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1.
探讨黔西北普宜地区富关键金属元素硫铁矿的同位素地球化学特征、元素地球化学特征及成因, 可以为硫铁矿资源开发、伴生有益元素综合利用与评价及理解富关键金属元素硫铁矿聚集机制提供更为丰富的信息。在全面收集已有地质、矿产资料的基础上, 结合野外实地调查, 应用元素地球化学及硫同位素分析等方法, 对该区硫铁矿地球化学特征及成因做了较为深入研究, 并初步建立成矿模式。结果表明: 富关键金属元素硫铁矿主要赋存于中二叠统龙潭组(P2l)底部的晶屑凝灰岩中, 矿体形态简单, 呈层状分布, 硫铁矿中共(伴)生的稀土, Li, Nb, Zr, Ga等有益元素均可综合利用。w(ΣREE)平均为431.24×10-6, 最大值为1 634.57×10-6, 一般在180×10-6~1 630×10-6之间; w(Ga)平均为32.51×10-6, 一般为25×10-6~120×10-6, 最大为120.00×10-6; w(Nd)平均为103.29×10-6, 一般为40×10-6~380×10-6, 最大为380.00×10-6; w(Li)最大值为1 366.00×10-6; w(Al2O3)最大值为42.17%。硫铁矿稀土元素配分模式表现为轻稀土元素富集、重稀土元素相对亏损的右倾型。矿石中成矿元素Ga, Li, Zr, Ti, Se, Cd, Nb, V, Hg等元素相对富集, Ba, Sr, Zn, Te等元素相对贫化。硫铁矿石中黄铁矿硫同位素δ34S变化范围主要在-33.90‰~-18.60‰之间, 平均值-16.04‰, 为轻硫富集型, 富关键金属元素硫铁矿的硫源受生物细菌还原作用影响较大。硫铁矿主要是在沉积阶段通过微生物铁还原、微生物硫酸盐还原和化学铁还原驱动下形成的。初步认为赋存于硫铁矿中的稀土主要以类质同象替代形式赋存于黏土矿物中, 形成过程可分为风化搬运阶段、沉积成矿阶段和成岩后生作用阶段。   相似文献   

2.
对柯坪地区克孜尔塔格组岩石地球化学特征的分析表明,其稳定元素(Al2O3,Fe2O3,MnO)明显多于不稳定元素(MgO,K2O,Na2O),显示岩石经过了较远的搬运。轻稀土元素相对富集,重稀土元素亏损,具明显的Eu异常。主量、微量元素综合分析表明,其构造背景为被动大陆边缘,其物源主要来自成熟的大陆石英质物源区,少量来自花岗岩源区。碎屑锆石的U Pb年龄明显存在4个区间:550~400,1 050~750,1 800~1 550,2 550~2 400 Ma,反映了塔里木地区的4次构造热事件。基于地球化学特征及碎屑锆石测年结果的分析表明,克孜尔塔格组主要物源区为塔北隆起的前寒武纪基底和早古生代岩浆岩。   相似文献   

3.
琼中黎母山-湾岭地区位于海南岛中部,调查发现该地区土壤同时具有富硒、富碘的特征。以研究区表层(0~20 cm)、中层(80~100 cm)、深层(180~200 cm)土壤样品分析结果为基础,探讨了土壤硒、碘的分布特征及其影响因素。结果显示,表层土壤中Se、I质量分数具有高正相关性,并与高程为正相关关系,结合已有研究成果,推断在研究区范围内降雨作用是研究区表层土壤Se、I质量分数空间分布格局的关键影响因素。通过分析表层、中层、深层土壤Se、I质量分数与土壤pH值、总有机碳(TOC)、Al2O3、Fe2O3质量分数的相关关系和变化规律,总结了研究区Se、I在土壤垂向剖面上的赋存、迁移规律。这些结果可为当地优质土地资源的高效利用提供科学依据,也可为土壤Se来源、迁移研究提供新的证据。   相似文献   

4.
肖打松多花岗闪长岩位于西藏冈底斯花岗岩带中段以南,主要岩石类型有:细中粒黑云母(角闪石)花岗闪长岩、细中粒
含斑黑云母(角闪石)花岗闪长岩、细中粒斑状黑云母(角闪石)花岗闪长岩,岩石具钙碱性特征,w(SiO2)=61.58%~72.16%,
w(K2O)/w(Na2O)=0.64~1.15,相对富钠,A/CNK=1.25~1.43,w(Al2O3)变化于11.45%~16.00%之间,为准铝质岩石,花
岗闪长岩岩体稀土元素总量w(ΣREE)变化于152.10×10-6~251.22×10-6之间;轻稀土元素富集,负Eu异常较明显,以富K、
Rb、Ba、Th等大离子亲石元素和亏损Nb、Y、Yb等高场强元素为特征。岩石学和岩石地球化学研究表明,该时期的花岗闪长岩具
俯冲I型花岗岩的特点,形成于板块俯冲下的岛弧环境。用SHRIMP测定肖打松多花岗闪长岩体锆石的U-Pb年龄为(191.9±
1.1)Ma。同时表明冈底斯岩浆弧带在早侏罗世岩浆曾经剧烈地活动过,肖打松多岩体是新特提斯洋向北俯冲作用的产物。   相似文献   

5.
黔西位于扬子板块西南缘,有关扬子板块内约2.5 Ga的岩浆事件记录极少。最近,对黔西赫章发现的石英二长闪长岩的研究表明,其成岩年龄为(2 542±9)Ma,为该区首次发现的新太古代晚期岩石。该岩石主要由斜长石、碱性长石、石英、角闪石、黑云母等矿物组成,具有较高的SiO2(59.2%~60.6%)、Na2O(4.70%~4.85%)质量分数和Na2O/K2O(3.02%~3.19%)比值,以及较低的Al2O3(17.0%~17.7%)、MgO(2.42%~2.61%)质量分数。样品稀土元素总质量分数为120×10-6~221×10-6,(La/Yb)N=8.32~17.98,轻、重稀土元素分异不明显,表现为弱的右倾稀土元素配分模式,并具有弱的Eu负异常。在微量元素蛛网图上,样品富集大离子亲石元素(Ba、Sr)、亏损高场强元素(Nb、Ta、Ti),具有弱负到正的εHf(t)值(-0.51~+6.93)和正的εNd(t)值(+0.22~+0.88),与太古宙低铝型高重稀土元素TTG的地球化学性质基本一致。综合研究显示,该岩石可能是在角闪岩相下,下地壳基性岩部分熔融形成的,源区残留相主要为金红石以及斜长石。黔西约2.5 Ga岩石的发现证实了扬子板块西南缘具有新太古代基底的存在,这为扬子周缘新太古代岩浆成因的碎屑锆石研究提供了依据,为扬子板块新太古代地壳演化提供了新的信息。   相似文献   

6.
磁海辉绿岩型铁矿位于塔里木北缘北山裂谷带,主要岩石类型为辉绿岩,岩石具有较高的Mg# (55.7~70.1)、中铝
Al2O3(13.75~14.65)特征,Na2O/K2O(1.79~14.04)变化较大,整体属于钙碱性系列(K2O/Na2O=0.07~0.56,FeO/MgO=
0.77~1.46)。稀土元素方面,磁海辉绿岩具有较高的稀土元素质量分数和δEu异常特征[w(ΣREE)=88.01×10-6~213.07×
10-6,δEu=0.63~1.44],球粒陨石标准化稀土元素配分模式为缓右倾型[(La/Yb)N=1.32~3.87,(La/Sm)N=1.05~2.17,
(Gd/Yb)N=1.12~1.58],微量元素上选择性富集大离子亲石元素(Rb、K),亏损高场强元素(Nb、Ta)。岩浆演化过程中斜长石
和单斜辉石的分离结晶作用是岩浆演化的主要机制,同时伴有较为明显的地壳混染作用。LA-ICP-MS锆石U-Pb年代学指示该
辉绿岩形成于约291.9Ma,构造环境分析表明磁海辉绿岩为板内拉张环境的产物。   相似文献   

7.
对北秦岭宝鸡地区鸡冠崖花岗岩进行了LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果显示,锆石206Pb/238Pb加权平均年龄为(435±2)Ma(MSWD=0.13,n=22),限定该岩体的形成时代为早志留世。鸡冠崖花岗岩具有高硅(w(SiO2)=72.77%~77.71%)、富钾(w(K2O)=3.51%~6.32%)、低铁(w(Fe2OT3)= 0.71%~1.30%,Fe2OT3/MgO=2.71~7.29)、低镁(w(MgO)=0.14%~0.31%)、低磷(w(P2O5)= 0.05%~0.10%)的特征,A/CNK=0.94~1.10,AR=2.95~4.10,属准铝质至弱过铝质、钙碱性系列。鸡冠崖花岗岩稀土元素质量分数较低(32×10-6~102×10-6),铕异常明显(δEu=0.22~13.83),富集Rb、U、Th、Nd、Zr、Hf等微量元素,贫Ba、Nb、P、Ti等元素,分异程度较高(DI=89~93),整体表现出高分异I型花岗岩特征。结合区域资料,认为鸡冠崖花岗岩形成于同碰撞构造环境,为下地壳物质部分熔融成因。   相似文献   

8.
青州市马家庄地区黏土矿主要赋存于第四纪中-上更新统大站组及全新统临沂组,赋矿层系分布面积较广,整体自南向北微有倾斜,呈等轴状展布,其厚度与古地形密切相关,古地形凹陷处矿体厚度较大,隆起区则较小,平均厚度12.61m,厚度变化系数27.79%。经差热分析可知,黏土矿石主要由蒙脱石+水云母+石英组成。属于陆相残—坡积混合型矿床,下部以残积相为主,中上部则以坡积相为主。全区矿石平均品位SiO2 67.61%,Fe2O3 5.35%,Al2O3 14.79%,硅酸率平均值n=3.37,铝酸率平均值p=2.77,可以作为水泥用黏土质原料开采。针对该区域内黏土矿,前人做了较多的勘探性工作,积累了丰富的原始地质资料,本文分析了区内黏土矿的赋矿层位及其空间变化特征,探讨其矿床成因、成矿地质特征,以期为今后该地区黏土找矿工作提供参考。  相似文献   

9.
新疆北塔山地区作为中亚造山带的重要组成部分,由于其独特的地理位置,故可以作为研究准噶尔地区构造演化的理想场所。北塔山地区晚石炭世侵入岩类型复杂,早期岩体多为闪长岩类,后期岩体以花岗岩为主,是原始岩浆不同时期演化形成的一套岩石序列,且岩浆具有明显壳幔混合源的特征。在地球化学特征上,里特曼指数σ<3.3、A/CNK<1.1、w(P2O5)<0.65%、Fe2O3/FeO>0.4,岩石相对富集LILE和亏损HFSE,均表现典型Ⅰ型花岗岩类的特征。然而进一步研究显示,晚期侵入体富硅富碱,高钾、低钙铁镁含量的特点指示其为碱性花岗岩的性质,表明北塔山地区在晚石炭世末期经历了由挤压碰撞向后碰撞伸展环境的转变,且转换时限为(290.4±3.2)Ma或更早。所获认识为进一步探讨准噶尔地区及中亚造山带构造环境的演化提供了依据。   相似文献   

10.
煤中关键金属是矿产资源勘探开发的新领域。目前对华北板块南缘早二叠世煤中微量元素赋存特征及主控机制研究较少,制约了关于该区煤沉积物源、沉积环境的认识以及煤的清洁高效利用。基于X射线衍射(XRD)、X射线荧光光谱(XRF)、电感耦合等离子体质谱(ICP-MS)等分析方法,对华北板块南缘早二叠世中煤矿物学与煤地球化学特征进行了研究。结果表明,华北板块南缘早二叠世煤中矿物主要发育高岭石、伊利石、铵伊利石、绿泥石和方解石等,主量元素以SiO2,Al2O3与CaO为主。煤层样品中Li元素相对富集,质量分数为54.5×10-6~116×10-6(均值76.83×10-6);Zr、Th元素轻微富集,质量分数分别为34.14×10-6~160.73×10-6(均值73.81×10-6)和3.22×10-6~17.79×10-6(均值7.85×10-6  相似文献   

11.
Over the recent three decades,exploration of a large-size Sn-Fe polymetallic ore deposit at the Huanggangliang, the Da Hinggan Mountains, Inner Mongolia, China, has been largely focused on the premise that the mineralization represents epigenetic magmatic hydrothermal ore deposit in genetic connection with the Mesozoic magmatism. The Huanggangliang Sn-Fe polymetallic ore deposits occurred in Permian strata, with siltstone/marble of the Zhesi Formation and spilite/andesite/tuff of the Dashizhai Formation. The characteristics of geological and geochemical data demonstrated that sedimentary hydrothermal mineralization occurred during the basin evolution at the Permian, rather than representing epigenetic magmatic hydrothermal genesis with the following evidences. The ore-bearing skarns are stratiform with underlying metasedimentary rocks and overlying volcanic sedimentary rocks. Sedimentary hydrothermal textures and structures are observed in the stratabound ore-bearing skarn such as bedded-laminated skarn and magnetite ores with small-size folding or soft deformation, synsedimentary breccia of skarn and magnetite ores and concentric shell structure of magnetite ores. So the stratabound ore-bearing skarns associated with magnetite ore and micro-disseminated tin, are peculiar examples of exhalite. The REE contents of the stratabound ore-bearing skarns display ΣLREE-rich (36.91×10-6) but ΣHREE-depletion (6.42×10-6), with positive Eu anomaly (Eu/ Eu 1.28) and negative Ce anomaly (Ce/Ce 0.88), which is totally different from REE pattern of the Huanggang magmatic rocks(with ΣREE 277.73×10-6, ΣLREE 220.24×10-6, ΣHREE 57.49×10-6, Eu/Eu 0.06, Ce/ Ce 1.52), which is comparable with modern sea-floor hydrothermal fluid,sedimentary hydrothermal ore deposit and associated hydrothermal sedimentary rocks. Calcite samples with δ13CPDB from -5.400 ‰ to -4.397 ‰ and δ18OSMOW from 9.095 ‰ to 9.364 ‰ in the stratabound ore-bearing skarns show sedimentary hydrothermal genesis of the Huanggangliang deposit. This proposition is useful not only for interpretation of the genesis of the Huanggangliang large Sn-Fe polymetallic ore deposit but also significant for mineral exploration in the area especially for finding large deposits caused by sedimentary exhalative mineralization processes.  相似文献   

12.
Trace and RE element geochemistry and genesis have been studied with respect to ferromanganese nodules from the sediments of the Pacific, Atlantic and Indian oceans.  相似文献   

13.
Synechococcus is a widely distributed photosynthetic pico-phytoplankton,which contributes mainly to carbon fixation and maintains the stability of the marine ecosystem.To investigate its distribution patterns in the Yellow Sea,seawater samples were collected during September 2018.Results of flow cytometry analysis showed that the Synechococcus abundance ranged from 6.36×102 to 4.51×104 cells mL?1,which correlated with salinity(P<0.01)and temperature(P<0.05).At deeper off-shore sites,Synecho-coccus showed high abundance at the subsurface thermo-halocline,which was in accordance with chlorophyll a(Chl a)content along the vertical column.Based on the high-throughput sequencing data of rpoC1(partial gene encoding RNA polymerase),two Synechococcus subclusters,S5.1 and S5.2,were found to coexist in the studied area.Several clades of S5.1,including Clades I,II,and III,were the dominant components,accounting for 6.63%,26.11%,and 45.5%of the total genus,respectively.Redundancy analysis(RDA)showed that nitrite was the main environmental factor that explained the genus composition among samples.Fur-thermore,co-occurrence network revealed that the main phyla that coexisted with Synechococcus were Proteobacteria,Bacteroidetes,Actinobacteria,Planctomycetes,and Verrucomicrobia,which were involved in the carbon(C),nitrogen(N),sulfur(S),and manga-nese(Mn)cycles.Overall,Synechococcus exhibited biogeographic distribution correlated with temperature-salinity and nitrite in the Yellow Sea,and their geochemical function showed diverse but should be further verified in the future.  相似文献   

14.
Manganese nodules collected from the North Penrhyn Basin are characterized by low content of Mn and Fe, medium content of Ni and Cu, and medium Mn/Fe ratios. The average content of Ni plus Co is 1.11%, maximum 1.89%. Ni content slightly exceeds the Cu content in the nodules. Ni and Cu are strongly correlated with Mn, whereas Co is strongly correlated with Fe. Nodules containing Ni+Cu+Co near or in excess of 1% are rich in Mn and have a high Mn/Fe ratio. Those with highest content of Ni+Cu+Co are concentrated at or near the carbonate compensation depth. Nodules metal contents vary with latitude and have a reciprocal relationship with abundance. Contents of Mn, Ni, Cu and Ni+Cu+Co are high in nodules found at 2–6°S and vary decreasingly toward 1°N and 12°S, whereas Co content varies increasingly from 2°S towards 12°S. Nodule compositional variations with latitude are controlled by biological productivity, carbonate compensation depth, sedimentation rate, and bottom current.  相似文献   

15.
In Antarctica, the marine ecosystem is dynamically interrelated with the terrestrial ecosystem. An example of the link between these two ecosystems is the biogeochemical cycle of phosphorus. Biovectors, such as penguins, transport phosphorus from sea to land, play a key role in this cycle. In this paper, we selected three colonies of penguins, the most important seabirds in Antarctica, and computed the annual quantity of phosphorus transferred from sea to land by these birds. Our results show that adult penguins from colonies at Ardley Island, the Vestfold Hills, and Ross Island could transfer phosphorus in the form of guano at up to 12 349, 167 036, and 97 841 kg/a, respectively, over their breeding period. These quantities are equivalent to an annual input of 3.96×109–1.63×1010 kg of seawater to the land of Antarctica. Finally, we discuss the impact of phosphorus on the ice-free areas of the Antarctica.  相似文献   

16.
The petrogenesis and geodynamic setting of the Late Jurassic Baita porphyry quartz monzodiorite in Xingcheng--Liaoxi area provide information for understanding the Mesozoic tectonic evolution of the northeastern North China Craton. In this paper, geochronological, whole-rock geochemical, and in-situ zircon Hf isotopic analyses of Baita porphyry quartz monzodiorite were investigated to constrain the crystallization age and petrogenesis. Zircons exhibit typical oscillatory zoning in cathodoluminescence images and show relatively high Th/U ratios(0.78--1.62), and U-Pb analyses indicate that these rocks were crystallized during the Late Jurassic(159±1 Ma). Geochemically, they are characterized by high contents of SiO_2(65.21 wt%--65.31 wt%), Al_2O_3(16.29 wt%--16.31 wt%), Sr(521×10~(-6)-539×10~(-6)), and Sr/Y ratio(45.1--47.8) but low Y(10.9×10~(-6)-12.0×10~(-6)), with obvious adakitic geochemical affinities. These above-mentioned findings, combined with their negative ε_(Hf)(t) values(-21.7 to-20.2), corresponding two-stage model age(T_(DM2)) of 2 579--2 484 Ma, as well as low MgO(1.38 wt%--1.39 wt%), Cr(18.5×10~(-6)-19.5×10~(-6)) and Ni(9.45×10~(-6)-9.46×10~(-6)) values, indicate that Baita porphyry quartz monzodiorite may be generated by partial melting of the Neoarchean-Paleoproterozoic thickened basaltic lower crust. Based on the results from this study and pre-vious regional studies, it is concluded that Baita porphyry quartz monzodiorite was spatially related to the westward subduction of the Paleo-Pacific plate.  相似文献   

17.
详细介绍了 1984~ 2 0 0 1年间越南地球物理研究所开展的地壳形变 (应变 )监测研究工作及其初步成果。文章指出 ,研究地壳运动时 ,应针对不同的情况 (如构造运动周期 )采用不同的方法 ,而本文着重介绍了地球物理仪器方法 ,此法 (有时与大地测量方法结合 )既可用来监测从几秒到几十年的运动 ,也可监测微小的局部位移。监测用的是前苏联制造的石英管伸缩仪 ,采用光电传感器换能 ,照相记录 ,灵敏度为 10 - 8m m。在用于观测固体潮汐应变时 ,观测精度还取决于应变的周期 :对周日波及更短周期 ,精度可达 10 - 9~ 10 - 1 0 ;而对缓慢的运动则只能达到10 - 7~ 10 - 8,但此时记录具有高稳定性。但用于监测所在地区是否存在断裂活动则无疑具有肯定的效果。最后 ,根据已有的 2处台站 10余年的观测成果 ,得出下列结论 :1.Phu L ien台站位于 Dong Trieu- Cam Pha断裂与红河断裂为边界的区域内 ,而此断裂自古至今都有活动 ,发生过 6级左右地震。但这一地区在 1989~ 1991期间却构造稳定 ,只记录到缓慢的运动速率 (1× 10 - 6 /a) ,也未观测到地震前兆性的应变现象。2 .而在 1993年才开始观测的 Hoa Binth台站 ,到 1997年止 ,则观测到比较大的地壳运动速率 ;其绝对最大幅度高达约 10 0× 10 - 6 ,日均值为 6 0× 10  相似文献   

18.
1 IntroductionOneofthemaintasksinstudyinggeodynamicprocessisevaluatingtherateofearthcrustmove ments.Normally ,themethodsforstudyingearthcrustmovementareestablishedonthebasisoftheobjectofstudyandtherequirementsfortheresultstobeobtainedasfollows.1 )Tostudythemovingprocessofcrustplatesinalargeareaandwithinacertaintectonicperiod ,geologicmethodsareusuallyused .2 )Geodeticmeasurementsarecarriedoutinanareacoveringfromsomekm2 totensofkm2 andal lowtodeterminethedisplacementoftheearthcrustwithinaperio…  相似文献   

19.
大庆油田扶余油层储量丰富,但是由于储层特征不清以及缺乏科学的"甜点"分类方案,导致研究区"甜点"优选难度大。为了明确研究区储层特征以及"甜点"筛选方案,应用岩心物性测试、全岩分析、铸体薄片、扫描电镜、岩石力学实验、高压压汞实验、测井资料建立了研究区物性和脆性指数计算模型,最终为明确储层特征和"甜点"筛选提供依据。结果表明:①研究区属于特低孔-超低渗致密储层,脆性指数集中在0.5~0.75之间,孔隙结构分为4类,Ⅰ类样品的孔隙度平均大于11%,渗透率平均大于0.7×10-3 μm2,以大孔为主,平均进汞饱和度大于75%,连通性最好;Ⅱ类样品的孔隙度主要为9%~12%,渗透率主要为0.3×10-3~0.7×10-3 μm2,大孔喉减少,小孔喉增加,平均进汞饱和度大于70%;Ⅲ类样品的孔隙度主要为8%~11%,渗透率主要为0.1×10-3~0.3×10-3 μm2,平均进汞饱和度大于60%,连通性变差;Ⅳ类样品的孔隙度主要小于9%,渗透率主要小于0.1×10-3 μm2,平均进汞饱和度小于60%,以小孔喉为主,储集、渗流能力最差。②结合物性、含油性、脆性指数利用灰色关联法建立了研究区经济"甜点"分类标准,Ⅰ类经济"甜点"的综合得分大于0.55,Ⅱ类经济"甜点"得分为0.4~0.55,Ⅲ类经济"甜点"得分为0.25~0.4,无效储层或干层综合得分 < 0.25,并且根据划分标准对井进行验证,发现该标准有效解决了根据测井判断储层是否含油所带来的误差。③沉积、成岩、断层相互耦合共同控制"甜点"的发育。沉积作用控制储层物性和孔隙结构,成岩作用增加了储层非均质性,断层的存在极大影响了储层含油性。该研究成果建立的"甜点"分类模型为研究区"甜点"筛选提供了科学依据。   相似文献   

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