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西藏甲玛超大型铜矿石榴子石特征及成因意义 总被引:3,自引:0,他引:3
石石榴子石是西藏甲玛超大型铜多金属矿床的主要矽卡岩矿物,分布广、颜色变化大,石榴子石矽卡岩中矿化好,是开展甲玛矽卡岩成因研究的一个重要切入点。通过对甲玛矿区大量岩矿心的地质编录,归纳石榴子石的颜色、晶形、矿物组合、矿化等地质现象,总结石榴子石在甲玛矿床的空间分布、矿化特征等,结合显微镜下鉴定,分析石榴子石的矿物学特征,并通过电子探针分析其化学成分。甲玛石榴子石集中于矽卡岩中,少量分布于角岩、大理岩和斑岩中。石榴子石为钙铁-钙铝榴石系列,以钙铁榴石为主,发育颜色与成分环带,光性异常致部分非均质。深色环带的SiO2、Al2O3含量较浅色环带高,而TFeO含量相反。石榴子石形成于矽卡岩早期,为晚期Cu、Mo、Pb、Zn、Au、Ag等多金属硫化物沉淀富集提供了有利空间。甲玛石榴子石的矿物学特征、化学成分组成、REE特征、流体包裹体、H-O同位素特征等显示其属于接触交代成因,认为甲玛是典型的岩浆热液接触交代矽卡岩型铜多金属矿床。 相似文献
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Alteration of hedenbergite,diopsite(both natural and synthetie),and andradite bas been experimentally studied at 300-800℃ and 200-2,000 atm.The alteration in various degree has been noted for all these minerals in solutions over a wide range of pH values.It has been shown that,hedenbergite is the most unstable,while andradite the most stable,A preliminary disenssion is given in the light of experimental resalts and pertinent geological environments. 相似文献
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国内首次发现的粤北下庄铀矿田竹筒尖矿床产出的束磷钙铀矿,在空间上与微晶石英和变钙铀云母紧密共生。该矿物多为纤维状、束状和放射状集合体;亮黄色,玻璃光泽,透明;条痕为浅黄色,摩氏硬度约为3;其具有一组平行于{010}的完全解理及平行于{100}和{001}的两组解理,贝壳状断口呈油脂光泽;单偏光下,该矿物为淡黄色;正交偏光下,具有鲜艳的高级干涉色。光性特征为对称消光,二轴晶负光性,正延性。电子探针分析显示,矿物主要由U、P、Ca这3种元素组成,其平均含量分别为UO3 68.64%、P2O5 11.70%、CaO 9.21%和杂质0.28%,另有H2O 9.25%,总量99.26%。按O=16计算的经验化学式可写为(Ca2.02,K0.05,Mg0.01)2.08(UO2,TiO2,PbO)2.97O1.97(PO4)2.03·6.32 H2O。X射线粉晶衍射分析表明,该矿物属于正交晶系,空间群为Pbca,晶胞参数:a=1.742 3(5) nm,b=1.603 2(4) nm,c=1.359 9(2) nm;α=β=γ=90°,V=3.798 64 nm3 ;强衍射线有7.994 Å和4.003 Å等。矿物的红外吸收光谱强峰主要为3 427.10、1 622.05、1 062.62、973.26和890.91 cm-1等。上述特征与已知的束磷钙铀矿极其类似。 相似文献
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国内首次发现的粤北下庄铀矿田竹筒尖矿床产出的束磷钙铀矿,在空间上与微晶石英和变钙铀云母紧密共生。该矿物多为纤维状、束状和放射状集合体;亮黄色,玻璃光泽,透明;条痕为浅黄色,摩氏硬度约为3;其具有一组平行于{010}的完全解理及平行于{100}和{001}的两组解理,贝壳状断口呈油脂光泽;单偏光下,该矿物为淡黄色;正交偏光下,具有鲜艳的高级干涉色。光性特征为对称消光,二轴晶负光性,正延性。电子探针分析显示,矿物主要由U、P、Ca这3种元素组成,其平均含量分别为UO368.64%、P2O511.70%、CaO 9.21%和杂质0.28%,另有H2O9.25%,总量99.26%。按O=16计算的经验化学式可写为(Ca2.02,K0.05,Mg0.01)2.08(UO2,TiO2,PbO)2.97O1.97(PO4)2.03·6.32 H2O。X射线粉晶衍射分析表明,该矿物属于正交晶系,空间群为Pbca,晶胞参数:a=1.742 3(5)nm,b=1.603 2(4)nm,c=1.359 9(2)nm;α=β=γ=90°,V=3.798 64 nm3;强衍射线有7.994和4.003等。矿物的红外吸收光谱强峰主要为3 427.10、1 622.05、1 062.62、973.26和890.91 cm-1等。上述特征与已知的束磷钙铀矿极其类似。 相似文献
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广西隆华铝土矿的矿物学特征研究 总被引:1,自引:0,他引:1
广西隆华铝土矿是一水硬铝石型铝土矿,该矿的矿物组成主要为硬水铝石,其次有三水铝石、软水铝石、高岭石、伊利石、鲕绿泥石、锐钛矿、金红石、铝赤铁矿及锂硬锰矿等。硬水矿石中主要元素为铝,且分布较均匀,适应于高压拜耳法溶矿。本矿床的底泥中发现有一未知矿物,经X射线衍射分析及格林—凯利(Greene-Kelly,1953)方法鉴别,该矿物为贝得石;经蒙脱石-贝得石系列的蒙脱石群定量法(Jones,1964)测定,该矿物的含量为15.45%。 相似文献
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对产于多米尼加的海纹石样品进行了矿物学测试和分析.镜下观察显示,海纹石呈致密的纤维状结构,纤维长约0.01~0.02 mm;X射线衍射表明,海纹石样品主要由针钠钙石组成,并未检测到其它杂质成分,与能谱分析结果一致;不同色调的海纹石样品在红外光谱和紫外-可见光吸收光谱上都没有表现出本质的差别. 相似文献
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湘中地区煤矸石的矿物学特征研究 总被引:4,自引:0,他引:4
本文通过化学分析、岩矿鉴定、X射线衍射和扫描电镜对湘中煤矸石的矿物学特征进行了研究,查明了湘中煤矸石的化学成分特征、矿物组成特征、高岭石和绢云母的结晶学特征,在此基础上简单地分类,并提出了相应类型的开发利用方向. 相似文献
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斜方辉石的反演畴结构对其衍射效应的影响 总被引:1,自引:0,他引:1
斜方辉石内部存在着众多的相邻间呈反演关系的(100)晶畴。这些晶畴的存在使斜方辉石的K为奇数的okl衍射之强度明显减弱,且参与衍射的晶畴的数目越多,其减弱的程度也就越大。这一现象在一定程度上掩盖了斜方辉石P2_(1ca)的真实对称性。与X射线衍射相比,利用电子衍射来研究斜方辉石的空间群类型具有明显的优越性。 相似文献
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Flared slopes originate as concave weathering fronts beneath the regolith, and several other minor granite landforms found in association with them (tafoni, Rillen) may be initiated subsurface also. Other features, particularly incipient gnammas and gutters, have been observed on surfaces that have only recently been cleared of granite debris in situ. 相似文献
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脆性断层运动学研究新进展 总被引:1,自引:0,他引:1
本文概述了80年代以来脆性断层运动研究方面的某些成果。介绍了脆性断层带中的一些小构造和显微构造的几何特征以及它们的运动学意义。重点论述了从露头尺度到薄片尺度确定脆性断层运动方向的三种构造判据,既从属裂隙、岩桥构造和方解石e双晶判据。 相似文献
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Abstract. Talnakhite occurs in an andradite skarn forming adjacent to a leucocratic quartz monzonite dike intruded into limestone at Fuka. The mineral densely contains exsolution lamellae of chalcopyrite, and the talnakhite-chalcopyrite inter-growth is intimately associated with bornite that contains chalcopyrite as a lattice-form exsolution. The chemical composition of the talnakhite acquired on an electron probe microanalyzer corresponds to Cu9.00 Fe8.08 S15.92 , very close to the ideal chemical formula Cu9 Fe8 S16 . Nickel is not detected. The X-ray powder diffraction lines are well indexed on a body-centered cubic cell with a = 10.589 Å. The characteristic (110) reflection of talnakhite is clearly observed at 7.49 Å. The present talnakhite retains the chalcopyrite-like colored polished surface without tarnish in air more than a month.
Talnakhite at Fuka is likely to be derived from breakdown of Cu-rich intermediate solid solution ( iss ), which was in equilibrium with Fe-rich bornite at elevated temperatures. Talnakhite thus formed has survived the subsequent cooling processes, probably because the ƒs 2 was maintained in suitable levels preventing its decomposition into bornite and chalcopyrite. 相似文献
Talnakhite at Fuka is likely to be derived from breakdown of Cu-rich intermediate solid solution ( iss ), which was in equilibrium with Fe-rich bornite at elevated temperatures. Talnakhite thus formed has survived the subsequent cooling processes, probably because the ƒ
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I.R. Plimer 《Australian Journal of Earth Sciences》2013,60(1):147-153
An extensive complex zoned skarn is developed at the contact of a leucoadamellite intrusive at Doradilla, NW New South Wales. The skarn is a disequilibrium assemblage resulting from a progressive sequence of replacement of a carbonate precursor. Early grossular‐clinopyroxene rocks are replaced by andradite with 0.5–3.5 wt.% SnO2 clinopyroxene and quartz. Later alteration along fractures and bedding planes of the garnet‐clinopyroxene quartz assemblage has produced calcite‐malayaite (CaSn0.95Ti0.05SiO5) veins. The final replacement stage was the overprinting of the silicate phases by assemblages containing sulphides, cassiterite, magnetite, titanite, fluorite, biotite and chlorite. The tin content of garent increases with increasing andradite component suggesting replacement of Fe3+ by Sn4+. Associated clinopyroxenes contain 0.1% SnO2. The coexistence of titanite and its tin isomorph malayaite with extremely limited solid solution indicates late stage skarn temperatures of less than 400°C. 相似文献
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通过衍射线指标和面网指标的联系讨论了晶体的对称性对衍射指标h和k互换的影响。在下列情况下衍射指标h和k是不能互换的:在低级晶族;在四方晶系C_(4h)—4/m劳厄点群,六方品系C_(6h)—6/m劳厄点群和立方晶系T_h—m3劳厄点群对于hko和kkl型衍射;在三方晶系选取六方晶胞的情况下,在C_(3i)—3劳厄点群对于hol,okl,hko和hkl型衍射,在D_(3d)—3m劳厄点群对于holokl和hkl型衍射,以及在菱面体点阵除非h和k都是三的倍数。 相似文献
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宁镇中段铜多金属矿床与矽卡岩、尤以石榴子石矽卡岩关系密切,故从矿物学角度研究该区矽卡岩的石榴子石与成矿的关系具有现实找矿意义。通过现场观察、光学显微镜、扫描电镜、X射线衍射分析、微区能谱分析及成矿元素含量分析等,对宁镇中段矽卡岩石榴子石的形貌、结构、成分、种类及其与成矿的关系进行研究,结果表明:本区石榴子石属钙铝-钙铁榴石系列,但铜矿化区的石榴子石均属其中的钙铁榴石亚种,并且铜矿化区石榴子石的铜含量远远低于无矿化区石榴子石。研究认为,成矿元素在矽卡岩期的富集或分散趋势是石榴子石成矿元素含量高低的关键原因,若岩浆分异出来的成矿元素总量相同,则在矽卡岩期即富集到石榴子石等矿物使其成矿元素较高不利于成矿,反之则石榴子石成矿元素较低而矽卡岩期后热液具有利物质条件利于成矿。 相似文献
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运用电子探针,透射电镜,粉晶衍射方法对广西大厂硫锑铅矿进行了综合研究,证实硫锑铅矿的晶体结构是单斜晶系,而且存在假晶胞。其分子式昌Pb5Sb4S11。 相似文献
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C. B. Vanpeteghem A. Sano K. Komatsu E. Ohtani A. Suzuki 《Physics and Chemistry of Minerals》2007,34(9):657-661
We have determined the position of deuterium atoms in δ-AlOOD by neutron powder diffraction at ambient pressure. As previously reported by theoretical and experimental studies, the deuterium atoms are located in the tunnel formed by the chains of AlO6 octahedra. The data are best fit with the P21 nm structure, producing bond lengths of D–O1 of 1.552(2) Å, O2–D of 1.020(2) Å and O1–O2 of 2.571(2). This study confirms that the hydrogen bond is asymmetric at ambient conditions in agreement with recent single-crystal synchrotron study for δ-AlOOH. 相似文献
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70年代以来,国外一些学者发表文章对尖晶石的晶体结构提出质疑,认为其空间群有可能是F(?)3m。我们应用会聚束电子衍射对其研究,结果测定尖晶石的空间群应是Fd(?)m。同时确认其h+k=4n+2的弱衍射斑的出现是高阶二次衍射所致。 相似文献