Solute dynamics of meltwater of Gangotri glacier,Garhwal Himalaya,India

The present study investigates solute dynamics of meltwater of Gangotri glacier system in terms of association of different chemical compounds with the geology of the area. In the meltwater, the presence of cations varied as c(Mg²⁺) > c(Ca²⁺) > c(Na⁺) > c(K⁺), while order of concentration of anions has been c(HCO₃ ⁻) > c(SO₄ ²⁻) > c(Cl⁻) > c(NO₃ ⁻) in years 2003 and 2004. The magnesium and calcium are found as the dominant cations along with bicarbonate and sulphate as dominant anions. The high ratios of c(Ca²⁺ + Mg²⁺)/total cations and c(Ca²⁺ + Mg²⁺)/c(Na⁺ + K⁺) indicate that the meltwater chemistry of the Gangotri glacier system catchment is mostly controlled by carbonate weathering. Attempts are made to develop rating curves for discharge and different cations. Sporadic rise in discharge without corresponding rise in concentration of most of cations is responsible for their loose correlation in a compound valley glacier like Gangotri glacier.     

GIS‐based reconstruction of Late Weichselian proglacial lakes in northwestern Russia and Belarus

Reconstructing ice‐lake histories is of considerable importance for understanding deglacial meltwater budgets and the role of meltwater reservoirs for sea‐level rise in response to climate warming. We used the latest data on chronology and ice‐sheet extents combined with an isostatically adjusted digital elevation model to reconstruct the development of proglacial lakes in the area of the Karelian ice stream complex of the Late Weichselian Scandinavian Ice Sheet on the East European Plain. We derived the deglacial ice lake development in seven time‐slices from 19 to 13.8 ka, assuming the individual ice‐marginal positions to be isochronous throughout the studied domain. Modelling is based on mapping of critical drainage thresholds and filling the depressions that are potentially able to hold meltwater. Such an approach underestimates the real dimensions of the ice lakes, because the role of erosion at the thresholds is not considered. Our modelling approach is sensitive to the (local) ice‐margin location. Our results prove the southward drainage of meltwater during the glacier extent maxima and at the beginning of deglaciation whereas rerouting to the west had taken place already around 17.5 ka, which is some 1.5 ka earlier than hitherto supposed. The total ice‐lake volume in the study area was lowest (~300 km³) during the maximum glacier extent and highest (~2000 km³) during the highstand of the Privalday Lake at c. 14.6 ka. At 14.6–14.4 ka, the Privalday Lake drained to the early Baltic Ice Lake. The released ~1500 km³ of water approximately corresponds to 20% of the early Baltic Ice Lake water volume and therefore it is unlikely that it was accommodated there. Thus, we argue that the additional meltwater drained through the Öresund threshold area between the early Baltic Ice Lake and the sea, becoming a part of the Scandinavian Ice Sheet's contribution to the Meltwater Pulse 1A event.     

Aluminium in Lake Cuicocha,Ecuador, an Andean Crater Lake: Filterable,Gelatinous and Microcrystal Al Occurrence

In Lake Cuicocha watershed, a young caldera lake, soils consist of volcanic deposits with a high SiO₂ and Al₂O₃ content; these andisols are in an early stage of development; and in drainage water from the watershed, aluminium concentrations reach 15.0 μmol L⁻¹. Total aluminium concentrations in Lake Cuicocha water raises up to 7.2 μmol L⁻¹, with nearly 70% occurring as filterable Al at neutral to weak alkaline conditions. Al polymerization to gelatinous aggregates of a few hundred micrometres in diameter as well as the occurrence of Al microcrystals like gibbsite as an ageing product of gelatinous Al polymers was noted in the lake water. The gelatinous Al leads to the formation of larger aggregates resulting in flocs of bacteria, algae, microorganisms and detritus.     

Reconstruction of the Peretolchin Glacier fluctuation (East Sayan) during the 20th century inferred from the bottom sediments of proglacial Lake Ekhoi

We present results of study of the bottom sediments of proglacial Lake Ekhoi, which is fed with the Peretolchin Glacier meltwater (East Sayan). The bottom deposit sequence, formed from 1885 to 2013, was investigated with a year-season time resolution, using X-ray fluorescence with synchrotron radiation (with and without scanning), the Fourier-transform infrared (FTIR) analysis, and color processing of core photos. The depth-age model of the core was based on counting of annual laminate layers with control by ²¹⁰Pb, ¹³⁷Cs, ²³⁸U, and ²²⁶Ra chronology. Intense glacier thawing was calculated from the amount of clastic matter supplied by the glacier meltwater into the lake. The elemental composition of the bottom sediments includes three groups reflecting periods of displacement of the glacier front and the intensity of evolution of aquatic biota. The first group of elements (Ca, K, Ti, Fe, and Mn) characterizes the supply of clastic matter without serious changes in the glacier edges. The second group (Ni, Cu, Br, and U) is responsible for the intensity of evolution of aquatic biota. Finally, the third group (Rb, Sr, Zr, Nb, Y, and Th) can describe the intensity of displacement of the glacier front. Intensive glacier thawing has proceeded since 1920; however, the glacier retreat was insignificant till 1947. From 1947 to 1970, the glacier rapidly retreated, especially in the period 1953–1970. This was induced by steady high regional summer surface temperature in 1938–1970. The following glacier retreat was during 1980–2000, synchronously with the global temperature anomaly in the Northern Hemisphere. Since 2000, the melting has slowed.     

Partition of arsenic in soils sediments and the origin of naturally elevated concentrations in groundwater of the southern pampa region (Argentina)

Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L⁻¹) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L⁻¹; in 27% As concentrations ranged from 10 to 50 μg L⁻¹ and in 58% it reached 60–500 μg L⁻¹. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r ² = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r ² = 0.85) and As–Cr (p < 0.05; r ² = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.     

Halogen geochemistry of the McMurdo dry valleys lakes, Antarctica: Clues to the origin of solutes and lake evolution

We have determined the halogen and boron concentrations in the ice-covered lakes of Taylor Valley, Antarctica, to better establish the sources of salts and evolutionary histories of these unusual water bodies. In addition, we report on a series of ¹²⁹I measurements that were compared with previous ³⁶Cl data that also help constrain the source of solutes and histories of the lakes. The new data, when put into context of previous work on these systems over the past forty years, allow us to make the following conclusions. The primary source of solutes to Lake Hoare, the youngest of the lakes, is the dissolution of marine aerosols and aeolian salts and the chemical weathering of dust on the glaciers. The geochemistry of Lake Fryxell, the brackish water lake, is primarily dominated by the diffusion from a halite-saturated brine at the sediment-water interface and the recent infilling of the lake by glacier meltwater. These waters have chemical weathering and marine aerosols components. Lake Bonney has two distinct lobes whose hypersaline hypolimnia have different chemistries. Both of the lobes are remnants of ancient marine waters that have been modified by the input of weathering products. This lake has also been modified by periods of cryogenic concentration when solutes have been lost via mineral precipitation. Thus the geochemistry of Lake Bonney owes its unusual geochemistry, in part, to variations in the climate in the Taylor Valley over at least the past 300kyr. The ¹²⁹I data from the Taylor Valley are similar to those from fracture fluids in crystalline rocks from the Northern Hemisphere.     

Glacial runoff characteristics of the Koxkar Glacier,Tuomuer-Khan Tengri Mountain Ranges,China

This paper presents the glacial runoff characteristics of the Koxkar Glacier, China using flow records collected near the snout of the glacier in four consecutive years (2005–2008). The mean annual discharge of the Koxkar Glacier is 102.86 × 10⁶ m³, in which 93.6% occurs in ablation season (May–October). August brings about maximum discharge of about 29.6% to the total streamflow followed by July of some 26.0%. During the study years, total discharge varies little from year to year, whereas the inter-annual variability in monthly discharge is prominent, particularly in the beginning and in the end of the melt season. Seasonal runoff variability shows great monthly variations in discharge with mean coefficient of variation ranging from 0.02 in January to 0.77 in April. The mean diurnal amplitudes are found to be 0.90, 1.86, 4.71, 4.92, 1.17 and 0.43 m³ s⁻¹ for May, June, July, August, September and October, respectively. In the melt season, the maximum runoff is observed during 1800–0200 hours and the minimum occurs during 0700–1000 hours. Delaying effects are prominent in discharge over the ablation period. The time-lag between meltwater generation and its appearance in the streamflow near the snout of the glacier varies between 4.00 and 10.00 h, and time to peak varies between 10.00 and 17.00 h over the entire melt season. The relationship between discharge and temperature on monthly scale (R ² = 0.77) is better than that on daily scale (R ² = 0.55).     

Stratigraphy and sedimentation of the stratotype sections of the Catfish Creek Drift Formation between Bradtville and Plum Point, north shore, Lake Erie, southwestern Ontario, Canada

The Catfish Creek Drift Formation is a significant and extensive lithostratigraphical marker unit in SW Ontario. Here the stratotype, exposed in the Lake Erie bluffs of the Plum Point-Bradtville (Grandview) area south of London, Ontario, Canada, is proposed. It consists of subglacial and proglacial sediments deposited at the beginning of the Nissouri Phase of the Wisconsinan glaciation. In the 2.5-km-long stratotype section, the Catfish Creek Drift consists of 9 members. Five of them, the Dunwich and Grandview I-IV members, mainly consist of till, with minor components of stratified drift. The Dunwich till was deposited by the Huron-Georgian Bay lobe, but the Grandview I-IV tills by the Erie lobe. The Zettler Farm Member consists of co-lobal till in the central part of the section and of a proglacial waterlain flow diamicton and a subglacial undermelt diamicton in the SW part. Three members consist entirely of stratified drift; the glaciolacustrine silty and clayey Waite Farm Member, the ice-marginal deltaic Oosprink Farm Member and the Boy Scout Camp Member - deposited by meltwater streams in subglacial channels. The sequence of interbedded till and stratified drift represents the oscillating advance of the Laurentide Ice Sheet in the Lake Erie basin.     

Hydrologic controls on radiogenic Sr in meltwater from an alpine glacier system: Athabasca Glacier,Canada

Filtered subglacial meltwater samples were collected daily during the onset of melt (May) and peak melt (July) over the 2011 melt season at the Athabasca Glacier (Alberta, Canada) and analyzed for strontium-87/strontium-86 (⁸⁷Sr/⁸⁶Sr) isotopic composition to infer the evolution of subglacial weathering processes. Both the underlying bedrock composition and subglacial water–rock interaction time are the primary influences on meltwater ⁸⁷Sr/⁸⁶Sr. The Athabasca Glacier is situated atop Middle Cambrian carbonate bedrock that also contains silicate minerals. The length of time that subglacial meltwater interacts with the underlying bedrock and substrate is a predominant determining factor in solute concentration. Over the course of the melt season, increasing trends in Ca/K and Ca/Mg correspond to overall decreasing trends in ⁸⁷Sr/⁸⁶Sr, which indicate a shift in weathering processes from the presence of silicate weathering to primarily carbonate weathering.Early in the melt season, rates of carbonate dissolution slow as meltwater approaches saturation with respect to calcite and dolomite, corresponding to an increase in silicate weathering that includes Sr-rich silicate minerals, and an increase in meltwater ⁸⁷Sr/⁸⁶Sr. However, carbonate minerals are preferentially weathered in unsaturated waters. During the warmest part of a melt season the discharged meltwater is under saturated, causing an increase in carbonate weathering and a decrease in the radiogenic Sr signal. Likewise, larger fraction contributions of meltwater from glacial ice corresponds to lower ⁸⁷Sr/⁸⁶Sr values, as the meltwater has lower water–rock interaction times in the subglacial system. These results indicate that although weathering of Sr-containing silicate minerals occurs in carbonate dominated glaciated terrains, the continual contribution of new meltwater permits the carbonate weathering signal to dominate.     

Effect of source water quality on arsenic (V) removal from drinking water by coagulation/microfiltration

The effect of the source water quality on As(V) removal by coagulation/microfiltration (C/MF) was investigated systematically using a jar test and a lab-scale test; the results of the lab-scale test coincide with those of the jar test. It showed that the increase of dissolved organic carbon (DOC), HPO₄ ²⁻ and HCO₃ ⁻ concentrations would moderately decrease As(V) removal, and the residual As(V) concentration in treated water is no more than 10 μg L⁻¹ when the concentration of DOC, HPO₄ ²⁻ and HCO₃ ⁻ in raw water is not beyond 9.22 mg L⁻¹, 1.6 mg L⁻¹ and 300 mg L⁻¹, respectively. Other co-ions, such as Cl⁻, NO₃ ⁻, F⁻, SO₄ ²⁻, and counter-ions including K⁺, Ca²⁺ and Mg²⁺, have little effect on As(V) removal. Both results of the jar test and the lab-scale test demonstrate that Fe³⁺ dose of 6 mg L⁻¹ is enough to eliminate the influence of HCO₃ ⁻ whose concentration changes from 350 mg L⁻¹ to 450 mg L⁻¹. In the lab-scale test, As(V) removal ranged from 92.8 to 98.2% at Fe³⁺ dose of 4 mg L⁻¹ and 5 mg L⁻¹ when As(V) concentration in raw water was about 100 μg L⁻¹. The results obtained in this study suggest that As(V) removal by C/MF process is sensitive to the quality of raw water, and a jar test needs to be done before C/MF process is used for arsenic removal from drinking water.     

Geochemical evolution of uraniferous soda lakes in Eastern Mongolia

Extremely high concentrations of uranium (U) were discovered in shallow, groundwater-fed hyperalkaline soda lakes in Eastern Mongolia. A representative groundwater sample in this area is dilute and alkaline, pH = 7.9, with 10 mM TIC and 5 mM Cl⁻. In contrast, a representative lake water sample is pH ~ 10 with TIC and Cl⁻ each more than 1,000 mM. Groundwater concentrations of U range from 0.03 to 0.43 μM L⁻¹. Lake water U ranges from 0.24 to >62.5 μM, possibly the highest naturally occurring U concentrations ever reported in surface water. Strontium isotopes ⁸⁷Sr/⁸⁶Sr varied in groundwaters from 0.706192 to 0.709776 and in lakes ⁸⁷Sr/⁸⁶Sr varied from 0.708702 to 0.709432. High concentrations of U, Na, Cl⁻, and K correlate to radiogenic Sr in lake waters suggesting that U is sourced from local Cretaceous alkaline rhyolites. Uranium-rich groundwaters are concentrated by evaporation and U(VI) is chelated by CO₃⁻² to form the highly soluble UO₂(CO₃)₃⁻⁴. Modeled evaporation of lakes suggests that a U-mineral phase is likely to precipitate during evaporation.     

Monitoring of Bashkara Glacier lakes (Central Caucasus, Russia) and modelling of their potential outburst

Glacier lakes pose threat to downstream settlements and infrastructure. In recent decades the number and area of lakes have been growing at an accelerating rate due to worldwide glacier shrinkage. In the Russian Caucasus this process is understudied. We present results obtained during a 12-year (1999–2010) continuous field monitoring of the Bashkara proglacial lakes group, which we identified as the place with the highest GLOF risk in the region. Recession of the parent Bashkara Glacier was the main driver of the rapid expansion of the lower Lake Lapa. The upper Lake Bashkara has not been enlarging, but its water level has shown significant inter- and intra-annual fluctuations. The lake outburst probability has increased in recent years, and in 2008 we observed surface overflow over the moraine dam. Taking into account that in the late 1950s lake outbursts at this site led to large-scale glacial debris flows, we have simulated a potential outburst using River and FLO-2D software and carried out hazard zonation. An early warning system has been designed and established at Lake Bashkara, and measures to mitigate risk have been proposed. Rapid change of proglacial lakes requires regular monitoring in ‘hot spot’ areas where the GLOF hazard is high and is dynamically changing.     

Characteristics of winter mass balance of Glacier No.1 at the headwaters of the Urumqi River,Tianshan Mountains

This study analyzes the response of glacier to climate change during the past 49 years in Urumqi River source region, the Tianshan Mountains of China. The temporal and spatial variations of winter mass balance (bn-w) at different time scales were analyzed to identify their response to climate change during 1988–2006 (The observation of winter mass balance observation began in 1988) on the Glacier No.1 at the headwaters of the Urumqi River, Tianshan Mountains, China. The winter accumulation shows a significantly decreasing trend. The results show that the cumulative values on Glacier No.1 is 2,202 mm water equivalent during 1988–2006 and the mean values is 116 mm a⁻¹. Furthermore, the trend analysis of the winter mass balance indicates a rapid decrease since 1990, and the mean mass balance is only 79 mm a⁻¹ during 1997–2006. Winter mass balance correlates well negatively with the total evaporation from September to April (r = −0.68, α = 0.01), and positively with the total precipitation from September to April (r = 0.74, α = 0.01). However, winter mass balance shows a weak correlation with mean minimum air temperature during September to April (r = −0.35), and runoff on September (r = −0.13).     

Glacier No. 4 of Sigong River over Mt. Bogda of eastern Tianshan, central Asia: thinning and retreat during the period 1962–2009

RTK-GPS data, aerial photographs and Aster images were used to quantify volume, surface elevation, terminus position and area changes of Glacier No. 4 of Sigong River over Mt. Bogda, Tianshan during the period from 1962 to 2009. Glacier surface elevation of the tongue area decreased by 15 ± 8 m (0.32 ± 0.17 m a⁻¹) and ice volume loss reached 0.014 ± 0.008 km³ (0.013 ± 0.007 km³ w. e.). The glacier terminus retreated at a rate of 8.0 m a⁻¹ and the area decreased by about 0.53 km², accounting for 15.8% of the glacier area in 1962 (3.33 km²). The changes can be primarily attributed to the significant increase in temperature in this region. A comparison with glacier changes by field measurements in other regions of eastern Tianshan showed obvious spatial differences in the magnitude of the changes, owing to a combination of regional climate change and topographical factors.     

Ice‐margin and meltwater dynamics during the mid‐Holocene in the Kangerlussuaq area of west Greenland

Land‐terminating parts of the west Greenland ice sheet have exhibited highly dynamic meltwater regimes over the last few decades including episodes of extremely intense runoff driven by ice surface ablation, ponding of meltwater in an increasing number and size of lakes, and sudden outburst floods, or ‘jökulhlaups’, from these lakes. However, whether this meltwater runoff regime is unusual in a Holocene context has not been questioned. This study assembled high‐resolution topographical data, geological and landcover data, and produced a glacial geomorphological map covering ~1200 km². Digital analysis of the landforms reveals a mid‐Holocene land‐terminating ice margin that was predominantly cold‐based. This ice margin underwent sustained active retreat but with multiple minor advances. Over c. 1000 years meltwater runoff became impounded within numerous and extensive proglacial lakes and there were temporary connections between some of these lakes via spillways. The ice‐dams of some of these lakes had several quasi‐stable thicknesses. Meltwater was apparently predominantly from supraglacial sources although some distributary palaeochannel networks and some larger bedrock palaeochannels most likely relate to mid‐Holocene subglacial hydrology. In comparison to the geomorphological record at other Northern Hemisphere ice‐sheet margins the depositional landforms in this study area are few in number and variety and small in scale, most likely due to a restricted sediment supply. They include perched fans and deltas and perched braidplain terraces. Overall, meltwater sourcing, routing and the proglacial runoff regime during the mid‐Holocene in this land‐terminating part of the ice sheet was spatiotemporally variable, but in a manner very similar to that of the present day.     

Nitrate pollution of groundwater in Toyserkan,western Iran

A total of 95 groundwater samples were collected from Toyserkan, western Iran to assess the chemical composition and nitrate (NO₃ ⁻) status of groundwater. The most prevalent water type is Ca–HCO₃ followed by water types Ca–Mg–HCO₃. In comparison with the World Health Organization (WHO) drinking water guideline of 50 mg l⁻¹ for NO₃ ⁻, a total of nine wells (9.5%) showed higher concentrations. In 36% of samples (34) NO₃ ⁻ concentration was low (<20 mg l⁻¹), and in 53.7% of samples (51), in the range of 20–50 mg l⁻¹. The samples were classified into four groups based on NO₃ ⁻ and chloride (Cl⁻) concentrations. Of the samples, 40% were classified as group 4 and were relatively high in Cl⁻ and NO₃ ⁻ (Cl⁻ > 47 mg l⁻¹, NO₃ ⁻ > 27 mg l⁻¹). The high correlation between NO₃ ⁻ and Cl⁻ (r = 0.86, p < 0.01) is consistent with a manure source, resulting from the practice of adding salt to animal feed. Pollution of groundwaters appeared to be affected by the application of inorganic fertilizer at greater than agronomic rates, Cl-salt inputs, and irrigation practice.     

The Contribution of Benthic Nutrient Regeneration to Primary Production in a Shallow Eutrophic Estuary,Weeks Bay,Alabama

Benthic oxygen, dinitrogen, and nutrient fluxes (NH₄⁺, NO₃⁻, and PO₄³⁻) were measured monthly during a 1-year period at two locations in Weeks Bay, a shallow (1.4 m) and eutrophic estuary in Alabama. Gross primary productivity (GPP), ecosystem respiration (R), and net ecosystem metabolism were determined from high-frequency dissolved oxygen measurements. Peak water column NO₃⁻ (55 μM) and chlorophyll a (138 μg/l) concentrations were measured during spring and fall, respectively. Sediments were a net source of NH₄⁺ (102 μmol m⁻² h⁻¹) and PO₄³⁻ (0.9 μmol m⁻² h⁻¹) but a sink for NO₃⁻ (−30 μmol m⁻² h⁻¹). Benthic N₂ fluxes indicated net N fixation (12 μmol N m⁻² h⁻¹). Sediment oxygen demand (0.55 g O₂ m⁻² day⁻¹) accounted for <10% of R (7.3 g O₂ m⁻² day⁻¹). Despite high GPP rates (4.7 g O₂ m⁻² day⁻¹), the estuary was net heterotrophic. Benthic regeneration supplied, on average, 7.5% and 4% of primary productivity N and P demands, respectively. These results contrast with the conventional view that benthic regeneration accounts for a large fraction of phytoplankton nutrient demand in shallow estuaries.     

Hydrochemical characteristics and quality assessment of shallow groundwater in a coastal area of Southwest Bangladesh

In this study, the hydrochemical characteristics of shallow groundwater in a coastal region (Khulna) of southwest Bangladesh have been evaluated based on different indices for drinking and irrigation uses. Water samples were collected from 26 boreholes and analyzed for major cations and anions. Other physico-chemical parameters like pH, electrical conductivity (EC), and total dissolved solids were also measured. Most groundwater is slightly alkaline and largely varies in chemical composition, e.g. EC ranges from 962 to 9,370 μs/cm. The abundance of the major ions is as follows: Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ = Cl⁻ > HCO₃ ⁻ > SO₄ ²⁻ > NO₃ ⁻. Interpretation of analytical data shows two major hydrochemical facies (Na⁺–K⁺–Cl⁻–SO₄ ²⁻ and Na⁺–K⁺–HCO₃ ⁻) in the study area. Salinity, total hardness, and sodium percentage (Na%) indicate that most of the groundwater samples are not suitable for irrigation as well as for domestic purposes and far from drinking water standard. Results suggest that the brackish nature in most of the groundwaters is due to the seawater influence and hydrogeochemical processes.     

Microelectrode Study of Oxygen Uptake and Organic Matter Decomposition in The Sediments of Xiamen Western Bay

Sediment cores were sampled from Xiamen Western Bay at five sites during the summer and winter of 2006 and Hg–Au microelectrodes were used to make on board measurements of the concentration gradients of dissolved oxygen, Mn²⁺, and Fe²⁺ within the sediments. The O₂ concentrations decreased sharply from about 200 μmol L⁻¹ in the bottom seawater to zero within a depth of a few millimeters into the sediment. Dissolved Mn²⁺ was detected below the oxic zones with peak concentrations up to 600 μmol L⁻¹, whereas dissolved Fe²⁺ had peak concentrations up to 1,000 μmol L⁻¹ in deeper layers. The elemental contents of organic carbon and nitrogen within the sediments were analyzed and their C/N ratios were in the range of 9.0 to 10.1, indicative of heavy terrestrial origin. Sediments from two sites near municipal wastewater discharge outlets had higher organic contents than those from the other sites. These high organic contents corresponded to shallow O₂ penetration depths, high dissolved Mn²⁺ and Fe²⁺ concentrations, and negative redox potentials within the sediments. This indicated that the high organic matter content had promoted microbial respiration within the sediments. Overall, the organic content did not show any appreciable decrease with increasing sediment depths, so a quadratic polynomial function was used to fit the curve of O₂ profiles within the sediments. Based on the O₂ profiles, O₂ fluxes across the seawater and sediment interface were estimated to be in the range 6.07 to 14.9 mmol m⁻² day⁻¹, and organic carbon consumption rates within the surface sediments were estimated to be in the range 3.3 to 20.8 mgC cm⁻³ a⁻¹. The case demonstrated that biogeochemistry within the sediments of the bay was very sensitive to human activities such as sewage discharge.     

Strontium isotope composition of runoff from a glaciated carbonate terrain

The relationship between subglacial chemical weathering processes and the Sr isotope composition of runoff from Robertson Glacier, Alberta, Canada, is investigated. This glacier rests on predominantly carbonate bedrock of Upper Devonian age, but silicate minerals are also present. The provenance of solute in meltwaters is found to vary systematically with solute concentration and, by inference, subglacial water residence time. In dilute waters, the principal process of solute acquisition is calcite dissolution fueled by protons derived from the dissolution of CO₂ and subsequent dissociation of carbonic acid. At higher solute concentrations, dolomite dissolution coupled to sulfide oxidation is more important. Sr concentration is found to increase with total solute concentration in two separate meltwater streams draining from the glacier, but ⁸⁷Sr/⁸⁶Sr only increases in the eastern melt stream. Carbonate and K-feldspar sources are shown to dominate the Sr content of the western stream, irrespective of concentration. They also dominate the Sr content of the eastern stream at low and intermediate concentrations, but at higher concentrations, muscovite (with high ⁸⁷Sr/⁸⁶Sr) is also an important Sr source. This reflects the outcrop of muscovite-bearing lithologies in the catchment of the eastern stream and an increase in the rate of weathering of K-silicates relative to that of carbonates as more concentrated solutions approach saturation with respect to carbonates. Nonstoichiometric release of ⁸⁷Sr/⁸⁶Sr and preferential release of Sr over K from freshly ground K-silicate surfaces may also occur. This may help to explain the radiogenic nature of runoff from distributed subglacial drainage systems, which are characterized by long water:rock contact times and water flow through environments in which crushing and grinding of bedrock are active processes.Although the exchangeable Sr in tills has higher ⁸⁷Sr/⁸⁶Sr than local carbonate bedrock, only the more concentrated meltwaters from the eastern stream display similarly high values. The most dilute waters, which probably transport the bulk of the dissolved Sr flux from the glacier, have ⁸⁷Sr/⁸⁶Sr characteristic of local carbonate bedrock. Thus, the results suggest that although enhanced weathering of silicate minerals containing radiogenic Sr (such as muscovite) does occur in glaciated carbonate terrains, it is unlikely to contribute to any enhanced flux of radiogenic Sr from glaciated continental surfaces to the oceans.