Studies of variations in the vertical ozone profiles over India

The latitudinal and temporal variations in the vertical profiles of ozone over the Indian subcontinent are discussed. In the equatorial atmosphere represented by Trivandrum (8°N) and Poona (18°N), while tropospheric ozone shows marked seasonal variations, the basic pattern of the vertical distribution of ozone in the stratosphere remains practically unchanged throughout the year, with a maximum at about 28 to 26 km and a minimum just below the tropopause. The maximum total ozone occurs over Trivandrum in the summer monsoon season and the latitudinal anomaly observed over the Indian monsoon area at this time is explained as arising from the horizontal transport of ozone-rich stratospheric air from over the thermal equator to the southern regions.In the higher latitudes represented by New Delhi (28°N), the maximum occurs at 23 km. Delhi, which lies in the temperate regime in winter, shows marked day-to-day variations in association with western disturbances and the strong westerly jet stream that lies over north and central India at this time.Although the basic pattern of the vertical distribution of ozone in the equatorial atmosphere is generally the same in all seasons, significant though small changes occur in the lower stratosphere and in the troposphere. There are small perturbations in the ozone and temperature structures, distinct ozone maxima being always associated with temperature inversions. There are also large perturbances not related to temperature, ozone-depleted regions normally reflecting a stratification of either destructive processes or materials such as dust layers or clouds at these levels. Particularly interesting are the upper tropospheric levels just below the tropopause where the ozone concentration is consistently the smallest, in all seasons and at all places where soundings have been made in India.     

Studies of the vertical distribution of atmospheric ozone in association with western disturbances over India

A series of ozone soundings were made at New Delhi (77°E 28°N) from 21 to 30 January 1969 and 10 to 22 February 1972 to study the changes in the vertical distribution of atmospheric ozone associated with western disturbances. The sonde used was the Indian ozonesonde made in the Instruments Laboratories at Poona.In February 1972, two western disturbances moved eastwards in quick succession across the western Himalayas, the first between the 11th and 13th and the second between the 13th and 15th. Associated with the first tropospheric trough was a high-speed jet stream with wind speeds reaching 180 knots, when the tropopause descended to 304 mb over Delhi. The second trough had no high-speed jet associated with it and the tropopause was at 227 mb. Ozone maxima were observed at 350, 180 and 125 mb in addition to the main peak at 35 mb in association with the upper tropospheric troughs over Delhi and its neighbourhood. A similar lowering of the tropopause and the influx of ozone in shallow layers was observed during the passage of two upper air troughs in January 1969. The study shows that with the approach of upper tropospheric troughs and the simultaneous lowering of the tropopause there is an increased influx in shallow layers of middle latitude ozone-rich air through breaks in the tropopause, replacing the subropical ozone-poor air over the station.     

Ozone distribution over India

The spatial and temporal distribution of total ozone over India and its vertical distribution in theatmosphere during 1964–1969 was studied using Dobson spectrophotometer data at a network of six stations in India, Srinagar (34°N), New Delhi (28°N), Varanasi (24°N), Ahmedabad (23°N), Dum Dum (22°N), and Kodaikanal (10°N). The annual and seasonal variations show a clear phase-shift in the occurrence of the ozone maxima and minima as one proceeds from higher to lower latitudes in the tropics. In the northern stations (north of 25°N) the increase in total ozone during the course of the annual variation is caused by the fractional increase in all layers from the ground to 28 km, the main contribution coming from 10–24 km. Above 28 km the concentration changes roughly in accordance with photochemical production.In lower latitudes (south of 25°N) an increase in total ozone amount during the annual cycle is caused by a gradual increase in all the layers from the ground to 36 km above which the variation is negligible.     

Changes of Ozone Content at Middle Latitudes During Forbush Decreases in Cosmic Rays

The variations of total ozone at Alma-Ata (43°N, 76 °E) and ozone profiles obtained by balloon sounding at Tateno (36°N, 140°E), Wallops Island (38°N, 75°W) and Cagliari (39°N, 9°E) in the periods of Forbush decreases (FD) in galactic cosmic rays have been analysed. A decrease of total ozone was observed in the initial stage of the FD and an increase 10–11 days later. The average total deviations calculated using the superposed epoch method for 9 FD events are equal to 30 D. U. in the positive and to –18 D. U. in the negative phase. The changes of average ozone profiles, associated with 26 FD events, are more significant in the lower stratosphere and upper troposphere. The decrease of the partial ozone pressure at a height of 12–15 km is about 30 mb. These vertical variations of ozone coincide with the average changes of the respective temperature profiles. A cooling, on the average, of 3°C was observed at 12–15 km, and a heating of 4°C below this level.     

Meridional distribution of tropospheric ozone from measurements aboard commercial airliners

Aboard commercial airliners twenty registrations of the ozone concentration of the upper troposphere were carried out within a period of 14 months between Europe and South Africa. Nearly each of these meridional ozone profiles shows an approximately constant ozone content between 25°S and 25°N with a pronounced seasonal variation. Most of these profiles show two marked peaks of the ozone concentration at about 30°N and between 40° and 45°N. Though the number of these registrations is not sufficient for statistical computations, the first results confirm the meridional ozone distribution, which was expected from studies with ozone-radiosonde soundings. Moreover a strong asymmetry of the northern and southern hemisphere is confirmed by these ozone measurements.     

Ozone concentration studies and ozone flux measurements near the ground at Poona

Using a modified Brewer bubbler ozone sensor, continuous measurements of the ozone concentration near the ground were made at Poona (18°N, 73°E) for one year 1969–1970. The surface ozone concentration shows a pronounced seasonal variation, with a minimum during the monsoon months and a maximum during the pre-monsoon summer months. There is also a marked diurnal variation in surface ozone concentration which clearly follows the diurnal variation of temperature and is again a maximum during the summer months and a minimum during the monsoon. A secondary maximum in ozone concentration occurs in the forenoon during the winter months, associated with the temperature inversions that occur near the ground in this season.Both ozone and radioactive tracers, such as Cs-137 both in air and in precipitation show variations indicating that they have identical source regions and sinks. The latitudinal anomaly of surface ozone and Cs-137 observed in the low latitudes over India is explained as arising from the reduction in the rate of transfer of these tracers from the stratosphere to the troposphere, as a result of the reversed circulation at the upper levels in this season.From continuous measurements of surface ozone made with three electrochemical sensors exposed at three levels, 0, 15 and 35 m above the ground, the ozone flux has been directly calculated for the first time in the tropics. The ozone flux was calculated using both the rate of decay method used by Kroening and Ney and Regener's profile method. The profile method gives values of the order of 1.71 to 7.04×10¹¹ mol/cm²/sec and that obtained by the rate of decay method is found to be 4.2 to 5.6×10¹¹ mol/cm²/sec and are in good agreement with the flux values reported by other investigators.     

Ozone distribution over Mediterranean,central and southeast Europe during the International Quiet Sun Year (1964–1965)

Summary Ozone observations made during 1964 and 1965 at nine Mediterranean, central and southeast European stations (latitudes 38–52°N, longitudes 9–23°E) reveal patterns of seasonal and shorter time-variations in total ozone as well as in vertical ozone distribution. During the winter-spring season, a significant increase (20%) of ozone occurs essentially simultaneously with the spring stratospheric warming, and is noticed at all stations.—Autocorrelation coefficients show that the total ozone on any day is strongly related to the total ozone of the preceding four days in summer or one or two days in winter-spring or autumn. Changes of total ozone in southeast Europe correlate closely with those in Mediterranean Europe, and less closely with those from north central Europe.—Power spectrum analysis detects the dependence of ozone changes on processes with periods longer than 6–8 days, and indicates a significant oscillation with a period of 14–15 days, perhaps a result of the direct influence of lower stratospheric circumhemispheric circulation. — Reliable vertical ozone soundings were not available from all stations. The mean vertical profiles at Arosa, Switzerland (47°N) and Belsk, Poland (51°) are very similar. More than 60% of the variability of the total ozone is contributed by changes in ozone concentration between 10 and 24 km; less than 10% is due to variations above 33 km. Changes in ozone partial pressure at different altitudes, and relationships of those changes to total ozone, indicates that a mean vertical ozone distribution may be described adequately by considering the ozone changes in four layers: a) the troposphere, b) the lower stratosphere up to 24 km, c) a transition layer from 24 km to a variable upper border at 33–37 km, and d) the layer above 33–37 km.Part of this paper was presented at the Ozone Seminar in Potsdam, Germany, 27 September 1966.     

Surface ozone variation associated with rainfall

Using an electrochemical surface ozone recorder, continuous monitoring of surface ozone is being carried out at Trivandrum (8°29N, 76°57E). A study of those surface ozone data together with rainfall and temperature reveals certain variations in ozone associated with rainfall, apart from other established variations reported so far. While daytime rainfall brings a decrease in surface ozone, nighttime rainfall produces an increase. The change in the surface ozone persists for a longer duration than the rainfall.     

Short-term ground ozone fluctuations at Poona

Short-term fluctuations superimposed on the diurnal variations of surface ozone recorded at Poona during 1969–1970 are discussed.While there is a net production of ozone during electrical discharges in a thunder cloud, the surface ozone recorder often registered a decrease in surface ozone concentration. This decrease coincided with updraughts generated during the formation of a thunderstorm. Similar sharp increases in ozone were observed with downdraughts. In cases of lightning without the development of a thunderstorm over the station, an increase in ozone density was observed just after the first lightning discharge.Apart from the fluctuations associated with thunderstorms in summer, sharp fluctuations in density were also noticed during winter, in the mornings. Abrupt falls in ozone occur with the formation of a stable layer near the ground at night and a sudden surge after the breaking up of the layers in the morning. The changes in ozone are, however, much more pronounced than those in temperature and wind and this striking correlation between surface ozone, surface air temperature and wind provides a unique tool for the study of low-level temperature inversions, their establishment and destruction.     

Statistical interpolation of ozone measurements from satellite data (TOMS, SBUV and SAGE II) using the kriging method

This study demonstrates that ordinary kriging in spherical coordinates using experimental semi-variograms provides highly usable results, especially near the pole in winter and/or where there could be data missing over large areas. In addition, kriging allows display of the spatial variability of daily ozone measurements at different pressure levels. Three satellite data sets were used: Total Ozone Mapping Spectrometer (TOMS) data, Solar Backscattered UltraViolet (SBUV), and the Stratospheric Aerosol and Gas Experiment (SAGE II) ozone profiles. Since SBUV is a nadir-viewing instrument, measurements are only taken along the sun-synchronous polar orbits of the satellite. SAGE II is a limb-viewing solar occultation instrument, and measurements have high vertical resolution but poor daily coverage. TOMS has wider coverage with equidistant distribution of data (resolution 1° × 1.25°) but provides no vertical information. Comparisons of the resulting SBUV-interpolated (column-integrated) ozone field with TOMS data are strongly in agreement, with a global correlation of close to 98%. Comparisons of SBUV-interpolated ozone profiles with daily SAGE II profiles are relatively good, and comparable to those found in the literature. The interpolated ozone layers at different pressure levels are shown.     

Gravity wave intensity and momentum fluxes in the mesosphere over Shigaraki, Japan (35°N, 136°E) during 1986–1997

Averaged seasonal variations of wind perturbation intensities and vertical flux of horizontal momentum produced by internal gravity waves (IGWs) with periods 0.2/1 h and 1/6 h are studied at the altitudes 65/80 km using the MU radar measurement data from the middle and upper atmosphere during 1986/1997 at Shigaraki, Japan (35°N, 136°E). IGW intensity has maxima in winter and summer, winter values having substantial interannual variations. Mean wave momentum flux is directed to the west in winter and to the east in summer, opposite to the mean wind in the middle atmosphere. Major IGW momentum fluxes come to the mesosphere over Shigaraki from the Pacific direction in winter and continental Asia in summer.     

Simultaneous vertical profiles of condensation nuclei and ozone in the lower troposphere

Summary Eight vertical profiles compiled from simultaneous measurements of Aitken nuclei and ozone concentrations over Germany in different weather conditions are discussed. The position and shape of the profiles is shown to depend on the prevailing weather conditions and the type of air masses. High aerosol concentrations in smoke plumes correlate in some cases with lower ozone concentrations, indicating that ozone in such cases is destroyed in the presence of high concentrations of pollutants such as aerosols and gases. A layered structure in the profiles was found only in association with temperature inversions and where the air above 2 km was subsiding, and was not found in convective parts of the troposphere.     

Three-dimensional analysis of ozone and PM<Subscript>2.5</Subscript> distributions obtained by observations of tethered balloon and unmanned aerial vehicle in Shanghai,China

A lightweight unmanned aerial vehicle (UAV) and a tethered balloon platform were jointly used to investigate three-dimensional distributions of ozone and PM_2.5 concentrations within the lower troposphere (1000 m) at a localized coastal area in Shanghai, China. Eight tethered balloon soundings and three UAV flights were conducted on May 25, 2016. Generalized additive models (GAMs) were used to quantitatively describe the relationships between air pollutants and other obtained parameters. Field observations showed that large variations were captured both in the vertical and horizontal distributions of ozone and PM_2.5 concentrations. Significant stratified layers of ozone and PM_2.5 concentrations as well as wind directions were observed throughout the day. Estimated bulk Richardson numbers indicate that the vertical mixing of air masses within the lower troposphere were heavily suppressed throughout the day, leading to much higher concentrations of ozone and PM_2.5 in the planetary boundary layer (PBL). The NO and NO₂ concentrations in the experimental field were much lower than that in the urban area of Shanghai and demonstrated totally different vertical distribution patterns from that of ozone and PM_2.5. This indicates that aged air masses of different sources were transported to the experimental field at different heights. Results derived from the GAMs showed that the aggregate impact of the selected variables for the vertical variations can explain 94.3% of the variance in ozone and 94.5% in PM_2.5. Air temperature, relative humidity and atmospheric pressure had the strongest effects on the variations of ozone and PM_2.5. As for the horizontal variations, the GAMs can explain 56.3% of the variance in ozone and 57.6% in PM_2.5. The strongest effect on ozone was related to air temperature, while PM_2.5 was related to relative humidity. The output of GAMs also implied that fine aerosol particles were in the stage of growth in the experimental field, which is different from ozone (aged air parcels of ozone). Geographical parameters influenced the horizontal variations of ozone and PM_2.5 concentrations by changing underlying surface types. The differences of thermodynamic properties between land and sea resulted in quick changes of PBL height, air temperature and dew point over the coastal area, which was linked to the extent of vertical mixing at different locations. The results of GAMs can be used to analyze the sources and formation mechanisms of ozone and PM_2.5 pollutions at a localized area.     

Night-to-night changes in the characteristics of gravity waves at stratospheric and lower-mesospheric heights

Observations made with the co-located Rayleigh lidar and MST radar systems at Aberystwyth (52.4°N, 4.1°W) in Wales and radiosondes from Valentia (51.9°N, 10.2°W) in Eire are used to investigate the changes in the vertical propagation of gravity waves during periods of 4 days in June 1995 and February 1993. In each month, the lidar observations show that the wave activity in the upper stratosphere and lower mesosphere changes between two pairs of days. The radar and radiosonde measurements indicate that mountain waves make no contribution to the changes in intensity. Instead, the changes seem to arise largely from the presence or absence of long-period waves with vertical wavelengths near 8 and 10 km in June and February, respectively. The influence of such waves on the vertical wavenumber spectra is examined and related to the evidence for convective instabilities provided by the temperature profiles.     

A decadal solar effect in the tropics in July–August

The availability of global gridded precipitation and outgoing long-wave radiation (OLR) data after 1978 makes possible an investigation of the influence of the decadal solar oscillation in the tropics during three solar maxima and two solar minima. The NCEP/NCAR reanalyses starting in the 1950s allows the inclusion of an additional two solar maxima and minima to look for consistency of response across a longer time period. In the northern summer (July–August), the major climatological tropical precipitation maxima are intensified in solar maxima compared to solar minima during the period 1979–2002. The regions of this enhanced climatological precipitation extend from the Indian monsoon to the West Pacific oceanic warm pool and farther eastwards in the Intertropical Convergence Zone of the North Pacific and North American Monsoon, to the tropical Atlantic and greater rainfall over the Sahel and central Africa. The differences between solar maxima and minima in the zonal mean temperature through the depth of the troposphere, OLR, tropospheric vertical motion, and tropopause temperature are consistent with the differences in the rainfall. The upward vertical motion is stronger in regions of enhanced tropical precipitation, tropospheric temperatures are higher, tropopause temperatures are lower, and the OLR is reduced due to higher, colder cloud tops over the areas of deeper convective rainfall in the solar maxima than in the minima. These differences between the extremes of the solar cycle suggest that an increase in solar forcing intensifies the Hadley and Walker circulations, with greater solar forcing resulting in strengthened regional climatological tropical precipitation regimes. These effects are as strong or even more pronounced when warm and cold extremes in the Southern Oscillation are removed from the analyses. Additionally, lower stratospheric temperatures and geopotential heights are higher with greater solar forcing suggesting ozone interactions with solar forcing in the upper stratosphere.     

Vertical velocities associated with gravity waves measured in the mesosphere and lower thermosphere with the EISCAT VHF radar

The EISCAT VHF radar (69.4°N, 19.1°E) has been used to record vertical winds at mesopause heights on a total of 31 days between June 1990 and January 1993. The data reveal a motion field dominated by quasi-monochromatic gravity waves with representative apparent periods of 30–40 min, amplitudes of up to 2.5 m s^–1 and large vertical wavelength. In some instances waves appear to be ducted. Vertical profiles of the vertical-velocity variance display a variety of forms, with little indication of systematic wave growth with height. Daily mean variance profiles evaluated for consecutive days of recording show that the general shape of the variance profiles persists over several days. The mean variance evaluated over a 10 km height range has values from 1.2 m²s^–2 to 6.5 m²s^–2 and suggests a semi-annual seasonal cycle with equinoctial minima and solsticial maxima. The mean vertical wavenumber spectrum evaluated at heights up to 86 km has a slope (spectral index) of -1.36 ± 0.2, consistent with observations at lower heights but disagreeing with the predictions of a number of saturation theories advanced to explain gravity-wave spectra. The spectral slopes evaluated for individual days have a range of values, and steeper slopes are observed in summer than in winter. The spectra also appear to be generally steeper on days with lower mean vertical-velocity variance.     

Solar response in the vertical structure of ozone and temperature in the tropical stratosphere

The aim of the present paper is to study the solar response in the vertical structure of ozone and temperature over the Indian tropical region and a search for any mutual relationship between their solar coefficients on a decadal scale in the lower stratosphere. For the purpose, the data obtained by ozonesonde and Umkehr methods for the lower stratospheric ozone and that of the total ozone amount from Dobson spectrophotometer during the period 1979–2001 have been analyzed. These data are analyzed using the multi-functional regression model, which takes into account most of the known natural and anthropogenic signals. The NCEP- and MSU-satellite data for the temperature over this region have been used. Results indicate an in-phase correlation of around 0.5 between ozone and solar flux (F10.7) in the vertical structure over the equatorial station, Trivandrum (8.3°N) but no significant correlation over Pune (18.3°N). The solar components of ozone and temperature indicate an in-phase but poor correlation in the lower stratospheric altitudes over both stations. However, when total ozone content data is analyzed, it indicates a very high correlation (⩾0.9) between the solar components of ozone and temperature. The solar trend in the vertical distribution of ozone is found to be of the order of 5–25% per 100 units of F10.7 solar flux for Trivandrum but it is relatively smaller (1.6–15.2%) over Pune. The solar dependence of temperature is found to be quite significant for the entire Indian tropical region with not much latitudinal variation.     

Diurnal and semidiurnal tide in the upper middle atmosphere during the first year of simultaneous MF radar observations in northern and southern Japan (45°N and 31°N)

The climatology of mean wind, diurnal and semidiurnal tide during the first year (1996–1997) of simultaneous wind observations at Wakkanai (45.4°N, 141.7°E) and Yamagawa (31.2°N, 130.6°E) is presented. The locations of the radars allow us to describe the latitudinal dependence of the tides. Tidal amplitude and phase profiles are compared with those of the global scale wave model (GSWM). While the observed amplitude profiles of the diurnal tide agree well with the GSWM values, the observed phase profiles often indicate longer vertical wavelengths than the GSWM phase profiles. In contrast to the GSWM simulation, the observations show a strong bimodal structure of the diurnal tide, with the phase advancing about 6 hours from summer to winter.     

The average tropospheric ozone content and its variation with season and latitude as a result of the global ozone circulation

Evaluations of radiosonde soundings over North America and Europe, measurements aboard commercial airlines, and permanent ozone registrations at nineteen ground-based stations between Tromsö, Norway, and Hermanus, South Africa, yield three belts of higher ozone intrusion from the stratosphera and maximum values of the annual means at about 30°N, at between 40°–45°N and at about 60°N. A marked decrease of the annual mean values of the tropospheric ozone is detected towards the equator and the pole, respectively.In the northen hemisphere the maximum of the annual cycle of the tropospheric ozone concentration occurs in spring at high latitudes and in summer at mid-latitudes.For the tropical region from 30°S to 30°N a strong asymmetry of the northern and southern hemisphere occurs. This fact is discussed in detail. The higher troposphere of the tropics seems to be a wellmixed reservoir and mainly supplied with ozone from the tropopause gap region in the northern hemisphere. The ozone distribution in the lower troposphere of the whole tropics seems to be controlled by the up and down movements of the Hadley cell. The features of large-scale and seasonal variation of tropospheric ozone are discussed in connection with the ozone circulation in the stratosphere, the dynamic processes near the tropopause and the destruction rate at the earth's surface.