Coupling Effects on Gold Mineralization of Deep and Shallow Structures in the Northwestern Jiaodong Peninsula, Eastern China

For understanding the possible deep-seated processes and geodynamic constrains on gold mineralization, comprehensive physicochemical and geochemical studies of gold mineralization have been undertaken within the paleo-lithosphere framework during the metailogenic epoch from the northwestern part of the Jiaodong Peninsula in this paper. A general image of the paleo-crust has been remained although it has been superimposed and reformed by post-metailogenic tectonic movements. The gold ore deposits occur usually in local uplifts and gradient belts featuring a turn from steep to gentle in granite-metamorphic contact zones, relative uplifts of gradient zones of the Curier isothermal interfaces, depressions of the Moho discontinuity and areas where depth contours are cut by isotherms perpendicularly. Gold mineralization and lithogenesis are characterized by high temperature, low pressure and high strength of thermal flux. The depth of mineralization ranges from 0.8 to 4.5 km. The depth of the top interface of the granitic complex in the metallogenic epoch is about 3 km. There is a low-velocity layer （LVL） at the bottom of the upper crust with a depth close to 19.5 km, which may be a detachment belt in the crust. The appearance of the LVL indicates the existence of paleo-hyperthermal fluid or relics of molten magma chambers, which reflects partial melting within the crust during the diagenetic and metallogenic epochs and the superposition effects of strike-slip shearing of the Taulu fault zone. The subsidence of the Moho is probably attributed to the coupling process of the NW-SE continental collision between North China and the Yangtze Block and the strike-slip movement of the Tanlu fault accompanied with underplating of mantle magma in the northwestern part of the Jiaodong Peninsula. The underplating of mantle magma may result in partial melting and make granite magma transfer upwards. This is favorable for the migration of metallogenic materials from deep to shallow to be enriched to form deposits. Coupling interactions between the strike-slip of the Taulu fault, the underplating of mantle magma, partial melting within the crust, and hyperthermal fluid, etc. may be the important factors controlling the gold mineralization and spatial structures in the metailogenic system.     

Emplacement Ages and Geochemical Characteristics of Grabbroic Intrusions and Prospecting Orientation of Related Deposit in Luodian, Guizhou Province

Emplacement ages, geochemical characteristics and analysis of continental dynamics on gabbroic intrusions in Luodian County, Guizhou Province, have been discussed based on studies of isotopic chronology （the whole-rock Sm-Nd and Rb-Sr isochron methods）, major elements, trace elements and PGE. Intrusive activities of the gabbroic intrusions in the study area took place during the Late Yanshanian Orogenic Movement （the Cretaceous Period）, as indicated by the Sm-Nd isochron ages （t）=（99.6±4.5） （2σ） Ma and by the Rb-Sr isochron ages t=（97±1.6） （2σ） Ma. The gabbroic intrusions are attached to mafic rocks in cal-alkaline basaltic series. They occurred as dikes and might be formed under an extensional background of the continent. Differentiation of their magmatic crystallization resulted in obvious zonation of petrography. In the gabbroic intrusions of this study, large ion lithophile elements and LREE are enriched, and the chondrite-normalized REE distribution pattern is leftward inclined without anomalies of JCe or JEu, and there are high concentrations of PGE and ratios of Pd/Ir （averaging 4.21）. All of these imply that their source areas may be basaltic magma in the upper mantle with high-level partial melting, derived from EMl-type enriched mantle. It is different from Emeishan basalt, which may be related to the upper mantle at low-grade partial melting. Emplacement mechanism of the gabbroic intrusions in this study may suppose to be asthenosphere upheaving as an isolated hot wave in the presence of mantle fluid, resulting in basaltic magma intruded into the continental crust as a diapiric intrusion. Therefore, uplifting of faulting-block and extensional deformation could take place in the shallow part of the continental crust while vertical amassing and accretion of magmatic materials in the deep part of the continental crust. These special processes could supposed to be a special background of continental dynamics for this large-scale epithermal metallogenic domain, such as Au     

Carboniferous Bimodal Volcanic Rocks and Their Plate Tectonic Setting,Hainan Island

The Carboniferous volcanic rocks in western Hainan Island consist of a series of oceanic tholeite and rhyoporphyrite,showing bimodal nature.Similar geochemical characters,in terms of abun-daces and relative rations of incompatible elements and REE and the REE patterns,between the basalt and continental rift-associated tholeiite indicate the occurrence of Late Paleozoic rifting in the area.The basaltic magma,with a low degree of evolution,was originated from deep mantle,show-ing contamination by low crustal material.The rhyolite is thought to be formed from partial melting of the continental crust by higher thermal flow in a rift environment rather than from fractional crystallization of a basaltic magma.     

Highly refractory Archaean peridotite cumulates:Petrology and geochemistry of the Seqi Ultramafic Complex,SW Greenland

This paper investigates the petrogenesis of the Seqi Ultramafic Complex, which covers a total area of approximately 0.5 km~2. The ultramafic rocks are hosted by tonalitic orthogneiss of the ca. 3000 Ma Akia terrane with crosscutting granitoid sheets providing an absolute minimum age of 2978 ± 8 Ma for the Seqi Ultramafic Complex. The Seqi rocks represent a broad range of olivine-dominated plutonic rocks with varying modal amounts of chromite, orthopyroxene and amphibole, i.e. various types of dunite(s.s.),peridotite(s.l.), as well as chromitite. The Seqi Ultramafic Complex is characterised primarily by refractory dunite, with highly forsteritic olivine with core compositions having Mg# ranging from about 91 to 93. The overall high modal contents, as well as the specific compositions, of chromite rule out that these rocks represent a fragment of Earth's mantle. The occurrence of stratiform chromitite bands in peridotite, thin chromite layers in dunite and poikilitic orthopyroxene in peridotite instead supports the interpretation that the Seqi Ultramafic Complex represents the remnant of a fragmented layered complex or a magma conduit, which was subsequently broken up and entrained during the formation of the regional continental crust.Integrating all of the characteristics of the Seqi Ultramafic Complex points to formation of these highly refractory peridotites from an extremely magnesian(Mg# ~ 80), near-anhydrous magma, as olivinedominated cumulates with high modal contents of chromite. It is noted that the Seqi cumulates were derived from a mantle source by extreme degrees of partial melting(40%). This mantle source could potentially represent the precursor for the sub-continental lithospheric mantle(SCLM) in this region,which has previously been shown to be ultra-depleted. The Seqi Ultramafic Complex, as well as similar peridotite bodies in the Fiskefjord region, may thus constitute the earliest cumulates that formed during the large-scale melting event(s), which resulted in the ultra-depleted cratonic keel under the North Atlantic Craton. Hence, a better understanding of such Archaean ultramafic complexes may provide constraints on the geodynamic setting of Earth's first continents and the corresponding SCLM.     

A Genetic Model for the Layered Intrusions and Related V—Ti—Magnetite Deposits in Panzhihua—Xichang Region,Southwest China

The area studied had developed into an inactive continental margin on the western edge of the Yangtze plate during the Jinning period in Proterozoic time.The Yangtze plate drifted from the south northwards in Paleozoic time and reached about 9oS between Late Cambrian and Early Ordovician .The alkalic olivine basalt magma,which was produced via 2-5% partial melting of a fractionated mantle and was accumulated in a deep-seated magma chamber near the Moho.found its way upward along the reviving boundary faults into the upper crust.Two types of layered intrusions,basic and ultrabasic-basic,crystallized from the magma at different pressures.The high initial oxygen fugacity of the magma provides a favorable condition for the deposition of Fe-Ti oxides in the early stage of magmaevolution,resulting in large-sized early magmatic deposits.Magma crystallization may have been interrupted and repeated as a result of pulsative magma influx,giving rise to rhythmic cycles (including the corresponding V-Ti-magnetite ore beds).The magma was stratified owing to double diffusion at the crystallization front and convection was thus occasioned by the density gradient.This has greatly complicated the sequence as would be expected from normal crystallization.     

The Petrology, Geochemistry, and Petrogenesis of E-MORB-type Mafic Rocks from the Guomangco Ophiolitic Mélange, Tibet

The Guomangco ophiolitic melange is situated in the middle part of the Shiquanhe- Yongzhu-Jiali ophiolitic melange belt （SYJMB） and possesses all the subunits of a typical Penrose- type ophiolite pseudostratigraphy. The study of the Guomangco ophiolitic melange is very important for investigating the tectonic evolution of the SYJMB. The mafic rocks of this ophiolitic melange mainly include diabases, sillite dikes, and basalts. Geochemical analysis shows that these dikes mostly have E-MORB major and trace element signatures; this is the first time that this has been observed in the SYJMB. The basalts have N-MORB and IAB affinities, and the mineral chemistry of harzburgites shows a composition similar to that of SSZ peridotites, indicating that the Guomangco ophiolitic melange probably originated in a back-arc basin. The Guomangco back-arc basin opened in the Middle Jurassic, which was caused by southward subduction of the Neo-Tethys Ocean in central Tibet. The main spreading of this back-arc basin occurred during the Late Jurassic, and the basalts were formed during this time. With the development of the back-arc basin, the subducted slab gradually retreated, and new mantle convection occurred in the mantle wedge. The recycling may have caused the metasomatized mantle to undergo a high degree of partial melting and to generate E- MORBs in the Early Cretaceous. E-MORB-type dikes probably crystallized from melts produced by about 20%-30% partial melting of a spinel mantle source, which was metasomatized by melts from low-degree partial melting of the subducted slab.     

Differentiation Mechanism and Evolution of High-level Magma Chamber at Xiangshan,China

The calc-alkaline volcanic magmas,which formed the Mesozoic uraniferous volcanic complex of Xiangshan,resulted from partial melting of the mixture of lower crust and enriched mantle with a high mixing proportion in a specific tectonic setting such as active continental margin or ocean-continent collision zone.The preliminary concentrations of Uand Th occur in low-degree par-tial melts.Only small part of these melts was rapidly extracted and erupted and most intruded into the high-level magma chamber(depth:12-13 km) of the compressed upper lithosphere ,in which occurred a strong differentiation which would resulted in strong preconcentrations of the high-hygromagmaphile elements U and Th associated with strong depletion of the 3-d transition ele-ments Ti,Sc,Co,Zr,etc.At the final stage of subduction of the West-Pacific-Kula plate towards the Asian continental plate,the regional tectonic environment was transformed from a compressive in-to a tensional setting.The strongly differentiated,U(and Th) enriched silicic alkalic magmas in high level magma chamber extensively erupted,extruded and intruded.The hydrothermal fluids released as a result of late volcano-degassing and dewatering during crystallization-solidification of magmas,re-sulted in the remobilization,leaching,migration and reconcentration of uranium ,which had been preconcentrated in volcanic rocks.Therefore,specific regional petrogeochemical criteria are expected for the uraniferous volcanic series.     

Crust-Mantle Interaction in Dabie Orogenic Belt, Central China： Geochemical Evidence from Late Cretaceous Basalts

It has been suggested that eclogites in the Dabie orogenic belt are exhumation prod-ucts, which had subducted into the deep-seated mantle and undergone ultra-high pressure meta-morphism during the Triassic. But no direct evidence supports this process except the calculated p-T conditions from mineral thermobarometem. The Late Cretaceous basalts studied in the pres-ent paper, however, have provided some geochemical evidence for crust-mantle interaction in the area. These basalts are distributed in Mesozoic faulted basins in central and southern Dabieorogenic belt. Since little obvious contamination from continental crust and differentiation-crys-tallization were observed, it is suggested, based on a study of trace elements, that the basaltsare alkaline and resultant from batch partial melting of the regional mantle rocks, and share thesame or similar geochemical features with respect to their magma source. In the spider diagram normalized by the primitive mantle, trace element geochemistry data show that their mantle sources are enriched in certain elements concentrated in the continental crust, such as Pb, K,Rb and Ba, and slightly depleted in some HFSE such as Hf, P and Nb. Pb-Sr-Nd isotopic com-positions further suggest the mantle is the mixture of depleted mantle (DM) and enriched one(EMI EMII). This interaction can .explain the trace element characteristics of basaltic mag-mas, i.e.,the enrichment of Pb and the depletion of Hf, P and Nb in basalts can be interpre-ted by the blending of the eclogites in DOB (enriched in Pb and depleted in Hf, P and Nd)with the East China depleted mantle (As compared to the primitive mantle, it is neither en-riched in Pb nor depleted in Hf, P and Nb). It is also indicated that the eclogites in the Dahieorogenic belt were surely derived from the exhumation materials, which had delaminated into thedeep-seated mantle. Moreover, the process subsequently resulted in compositional variation of the mantle (especially in trace elements and isotopes) , as revealed by the late mantle-derivedbasalts in the Dabie orogenic belt.     

GEOCHEMICAL CHARACTERISTICS OF PLATINUM GROUP ELEMENTS IN JINCHUAN SUPER-LARGE SULFIDE COPPER-NICKEL DEPOSIT, JINCHANG CITY, GANSU PROVINCE, CHINA

The platinum-group element geochemistry of rocks and ores from Jinchuan super-large copper-nickel sulfide deposit is systemically studied in this paper. The Cu/Pd mean ratio of Jinchuan intrusion is lower than that of original mantle magma, which indicates that these ultrabasic rocks were crystallized from magma that lost Pd in the form of melting segregation of sulfides. The PGE of the rocks show trend of partial melting, similar to that of mantle peridotite, which shows that magma formation occurs during rock-forming and ore-forming processes. The chondrite normalized PGE patterns of the rocks and ores are well related to each other, which signifies the signatures of multi-episode magmatic intrusion, melting and differentiation in the formation processes of rocks and ores. In addition, analyses about the relation between PGE and S, and study on Re-Os isotopes indicate that few contamination of the crustal substances occurred during the magmatic intrusion and the formation of deposit. However, contamination by crustal substances helps to supply part of the S for the enrichment of PGE. Meanwhile, the hydrothermal process is also advantageous for the enrichment of PGE, especially lbr Pt and Pd, due to deep melting segregation. The characteristic parameters （such as Pt/（Pt＋Pd）, （Pt＋Pd）/（Ru＋Ir＋Os）, Pd/Ir, Cu/（Ni＋Cu）, and so on.） for platinum-group elements for Jinchuan sulfide copper-nickel deposit show the same features as those for sulfide copper-nickel deposit related to basic magma, which also illustrates its original magma property representative of Mg-high tholeiite. Therefore, it is the marie （not ultramafic） magma that resulted in the formation of the superlarge sulfide copper-nickel deposit enriched in Cu and PGE. To sum up, the geochemical characteristics of platinum-group elements in rocks and ores from Jinchuan copper-nickel sulfide deposit are constrained by the continental rift tectonic environment, the parent magma features, the enriched mantel magma source, the complex metallogenesis and PGE geochemical signatures, and this would be rather significant for the study about the genetic mechanism of copper-nickel sulfide deposits.     

The latest geodynamics in Asia: Synthesis of data on volcanic evolution,lithosphere motion,and mantle velocities in the Baikal-Mongolian region

From a synthesis of data on volcanic evolution,movement of the lithosphere,and mantle velocities in the Baikal-Mongolian region,we propose a comprehensive model for deep dynamics of Asia that assumes an important role of the Gobi,Baikal,and North Transbaikal transition-layer melting anomalies.This layer was distorted by lower-mantle fluxes at the beginning of the latest geodynamic stage(i.e.in the early late Cretaceous) due to avalanches of slab material that were stagnated beneath the closed fragments of the Solonker,Ural-Mongolian paleoceans and Mongol-Okhotsk Gulf of Paleo-Pacific.At the latest geodynamic stage,Asia was involved in east-southeast movement,and the Pacific plate moved in the opposite direction with subduction under Asia.The weakened upper mantle region of the Gobi melting anomaly provided a counterflow connected with rollback in the Japan Sea area.These dynamics resulted in the formation of the Honshu-Korea flexure of the Pacific slab.A similar weakened upper mantle region of the North Transbaikal melting anomaly was associated with the formation of the Hokkaido-Amur flexure of the Pacific slab,formed due to progressive pull-down of the slab material into the transition layer in the direction of the Pacific plate and Asia convergence.The early—middle Miocene structural reorganization of the mantle processes in Asia resulted in the development of upper mantle low-velocity domains associated with the development of rifts and orogens.We propose that extension at the Baikal Rift was caused by deviator flowing mantle material,initiated under the moving lithosphere in the Baikal melting anomaly.Contraction at the Hangay orogen was created by facilitation of the tectonic stress transfer from the Indo-Asian interaction zone due to the low-viscosity mantle in the Gobi melting anomaly.     

On the cratonization of the Arabian-Nubian Shield:Constraints from gneissic granitoids in south Eastern Desert,Egypt

The Shaitian granite complex(SGC) spans more than 80 Ma of crustal growth in the Arabian–Nubian Shield in southeast Egypt.It is a voluminous composite intrusion(60 km~2) comprising a host tonalite massif intruded by subordinate dyke-like masses of trondhjemite,granodiorite and monzogranite.The host tonalite,in turn,encloses several,fine-grained amphibolite enclaves.U-Pb zircon dating indicates a wide range of crystallization ages within the SGC(800 ± 18 Ma for tonalites;754 ± 3.9 Ma for trondhjemite;738 ± 3.8 Ma for granodiorite;and 717 ± 3.2 Ma for monzogranite),suggesting crystallization of independent magma pulses.The high positiveεNdi(+6–+8) indicate that the melting sources were dominated by juvenile material without any significant input from older crust.Application of zircon saturation geothermometry indicates increasing temperatures during the generation of melts from 745 ± 31 ℃ for tonalite to 810 ± 25 ℃ for trondhjemite;840 ± 10 ℃ for granodiorite;and 868 ± 10 ℃ for monzogranite.The pressure of partial melting is loosely constrained to be below the stability of residual garnet(10 kbar) as inferred from the almost flat HREE pattern((Gd/Lu)N= 0.9–1.1),but 3 kbar for the stability of residual amphibole as inferred from the significantly lower NbNand TaNcompared with LREENand the sub-chondrite Nb/Ta ratios exhibited by the granitic phases.The inverse relation between the generation temperatures and the ages estimates of the granitoid lithologies argue against a significant role of fractional crystallization.The major and trace element contents indicate the emplacement of the SGC within a subduction zone setting.It lacks distinctive features for melt derived from a subducted slab(e.g.high Sr/Y and high(La/Yb)Nratios),and the relatively low MgO and Ni contents in all granite phases within the SGC suggest melting within the lower crust of an island arc overlying a mantle wedge.Comparison with melts produced during melting experiments indicates an amphibolite of basaltic composition is the best candidate as source for the tonalite,trondhjemite and granodiorite magmas whereas the monzogranite magma is most consistent with fusion of a tonalite protolith.Given the overlapping Sm-Nd isotope ratios as well as several trace element ratios between monzogranite and tonalite samples,it is reasonable to suggest that the renewed basaltic underplating may have caused partial melting of tonalite and the emplacement of monzogranite melt within the SGC.The emplacement of potassic granite(monzogranite) melts subsequent to the emplacement of Na-rich granites(tonalitetrondhjemite-granodiorite) most likely suggests major crustal thickening prior arc collision and amalgamation into the over thickened proto-crust of the Arabian-Nubian shield.Eventually,after complete consolidation,the whole SGC was subjected to regional deformation,most probably during accretion to the Saharan Metacraton(arc–continent collisions) in the late Cryogenian-Ediacaran times(650–542 Ma).     

http://www.sciencedirect.com/science/article/pii/S1674987113000881

Granitod batholiths of I-type features(mostly granodiorites and tonalites),and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts,represent the most outstanding magmatic episodes occurred in the continental crust.The origin of magmas,however,remains controversial.The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation.An adequate comparison between rock compositions and experimental liquids has been addressed by using a projected compositional space in the plane F(Fe t Mg)eAnorthiteeOrthoclase.Many calc-alkaline granitoid trends can be considered cotectic liquids.Assimilation of country rocks and other not-cotectic processes are identifed in the projected diagram.The identifcation of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation(or partial melting)from an intermediate(andesitic)source.The comparison of batholiths with lower crust granulites,in terms of major-element geochemistry,yields that both represent liquids and solid residues respectively from a common andesitic system.This is compatible with magmas being formed by melting,and eventual reaction with the peridotite mantle,of subducted mélanges that are fnally relaminated as magmas to the lower crust.Thus,the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implications can be satisfactorily explained.Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.     

Granitic Magmatism in Eastern Tethys Domain (Western China) and their Geodynamic Implications

Western China locates in the eastern section of the Tethys domain, granitic rocks in this region with variable formation ages and geochemistry record key information about the crust-mantle structure and thermal evolution during the convergent process of Tethys. In this study, we focus on some crucial granitic magmatism in the western Yangtze, Qinling orogen, and western Sanjiang tectonic belt, where magma sequence in the convergent orogenic belt can provide important information about the crust-mantle structure, thermal condition and melting regime that related to the evolution processes from Pre- to Neo-Tethys. At first, we show some features of Pre-Tethyan magmatism, such as Neoproterozoic magmatism (ca. 870–740 Ma) in the western margin of the Yangtze Block were induced by the assembly and breakup of the Rodinia supercontinent. The complication of voluminous Neoproterozoic igneous rocks indicated that the western Yangtze Block underwent the thermodynamic evolution from hot mantle-cold crust stage (ca. 870–850 Ma) to hot mantle and crust stage (ca. 850–740 Ma). The Neoproterozoic mantle sources beneath the western Yangtze Block were progressively metasomatized by subduction-related compositions from slab fluids (initial at ca. 870 Ma), sediment melts (initial at ca. 850 Ma), to oceanic slab melts (initial at ca. 825–820 Ma) during the persistent subduction process. Secondly, the early Paleozoic magmatism can be well related to three distinctive stages (variable interaction of mantle-crust to crustal melting to variable sources) from an Andeans-type continental margin to collision to extension in response to the evolution of Proto-Tethys and final assembly of Gondwana continent. Thirdly, the Paleo-Tethys magmatism, Triassic granites in the Qinling orogenic display identical formation ages and Lu-Hf isotopic compositions with the related mafic enclaves, indicate a coeval melting event of lower continental crust and mantle lithosphere in the Triassic convergent process and a continued hot mantle and crust thermal condition through the interaction of subducted continental crust and upwelling asthenosphere. Finally, the Meso- and Neo-Tethyan magmatism: Early Cretaceous magmatism in the Tengchong Block are well responding to the subduction and closure of Bangong-Nujiang Meso-Tethys, recycled sediments metasomatized mantle by subduction since 130 Ma and subsequently upwelling asthenosphere since ca. 122 Ma that causes melting of heterogeneous continental crust until the final convergence, this process well recorded the changing thermal condition from hot mantle-cold crust to hot mantle and crust; The Late Cretaceous to Early Cenozoic magmatism well recorded the processes from Neo-Tethyan ocean slab flat subduction, steep subduction, to initial collision of India-Asia, it resulted in a series of continental arc magmatism with enriched mantle to crustal materials at Late Cretaceous, increasing depleted and/or juvenile materials at the beginning of early Cenozoic, and increasing evolved crustal materials in the final stage, implying a continued hot mantle and crust condition during that time. Then we can better understand the magmatic processes and variable melting from the mantle to crust during the evolution of Tethys, from Pre-, Paleo-, Meso-, to Neo-, both they show notably intensive interaction of crust-mantle and extensive melting of the heterogeneous continent during the final closure of Tethys and convergence of blocks, and thermal perturbation by a dynamic process in the depth could be the first mechanism to control the thermal condition of mantle and crust and associated composition of magmatism.     

Geochemistry, Nd Isotopic Characteristics of Metamorphic Complexes in Northern Hebei： Implications for Crustal Accretion

The middle segment of the northern margin of the North China Craton （NCC） consists mainly of metamorphosed Archean Dantazi Complex, Paleoproterozoic Hongqiyingzi Complex and unmetamorphosed gabbro-anorthosite-meta-alkaline granite, as well as metamorphosed Late Paleozoic mafic to granitoid rocks in the Damiao-Changshaoying area. The -2.49 Ga Dantazi Complex comprises dioritic-trondhjemitic-granodoritic-monzogranitic gneisses metamorphosed in amphibolite to granulite facies. Petrochemical characteristics reveal that most of the rocks belong to a medium- to high-potassium calc-alkaline series, and display Mg^# less than 40, right-declined REE patterns with no to obviously positive Eu anomalies, evidently negative Th, Nb, Ta and Ti anomalies in primitive mantlenormalized spider diagrams, εNd（t）=＋0.65 to -0.03, and depleted mantle model ages TDM=2.78-2.71 Ga. Study in petrogenesis indicates that the rocks were formed from magmatic mixing between mafic magma from the depleted mantle and granitoid magma from partial melting of recycled crustal mafic rocks in a continental margin setting. The 2.44-2.41 Ga Hongqiyingzi Complex is dominated by metamorphic mafic-granodioritic-monzogranitic gneisses, displaying similar petrochemical features to the Dantazi Complex, namely medium to high potassium calc-alkaline series, and the mafic rocks show evident change in LILEs, negative Th, Nb, Ta, Zr anomalies and positive P anomalies. And the other granitiod samples also exhibit negative Th, Nb, Ta, P and Ti anomalies. All rocks in the Hongqiyingzi Complex show right-declined REE patterns without Eu anomaly. The metamorphic mafic rocks with εNd（t） = -1.64 may not be an identical magmatic evolution series with granitoids that have εNd（t） values of ＋3.19 to ＋1.94 and TDM ages of 2.55-2.52 Ga. These granitic rocks originated from hybrid between mafic magma from the depleted mantle and magma from partial melting of juvenile crustal mafic rocks in an island arc setting. All the -311 Ma Late Paleozoic metamorphic mafic rocks and related granitic rocks show a medium-potassium calc-alkaline magmatic evolution series, characterized by high Mg^#, obviously negative Th, Nb, Ta anomalies and positive Sr anomalies, from no to strongly negative Ti anomalies and flat REE patterns with εNd（t） = ＋8.42, implying that the maflc magma was derived from the depleted mantle. However the other granitic rocks are characterized by right-declined REE patterns with no to evidently positive Eu anomalies, significantly low εNd（t） = -13.37 to -14.04, and TDM=1.97-1.96 Ga, revealing that the granitoid magma was derived from hybrid between maflc magma that came from -311 Ma depleted mantle and granitoid magma from Archean to Early Paleoproterozoic ancient crustal recycling. The geochemistry and Nd isotopic characteristics as well as the above geological and geochronological results indicate that the middle segment of the northern margin of the NCC mainly experienced four crustal growth episodes from Archean to Late Paleozoic, which were dominated by three continental marginal arc accretions （-2.49, -2.44 and 311 Ma）, except the 1.76-1.68 Ga episode related to post-collisional extension, revealing that the crustal accretion of this segment was chiefly generated from arc accretion and amalgamation to the NCC continental block.     

Platinum-Group Element Geochemical Characteristics of the Picrites and High-Ti Basalts in the Binchuan Area,Yunnan Province

The Binchuan area of Yunnan is located in the western part of the Emeishan large igneous province in the western margin of the Yangtze Block.In the present study,the Wuguiqing profile in thickness of about 1440 m is mainly composed of high-Ti basalts,with minor picrites in the lower part and andesites,trachytes,and rhyolites in the upper part.The picrites have relatively higher platinum-group element（PGE） contents（ΣPGE=16.3-28.2 ppb）,with high Cu/Zr and Pd/Zr ratios,and low S contents（5.03-16.9 ppm）,indicating the parental magma is S-unsaturated and generated by high degree of partial melting of the Emeishan large igneous province（ELIP） mantle source.The slightly high Cu/Pd ratios（11 000-24 000） relative to that of the primitive mantle suggest that 0.007%sulfides have been retained in the mantle source.The PGE contents of the high-Ti basalts exhibit a wider range（ΣPGE=0.517-30.8 ppb）.The samples in the middle and upper parts are depleted in PGE and haveε_Nd（260 Ma） ratios ranging from -2.8 to -2.2,suggesting that crustal contamination of the parental magma during ascent triggered sulfur saturation and segregation of about 0.446%-0.554% sulfides,and the sulfide segregation process may also provide the ore-forming material for the magmatic Cu-Ni-PGE sulfide deposits close to the studied basalts.The samples in this area show Pt-Pd type primitive mantle-normalized PGE patterns,and the Pd/Ir ratios are higher than that of the primitive mantle（Pd/Ir=1）,indicating that the obvious differentiation between Ir-group platinum-group elements（IPGE） and Pd-group platinum-group elements（PPGE） are mainly controlled by olivine or chromites fractionation during magma evolution.The Pd/Pt ratios of most samples are higher than the average ratio of mantle（Pd/Pt=0.55）,showing that the differentiation happened between Pt and Pd.The differentiation in picrites may be relevant to Pt hosted in discrete refractory Pt-alloy phase in the mantle;whereas the differentiation in the high-Ti basalts is probably associated with the fractionation of Fe-Pt alloys,coprecipitating with Ir-Ru-Os alloys.Some high-Ti basalt samples exhibit negative Ru anomalies,possibly due to removal of laurite collected by the early crystallized chromites.     

A Study of Sr, Nd and O Isotopes of the K-rich Melanocratic Dykes in the Late Mesozoic Gold Field in the Jiaodong Peninsula

Geologic, petrographic and petrochemical studies of the late Mesozoic K-rich melanocratic dykes, including lamprophyres, andesite porphyrites and dacite-porphyry in the gold field system in the Jiaodong Peninsula, China, have shown that these dykes are characterized by rich potassium and alkali but poor titanium. They belong to an ultra-high potassic, shoshonitic and high potassic calc-alkaline rock series. The parental magma has relatively high initial strontium ratios ((87Sr/86Sr)i=0.70895-0.71140) and low (143Nd/144Nd)i ratios (varying from 0.51135 to 0.51231); and its δ18OSMow. whole rock values vary from +5.8‰ to +10.6‰ with a mean of+7.1‰. These features suggest that the source region of the magma is an enriched mantle wedge transformed from a continental lithosphere mantle which has experienced metasomatism by mantle-derived fluids with H2O-dominated fluids that were provided during the underthrusting of an ocean crust. The initial magma was generated by low-degree partial melting of the enri     

CO_2 degassing and melting of metasomatized mantle lithosphere during rifting-Numerical study

:Reactivation of metasomatized mantle lithosphere may occur during continental extension,which is an important component of plate tectonics.The lower most part of the metasomatized domains in the subcontinental mantle lithosphere can be locally enriched in CO2.Therefore,partial melting of these metasomatized domains may play a crucial role in the global carbon cycle.However,little is known about this process and up until now few numerical constraints are available.Here we address this knowledge gap and use a 2-D high resolution petrological-thermomechanical model to assess lithospheric rifting.CO2 degassing and melting.We test 4 lithospheric thicknesses:90,110,130 and 200 km with a 10 km thick metasomatized layer at the base using CO2 of 2 wt.%in the bulk composition.The carbonate enriched layer is stable below^3 GPa(>110 km)for a temperature of 1300℃;therefore,we only observe degassing patterns for lithospheric models that are 130 km and 200 km thick.The metasomatized layer for the 130 km thick lithosphere mostly comprises carbonatite melting,whereas in the 200 km thick scenario propagation of melt development from kimberlites to carbonatites occurs as the metasomatic mantle is exhumed during extension.The numerical models fit well into natural rifting zones of the European Cenozoic Rift System for young(shallow)and of the North Atlantic Rift for old(thick)lithosphere.     

Permian Tectonic Evolution in Southwestern Khanka Massif: Evidence from Zircon U‐Pb Chronology,Hf isotope and Geochemistry of Gabbro and Diorite

Laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U-Pb dating and geochemical data for the Permian gabbros and diorites in the Hunchun area are presented to constrain the regional tectonic evolution in the study area. Zircons from gabbro and diorite are euhedral-subhedral in shape and display fine-scale oscillatory zoning as well as high Th/U ratios (0.26–1.22), implying their magmatic origin. The dating results indicate that the gabbro and diorite formed in the Early Permian (282±2 Ma) and in the Late Permian (255±3 Ma), respectively. In addition, the captured zircons with the weighted mean age of 279±4 Ma are also found in the diorite, consistent with the formation age of the gabbro within uncertainty. The gabbros belong chemically to low-K tholeiitic series, and are characterized by low rare earth element (REE) abundances, flat REE pattern, weak positive Eu anomalies (δEu), and depletion in high field strength elements (HFSEs, Nb, Ta, and Ti), similar to the high-aluminum basalts from island arc setting. Initial Hf isotopic ratios of zircons from the gabbro range from +7.63 to +14.6, suggesting that its primary magma could be mainly derived from partial melting of a depleted lithospheric mantle. The diorites belong to middle K calc-alkaline series. Compared with the gabbros, the diorites have higher REE abundance, weak negative Eu anomalies, and more depletion in HFSEs (Nb, Ta, and Ti), similar chemically to the volcanic rocks from an active continental margin setting. Initial Hf isotopic ratios and Hf two-stage model ages of zircons from the diorite range from +11.22 to +14.17 and from 424 to 692 Ma, respectively, suggesting that its primary magma could be mainly derived from partial melting of the Early Paleozoic and/or Neoproterozoic accretted lower crust. Taken together, it is suggested that geochemical variations from the Early Permian gabbros to the Late Permian diorites reveal that the subduction of the Paleo-Asian oceanic plate beneath the Khanka Massif and collision between the arc and continent (Khanka Massif) happened in the late stage of the Late Paleozoic.     

Petrogenesis of Two Types of Archean TTGs in the North China Craton: A Case Study of Intercalated TTGs in Lushan and Non-intercalated TTGs in Hengshan

TTG(Tonalite-Trondhjemite-Granodiorite) gneisses,a major component of Precambrian continental crust,play a significant role in understanding the process and mechanism of the crustal evolution in the early periods of the Earth. In terms of field occurrence,there are two kinds of Archean TTGs in the NCC(North China Craton): intercalated and non-intercalated TTGs. In this contribution,we make a comprehensive comparison of these two types of TTGs from the typical areas(Lushan and Hengshan) in the NCC with an aim to constrain their petrogenesis. The results suggest that they have similar mineral assemblages of Pl + Qtz + Bt ± Amp ± Kfs but different field appearances and geochemical compositions,thus probably reflecting different source materials and tectonic settings. Differences in the contents of characteristic elements,such as Sr,REE and HFSE,suggest that the nonintercalated TTGs in Hengshan were generated at deeper levels than those of intercalated TTGs in Lushan. Constraints from element contents and geochemical modeling results are consistent with derivation from dual sources involving both garnet amphibolite and rutile-bearing eclogite residues for the non-intercalated TTGs in Hengshan,whereas the compositions of intercalated TTGs in Lushan indicate that they were formed by partial melting with amphibolite to garnet-amphibolite residues. Moreover,accumulation of plagioclase is also required in the petrogenesis of intercalated TTGs in Lushan,at least for part of them. In addition,the non-intercalated TTGs in Hengshan display distinctly higher Mg O,Mg#,Cr and Ni values and lower SiO_2 average contents compared to the intercalated TTGs in Lushan. These features suggest that the former magma,at least a part,might have interacted with the mantle wedge during ascent. Considering all the above factors and in combination with the whole-rock Nd and zircon Hf isotopic data,it is suggested that the non-intercalated TTGs in Hengshan were produced by partial melting of subducted slab contaminated by the overlying mantle wedge at deeper levels and high pressures,whereas the intercalated TTGs in Lushan were generated by melting of the thickened lower crust at lower pressures and shallower depths. The tectonic settings of the two types of TTGs shed new light on the growth of the NCC.     

Petrogenesis of the Paleoproterozoic Guandishan Granitoids in Shanxi Province： Constraints from Geochemistry and Nd Isotopes

The Guandishan granitoids consist mainly of various granitoid intrusions with different scales, including the Huijiazhuang intrusion, Shizhuang intrusion and Hengjian intrusion, which were formed between 1906 Ma and 1848 Ma. On the basis of geological and petrological characteristics, these granitoids can be classified into two groups： the earlier gneissic granodiorites and monzogranites, and the later massive leuco-monzogranites. Their geochemical and Nd isotopic features indicate that they could be derived from complicated partial melting of supracrustal rocks with an affinity of continental arc materials, such as sandy shale and pelite, and with garnet, pyroxene, hornblende and plagioclase as residual phases. Biotite, feldspar and other minerals were most likely fractionated during the magma evolution. Their source may have an affinity with continental arcs, and the granitoids could be derived from the main syn-collisional to late-orogenic tectonic environment, which may be related to the final amalgamation between the Eastern and Western continental blocks in the North China Craton.