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1.
塔里木盆地群4井原油吡咯类含氮化合物地球化学研究 总被引:27,自引:7,他引:27
在塔里木盆地群4井原油中成功地分离并检测出丰富的吡咯类含氮化合物-链基咔唑类,而链基苯并咔唑和链基二苯并咔唑则未被发现。链基咔唑中以二甲基咔唑、C3-咔唑和C4-咔唑为主。在甲基咔唑和二甲基咔唑中又鉴别出多个异构体。甲基咔唑中G2 G3含量相当,而二甲基咔唑中G3占优势。在我国,原油含氮化合物研究刚刚起步。实践证明,该类化合物是研究油气运移的可靠的、专属性强的标志化合物。通过本项研究,我们认为群4井原油已经历了长距离的运移。 相似文献
2.
准噶尔盆地北三台地区湖相原油咔唑类化合物的地球化学特征 总被引:3,自引:3,他引:3
准噶尔盆地北三台地区北 82井、北 83井和沙 10 8井湖相原油咔唑类化合物的分布特征表明,油气运移作用是影响该区原油中咔唑类化合物分布的重要因素。沿油气运移方面,咔唑类化合物具有明显的分馏效应。总的趋势是原油中咔唑类化合物、高分子量的烷基咔唑化合物和苯并咔唑化合物的含量逐渐减少,低分子量咔唑和甲基咔唑,以及具屏蔽效应的二甲基咔唑和苯并 [a]咔唑异构体的相对含量则逐渐增加。利用咔唑类化合物的分馏效应,可有效地指示油气运移方向。 相似文献
3.
对渤海湾盆地一系列生物降解原油的色谱-质谱分析结果表明,庙西凹陷PL15-8D与PL9-4井四个严重生物降解原油三环萜烷系列分布较为异常,主要表现为以C23为主峰的后峰型、C20与C23为主峰的微弱双峰型以及以C20与C24为主峰的双峰型分布模式。强烈的生物降解作用导致C19~C23三环萜烷优先于C24+三环萜烷被不同程度地侵蚀,是形成这一异常分布的根本原因。三环萜烷系列相对丰度与绝对浓度的变化规律表明,不同碳数三环萜烷的生物降解作用同时发生,但其降解速率有明显差别,即抗生物降解能力不同。三环萜烷系列化合物(除C20三环萜烷以外)的抗生物降解能力具有随碳数增加而增强的趋势,而C20三环萜烷抗降解能力似乎强于C21~C23三环萜烷。原油中未检测到脱甲基三环萜烷,表明三环萜烷的降解并非通过微生物的脱甲基化作用,推测其降解途径是微生物氧化三环萜烷C环支链末端的甲基,形成对应的羧酸化合物。四个原油样品甾烷、藿烷与三环萜烷被微生物严重侵蚀,不能用于油源对比研究,而三芳甾烷未受生物降解影响,可作为研究区严重生物降解原油油源对比的有效指标。 相似文献
4.
基于C30重排藿烷(C30DH)和C30藿烷(C30H)热稳定性差异,研究了C30DH/C30H作为油气运移方向和充注途径的可行性.结果发现:C30DH结构稳定性高于C30H,C30DH/C30H参数具有成熟度属性;同时对比分析C30DH/C30H参数与咔唑类参数的相关性,认为两者之间正相关性明显,表明C30DH/C30H参数不仅是良好的热成熟度参数还是良好的石油充注运移参数.M油田位于Fula凹陷东部,M油田原油为弱氧化-还原、淡水-微咸水环境下低等藻类与高等植物混源生成,属于同一族群原油.利用C30DH/C30H参数示踪Fula凹陷M油田石油充注方向,油气运移途径主要为自北向南,同时还发育自西向东的运移途径;咔唑类参数也验证了C30DH/C30H参数示踪油气运移的准确性.结果表明C30DH/C30H参数是示踪石油充注途径的有效参数. 相似文献
5.
塔北地区三叠系油藏原油中性含氮化合物和烷基苯酚的运移分馏作用 总被引:10,自引:2,他引:10
塔北地区三叠系油藏原油中性含氮化合物和烷基苯酚自南向北存在着运移分馏作用,表现为中性含氮化合物的绝对浓度由高变低,屏蔽型化合物相对富集而部分屏蔽型化合物和裸露型化合物相对贫瘠,1,8 DMCA/1,7 DM CA,1,8 DMCA/2,7 DMCA,1,8 DMCA/部分屏蔽化合物,1,8 DMCA/裸露化合物的比值由小变大,而 [a]/[c]的比值则由大变小,烷基苯酚化合物 2 MPH/3 MPH和 2,6 DMPH/2,3 DMPH的比值亦由小变大。此外同一构造带中原油自西向东,从下而上中性含氮化合物同样存在着运移分馏效应。研究还表明塔北地区三叠系原油横向上自南向北,从吉拉克地区向桑塔木断垒和轮南断垒带方向运移,而侧向上原油从下而上,自西至东进行了运移和调整 相似文献
6.
为阐明下扬子皖南地区上二叠统大隆组页岩特征,通过对港地1井岩心进行取样,开展了大隆组页岩样品的有机地球化学测试、氩离子抛光-扫面电镜观察、矿物组成分析等工作.结果表明皖南地区大隆组页岩TOC含量为1.18%~4.35%,干酪根以Ⅰ型为主,少数为Ⅱ1型,Ro介于1.15%~1.29%,反映大隆组页岩整体处于成熟的生油气阶段.饱和烃气相色谱图呈典型的单峰型分布,正构烷烃主峰碳数分布在nC18~nC22之间,nC25+高碳数正构烷烃含量较低.规则甾烷的丰度整体上表现为C27≈C29>C28,属于V型分布,且高、低碳数的正构烷烃单体碳同位素δ13C相差较大(3.0‰~5.6‰),略高于单一来源的不同碳数正构烷烃的δ13C变化(一般小于1.6‰),反映大隆组页岩有机质主体来源于菌藻类等低等水生生物,局部存在陆源高等植物.TOC与TS的相关性、Pr/Ph比值、Pr/nC17-Ph/nC1... 相似文献
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8.
生物降解原油中吡咯氮化合物组成的变化 总被引:1,自引:0,他引:1
渤海海域地区近50个原油样品中性氮组分的GC/MS定量分析资料表明,油藏中的生物降解作用对原油的吡咯氮化合物含量和分布有明显影响。经与同源未降解原油比较,各种烷基咔唑和苯并咔唑在3。4级中轻度降解油中就出现明显降解迹象,随生物降解程度增高其含量逐渐减少,在6—8级严重降解油中它们的总含量降低到原有的五分之一左右。在3—4级中轻度降解油中,裸露型甲基咔唑异构体更容易被微生物侵袭而代谢,抗生物降解能力按1-甲基咔唑〉4-甲基咔唑〉2-、3-甲基咔唑顺序递减;当降解程度更高时,这些化合物降解速率相当,1-/4-MCA等比值相对稳定。低-中等降解阶段,不同类型二甲基咔唑异构体的抗生物降解能力也存在明显差异性,呈屏蔽型〉半屏蔽型〉裸露型降低;在生物降解水平进一步增高时,这些异构体之间的相对含量变化不大。生物降解作用对苯并咔唑系列化合物分布的影响具有不确定性,且随降解程度的增加变得更为显著,降解油中【a】/[c】苯并咔唑比值或增高或降低。生物降解原油中吡咯氮化合物的组成变化,使降解油的二次运移示踪面临新的问题。 相似文献
9.
松辽盆地北部上白垩统油页岩属中一差油页岩;有机质类型以Ⅰ型为主,Ⅱ.型为辅,处于低成熟一成熟阶段.生物标记化合物都含有丰富的正构烷烃、类异戊二烯型烷烃、萜类化合物和甾类化合物.正构烷烃呈前高后低的单峰型分布,nC23、nC27为主峰碳,重烃组份占绝对优势,OEP值为1.02~6.63,具有明显的奇碳数优势.Pr/Ph比值为0.13~1.37,多数小于0.6,具植烷优势,伽马蜡烷含量较高,油页岩沉积环境为咸化还原环境且盐度较高.萜烷丰度顺序为五环三萜烷>三环萜烷,三环萜烷中C20、C21和C23,丰度相对较高,且C20、C21和C23多呈倒“V”形分布,C23相对富集.甾类化合物主要成份为规则甾烷C27、C28和C29,ααα20RC27、C28和C29甾烷多数呈几乎对称的“V”形分布,C29 >C28 >C27.甾萜烷分布特征反映其原始有机母质构成中既有丰富的菌藻类等低等水生生物,又有一定比例的陆生高等植物混合输入. 相似文献
10.
塔里木盆地哈得逊及相邻地区原油含氮化合物分布特征及油藏充注方向探讨 总被引:9,自引:4,他引:9
塔里木盆地哈得逊及相邻地区存在一些化学组成相似的中一高密度原油。对原油中含氮化合物浓度和相对组成特征进行了较系统的研究,结果表明,原油中含氮化合物分布特征和原油的运移分馏效应存在较好的成因联系。随着运移作用的加强,“屏蔽”型与“暴露”型或“半屏蔽”型化合物的比值增加,含氮化合物浓度下降,且不同化合物之间的比值均表现出较强的协同变化关系。含氮化合物运移参数的分布特征表明,哈得4油田原油总体上具有由北向南的运移和充注过程。这与区域上原油的运移方向是一致的。 相似文献
11.
酒西盆地石油非均质性的控制因素 总被引:7,自引:0,他引:7
运用先进的分析测试手段对来自酒西盆地六个油田的 2 0多个油样进行了全油碳同位素、饱和烃气相色谱与质量色谱及正构烷烃分子碳同位素等较为全面的分析与研究。确定源岩相、水洗、生物降解作用与成熟度不是酒西盆地石油非均质性的控制因素。最后选取 1 5个油样进行中性吡咯氮化合物分析,用中性吡咯氮中的咔唑类化合物作为运移参数,较为详细地研究原油的运移分馏作用。此类化合物作为运移参数的基本原理是石油运移过程中,不同结构的咔唑类化合物与水及岩石中矿物发生吸咐作用的强烈程度不同,导致不同的运移分馏作用。根据咔唑类化合物的变化得出控制酒西盆地石油组成非均质性的主要因素是油气运移分馏作用,证实酒西盆地石油运移方向主要是从西至东,青西凹陷是其油源区。 相似文献
12.
Petroleum migration process of Bamianhe oilfield of Dongying depression, East China is evaluated on the basis of our detailed work on geochemistry of the crude oil and the source. Molecular tracers, especially nitrogen compounds, are employed in assessing style of oil migration and accumulation. Additionally, absolute quantitative results of heteroaromatics including dibenzofuran, dibenzothiophene and fluorene with similar basic frames to pyrrolic nitrogenic compounds are also used to evaluate the quantity of petroleum migration. According to apparent migration effects of the pyrrolic nitrogen compounds, it is indicated that most of Bamianhe oil was derived from potential source kitchen-Niu-zhuang sag, migrated and accumulated at Bamianhe fault belt through selective paths according to a main filling point displayed. Generally, upward migration trend from the main point along the south slope is noted. There are observable migration effects from Guangli subsag to the north Bamianhe and Yangjiaogou oilfields showing Guangli subsag was a secondary kitchen accounting for the oils in the north portion. Significant vertical migration effects shown in several cross sections demonstrate that faults well developed in the area play an important role in oil migration and accumulation. Unformality, sandstone reservoirs distributed locally also suggest important fairways in connecting sources with traps. The tectonic and a combination of tectonic and lithological mechanism are identified as the critical mechanisms in entrapping hydrocarbons. Migration trend suggested by nitrogenic compounds agrees well with analysis of lateral compositional variety and thermal maturity gradient. This study also confirms well with our previous studies. It is the location of source rocks, tectonic and stratigraphic characteristics that have a comprehensive control on the model of hydrocarbon migration and accumulation in Bamianhe oilfield. Results also show that the oils are mostly derived from the deep parts of the Niuzhuang and Guangli sags within normal oil window. 相似文献
13.
金湖凹陷西斜坡油气运移分子地球化学研究 总被引:13,自引:0,他引:13
应用非烃技术、多馏分绝对定量技术,在分析苏北金湖凹陷原油、烃源岩地球化学特征、油源对比的基础上,重点对吡咯类含氮化合物在岩-油、油-油运移中的分馏效应进行了研究,并对骨架相似的另两类杂原子化合物-氧芴 (二苯并呋喃 )、硫芴 (二苯并噻吩 )的运移分馏效应作了初步探讨。结果表明,金湖凹陷西斜坡原油中吡咯类化合物具有较好的运移分馏效应,油气主体运移方向为东北至西南,相邻的三河次凹为其主要的油源区;杂原子化合物-氧芴、硫芴系列运移分馏效应不及吡咯类;绝对定量技术可弥补常规生物标志物在油气二次运移过程中异构体间分馏效应难以观察的不足,可作为继非烃技术后的另一评价油气运移过程的重要工具。 相似文献
14.
Oils in the Maling oil field, Ordos Basin, are produced from fluvial deposits within the Yan-9 and Yan-10 subsections of the Yanan formation. Through the analysis of pyrrolic nitrogen compounds and fluid inclusions, the oil charging site, migration direction and pathway, and timing were interpreted in relationship with the sedimentary features and the high pressure observed in the Mesozoic sequence. The spatial distribution pattern of the fractionation of neutral nitrogen compounds in the crude oils suggested two possible charging positions in the studied area. The ratios of the isomeric nitrogen compounds increase toward the center of the study area from both northwest and southeast directions of the region, indicating that the lateral charging directions were likely from both the southeast and the northwest toward the center of the oil field. The isomeric ratios of pyrrolic nitrogen compounds in the oils from different area of the Maling oilfield increase with the decrease of depth from Yan-10 to Yan-4 + 5 subsections, showing vertical migration of oil to the reservoirs. The homogenization temperature of fluid inclusions in the reservoir rocks exhibited two peaks, reflecting the two stages of oil migration and accumulation. The migration pathways include fluvial sand bodies and unconformity surfaces. The migration driving force was likely the capillary pressure and the abnormally high strata pressure in the Mesozoic sequences. 相似文献
15.
低熟油、烃源岩中含氮化合物分布规律及其地球化学意义 总被引:18,自引:3,他引:18
对八面河地区原油、油砂以及不同成熟度和岩性有异的烃源岩中吡咯类化俣物的分布特征及其潜在的地球化学意义进行了探讨。结果表明,随着成熟度的增加,八面河地区烃源岩中吡咯类化合物中屏蔽化程度高的异构体比屏蔽化程度低的异构体富集,咔唑及苯并咔唑系列中低相对分子质量的同系物比高相对分子质量的同系物富集,苯并[a]咔唑比苯并[c]咔唑富集。八面河地区原油中吡咯类化合物有较为明显的运移分馏效应,观察到高、低相对分子质量的同系物间的运移分馏效应比不同类型异构体间的分馏效应更为显著,而前者受成熟度的影响可能相对小于后者;发现吡咯类化合物的油气运移分馏效应不仅体现于不同氮官能团屏蔽、半屏蔽和暴露三类异构体间,同样体现于同一类型的同分导师构体之间,指示此类化合物有较强的活性。吡咯类化俣物与烃类化合物一样具有多方面潜在的地球化学意义。 相似文献
16.
新疆焉耆盆地油气运移方向综合地球化学分析 总被引:1,自引:1,他引:1
分析了新疆焉耆盆地侏罗系原油的物性、含氮化合物含量和储层自生伊利石的同位素年龄在纵向和横向上的变化规律,探讨了焉耆盆地侏罗系油气运移方向。由上述分析可知,该区原油密度、含氮化合物含量和自生伊利石K-Ar年龄在平面上和垂向上均呈现出规律性的变化,即:平面上自南而北这些参数逐渐降低,垂向上同一构造带内随埋深减小这些参数逐渐变小。由此表明焉耆盆地侏罗系油气运移方向在平面上是从南向北,即油气先充注宝南储层,然后依次注入宝中和宝北储层;在纵向上是从深层向浅层运移,从八道湾组向三工河组和西山窑组储层中运移聚集。 相似文献
17.
ZHAO Yande YAO Jingli SUN Bainian Duan Yi DONG Chong DENG Xiuqing and LIU Luofu 《《地质学报》英文版》2014,88(6):1798-1810
Abstract: The Ordos Basin is an important intracontinental sedimentary basin in western China for its abundant Mesozoic crude oil resources. The southern part of the Tianhuan Depression is located in the southwestern marginal area of this Basin, in which the Jurassic and Triassic Chang-3 are the main oil-bearing strata. Currently, no consensus has been reached regarding oil source and oil migration in the area, and an assessment of oil accumulation patterns is thus challenging. In this paper, the oil source, migration direction, charging site and migration pathways are investigated through analysis of pyrrolic nitrogen compounds and hydrocarbon biomarkers. Oil source correlations show that the oils trapped in the Jurassic and Chang-3 reservoirs were derived from the Triassic Chang-7 source rocks. The Jurassic and Chang-3 crude oils both underwent distinct vertical migration from deep to shallow strata, indicating that the oils generated by Chang-7 source rocks may have migrated upward to the shallower Chang-3 and Jurassic strata under abnormally high pressures, to accumulate along the sand bodies of the ancient rivers and the unconformity surface. The charging direction of the Jurassic and Chang-3 crude oils is primarily derived from Mubo, Chenhao, and Shangliyuan, which are located northeast of the southern Tianhuan Depression, with oils moving toward the west, southwest, and south. The results show that an integration of biomarker and nitrogen-bearing compound analyses can provide useful information about oil source, migration, and accumulation. 相似文献
18.
苏北盆地溱潼凹陷油气运聚模式 总被引:2,自引:0,他引:2
通过对苏北盆地溱潼凹陷不同构造带部分具代表性油藏原油的饱和烃、芳烃生物标志物和吡咯类含氮化合物分布特征的分析,结合油区构造研究和油源对比成果,讨论了研究区油气的运移方向与运聚模式。结果表明,研究区不同构造带原油中吡咯类含氮化合物分馏效应存在差别,处于断阶带南侧的成熟原油运移效应明显,来源于其西北侧的俞垛次凹始新统阜宁组二段烃源岩;断阶带北侧的原油运移分馏效应较差,推测其主要来源于北侧的储家楼次凹阜宁组二段烃源岩,以短距离侧向运移为主;内斜坡带原油主要来自于储家楼深凹阜宁组二段烃源岩,沿其构造带上倾方向自西南到东北方向,含氮化合物分馏效应明显;坡垒带与外斜坡带阜宁组三段原油成熟度偏低,吡咯类含氮化合物浓度较高,原油自东北向西南方向以短距离运移为主,主要来自于深凹的低熟烃源岩。不同构造带的油气成藏模式也不一致,断阶带为阶梯状断块油气聚集模式,内斜坡带与坡垒带主要分布受断层控制的断块—岩性油藏,外斜坡带为反向正断层垒块控油模式。 相似文献
19.
Measurements of the absolute and relative concentrations of nitrogen-containing compounds in crude oils from different reservoir strata (Ordovician, Silurian and Carboniferous) in the Tazhong region of the Tarim Basin, Xinjiang, China, showed that even though there are quite a number of factors affecting the distributional and compositional characteristics of neutral nitrogen-containing compounds in crude oils, the distributional and compositional characteristics of crude oils whose source conditions are approximate to one another are influenced mainly by the migration and fractionation effects in the process of formation of oil reservoirs. In addition, crude oils in the Tazhong region show obvious migration-fractionation effects in the vertical direction. Carboniferous crude oils are characterized by high migration parameters and low compound concentrations, just in contrast to Ordovician crude oils. This indicates that crude oils from shallow-level oil reservoirs were derived from those of deep-level oil reservoirs via faults, unconformable contact or carrier beds. Crude oils from the Tazhong region show some migration-fractionation effects in the lateral direction, but mixing of crude oils derived from different hydrocarbon source rocks in the process of formation of oil reservoirs made it more complicated the migration and accumulation of crude oils, as well as the formation of oil reservoirs. 相似文献
20.
东营凹陷北部陡坡带稠油成藏机理与油气运聚特征 总被引:6,自引:1,他引:5
东营凹陷北部陡坡带的王庄—宁海地区发现了大量稠油 ,但原油的成因及其成藏机理仍不甚了解 .在以往原油成因与油源调查基础上 ,利用非烃含氮化合物及包裹体均一化温度对该区进行油气运移方向与相对距离、成藏时间与期次的分析 .结果表明 ,东营凹陷北部带原油具有由南而北的运移分馏效应 ,反映北部陡坡带原油来自南部的利津洼陷 ;王庄—宁海地区原油总体具有由东而西的运移分馏效应 ,其东、西两侧各有一主要油气注气点 .王庄—宁海原油烃类与非烃组成与分布特征揭示该区油气具有混合聚集特征 .包裹体测试反映王庄—宁海地区油藏主要为晚期成藏 ,距今小于 5Ma ;而靠近生油中心地带包裹体具有早期成藏的记录 (± 36Ma) . 相似文献