雷州半岛第四纪火山岩激光40Ar/39Ar等时线定年研究

雷州半岛是我国新生代火山岩最重要的分布地区之一,火山活动主要集中在中晚更新世。前人对雷州火山岩的年代学研究以K-Ar法为主。研究表明,雷州火山岩测年结果大致分布在0.38～3.04Ma范围内。根据地层和火山岩层的叠置关系,雷州第四纪火山岩由于覆盖在被确定是1.87Ma和0.76Ma沉积的地层之上,故火山岩年龄应小于该地层年龄。K-Ar法定年结果与雷州地区地层叠置关系存在矛盾。本文通过对雷州半岛第四纪火山岩进行野外考察及采样,利用激光40Ar/39Ar年代学方法进行了精细定年。结果表明,雷州火山岩的喷发主要集中18万年前后。定年结果还表明,对于年轻样品,基于尼尔值计算的K-Ar年龄及40Ar/39Ar表观年龄偏老,等时线年龄相对较为可靠。对同一样品的斑晶、基质作斑晶-基质等时线计算,只有在斑晶基质满足同源条件时才有意义。本文首次提出,通过对比未照射样品的初始36Ar/38Ar值的均一性,以检验样品是否同源,确认斑晶-基质等时线年龄的可信度。据此,等时线的处理方法可以推广应用于特定区域内全部同源同时样品。     

Isotopic evidence of middle proterozoic magmatism from bombay high field: Implications to crustal evolution of western offshore of India

Precambrian granitic basement rocks obtained from well BH-36 of Bombay High Field, western offshore of India has been studied both by Rb-Sr and K-Ar dating methods. Seven basement samples chosen from two cores have yielded whole rock Rb-Sr isochron age of 1446 ± 67 Ma with an initial⁸⁷Sr/⁸⁶Sr ratio of 0.7062 ± 0.0012. This age has been interpreted as the formation/emplacement time of the granite. Two biotite fractions of different grain size separated from a sample CC6B2T have yielded Rb-Sr mineral isochron age of 1385 ± 21 Ma. However, these fractions when studied by K-Ar dating method have yielded slightly higher but mutually consistent ages of 1458 ± 43 Ma and 1465 ± 43 Ma, respectively. Further, two biotites separated from additional samples CC5B9T and CC6B3B have yielded K-Ar ages of 1452 ± 42 Ma and 1425 ± 40 Ma with an overall mean age of 1438 ± 19 Ma. This mean K-Ar age is indistinguishable from whole rock Rb-Sr isochron as well as mineral isochron age within experimental error. The similarity in the whole rock and biotite ages obtained by different isotopic methods suggests that no thermal disturbance has occurred in these rocks after their emplacement/formation around 1450 Ma ago. The present study provides the evidence for the existence of an important Middle Proterozoic magmatic event around 1400-1450 Ma on the western offshore of India which, hitherto, was thought to be mainly confined to the eastern Ghats, Satpura and Delhi fold belt of India. This finding may have an important bearing on the reconstruction of Proterozoic crustal evolution of western Indian shield.     

羌塘腹地新生代火山岩的地球化学特征与青藏高原隆升

羌塘腹地新生代火山岩产出于青藏高原地壳向北减薄、地壳泊松比值向北发生异常增高的过渡地区。该区火山岩在藏北地区新生代火山岩中形成时代最老,为 4 4.1± 1.0Ma～32.6± 0.8Ma。岩石学及地球化学研究表明,区内新生代火山岩形成于大陆碰撞造山后的拉张环境,为壳源岩浆和幔源岩浆的混合产物。藏北高原的隆升与岩石圈地幔的拆离、地壳拉伸减薄及火山活动密切相关,由此推测藏北高原的主要隆升起始期为 4 0Ma左右。     

Biostratigraphy and deposition environments of the Middle-Late Miocene volcanosedimentary section in the Dzhilinda basin,Western Transbaikalia

We report results of an integrated study of volcanosedimentary rocks of the Middle-Late Miocene Dzhilinda Formation consisting of the prevolcanic sedimentary Lower Dzhilinda and volcanosedimentary Upper Dzhilinda subformations. The section was studied in three wells drilled near Lake Mukhal (Khoigot paleovalley, Vitim upland). The Dzhilinda sediments contain ubiquitous Alveolophora jouseana (Moiss.) Moiss. typical of Miocene environments. Deposition occurred in two main stages represented by different water (diatoms) and land (spores and pollen) plant communities. The upsection successive changes in diatom species are attendant with changes in pollen and spore assemblages. The K-Ar ages of lavas indicate that the mostly sedimentary lower section of the Dzhilinda Formation deposited between 12 and 14 Ma and the more volcanic upper section, with a lacustrine lens at base, formed at about 10.8–9.5 Ma. The isotope dating of volcanic rocks agrees with the ages inferred from the diatom and spore-pollen analyses. The prevolcanic Lower Dzhilinda subformation deposited during the Middle Miocene climate optimum. The stratigraphy, lithology and facies of sediments suggest that the Dzhilinda deposition was associated with the development of a deep freshwater lake in the conditions of active tectonism and volcanism.     

K-Ar等时线定年法及其应用

本文提供了11条不同成因、不同时代岩石和矿物的⁴⁰Ar/³⁶Ar-⁴⁰K/³⁶Ar等时线,其中3条是新近测定的,另8条是对以前常规K-Ar定年资料的重新处理。测定对象包括年轻火山岩、花岗岩、矿脉及古老岩系中的铁镁质岩墙。测定的时间跨度从第四纪到前寒武纪。研究证明,K-Ar等时线定年既具有常规定年测定对象广泛、可测时间跨度大的优点,又能避免常规法的缺陷,可获得更可信的年龄和更多的有用信息。但是负截距的形成及其所代表的地质意义尚有待深入研究。     

Timing of the Mineralization and Volcanism at Cibaliung Gold Deposit, Western Java, Indonesia

Abstract. The Cibaliung deposit is a low-sulfidation type epithermal gold deposit situated about 70 km west of the Bayah dome complex. The gold-bearing quartz veins are hosted by basaltic andesite of the Honje Formation, which is comparable to the host rock of gold deposits at the Bayah dome complex.
In order to clarify the timing of the mineralization and the volcanism at the Cibaliung area, two radiometric dating methods were applied. First, ⁴⁰Ar/³⁹Ar dating was conducted on six adularia samples to elucidate the age of mineralization. Second, K-Ar method was applied to two samples of the host rock, andesite and the Cibaliung tuff, in order to reveal the timing of volcanism.
The ⁴⁰Ar/³⁹Ar dating determined mineralization ages in the range from 11.18 to 10.65 Ma while the K-Ar dating indicated the age of the andesite and the Cibaliung tuff to be 11.4±0.8 Ma and 4.9±0.6 Ma, respectively. These results imply that the epithermal gold mineralization in the Cibaliung area is related to the volcanic activity that produced the Honje Formation, while the Cibaliung tuff played an important role in the preservation of the Cibaliung deposit. The Cibaliung deposit is the oldest epithermal gold deposit yet discovered in western Java.     

Thermochronology for the Granitic Pluton Related to Lead-Zinc Mineralization in Tsushima, Japan

Abstract: K–Ar datings and oxygen isotope analyses revealed a cooling history of the Uchiyama granitic pluton, which is genetically related to the Pb-Zn deposits (Taishu mine) in the Tsushima Islands, Japan. The pluton intrudes into the Paleogene Taishu Group to form the biotite-hornfels zone, while the Taishu vein-type Pb–Zn deposits occur in fissures developed in the non-hornfels zone about 1 to 3 km westward from the contact. Amphibole and biotite K-Ar ages of the pluton have a wide range from 19 to 13 Ma. Oxygen isotopes of the biotite and coexisting quartz grains indicate that isotopic exchange reactions have occurred under subsolidus conditions, and that the K-Ar ages are affected by various cooling rates in the pluton. The mineralization age of the Taishu ore deposits is obtained for the first time to be 15.40.8 Ma by a K-Ar age of 2 M ₁–muscovite in a calcite–quartz–muscovite–chlorite veinlet of the Shintomi orebody. Whole rock K-Ar ages of biotite-hornfels near the pluton represent similar ages to the ore deposits. Using blocking temperature calculated from reported diffusivity for argon, the pluton was cooled from 560 to 350C in the period of 17 to 14 Ma. The vein formation took place after the time when temperature in wall rocks of the pluton had dropped below the brittle-plastic transition (about 400C). These results imply that the cooling of the pluton has caused injection of magmatic fluids into meteoric hydrothermal systems, and the Pb-Zn mineralization has occurred due to this mixing at the age of about 15 Ma.     

Geochronometry of the Middle Paleozoic volcanics of the Omolon Massif in Northeast Asia: A comparison of the K-Ar, Rb-Sr, and U-Pb data and their geological interpretation

The results of the K-Ar, Rb-Sr, and U-Pb (SHRIMP zircon method) dating of the Middle Paleozoic volcanogenic rocks of the Omolon Massif are summarized. It was concluded that they are principally consistent with each other, as well as with the geological data. The formation of the Kedon Group, which makes up the main volume of the Middle Paleozoic volcanics, began at the Early-Middle Devonian boundary about 400 Ma ago (U-Pb dates of 400.5 ± 4.4 and 387 ± 6.4; Rb-Sr isochron age of 402 ± 6 Ma). The isotopic age of the upper boundary of the Kedon Group remains unclear due to disagreements concerning its stratigraphic assignment. The histogram based on the 111 K-Ar dates of the volcanic rocks from the Kedon Group gives a polymodal distribution, which indicates that the K-Ar isotopic system was disturbed by thermal events, which occurred 310–290 (terminal Carboniferous—beginning of the Permian) and 240–220 (Middle-beginning of the Late Triassic) Ma ago. Both thermal events were associated with mantle (ultrabasic-basic) magmatism, which spanned a significantly wider territory than the distribution area of the Kedon Group     

Isotopic dating of pre-Alpidic rocks from the island of Ios (Cyclades,Greece)

The lower tectonic unit of Ios provides evidence of an at least four stage metamorphic and intrusive history which well might be generalized for large parts of the internal Pelagonian.Metamorphic country rocks of unknown age were intruded about 500 Ma ago, as concluded from a Rb-Sr whole rock (WR) isochron on relic tonalites to granodiorites which largely escaped the polyphase postmagmatic overprints.A Hercynian amphibolite facies metamorphism, during which the igneous rocks were partly recrystallized to orthogneisses, is dated by a lower intercept age of 300–305 Ma of U-Pb determinations on zircons and by three almost concordant Rb-Sr muscovite-WR ages of 295 to 288 Ma.K-Ar analyses on these muscovites and on biotites, and Rb-Sr tie lines WR-biotite and WR with other relic magmatic minerals yielded various apparent ages between 260 and 60 Ma. They are interpreted as mixed ages between a Hercynian cooling age and the two stage Alpidic overprints.White micas formed during the Eocene high P/T and/or Oligocene/Miocene Barrovian-type overprints yielded K-Ar dates ranging from 82 to 26 Ma, as well as a single Rb-Sr date of 13 Ma. These Alpidic dates resemble the more detailed age patterns of other Cycladic islands. But they are not sufficient for an independent dating of the Tertiary evolution on Ios island.     

华南某些含钨花岗岩的K-Ar年龄

测定了华南某些与钨矿床有关的花岗岩和钨矿脉样品的K—Ar年龄,共37件。这些花岗岩的表观年龄自183Ma至99.5Ma(年龄值为715Ma的岩体与钨矿无关),其中68％以上样品值域在150Ma左右。~(40)Ar/~(36)Ar—40K/~(36)Ar等时线图解给出的等时年龄为132.1Ma,说明这些花岗岩在形成时代上属中侏罗到早白垩世。我们发现在华南钨矿成矿域内,有一个从中心带向外年龄逐渐变青的趋势。用矿脉中和矿脉侧云英岩中云母类矿物所做的K—Ar定年得到的矿化作用的年龄,与各自相关的花岗岩的年龄非常接近,以至于很难用K—Ar定年法加以区别。即成矿作用和成岩作用有一种准同期性。等时线对应的~(40)Ar/~(36)Ar初始比高于现今大气Ar的比值,表明花岗岩在固结时有继承Ar存在。     

Timing of the cataclastic deformation along the Akaishi Tectonic Line,central Japan

This paper describes K-Ar ages of cataclasites and fault gouges from the Akaishi Tectonic Line (ATL), central Japan. Petrological and mineralogical features of these rocks are also examined. Based on the results, we test the hypothesis that the K-Ar ages of these rocks represent the age of hydrothermal alteration associated with the fault movement. Intensity of deformation and alteration increase passing from host rock into cataclasite and finally into fault gouge. This increase corresponds to an increase of the value of crystallinity index (Kübler index) of the micaceous minerals contained in these rocks. Furthermore, the degree of rejuvention of K-Ar ages of the micaceous minerals increases in the same sense. A correlation of K-Ar ages (plotted on the y axis) versus Kübler index (plotted on the x axis) yields a concave curve asymptotically parallel with the x axis at approximately 15 Ma. This curve is interpreted to represent the mode of decrease of the relative amounts of inherited argon in the K-Ar system of the micaceous minerals, corresponding to an increase in the intensity of deformation and alteration. Inclination of the curve becomes zero if all the inherited argon is lost from the K-Ar system of the micaceous minerals. Thus, it is concluded that the hydrothermal alteration occurred at approximately 15 Ma. The strike-slip basin along the ATL formed the middle Miocene. The K-Ar dating of ATL gouges indicates that the ATL was active simultaneously with formation of the strike-slip basin along its trace during the middle Miocene.     

Age distribution of Serra Geral (Paraná) flood basalts, southern Brazil

We evaluated 193 K-Ar ages (10 newly determined) of basaltic and differentiated rocks of the Serra Geral (Paraná) flood-basalt province for indications of magmatism occurring systematically with progressive rifting and complete separation ( ≈130-105 Ma) of South America from Africa. The K-Ar ages represent basalt emplacement between 35° and 19°S covering about 1,200,000 km². We note that volcanism appears ubiquitous across the province between about 140 and 115 Ma, and that there are no significant age differences within that relate directly to progressive south-to-north tectonism. On the other hand, the oldest samples, about 140–160 Ma, are among those nearest the Brazil coastline (rift margin), perhaps suggesting migration of activity away from the rift with time. Studies of other flood-basalt provinces now indicate short (<3 m.y.) eruption periods, thereby pointing to the need for re-examination of Serra Geral ages by ⁴⁰Ar-³⁹Ar incremental heating techniques.     

K-Ar ages of the Brandberg and Okenyenya igneous complexes,north-western Namibia

K-Ar mineral ages from intrusive units of the Brandberg and Okenyenya igneous complexes, north-western Namibia, confirm the Early Cretaceous age of the subvolcanic centres. The two centres are contemporaneous, although the range of ages from Brandberg, 135.2 ± 1.5 to 125.4 ± 1.3 Ma, suggests a rather longer period of intrusion than is represented by the rocks of Okenyenya, 133.3 ± 1.4 to 129.2 ± 0.7 Ma. The mean K-Ar age of the Okenyenya complex is essentially equivalent to previously determined Rb-Sr ages for the Messum and Paresis complexes on the same igneous lineament, but is a little greater than that suggested recently from Rb-Sr dating of this complex (129.1–123.4Ma). K-Ar chronology for the Brandberg complex is in conflict with the order of emplacement of granite units previously inferred from field evidence. In particular, the Amis peralkaline layered intrusion yields the oldest age from the complex, 135.2 ± 1.4 Ma. The concordancy of age measurements of amphibole and biotite, having very different potassium contents, from single rock samples is compelling evidence that neither inherited radiogenic argon, nor argon loss, presents a significant problem in the dated rocks. If the K - Ar age of 135 Ma for the Amis intrusion is correct, it constrains the minimum age for the onset of Etendeka flood volcanism, associated with continental break-up, as Etendeka lavas exhibit contact metamorphism and metasomatism around the rim of the Brandberg complex.     

松辽盆地庆深气田储层火山岩锆石U-Pb同位素年龄及其地质意义

庆深气田储层火山岩是由多期火山喷发叠置形成,分布在白垩系下统的营城组,以酸性喷发岩为主。火山岩离子探针(SHRIMP)锆石U-Pb年龄测定结果表明,储层火山岩年代集中在111～115 Ma,介于早白垩世晚期阿普第阶(Aptian)和阿尔布阶(Albian)的分界线附近。对比兴城与升平两个天然气产区的储层火山岩的形成年代,发现它们是同一时代的火山作用产物,并不是以前所认为的兴城地区火山岩属于营城组一段,升平地区火山岩属于营城组三段。这一结果对于松辽盆地火山岩气藏的勘探开发具有实际意义。     

Collision Event during 177-135 Ma on the Eastern Marginof the Qinghai-Tibet Plateau: Evidence from ~(40)Ar/ ~(39)Ar Dating for Basaltson the Western Margin of the Yangtze Platform

Geochronology of continental flood basalts sampled from the Emei large igneous province (LIP) on the western margin of the Yangtze platform was investigated by the laser microprobe 40Ar/39Ar dating technique. These basalts yield a fairly wide range of 40Ar/39Ar ages, varying from 259 to 135 Ma. One basalt sample, at least altered, recorded the oldest 40Ar/39Ar age of about 259 Ma, corresponding to a peak eruption age of the Emei LIP continental flood basalts. Most of the samples yield much younger ages from 135 to 177 Ma, which are consistent with the K-Ar ages for the same samples (122.8-172.1 Ma). The dating data suggest that these Permian basalts had been widely affected by the regional tectonothermal event at 177-135 Ma. The event was probably caused by the convergence and collision among the Laurasia, Yangtze and Qiangtang-Qamdo continental blocks on the eastern margin of the Qinghai-Tibet plateau after the late Triassic. The age of the event reflects the timing of the peak collisional orogeny.     

应用SHRIMP铀-铅定年法研究腾冲地区中更新世英安岩的形成时代

腾冲火山岩群是我国著名的年轻火山岩群,前人主要采用K-Ar法、不平衡铀系等同位素定年方法研究该区火山岩的年龄并划分其喷发期次,采用K-Ar法获得腾冲火山岩0.013~17.84 Ma的年龄以及0.13~2.9 Ma的等时线年龄,不平衡铀系法主要用于该地区0.23 Ma以来的样品年龄研究。传统的同位素定年体系的精确度和定年范围对于研究该区火山岩的年龄存有很大局限性。近年来,微区原位离子探针U-Pb定年在年轻地质体年代学研究中表现出巨大潜力,在国际上已经应用于中更新世晚期地质体的年龄测定。本文报道了应用锆石SHRIMP U-Pb定年方法对腾冲曲石地区中更新世英安岩的3次测定结果,3次实验的年龄值在误差范围内一致。在对一次离子流选择及其强度、二次离子积分时间等实验条件探讨的基础上,综合分析3次实验中的二次离子计数表明第3次实验结果具有更高的精确度,年龄值为0.41±0.01 Ma,属中更新世,代表该英安岩的形成时代,该年龄结果是目前我国获得的最年轻的高精度锆石SHRIMP U-Pb年龄。本研究获得的中更新世锆石U-Pb年龄为年轻地质体的年代学研究提供了新的思路。     

藏西北黑石北湖一带新近纪火山岩的特征及构造意义

青藏高原西北部黑石北湖一带发育的橄榄安粗岩系列火山岩具有由早到晚从基性到中性连续演化的特征，3期火山活动期次分明，以中心式喷发为主，K-Ar年龄分别为9．23Ma、3．19Ma和3Ma。该火山岩的稀土元素、微量元素、同位素组成特征与藏北其他地区的新生代火山岩基本相近。火山活动为新构造活动的响应，受控于青藏高原隆升过程中产生的走滑断裂。     

琼北火山岩激光40Ar/39Ar定年研究

新生代以来,雷琼地区多次、大量地喷发了一系列火山岩。前人主要基于K-Ar法对此划分了期次。本文采用激光40Ar/39Ar年代学方法,对琼北火山岩区进行了精细定年研究。低本底激光40Ar/39Ar法能够对低钾含量,极少量样品(毫克级)进行精细测定,非常适合极年轻火山岩的定年工作。结果显示的火山岩激光40Ar/39Ar法高质量数据表明琼北火山喷发活动时限跨越1.3～0.052Ma。在比较了表观年龄与等时线年龄差异之后,本文给出了年龄推荐值。正如测试数据所显示,本地区新生代火山岩普遍存在40Ar和36Ar过剩的问题,此时只有等时线年龄才代表喷发的真实年龄。     

^Ar／^39Ar Dating of Deformation Events and Reconstruction of Exhumation of Ultrahigh—Pressure Metamorphic Rocks in Donghai,East China

Abstract Recent investigations reveal that the ultrahigh‐pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile‐brittle structural events during their exhumation. The earlier ductile deformation took place under the condition of amphibolite facies and the later transitional ductile‐brittle deformation under the condition of greenschist facies. The hanging walls moved southeastward during both of these two events. The ⁴⁰Ar/³⁹Ar dating of muscovites from muscovite‐plagioclase schists in the Haizhou phosphorous mine, which are structurally overlain by UHPM rocks, yields a plateau age of 218.0±2.9 Ma and isochron age of 219.8Ma, indicating that the earlier event of the ampibolite‐facies deformation probably took place about 220 Ma ago. The ⁴⁰Ar/³⁹Ar dating of oriented amphiboles parallel to the movement direction of the hanging wall on a decollement plane yields a plateau age of 213.1 ± 0.3 Ma and isochron age of 213.4±4.1 Ma, probably representing the age of the later event. The dating of pegmatitic biotites and K‐feldspars near the decollement plane from the eastern Fangshan area yield plateau ages of 203.4±0.3 Ma, 203.6±0.4 Ma and 204.8±2.2 Ma, and isochron ages of 204.0±2.0 Ma, 200.6±3.1 Ma and 204.0±5.0 Ma, respectively, implying that the rocks in the studied area had not been cooled down to closing temperature of the dated biotites and K‐feldspars until the beginning of the Jurassic (about 204 Ma). The integration of these data with previous chronological ages on the ultrahigh‐pressure metamorphism lead to a new inference on the exhumation of the UHPM rocks. The UHPM rocks in the area were exhumed at the rate of 3–4 km/Ma from the mantle (about 80–100 km below the earth's surface at about 240 Ma) to the lower crust (at the depth of about 20‐30km at 220 Ma), and at the rate of 1–2 km/Ma to the middle crust (at the depth of about 15 km at 213 Ma), and then at the rate of less than 1 km/Ma to the upper crust about 10 km deep at about 204 Ma.     

内蒙古大青山地区同盛茂晚石炭世火山岩的年代学、地球化学和Hf同位素研究及其地质意义

华北北缘作为古亚洲洋闭合和演化的重要研究地区,一直受到学者们广泛关注。已有研究表明其晚古生代岩浆作用 强烈,但以侵入岩为主,缺乏同期火山岩的报道。文章对华北北缘内蒙古大青山地区同盛茂拴马桩组上部的火山岩进行详 细的LA-ICP-MS锆石U-Pb年代学、地球化学和Hf同位素研究。结果表明,同盛茂火山岩形成于晚石炭世末期（305 Ma）, 火山岩岩性为流纹质弱熔结凝灰岩,岩石发生强的高岭石化,具有相对低的REE总量、弱的Eu负异常以及低的重稀土 （Y、Yb） 含量,样品中原位锆石的εHf(t)值为-8.3~-4.0。综合资料表明,火山岩可能是由华北克拉通加厚的基底经部分熔融 形成,并有幔源物质参与。结合最近报道的区域晚古生代火山岩研究资料,推测华北北缘晚古生代至少发生过两期火山活 动：分别为305~290 Ma和278~261 Ma,且峰期在272 Ma。