From Cadomian arc to Ordovician passive margin: geochemical records preserved in metasedimentary successions of the Orlica-Śnieżnik Dome in SW Poland

The chemical composition of metamorphosed siliciclastic rocks in the Orlica-?nie?nik Dome (Bohemian Massif) identifies the main sources for the Neoproterozoic [the M?ynowiec Formation (MF)], Early Cambrian [the Stronie Formation (SF)] and Late Cambrian/Early Ordovician [the Goszów quartzites (GQ)] sediments. The MF developed from erosion of a Cadomian magmatic arc along the northern Gondwana margin. The variegated SF, with supra-subduction affinities, shows chemical characteristics pointing to erosion of the freshly exhumed Cadomian orogen and detritus deposition in the back-arc basin. The very different chemical features of the GQ indicate deposition in a basin sited on a passive continental margin. The explanation proposed for the observed changes in chemical composition involves three main stages: (1) The pre ~540 Ma evolution of an active continental margin and related back-arc basin ceased with the collision and accretion of the magmatic arc to the Gondwana margin; (2) Early Cambrian rift to drift transition (540–500 Ma) and development of a depositional basin filled with detritus derived from remnants of the magmatic arc; (3) Peri-Gondwana break-up leading to the formation of shallow-water passive margin depositional basins filled with quartz-rich detritus resembling Early Ordovician Armorican quartzites known from other parts of the Variscan Belt.     

Deeply concealed half-graben at the SW margin of the East European Craton(SE Poland)—Evidence for Neoproterozoic rifting prior to the break-up of Rodinia

Baltica was one of continents formed as a result of Rodinia break-up 850-550 Ma. It was separated from Amazonia(?) by the Tornquist Ocean, the opening of which was preceded by Neoproterozoic extension in a network of continental rifts. Some of these rifts were subsequently aborted whereas the Tornquist Rift gave rise to splitting of Rodinia and formation of the Tornquist Ocean. The results of 1-D subsidence analysis at the fossil passive margin of Baltica provided insight in the timing and kinematics of continental rifting that led to break-up of Rodinia. Rifting was associated with Neoproterozoic syn-rift subsidence accompanied by deposition of continental coarse-grained sediments and emplacement of continental basalts.Transition from a syn-rift to post-rift phase in the latest Ediacaran to earliest early Cambrian was concomitant with deposition of continental conglomerates and arkoses, laterally passing into mudstones. An extensional scenario of the break-up of Rodinia along the Tornquist Rift is based on the character of tectonic subsidence curves, evolution of syn-rift and post-rift depocenters in time, as well as geochemistry and geochronology of the syn-rift volcanics. It is additionally reinforced by the high-quality deep seismic reflection data from SE Poland, located above the SW edge of the East European Craton. The seismic data allowed for identification of a deeply buried(11-18 km), well-preserved extensional half-graben, developed in the Palaeoproterozoic crystalline basement and filled with a Neoproterozoic syn-rift volcano-sedimentary succession. The results of depth-to-basement study based on integration of seismic and gravity data show the distribution of local NE-SW elongated Neoproterozoic depocenters within the SW slope of the East European Craton. Furthermore,they document the rapid south-eastwards thickness increase of the Neoproterozoic succession towards the NW-SE oriented craton margin. This provides evidence for extensive crustal thinning occurring prior to the break-up of Rodinia and formation of the Tornquist Ocean.     

Ordovician passive continental margin magmatism in the Central-European Variscides: U–Pb zircon data from the SE part of the Karkonosze-Izera Massif, Sudetes, SW Poland

Approximately 500-Ma-old orthogneisses are widespread in the eastern part of the Variscan belt and are commonly interpreted to have intruded mica-schist series of assumed Neoproterozoic age. New SHRIMP zircon ages of quartzofeldspathic metavolcanogenic rocks of the mica schist series in the eastern part of the Karkonosze-Izera Massif (SW Poland) indicate that they are late Cambrian/early Ordovician rather than Neoproterozoic in age, based on the zircon age spectra distributed mainly between ca. 500 and 660 Ma (with a few Proterozoic inherited minimum ages of ca. 970 and 1,825 Ma). Younger zircon dates, dispersed between ca. 412 and 464 Ma, are interpreted as a result of Pb-loss likely caused by subsequent metamorphism. Consequently, the felsic metavolcanogenic rocks appear to be roughly contemporaneous with the intrusion of ca. 500-Ma-old orthogneiss protoliths (with the pooled concordia age of 487 ± 8 Ma interpreted as the best approximation of the protolith intrusive age). Field relationships, petrological and geochemical features of the felsic and mafic rocks studied support a model in which the accompanying mica schist series are not the original country rocks to the ca. 500 Ma granite intrusions, and indicate that their recent close proximity is the result of tectonic juxtaposition. However, both the mica schists enclosing the bimodal metavolcanic rocks, and the orthogneisses, are interpreted to represent a Cambro-Ordovician passive continental margin sequence being part of the Saxothuringian domain. They are tectonically overlain to the east by HP/T metamorphic units, comprising MORB-type metaigneous rocks, and delineating a tectonic suture separating the Saxothuringian block in the west from an assumed continental block (Tepla-Barrandian) to the south-east.     

Petrology,geochemistry and zircon U–Pb dating of Band-e-Hezarchah metabasites (NE Iran): An evidence for back-arc magmatism along the northern active margin of Gondwana

The Band-e-Hezarchah granitoids (BHG) is located in the northern margin of the central Iran, where the very old continental crust of Iran is found. The BHG mainly include granodiorite, granite and leucogranite. Small meta-gabbroic stocks and dykes are associated with BHG. U–Pb zircon dating of the BHG granites and metabasites yield ²³⁸U/²⁰⁶Pb crystallization ages of ca. 553.6 and 533.5 Ma respectively (Ediacaran–early Cambrian). The metabasites have calc-alkaline signature and their magmas seem to have originated from a mantle wedge above a subduction zone. These rocks are thought to be formed in a continental back-arc setting, related to the oblique subduction of Proto-Tethys oceanic lithosphere beneath the northern margin of Gondwanan supercontinent during Ediacaran–Cambrian time. The initial ⁸⁷Sr/⁸⁶Sr ratios and ɛNd (t) values for metabasites are change from 0.705 to 0.706 and −3.5 to −3.6 respectively. Sr–Nd isotope composition of metabasites indicates that these rocks were derived from a subcontinental lithospheric mantle source. The BHG and associated metabasites are coeval with other similar aged metagranites and gneisses from Iranian basements exposed in central Iran, Sanandaj-Sirjan and Alborz zones. These rocks were formed due to continental arc magmatism of Neoproterozoic–early Cambrian, bordering the northern active margin of Gondwana.     

Amphibolites from the Szklarska Por?ba hornfels belt, West Sudetes, SW Poland: magma genesis and implications for the break-up of Gondwana

Amphibolites from the Szklarska Por?ba hornfels belt (northern part of the Karkonosze-Izera Massif) represent rocks of alkali-basalt composition metamorphosed during Variscan times. Despite the intense thermal influence of the Karkonosze granite superimposed on the effects of regional amphibolite-facies metamorphism, the geochemical affinities of the Szklarska Por?ba amphibolites are well preserved. They are similar to alkaline OIB basalts derived from an enriched (undepleted) sub-lithospheric source in the garnet stability field at depths ca 80–120?km. Trace-element characteristics and geochemical modelling indicate that the source was not modified by metasomatism in a supra-subduction zone or by alkali (silicate, carbonatitic) infiltration. Subsequent intra-crustal fractional crystallization involved olivine and clinopyroxene, and subordinate spinel and, presumably, plagioclase. The chemical composition of the rocks is most similar to that of modern magmas generated in an extensional setting (intra-continental rift). Neither geochemical characteristics nor estimated mantle temperatures only slightly higher than those of ambient mantle convincingly attest to the involvement of deep-mantle plume activity. Instead, decompression melting of passively upwelling asthenosphere beneath opening fractures in fragmented lithosphere is invoked. The origin of the amphibolite protolith was presumably associated with the Early Palaeozoic rifting of northern Gondwana, well documented throughout the Karkonosze-Izera massif. Locally rifting must have ceased earlier (immature rift) as reflected by mafic dykes exposed in the northern part of the massif, i.e., in the Szklarska Por?ba hornfelses, and by the Izera gneisses and the Stara Kamienica metapelites. A passive rift system controlled by lithosphere extension provides a plausible explanation for the origin of mafic rocks in the Karkonosze-Izera Massif and sheds light on possible mechanisms involved in the break-up of Gondwana.     

Lithosphere thermal structure at the eastern margin of the Bohemian Massif: a case petrological and geophysical study of the Nied?wied? amphibolite massif (SW Poland)

The crustal section beneath amphibolite Nied?wied? Massif (Fore-Sudetic Block in NE Bohemian Massif), modelled on the basis of geological and seismic data, is dominated by gneisses with subordinate granites (upper and middle crust) and melagabbros (lower crust). The geotherm was calculated based on the chemical analyses of the heat-producing elements in the rocks forming the crust and the measurements of their density and heat conductivity. The results were verified by heat flow calculations based on temperature measurements from 1,600?m deep well in the Nied?wied? Massif and by temperature–depth estimates in mantle xenoliths coming from the nearby ca. 4.5?My basanite plug in Lutynia. The paleoclimate-corrected heat flow in the Nied?wied? Massif is 69.5?mW?m^?2, and the mantle heat flow is 28?mW?m^?2. The mantle beneath the Massif was located marginally relative to the areas of intense Cenozoic thermal rejuvenation connected with alkaline volcanism. This results in geotherm which is representative for lithosphere parts located at the margins of zones of continental alkaline volcanism and at its waning stages. The lithosphere–asthenosphere boundary (LAB) beneath Nied?wied? is located between 90 and 100?km depth and supposedly the rheological change at LAB is not related to the appearance of melt.     

Neoproterozoic and Cambro-Ordovician magmatism in the Variscan Kłodzko Metamorphic Complex (West Sudetes,Poland): new insights from U/Pb zircon dating

The Kodzko Metamorphic Complex (KMC) in the Central Sudetes consists of meta-sedimentary and meta-igneous rocks metamorphosed under greenschist to amphibolite facies conditions. They are comprised in a number of separate tectonic units interpreted as thrust sheets. In contrast to other Lower Palaeozoic volcano-sedimentary successions in the Sudetes, the two uppermost units (the Orla-Googowy unit and the Kodzko Fortress unit) of the KMC contain meta-igneous rocks with supra-subduction zone affinities. The age of the KMC was previously assumed to be Early Palaeozoic–Devonian, based on biostratigraphic findings in the lowermost tectonic unit. Our geochronological study focused on the magmatic rocks from the two uppermost tectonic units, exposed in the SW part of the KMC. Two orthogneiss samples from the Orla-Googowy unit yielded ages of 500.4±3.1 and 500.2±4.9 Ma, interpreted to indicate the crystallization age of the granitic precursors. A plagioclase gneiss from the same tectonic unit, intimately interlayered with metagabbro, provided an upper intercept age of 590.1±7.2 Ma, which is interpreted as the time of igneous crystallization. From the topmost Kodzko Fortress unit, a metatuffite was studied, which contains a mixture of genetically different zircon grains. The youngest ²⁰⁷Pb/²⁰⁶Pb ages, which cluster at ca. 590-600 Ma, are interpreted to indicate the maximum depositional age for this metasediment. The results of this study are in accord with a model that suggests a nappe structure for the KMC, with a Middle Devonian succession at the base and Upper Proterozoic units at structurally higher levels. It is suggested here that the KMC represents a composite tectonic suture that juxtaposes elements of pre-Variscan basement, intruded by the Lower Ordovician granite, against a Middle Palaeozoic passive margin succession. The new ages, combined with the overall geochemical variation in the KMC, indicate the existence of rock assemblages representing a Gondwana active margin. The recognition of Neoproterozoic subduction-related magmatism provides additional arguments for the hypothesis that equivalents of the Teplá-Barrandian domain are exposed in the Central Sudetes.     

Geological, mineralogical and geochemical characteristics of the Radzimowice Au–As–Cu deposit from the Kaczawa Mountains (Western Sudetes, Poland): an example of the transition of porphyry and epithermal style

The sheeted quartz–sulfide veins of the Radzimowice Au–As–Cu deposit in the Kaczawa Mountains are related to Upper Carboniferous post-collisional potassic magmatism of the composite Zelezniak porphyry intrusion. Multiple intrusive activity ranges from early calc-alkaline to sub-alkaline and alkaline rocks and is followed by multiple hydrothermal events. Early crustally derived dacitic magma has low mg# (<63) and very low concentrations of mantle-compatible trace elements, high large-ion lithophile elements (LILE), moderate light rare-earth elements (LREE), and low high-field-strength elements (HFSE). Later phases of more alkaline rocks have higher mg# (60–70), and LILE, LREE, and HFSE characteristics that indicate mafic magma contributions in a felsic magma chamber. The last episode of the magmatic evolution is represented by lamprophyre dikes which pre-date ore mineralization and are spatially related to quartz–sulfide–carbonate veins. The dikes consist of kersantite and spessartite of calc-alkaline affinity with K₂O/Na₂O ratios of 1.1–1.9, mg# of 77–79, and high abundances of mantle-compatible trace elements such as Cr, Ni, and V. They have high LILE, low LREE, and low HFSE contents suggesting a subduction-related post-collisional arc-setting. The mineralization started with arsenopyrite that was strongly brecciated and overprinted by multiple quartz–carbonate phases associated with base-metal sulfides and Au–Ag–Bi–Te–Pb±S minerals. The sulfur isotope composition of sulfides ranges from –1.1 to 2.8 ³⁴S and suggests a magmatic source. At least two generations of gold deposition are recognized: (1) early refractory, and (2) subsequent non-refractory gold mineralization of epithermal style. Co-rich arsenopyrite with refractory gold and pyrite are the most abundant minerals of the early stage of sulfide precipitation. Early arsenopyrite formed at 535–345°C along the arsenopyrite–pyrrhotite–loellingite buffer and late arsenopyrite crystallized below 370°C along the arsenopyrite–pyrite buffer. Non-refractory gold associated with base-metal sulfides and with Bi–Te–Ag–Pb–S mineral assemblages has an average fineness of about 685, and is represented by electrum of two generations, and minor maldonite (Au₂Bi). Fluid inclusions from various quartz generations co-genetic with base-metal sulfides and associated with carbonates, tellurides and non-refractory gold indicate fluids with moderate salinity (9–15 wt% NaCl equiv.) and a temperature and pressure drop from 350 to 190°C and 1.2 to 0.8 kbar, respectively. According to the result of the sulfur isotope fractionation geothermometer the temperature of base-metal crystallization was in the range from 322 to 289°C. Preliminary results of oxygen isotope studies of quartz from veins indicate a gradual increase in the proportion of meteoric water in the epithermal stage. The gold to silver ratio in ore samples with >3 ppm Au is about 1:5 (geometric mean). Hydrothermal alteration started with sericitization, pyritization, and kaolinitization in vein selvages followed by alkaline hydrothermal alteration of propylitic character (illitization and chloritization), albitization and carbonatization. The mineralization of the Radzimowice deposit is considered as related to alkaline magmatism and is characterized by the superposition of low-sulfidation epithermal mineralization on higher-temperature and deeper-seated mesothermal/porphyry style.Editorial handling: B. Lehmann     

Assembly of Pampia to the SW Gondwana margin: A case of strike-slip docking?

Different hypotheses have been proposed to account for the geologic evolution of the southwestern margin of Gondwana in the Early Paleozoic, involving accretion and displacement of different terranes in a protracted convergent margin. In order to constrain and understand the kinematic and paleogeographic evolution of the Pampia terrane a paleomagnetic study was carried out in different Cambrian to Devonian units of the Eastern Cordillera (Cordillera Oriental) and the Interandean Zone (Interandino) of NW Argentina. Paleomagnetic poles from the Campanario Formation (Middle to Upper Cambrian): 1.5°N 1.9°E A₉₅ = 9.2° K = 37.46 N = 8; and Santa Rosita Formation (Lower Ordovician): 8.6°N 355.3°E A₉₅ = 10.1° K = 26.78 n = 9, representative of the Pampia terrane, are interpreted to indicate a Late Cambrian significant displacement with respect to the Río de la Plata and other Gondwana cratons. A model, compatible with several geological evidences that explains this displacement in the framework of the final stages of Gondwana assembly is presented. We propose a simple dextral strike-slip kinematic model in which Pampia and Antofalla (? Arequipa?) blocks moved during Late Cambrian times from a position at the present southern border of the Kalahari craton into its final position next to the Rio de la Plata craton by the Early Ordovician.     

Geochemical and Sr–Nd isotopic characteristics of Murgul (Artvin) volcanic rocks in the Eastern Black Sea Region (Northeast Turkey)

The studied volcanic rocks are footwall and hanging wall dacites from the Murgul mine and the surrounding area. Moreover, the hanging wall dacites contain enclaves. Footwall dacite contains biotite, whereas hanging wall dacitic rocks contain hornblende as a ferromagnesian mineral. The enclaves in the hanging wall dacite have sizes that range from 1 cm to 20 cm and contain hornblende as a ferromagnesian mineral. The volcanic rocks show tholeiitic and transitional affinities. They are rich in large ion lithophile element and light rare earth element with pronounced depletion of high field strength elements. The chondrite-normalized rare earth element patterns (La_N/Lu_N = 1.47–5.12) show low to medium enrichment, which reveal that the rocks were obtained from similar sources in Murgul volcanic rocks. The initial ⁸⁷Sr/⁸⁶Sr values range from 0.70442 to 0.70525, and the initial ¹⁴³Nd/¹⁴⁴Nd values range from 0.512741 to 0.512770. The main solidification processes involved in the evolution of the volcanic rocks consist of fractional crystallization with minor amounts of crustal contamination and magma mixing. All geochemical data support that these rocks originated from andesitic magma, and that the parental magma of the rocks were probably derived from an enriched upper mantle, previously modified by subduction-induced metasomatism in a geodynamic setting.     

Geochemical Characteristics and Genesis of Late Cretaceous to Paleogene Basalts in the Tuyon Basin, South Tianshan Mountains

1. Introduction The Tianshan Mountains is a typical intercontinental orogenic belt in the world. From late Carboniferous to Permian, the old Tianshan formed during the tectonic amalgamation of the Tarim block, Tianshan block and Siberia craton (Carroll et al, 1990). Mid-Cenozoic basalts are widely distributed in both the Tuyon basin of southwest Tianshan and its western part of Tianshan in Jierjisi in late Cretaceous-Paleogene period, which indicates the activation of the old Tianshan.…     

Neoproterozoic crustal growth at the margin of the East Gondwana continent – age and isotopic constraints from the easternmost inliers of Oman

ABSTRACT

The Jebel Ja’alan and Qalhat inliers of Oman represent the easternmost exposures in the Arabian peninsula of the Neoproterozoic basement associated with the East African Orogen (EAO) and the assembly of East and West Gondwana. These inliers expose tonalitic gneisses and metasediments intruded by granodiorites and granites of the Ja’alan batholith. Zircons from the gneisses yield U–Pb SIMS ages of ca. 900–880 Ma, which are interpreted as crystallization ages. These represent the oldest magmatic events associated with the closure of the Mozambique Ocean reported to date. Zircon of this age is also the dominant component in the metasediments. The Ja’alan batholith yields ages of ca. 840–825 Ma. Nd isotopes indicate that both the gneisses and the batholith range from juvenile to slightly more evolved, with ε_Nd(t) of +6 to +1.5 interpreted to reflect variable contamination by older, evolved continental material; this is also indicated by >900 Ma detrital zircon from the metasediments. The Nd data also contrast with the uniformly juvenile signature of younger, ca. 840 Ma, rocks of the Marbat region of southern Oman that lie structurally to the west. The Ja’alan and Qalhat inliers thus document eastward increasing age and continental influence, consistent with the progressive development of arc rocks onto the western margin of East Gondwana, although the location and nature of the eastern continental block remain elusive.     

SHRIMP U–Pb zircon geochronology and Sr–Nd isotopic systematic of the Neoproterozoic Ghimbi-Nedjo mafic to intermediate intrusions of Western Ethiopia: a record of passive margin magmatism at 855 Ma?

The reworked Pre-Neoproterozoic and juvenile Neoproterozoic terrane of the Western Ethiopian Shield (WES) consists of three N–S trending terranes. These are the western migmatitic gneissic terrane, the central metavolcano sedimentary terrane (CVST) and the eastern migmatitic gneissic terrane. The eastern part of the CVST mostly consists of suture-related ultramafic-metasedimentary complexes, whereas metavolcanics predominate in the western part. Gabbroic to granitic intrusions frequently occur in the CVST and in adjacent areas. New zircon SHRIMP U–Pb ages for two gabbros and three diorites in the Ghimbi-Nedjo region of the WES indicate magmatic crystallization ages. Two pulses of magmatism, at 860–850 and 795–785 Ma, are documented with the former for the first time. The tholeiitic Kemashi diorite and Bikilal-Ghimbi gabbros have oceanic affinities and yield U/Pb zircon ages of 856.3 ± 9.8 and 846.0 ± 7.6 Ma, respectively. The calc-alkaline Gebeya Kemisa pyroxene diorite, and the Senbet Dura hornblende diorite plus the tholeiitic Wayu Meni gabbro, which collectively have arc-back arc characteristics are indistinguishable at ages of 794.3 ± 9.4, 787.7 ± 8.8 and 778.1 ± 6.3 Ma, respectively. Positive εNd (4.5–7.0) and low initial ⁸⁷Sr/⁸⁶Sr (0.7029 ± 0.0002) and a mean T _DM model age of 0.95 Ga for the Ghimbi-Nedjo region (mean T _DM model age of 0.95 Ga for the WES overall) indicate that the magmas were generated from juvenile Neoproterozoic depleted mantle sources, with no discernable involvement of pre-Neoproterozoic continental crust. The occurrence of gabbros and diorites with oceanic tholeiite affinities combined with the new ages suggests that the intrusions were emplaced in the earliest stages of the rifting of Rodinia. This event in the WES led to the development of a passive margin and associated plume-type magmatism at ~855 Ma. The two intrusive groups with differing magma chemistry and ages suggest that the earliest magmatism was tholeiitic and associated with the passive margin system followed by continental breakup to form the Mozambique Ocean. The combination of tholeiitic and calc-alkaline magmatism was related to arc and back-arc basin formation and later terrane accretion (~830–690 Ma).     

Neoproterozoic glacial and gravitational sedimentation on a continental rifted margin: The Jequitaı́–Macaúbas sequence (Minas Gerais,Brazil)

This paper is a contribution to the knowledge of the sedimentation of Neoproterozoic sequences, known as the Jequitaı́ Formation and Macaúbas Group. These sequences are present along the transitional zone between the São Francisco Craton and the Brasiliano (≌600 Ma) Araçuaı́ fold belt in Minas Gerais, Brazil. A sedimentological study of these Neoproterozoic sequences enables us to distinguish between true continental and marine glacial facies and glacial material reworked by various subaqueous gravitational processes. The cratonic Jequitaı́ Formation consists of massive and stratified diamictites up to 100 m thick. This diamictite association is tentatively interpreted as glaciomarine in origin. It continues eastward, in the Araçuaı́ fold belt, as the metasedimentary Macaúbas Group, which is composed of metadiamictites, quartzites and schists from 5–12(?)km thick. The Macaúbas Group consists of resedimented glacial material deposited by subaqueous debris flows and turbidity currents. A depositional model is proposed for the Jequitaı́–Macaúbas glacial/gravitational sequence. From west to east, a glaciomarine sequence, possibly deposited from an ice-sheet and slightly reworked by gravitational processes, was reworked along the São Francisco cratonic border and generated a slope apron system made up of diamictites associated with turbidites and rhythmites.     

Exotic rifted passive margin of a back-arc basin off western Pangea: geochemical evidence from the Early Mesozoic Ayú Complex,southern Mexico

Recent detrital zircon studies of metamorphosed and polydeformed rocks of the early Mesozoic Ayú Complex in southern Mexico suggest an allochthonous origin along the western Pangean margin. Bulk-rock geochemistry of the ca. 170–200 Ma ortho-amphibolites suggests a composition ranging from alkalic and transitional basalts to normalized mid-ocean ridge basalt (N-MORB) tholeiites. Rare earth element (REE) patterns of alkaline basalts (Group I) are characterized by steep negative slopes, whereas transitional basalts (Group II) show moderate light REE (LREE) enrichment. Subalkalic Group III displays slight LREE enrichment and Group IV has relatively flat REE patterns with slight depletion in LREEs. Multiple trace element plots of Group III–IV amphibolites reveal strongly negative Nb–Ta anomalies caused by subduction zone contamination. Initial ?_Nd values (t = 190 Ma) of the amphibolites range from +9.01 to –2.16. Alkalic basalts have negative ?_Nd values, suggesting derivation from an older subcontinental mantle source (T _DM = 877 and 791 Ma). Group II–IV amphibolites have positive ?_Nd values ranging from +2.31 to +9.01, indicating a transition from an older to a relatively juvenile mantle source that is typical of a back-arc setting. The geochemistry of the metasedimentary rocks suggests derivation from an acid-arc source. Chondrite-normalized REE patterns are characterized by enriched LREEs, flat HREE, and negative Eu anomalies. Sm–Nd systematics indicate that most samples were derived from cratonic basement and plot within the Oaxacan Complex envelope with ?_Nd values (t = 195 Ma) ranging from –5.53 to –7.65. We interpret two samples with higher ?_Nd values (–1.42 and +1.06) to reflect the additional influence of a more juvenile component. The amphibolites and metasedimentary rocks of the Ayú Complex document back-arc activity and are inferred to be correlative with various western Mexican Triassic–Jurassic mafic suites and the Potosí fan that formed along the western rifted margin of Pangea.     

Chronological and geochemical studies of the Middle Neoproterozoic mafic rock and turbidite in the Dahongshan orogenic belt on the northern margin of the Yangtze Block: Implications for the evolution of the back-arc basinSCIEI北大核心CSCD

扬子北缘~820Ma可能记录了从挤压环境向伸展环境的重要转换,是解决扬子新元古代演化争议的关键时间节点。本研究在扬子北缘大洪山造山带圆潭地区识别出一套基性岩和浊积岩组合。其中基性岩全岩Sm-Nd等时线年龄为845Ma±81Ma(MSWD=1.5),浊积岩碎屑锆石年龄谱包括四个主要峰值年龄(~835Ma、~1597Ma、~2002Ma、~2482Ma)和两个次要峰值年龄(~2680Ma、~2934Ma),综合前人研究成果将浊积岩的形成时代约束在835~820Ma。浊积岩与花山群的形成时代一致,应代表花山群的北向延伸。浊积岩的物源来自扬子北缘桐柏-大别地区,不同于前人对花山群的分析结果,指示花山群可能具有多个物源。以上地层碎屑锆石年龄谱和地层层序特征与弧后盆地相似。本研究基性岩样品具有低的SiO_(2)(45.41%~50.29%)、K 2O(0.03%~1.49%),高的TiO_(2)(1.42%~3.03%),和低的U/Th(0.15~0.29)、Th/Zr(0.003~0.011)和Nb/Y(0.059~0.147)以及正的εNd(t)(+1.18~+1.57),类似N-MORB地球化学特征。基性岩来自于软流圈,经历<3%部分熔融而生成,并在上升过程中受到了一定程度的地壳混染。综合以上分析,本文认为这些基性岩和浊积岩共同构成一套弧后背景环境岩石组合。     

Geochemical and Sr–Pb–Nd isotopic characteristics of the Shakhtama porphyry Mo–Cu system (Eastern Transbaikalia,Russia)

The Shakhtama Mo–Cu porphyry deposit is located within the eastern segment of the Central Asian Orogenic Belt, bordering the southern margin of the Mongol–Okhotsk suture zone. The deposit includes rocks of two magmatic complexes: the precursor plutonic (J₂) and ore-bearing porphyry (J₃) complexes. The plutonic complex was emplaced at the final stages of the collisional regime in the region; the formation of the porphyry complex may have overlapped with a transition to extension. The Shakhtama rocks are predominantly metaluminous, I-type high K calc-alkaline to shoshonitic in composition, with relatively high Mg#, Ni, Cr and V. They are characterized by crustal-like I_Sr (0.70741–0.70782), relatively radiogenic Pb isotopic compositions, ε_Nd(T) values close to CHUR (−2.7 to +2.1) and Nd model ages from 0.8 to 1.2 Ga. Both complexes are composed of rocks with K-adakitic features and rocks without adakite trace element signatures. The regional geological setting together with geochemical and isotopic data indicate that both juvenile and old continental crust contributed to their origin. High-Mg# K-adakitic Shakhtama magmas were most likely generated by partial melting of thickened lower crust during delamination and interaction with mantle material, while magmas lacking adakite-like signatures were probably generated at shallower levels of lower crust. The derivation of melts, related to the formation of plutonic and porphyry complexes involved variable amounts of old Precambrian lower crust and juvenile Phanerozoic crust. Isotopic data imply stronger contribution of juvenile mantle-derived material to the fertile magmas of the porphyry complex. Juvenile crust is proposed as an important source of fluids and metals for the Shakhtama ore-magmatic system.     

Geochemical Characteristics and Tectonic Setting of the Laohushan Basalts, North Qilian Mountains

The Ordovician Laohushan ophiolite, located in the eastern part of the North Qilian Mountains, is mainly composed of meta-peridotites, gabbros and basalts alternating with sediments. The sediments are mainly turbidites, including sandstones, siltstones, cherts etc. Major elements show that the basalts are subalkaline tholeiites and may be analogous to ocean-floor basalts. Except a few N-MORBs, most of the basalts are E-MORBs as indicated by incompatible element ratios such as (La/Ce)N, La/Sm, Ce/Zr, Zr/Y and Zr/Nb. Negative Nb anomaly is common but negative Zr, Hf and Ti anomalies are quite rare. Based on the geochemical characteristics, it is suggested that the Laohushan basalts were formed in a back-arc basin. εNd (t) of the basalts ranges between +3.0 and +8.9 and (87Sr/86Sr), ranges between 0.7030 and 0.7060, indicating a depleted mantle source which was mixed with more or less enriched mantle components. Furthermore, the petrography of the sandstones and geochemistry of the cherts suggest that the