/strain‐free conditions. In this paper, we propose an enhanced pore network model to compute permeability of rocks and rock‐like porous media under a stress/strain field. Data of pore‐size distribution obtained from mercury intrusion porosimetry are used to compute permeability of rock samples from various unspecified oilfields in the world. It is shown that the two permeabilities can be predicted from the model with sufficient accuracy. A hypothesis for change in porosity, pore‐size distribution and pore architecture as a result of imposed mechanical strains is then proposed. Based on this, permeability is computed again for one of the rock samples under uniaxial and triaxial compressive and tensile strain fields. It is shown that depending on the state of strain field imposed, permeability evolves in an anisotropic manner. Permeability under tensile strain field increases dramatically compared with the reduction that takes place under compressive strain field of the same magnitude. Copyright © 2014 John Wiley & Sons, Ltd.     

Interaction between different internal length scales in strain localization analysis of fully and partially saturated porous media—the 1‐D case

The paper analyses the interaction between two internal length scales during dynamic strain localization in multiphase porous materials. The first internal length is introduced in the mathematical model by the gradient‐dependent plasticity for the solid skeleton, while the second one is naturally contained in the multiphase model and is due to the seepage process of the water via Darcy's law, which induces a rate‐dependent behaviour of the solid skeleton. Numerical results of a one‐dimensional example of water saturated porous medium demonstrate the competing effect between these two length scales. The porous medium is here treated as a multiphase continuum, with the pores filled by water and air, the last one at constant atmospheric pressure. Copyright © 2005 John Wiley & Sons, Ltd.     

Three‐dimensional nonlinear finite element analysis of pile groups in saturated porous media using a new transmitting boundary

The dynamic behaviour of pile groups subjected to an earthquake base shaking is analysed. An analysis is formulated in the time domain and the effects of material nonlinearity of soil, pile–soil–pile kinematic interaction and the superstructure–foundation inertial interaction on seismic response are investigated. Prediction of response of pile group–soil system during a large earthquake requires consideration of various aspects such as the nonlinear and elasto‐plastic behaviour of soil, pore water pressure generation in soil, radiation of energy away from the pile, etc. A fully explicit dynamic finite element scheme is developed for saturated porous media, based on the extension of the original formulation by Biot having solid displacement (u) and relative fluid displacement (w) as primary variables (u–w formulation). All linear relative fluid acceleration terms are included in this formulation. A new three‐dimensional transmitting boundary that was developed in cartesian co‐ordinate system for dynamic response analysis of fluid‐saturated porous media is implemented to avoid wave reflections towards the structure. In contrast to traditional methods, this boundary is able to absorb surface waves as well as body waves. The pile–soil interaction problem is analysed and it is shown that the results from the fully coupled procedure, using the advanced transmitting boundary, compare reasonably well with centrifuge data. Copyright © 2007 John Wiley & Sons, Ltd.     

Numerical study of two‐phase fluid distributions in fractured porous media

Two‐phase fluid distributions in fractured porous media were studied using a single‐component multiphase (SCMP) lattice Boltzmann method (LBM), which was selected among three commonly used numerical approaches through a comparison against the available results of micro X‐ray computed tomography. The influence of the initial configuration and the periodic boundary conditions in the SCMP LBM for the fluid distribution analysis were investigated as well. It was revealed that regular porous media are sensitive to the initial distribution, whereas irregular porous media are insensitive. Moreover, to eliminate the influence of boundaries, the model's buffer size of an SCMP LBM simulation was suggested to be taken as approximately 12.5 times the average particle size. Then, the two‐phase fluid distribution of a porous medium was numerically studied using the SCMP LBM. Both detailed distribution patterns and macroscopic morphology parameters were reasonably well captured. Finally, the two‐phase fluid distributions in a fractured porous media were investigated. The influence of the degree of saturation, fracture length, and fracture width on the fluid distributions and migration was explored. Copyright © 2015 John Wiley & Sons, Ltd.     

Two‐scale modeling of solute dispersion in unsaturated double‐porosity media: Homogenization and experimental validation

A two‐scale modeling of solute transport in double‐porosity (DP) media under unsaturated water flow conditions is presented. The macroscopic model was developed by applying the asymptotic homogenization method. It is based on theoretical and empirical considerations dealing with the orders of magnitude of characteristic quantities involved in the process. For this purpose a physical model that mimics the behavior of DP medium was built. The resulting two‐equation model relies on a coupling exchange term between micro‐ and macro‐porosity subdomains associated with local non‐equilibrium solute concentrations. The model was numerically implemented (Comsol Multiphysics^®) to simulate the macroscopic one‐dimensional physical process taking place into the porous medium of 3D periodic microstructure. A series of dispersion experiments of NaCl solution under unsaturated steady‐state flow conditions were performed. The experimental results were used first to calibrate the dispersion coefficient of the model, and second to validate it through two other independent experiments. The excellent agreement between the numerical simulations and the measurements of the time evolution of the non‐symmetrical breakthrough curves provides a proof of predictive capacity of the developed model. Copyright © 2010 John Wiley & Sons, Ltd.     

One‐dimensional dynamics of saturated incompressible porous media: analytical solutions and influence of inertia terms

The complexity of formulations for the hydromechanical coupled mechanics of porous media is typically minimised by simplifying assumptions such as neglecting the effect of inertia terms. For example, three formulations commonly employed to model practical problems are classified as fully dynamic, simplified dynamic and quasi‐static. Thus, depending on the porous media conditions, each formulation will have advantages and limitations. This paper presents a comprehensive analysis of these limitations when solving one‐dimensional fully saturated porous media problems in addition to a new solution that considers a more general loading situation. A phase diagram is developed to assist on the selection of which formulation is more appropriate and convenient regarding particular cases of porosity and hydraulic conductivity values. Non‐dimensional formulations are proposed to achieve this goal. Results using the analytical solutions are compared against numerical values obtained with the finite element method, and the effect of porosity is investigated. Copyright © 2016 John Wiley & Sons, Ltd.