Groundwater management scenarios for the Biyadh-Wasia aquifer systems in the eastern part of Riyadh region,Saudi Arabia

Groundwater stored in the deep seated sedimentary aquifers is the most important source of water supply. The lack of sufficient groundwater recharge and the overdependence on groundwater might lead to unavailability of this precious natural resource if proper management practices are not adopted. Finite difference modelling using the MODFLOW program was carried out in the east of Riyadh city to simulate the groundwater level conditions under different abstraction scenarios. The simulated aquifer system combines the Wasia and Biyadh aquifer (composed of sandstone) and Aruma aquifer (limestone) which lies between 24°30'00"- 25°30'00" N and longitudes 47°00'00"- 48°00'00"E. The transmissivity and storage coefficient values of Biyadh aquifer are 7.0x10^-3 to 7.0x10^-2 m²/day and 3.7x10^-4 to 9.4x10^-4 respectively. The transmissivity and storage coefficient values of Wasia aquifer ranges from 6.7x10^-3 to 8.5x10^-2 m²/day and 2x10^-4 to 2.3x10^-4 respectively. The model calibration involved altering the values of model input parameters to match field conditions within certain acceptable limits to forecast the aquifer response over a period of 35 years (2015-2050). The modelling grid consisted of 20 and 24 columns with the grids spacing of 4 km for the small grids and 6 km for large grids. The results showed that though the Wasia aquifer was productive, it showed a large decline in water levels if water abstraction continued at the present rate. If the existing trends of groundwater withdraw continues; the piezometric heads in Wasia and Biyadh aquifers will decline by the year 2050. A reduction in 25% of the existing groundwater pumping rate in the well field will minimize the rate of groundwater decline in the aquifer to a considerable extent.     

Potentiality of land and water resources in African Sahara: a case study of south Egypt

The investigated area is located south Egypt, between latitudes 22°00′N and 24°15′N, and longitudes 28°00′E and 30°00′E. It covers a total area of about 95,000.17 km². The area was remotely sensed to identify landscape and its land and water resources. A reconnaissance survey followed by detailed one was done to verify the information resulted from satellite images. The prevailing deposits of the area could be expressed as (1) the Nubian sandstone, (2) the Quaternary sediments, and (3) the sand dunes belt. Fourteen main and sub-main landforms were recognized, i.e., sand sheets (high, moderately high, moderate, and low), depressions (high, moderately high, moderate, and low), dry valleys, peniplains, footslopes, barchans, tablelands, and scattered hills. Associated soils were distinguished and classified as Typic Torripsamments, Typic Haplocalcids, Typic Torrifluvents, and Typic Haplodurids. Spatial variability of soil and water characteristics was identified through using ordinary Kriging interpolation method. Land surface temperatures in both summer and winter seasons were derived from thermal band, and soil temperature regimes were defined digitally as hyperthermic. Water potentiality was identified and classified according to salinity and sodicity hazards to C2-S1 and C3-S1. Using GIS techniques, soil potentiality spatial model (SPSM) was designed to get potentiality classes, i.e., high, moderately high, moderate, low, and very low.     

Equatorial electrojet in east Brazil longitudes

This paper describes the morphology of the equatorial electrojet (EEJ) along 45°W longitude in east Brazil, where the ground magnetic (dip) equator is associated with the largest declination in the world. Daily range of the horizontal field (ΔH), as expected, was largest at the station in the chain closest to the dip equator, Sao Luiz (inclination −0.25°S). ΔZ was largest positive at Eusebio (inclination 9.34°S) and largest negative at Belem (inclination 7.06°N); both near the fringe of EEJ belt. ΔZ at Sao Luiz during the daytime was unexpectedly large negative in-spite of a small dip and also located south of the dip equator where ΔZ should be positive. Center of EEJ was found to be shifted southward of the dip equator by about 1° in latitude. During southern summer, ΔY started decreasing from 00 h and reached a minimum value in the afternoon, an abnormal feature not discussed for any station so far. The mid-day value of the direction of ΔH vector was 22°–24°W compared to the declination of 19°–21°W in the region.     

Physicochemical Conditions during the Formation of Dalingkou Ag—Pb—Zn Deposit,Zhejiang Province

On the basis of mineral paragenesis and the chemistry and homogenization temperatures of fluid inclusions, the physicochemical parameters were calculated for the formation of the Dalingkou Ag-Pb-Zn deposit in Zhejiang. From the early to the late stage of mineralization the ore-forming temperature venation was found to be 298.5 °C → 267.0 °C → 217.6 °C → 167.3 °C, with a corresponding pH change of 3.0 ∼ 5.8 → 6.1 → 6.7→ 5.0 ∼ 7.3. The pressure changed from 403.8 to 128.5 atm, andlogf S₂-9.9 → -11.2 → < -15; logf o₂< -44→ -45.6 ∼ -42.6 → > -44.2; and logf co₂ around -1.55. In conjunction with geological observations, the deposit is considered to be of meso-epithermal origin, i.e., it was formed after continental volcanic-subvolcanic activity. The major factors affecting ore precipitation are the decreasing temperature and the increasing pH of ore-forming solutions.     

Time calibration of a P–T path from a Variscan high-temperature low-pressure metamorphic complex (Bayerische Wald, Germany), and the detection of inherited monazite

A temperature–time path was constructed for high-temperature low-pressure (HT–LP) migmatites of the Bayerische Wald, internal zone of the Variscan belt, Germany. The migmatites are characterised by prograde biotite dehydration melting, peak metamorphic conditions of approximately 850 °C and 0.5–0.7 GPa and retrograde melt crystallisation at 800 °C. The time-calibration of the pressure–temperature path is based on U–Pb dating of single zircon and monazite grains and titanite separates, on ⁴⁰Ar/³⁹Ar ages obtained by incremental heating experiments on hornblende separates, single grains of biotite and K-feldspar, and on ⁴⁰Ar/³⁹Ar spot fusion ages of biotite determined in situ from sample sections. Additionally, crude estimates of the duration of peak metamorphism were derived from garnet zoning patterns, suggesting that peak temperatures of 850 °C cannot have prevailed much longer than 2.5 Ma. The temperature–time paths obtained for two areas approximately 30 km apart do not differ from each other considerably. U–Pb zircon ages reflect crystallisation from melt at 850–800 °C at 323 Ma (southeastern area) and 326 Ma (northwestern area). The U–Pb ages of monazite mainly coincide with those from zircon but are complicated by variable degrees of inheritance. The preservation of inherited monazite and the presence of excess ²⁰⁶Pb resulting from the incorporation of excess ²³⁰Th in monazite formed during HT–LP metamorphism suggest that monazite ages in the migmatites of the Bayerische Wald reflect crystallisation from melt at 850–800 °C and persistence of older grains at these temperatures during a comparatively short thermal peak. The U–Pb ages of titanite (321 Ma) and ⁴⁰Ar/³⁹Ar ages of hornblende (322–316 Ma) and biotite (313–309 Ma) reflect cooling through the respective closure temperatures of approximately 700, 570–500 and 345–310 °C published in the literature. Most of the feldspars' ages (305–296 Ma) probably record cooling below 150–300 °C, while two grains most likely have higher closure temperatures. The temperature–time paths are characterised by a short thermal peak, by moderate average cooling rates and by a decrease in cooling rates from 100 °C/my at temperatures between 850–800 and 700 °C to 11–16 °C/my at temperatures down to 345–310 °C. Further cooling to feldspar closure for Ar was probably even slower. The lack of decompressional features, the moderate average cooling rates and the decline of cooling rates with time are not easily reconciled with a model of asthenospheric heating, rapid uplift and extension due to lithospheric delamination as proposed elsewhere. Instead, the high peak temperatures at comparatively shallow crustal levels along with the short thermal peak require external advective heating by hot mafic or ultramafic material. Received: 7 July 1999 / Accepted: 28 October 1999     

贵州的断裂与地震

贵州的地震明显受（活动性）断裂控制和影响,地震的平面分布分区边界受区域断裂控制,地震多发生在断裂附近或多组断裂交汇区附近。1819年以来,贵州境内发生的4次6级左右地震,震中都在多组断裂交汇区附近。1875年6月8日发生的6.5级地震,震中在开远-平塘断裂和垭都-紫云断裂交汇区附近的床井背斜,地理位置位于罗甸县西部,紧邻望谟县和紫云县,即北纬25°18',东经106°36'。      

Relics of eclogite facies metamorphism in the Austroalpine basement,Hochgrössen (Speik complex), Austria

Summary Retrograde eclogites and serpentinites from the Hochgr?ssen massif, Styria, are parts of the Speik complex in the Austroalpine basement nappes of the Eastern Alps. They are in tectonic contact with pre-Alpine gneisses, amphibolites, and Permo-Triassic quartz phyllites (Rannach Series). The eclogites are derived from ocean-floor basalts with affinities to mid-ocean ridge and back-arc basin basalts. Fresh eclogites are rare and contain omphacite with a maximum of 39 mol% jadeite content, garnet (Py_15–19) and amphibole. Retrograde eclogites consist of amphibole and symplectites of Na-poor clinopyroxene (5–8 mol% Jd) + albite ± amphibole. Amphiboles are classified as edenite, pargasite, tschermakite, magnesiohornblende and actinolite. In relatively fresh eclogite, edenite is a common amphibole and texturally coexists with omphacite and garnet. An average temperature of 700 °C was obtained for eclogite facies metamorphism using garnet-pyroxene thermometry. A minimum pressure of 1.5 GPa is indicated by the maximum jadeite content in omphacite. Thermobarometric calculations using the TWEEQ program for amphibole in textural equilibrium with omphacite and garnet give pressures of 1.8–2.2 GPa at 700 °C. The equilibrium assemblage of Na-poor clinopyroxene, albite, amphibole and zoisite in the symplectites gives a pressure of about 0.6–0.8 GPa at 590–640 °C. ⁴⁰Ar/³⁹Ar radiometric dating of edenitic amphibole in textural equilibrium with omphacite gave a plateau age of 397.3 ± 7.8 Ma, and probably indicates retrograde cooling through the closure temperature for amphibole (∼500 °C). The age of the high-pressure metamorphism thus must be pre-Variscan and points to one of the earliest metamorphic events in the Austroalpine nappes known to date. Received June 11, 2000; revised version accepted January 2, 2001     

郑州邙山马兰黄土的光释光(OSL)测年初步研究

对郑州市西北邙山黄土塬赵下峪(34°58'N,113°22'E)剖面上部马兰黄土(厚约87m)不同层位的24个样品作了细颗粒(4-11μm)组分红外释光(IRSL)测年,其中8个样品同时进行了细颗粒组分绿光释光(GLSL)测年。样品的IRSL和GLSL信号强度都在Daybreak1100TL/OSL检测系统中测量。该系统的本底计数为70-80光子/秒。被检测的IRSL和GLSL波长分别为340-480nm和340±25nm;激发光束波长分别为880±80nm和514±14nm,功率为18mW和15-16mW。所有样品的等效剂量都用再生释光法测定;环境剂量率是通过测定样品的铀、钍和钾含量,按Aitken(1985)的转换系数确定的,考虑了含水量的影响及宇宙射线的贡献。从这批样品的光释光测年结果可得以下初步认识:
(1)8个样品细颗粒组分的IRSL和GLSL测定的等效剂量和年龄值,除1个样品外,都在1-2σ范围内一致。这可能提供了沉积物光释光测年可靠性的一种自检方法。(2)邙山剖面马兰黄土不同层位段的沉积速率变化十分显著,从0.4m/ka到5.6m/ka,并与剖面上质量磁化率测定值的变化大致相吻合。该剖面马兰黄土至少有4个快速堆积层(沉积速率>3m/ka),其磁化率低而变化小;3个缓慢堆积层(沉积速率<0.5m/ka),其磁化率大或变化显著,它们之间有一系列过渡层。(3)邙山马兰黄土大体可三分即上部(L_1-1)埋深2.7-27.5m,中部(L_1-2)埋深27.5-57.9m)和下部(L_1-3)埋深57.9-87.9m。它们的形成年代分别为10.8-36.2ka B P,36.2-70.3ka B P和70.3-80.2ka B P。较详细的黄土-古土壤序列年代表将在文中讨论      

Paleo—Latitude Variation of Guizhou Terrain from Devonian to Cretaceous

Over 800 paleomagnetic samples were collected from 79 sample localities, ranging in age from Devonian, Carboniferous, Permian to Jurassic for paleo-latitude research on the Guizhou terrain. The area sampled covers 13 counties with an area of about 50000 km². The paleomagnetic results obtained indicate that the Guizhou terrain was at 11.4°S in Devonian, 4.5°-9.3°S in Carboniferous, 2.6° − 4.5°S in Permian, 14.8°N in Triassic and 24.5° − 26.0°N in Jurassic. In the Cretaceous period, the paleo-latitude of the area was at 22.4 − 23.6°N. Therefore, a variation curve of paleo-latitude is established in this paper for the Guizhou terrain from Late Devonian to Late Cretaceous time.     

New thermochronologic constraints on the evolution of the Zaldívar porphyry copper deposit,Northern Chile

Life spans and thermal evolution of hydrothermal systems are of fundamental metallogenic importance. We were able to establish the chronology and cooling history of the Zaldívar porphyry copper deposit (Northern Chile) by applying a combination of different isotopic dating methods in minerals with different closure temperatures, including ⁴⁰Ar/³⁹Ar geochronology and zircon fission track thermochronology, together with fluid inclusion thermometry and previous published U–Pb zircon geochronology. The hydrothermal mineralization in the Zaldívar deposit is genetically related to the Llamo Porphyry unit. Samples of igneous biotites from this intrusion yielded ⁴⁰Ar/³⁹Ar plateau ages between 35.5 ± 0.7 and 37.7 ± 0.4 Ma defining a weighted average of 36.6 ± 0.5 Ma (2σ). In contrast, one sample from the Zaldívar porphyry, one from the andesites, and two from the Llamo porphyry yielded considerably younger fission track ages of approximately 29 Ma with a weighted mean for all ages of 29.1 ± 1.7 Ma (2σ). Thermal and compositional constraints for the hydrothermal system in the Zaldívar deposit from fluid inclusions thermometry show that at least three fluid types broadly characterize two main hydrothermal episodes during the evolution of the deposit. The main mineralization and alteration event is characterized by high temperature (above 320°C) hypersaline fluids (salinity between 30 and 56 wt.% NaCl equivalents) coexisting with low-density gas-rich inclusions (salinity less than 17 wt.% NaCl equivalents) that homogenizing into the gas phase at temperatures above 350°C. The second episode corresponds to a low-temperature event which is characterized by liquid-rich fluid inclusions that homogenize into the liquid phase at temperatures ranging from 200°C to 300°C with salinities lower than 10 wt.% NaCl equivalents. The ⁴⁰Ar/³⁹Ar data (36.6 ± 0.5 Ma, weighted average) obtained from igneous biotites represent the minimum age for the last high-temperature (above 300°C) hydrothermal pulse. When compared with previously published U–Pb ages (38.7 ± 1.3 Ma) in zircons from the Llamo porphyry, a close temporal relationship between crystallization of the parental intrusion and the thermal collapse of the last high-temperature hydrothermal event is evident. Cooling took place from approximately 800°C (crystallization of the intrusive complex defined by zircon U–Pb ages) to below 300 ± 50°C (biotite ⁴⁰Ar/³⁹Ar closure temperature) within approximately 1.5 m.y. Because the thermal annealing of fission tracks in zircons occurs at temperatures of 240 ± 30°, the zircon fission track (ZFT) ages of 29.1 ± 1.7 Ma (2σ) mark the end of the thermal activity in the Zaldívar area, specifically the time when the whole area cooled below this temperature, well after the collapse of the main hydrothermal event in the Zaldívar porphyry copper deposit. This cooling age roughly coincides with the age defined for the emplacement of dacitic dikes at 31 ± 2.8 Ma (2σ) (published K–Ar whole rock), 5 km south of the Zaldívar deposit, in the Escondida area. This late magmatic pulse probably is responsible for high heat flow in the Zaldívar deposit as late as 29 Ma. There is no evidence that the low temperature hydrothermal pulse recognized by fluid inclusion studies is related to this thermal event. The zircon fission track cooling ages are interpreted to be related to the time lag required for complete relaxation of the perturbation of the isotherms in the geothermal field imposed by the intrusion of magmatic bodies, with or without any association with low temperature hydrothermal activity.     

Deflation processes and their role in desertification of the southern Pre-Balkhash deserts

Deflation processes are important in arid environments such as deserts. The deserts of Kazakhstan mostly cover lowlands and extend from the eastern coast of the Caspian Sea to the piedmonts of the Tien-Shan Mountain. Desert areas are also major source areas of dust/sand storm activities. We considered deflation processes in the southern Pre-Balkhash deserts. In Kazakhstan, desertification processes due to wind erosion in the form of dust/sand storms were observed in semi-desert and desert landscapes. During analysis of numerous long-term meteorological data and cartographic materials, we revealed the sand movement directions which allow prediction of future potential sand movement patterns or processes in southern Pre-Balkhash deserts. The Taukum, Moiynkum deserts, Ili river deltas and valleys, and southern coastal of Lake Balkhash are most prone to dust/sand storms. The most frequent storms were observed in the Bakanas weather station (Ile river valley). Sand/dust transport occurs mainly in the east, south-east north-east direction in the southern Pre-Balkhash deserts. The high amount of sand transportation was observed at the Kuigan weather station; low amounts were encountered at the Naimansuiek weather station. The amount of airborne sand/dust varies in accordance with the general and local meteorological features, the complexity of relief forms, soil conditions and properties, lithology, and various contributions of the human activities. Thus, our study on deflation processes in the southern Pre-Balkhash deserts has great importance towards aiding in the prediction and monitoring of dust/sand storms and movement patterns.     

High-temperature phase transitions and elasticity of silica polymorphs

The single-crystal acoustic velocities of α- and β-quartz were measured by Brillouin spectroscopy to a maximum temperature >1,500°C at room pressure. From these velocities, the single-crystal elastic moduli were calculated up to 1,050°C, exceeding the temperature range of previous measurements by 350°C for the elastic moduli and by 710°C for acoustic velocities. The ordinary refractive index (n _o) of α- and β-quartz was measured from room temperature to 800°C. In the temperature interval from ∼950 to 1,000°C a subtle change in the temperature derivative of the longitudinal acoustic velocity was observed in platelet geometry for all measured directions. The high-temperature acoustic velocity data may indicate the presence of a second phase, presumably β-cristobalite, that nucleates below 1,000°C.

Map of the 6.7 GHz class II methanol maser emission of the protoplanetary disk G23.01-0.41

We present images of the star-forming regionG23.01–0.41 at 6.7GHz in the Class II methanol maser transition 5₁–6₀ A ⁺, produced from archival observations on the European VLBI Network. Our map of the source and its maser spots contains 24 maser components. The data for each spot—absolute coordinates, coordinates relative to the calibration feature, peak flux and flux integrated over the spot, size, position angle, velocity along the line of sight, and line full width at half-maximum—are collected in tabular form. The spatial region occupied by the maser spots is approximated by a 200×130 milliarcsec ellipse in position angle PA = −0.40°, centered on the absolute coordinates α ₀ = 18^h34^m40.282^s, δ ₀ = −09°00′38.27″ (J2000). If the source is a protoplanetary disk, then, for the distance estimate derived from trigonometric parallax, its diameter is 1800 AU, and the mass of the central protostar is 23.5M _⊙.     

Complete preservation of ophiolite suite from south Andaman,India: A mineral-chemical perspective

Field studies supplemented by petrographic analyses clearly reveal complete preservation of ophiolite suite from Port Blair (11°39′N: 92°45′E) to Chiriyatapu (11°30′24″N: 92°42′30″E) stretch of South Andaman. The ophiolite suite reveals serpentinite at the base which is overlain unconformably by cumulate ultramafic-mafic members with discernible cumulus texture and igneous layering. Basaltic dykes are found to cut across the cumulate ultramafic-mafic members. The succession is capped by well exposed pillow basalts interlayered with arkosic sediments. Olivine from the basal serpentinite unit are highly magnesian (Fo_80.1–86.2). All clinopyroxene analyses from cumulate pyroxenite, cumulate gabbro and basaltic dyke are discriminated to be ‘Quad’ and are uniformly restricted to the diopside field. Composition of plagioclase in different lithomembers is systematically varying from calcic to sodic endmembers progressively from cumulate pyroxenite to pillow basalt through cumulate gabbro and basaltic dyke. Plagioclase phenocrysts from basaltic dyke are found to be distinctly zoned (An_60.7-An_35.3) whereas groundmass plagioclase are relatively sodic (An₃₃-An_23.5). Deduced thermobarometric data from different lithomembers clearly correspond to the observed preservation of complete ophiolite suite.     

The geodynamics of collision of a microplate (Chilenia) in Devonian times deduced by the pressure–temperature–time evolution within part of a collisional belt (Guarguaraz Complex,W-Argentina)

The Guarguaraz Complex in West Argentina formed during collision between the microplate Chilenia and South America. It is composed of neritic clastic metasediments with intercalations of metabasic and ultrabasic rocks of oceanic origin. Prograde garnet growth in metapelite and metabasite occurred between 1.2 GPa, 470°C and 1.4 GPa, 530°C, when the penetrative s₂-foliation was formed. The average age of garnet crystallization of 390 ± 2 Ma (2σ) was determined from three four-point Lu–Hf mineral isochrones from metapelite and metabasite samples and represents the time of collision. Peak pressure conditions are followed by a decompression path with slight heating at 0.5 GPa, 560°C. Fluid release during decompression caused equilibration of mineral compositions at the rims and also aided Ar diffusion. An ⁴⁰Ar/³⁹Ar plateau age of white mica at 353 ± 1 Ma (1σ) indicates the time of cooling below 350–400°C. These temperatures were attained at pressures of 0.2–0.3 GPa, indicative of an average exhumation rate of ≥1 mm/a for the period 390–353 Ma. Late hydrous influx at 0.1–0.3 GPa caused pervasive growth of sericite and chlorite and reset the Ar/Ar ages of earlier coarse-grained white mica. At 284–295 Ma, the entire basement cooled below 280°C (fission track ages of zircon) after abundant post-collisional granitoid intrusion. The deeply buried epicontinental sedimentary rocks, the high peak pressure referring to a low metamorphic geotherm of 10–12°C/km, and the decompression/heating path are characteristics of material buried and exhumed within a (micro) continent–continent collisional setting.     

Low-temperature heat capacities,entropies and enthalpies of Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript> polymorphs,and α−β−γ and post-spinel phase relations at high pressure

The low-temperature isobaric heat capacities (C _p) of β- and γ-Mg₂SiO₄ were measured at the range of 1.8–304.7 K with a thermal relaxation method using the Physical Property Measurement System. The obtained standard entropies (S°₂₉₈) of β- and γ-Mg₂SiO₄ are 86.4 ± 0.4 and 82.7 ± 0.5 J/mol K, respectively. Enthalpies of transitions among α-, β- and γ-Mg₂SiO₄ were measured by high-temperature drop-solution calorimetry with gas-bubbling technique. The enthalpies of the α−β and β−γ transitions at 298 K (ΔH°₂₉₈) in Mg₂SiO₄ are 27.2 ± 3.6 and 12.9 ± 3.3 kJ/mol, respectively. Calculated α−β and β−γ transition boundaries were generally consistent with those determined by high-pressure experiments within the errors. Combining the measured ΔH°₂₉₈ and ΔS°₂₉₈ with selected data of in situ X-ray diffraction experiments at high pressure, the ΔH°₂₉₈ and ΔS°₂₉₈ of the α−β and β−γ transitions were optimized. Calculation using the optimized data tightly constrained the α−β and β−γ transition boundaries in the P, T space. The slope of α−β transition boundary is 3.1 MPa/K at 13.4 GPa and 1,400 K, and that of β−γ boundary 5.2 MPa/K at 18.7 GPa and 1,600 K. The post-spinel transition boundary of γ-Mg₂SiO₄ to MgSiO₃ perovskite plus MgO was also calculated, using the optimized data on γ-Mg₂SiO₄ and available enthalpy and entropy data on MgSiO₃ perovskite and MgO. The calculated post-spinel boundary with a Clapeyron slope of −2.6 ± 0.2 MPa/K is located at pressure consistent with the 660 km discontinuity, considering the error of the thermodynamic data.     

The El Teniente porphyry Cu–Mo deposit from a hydrothermal rutile perspective

Mineralogical, textural, and chemical analyses (EPMA and PIXE) of hydrothermal rutile in the El Teniente porphyry Cu–Mo deposit help to better constrain ore formation processes. Rutile formed from igneous Ti-rich phases (sphene, biotite, Ti-magnetite, and ilmenite) by re-equilibration and/or breakdown under hydrothermal conditions at temperatures ranging between 400°C and 700°C. Most rutile nucleate and grow at the original textural position of its Ti-rich igneous parent mineral phase. The distribution of Mo content in rutile indicates that low-temperature (∼400–550°C), Mo-poor rutile (5.4 ± 1.1 ppm) is dominantly in the Mo-rich mafic wallrocks (high-grade ore), while high-temperature (∼550-700°C), Mo-rich rutile (186 ± 20 ppm) is found in the Mo-poor felsic porphyries (low-grade ore). Rutile from late dacite ring dikes is a notable exception to this distribution pattern. The Sb content in rutile from the high-temperature potassic core of the deposit to its low-temperature propylitic fringe remains relatively constant (35 ± 3 ppm). Temperature and Mo content of the hydrothermal fluids in addition to Mo/Ti ratio, modal abundance and stability of Ti-rich parental phases are key factors constraining Mo content and provenance in high-temperature (≥550°C) rutile. The initial Mo content of parent mineral phases is controlled by melt composition and oxygen fugacity as well as timing and efficiency of fluid–melt separation. Enhanced reduction of SO₂-rich fluids and sulfide deposition in the Fe-rich mafic wallrocks influences the low-temperature (≤550°C) rutile chemistry. The data are consistent with a model of fluid circulation of hot (>550°C), oxidized (ƒO₂ ≥ NNO + 1.3), SO₂-rich and Mo-bearing fluids, likely exsolved from deeper crystallizing parts of the porphyry system and fluxed through the upper dacite porphyries and related structures, with metal deposition dominantly in the Fe-rich mafic wallrocks.     

Fracture pattern and electrical resistivity studies for groundwater exploration

 The occurrence, movement and control of groundwater, particularly in hard-rock areas, are governed by different factors such as topography, lithology, structures like fractures, faults and nature of weathering. An attempt is made in the present study to investigate the extent of the influence of structures such as fractures and thereby delineate the nature of subsurface lithology with the help of an electrical resistivity method. For this study, the Upper Gunjanaeru River basin, Cuddapah district Andhra Pradesh was chosen to determine groundwater potentials. In order to understand the significance of the fracture pattern, geological, hydrogeomorphological and lineament maps were prepared based on the field data and also from the LANDSAT TM imagery. Further, electrical resistivity surveys were conducted to determine the subsurface lithology and also to confirm the studies of LANDSAT imagery. The isoresistivity contour map has been prepared based on the 45 VES conducted to determine the resistivity variations in the study area. The isoresistivity contours obtained were found to conform to the structural trends obtained by geological studies and also confirm the relationship between the structure and secondary porosity present in the rocks. The lineaments in the area have two preferred directions. One set is a NE-SW direction (N 30°–70° E; S 30°–70° W) and another is a NW-SE direction (N 0°–30° W; S 0°–30° E and N 60°–80° W; S 60°–80° E). The water-table contour map shows that the direction of groundwater flow is south to north. Received: 3 March 1997 · Accepted: 17 June 1997     

Melting of portlandite up to 6 GPa

 Using the high-pressure differential thermal analysis (HP-DTA) system in a cubic multianvil high-pressure apparatus, we measured the melting points of portlandite, Ca(OH)₂, up to 6 GPa and 1000 °C. We detected endothermic behavior at the temperature and pressure conditions of 800 °C and 2.5 GPa, 769 °C and 3.5 GPa, 752 °C and 4.0 GPa, 686 °C and 5.0 GPa, and 596 °C and 6.0 GPa, respectively, due to melting of portlandite. By in situ X-ray studies under pressure, the melting of portlandite was observed at 730 °C and 4.32 GPa and at 640 °C and 5.81 GPa, respectively. Results of both HP-DTA and X-ray studies were consistent within experimental error. The melting is congruent and has a negative Clapeyron slope, indicating that liquid Ca(OH)₂ has higher densities than crystalline portlandite in this pressure range. Received: 19 June 1999 / Revised, accepted: 11 September 1999     

Thermobarometry of the Bleikvassli Zn-Pb-(Cu) deposit, Nordland, Norway

The Bleikvassli massive sulfide ore deposit is hosted by Proterozoic pelitic, quartzofeldspathic, and amphibolitic rocks of the Uppermost Allochthon of the Scandinavian Caledonides. Staurolite-garnet-biotite and kyanite-staurolite-biotite assemblages indicate that metamorphism reached the kyanite zone of the amphibolite facies. Geothermobarometry was conducted on rocks in and around the deposit using a variety of silicate and sulfide calibrations. Temperature determinations are most reliant on the garnet-biotite exchange reaction, with analyses obtained from 259 garnet rims and adjacent biotite. Results from nine calibrations of the garnet-biotite geothermometer are considered, but compositional limitations of many calibrations involving high Ca and Mn contents in garnet and Al^VI and Ti in biotite make many of the coexisting mineral pairs unsuitable. Average temperatures calculated from the two calibrations that most closely address the garnet-biotite compositions observed at Bleikvassli are 584 °C ± 49 °C and 570 °C ± 40 °C. The application of two calibrations of the garnet-staurolite geothermometer on a limited number of samples yields 581 °C ± 2 °C and 589 °C ± 12 °C, assuming a _H2O=0.84, based upon calculations of the modal proportions of gaseous species. Pressure determinations are less constrained. Phengite and plagioclase-biotite-garnet-muscovite geobarometers give average pressures of approximately 5.0 kbar and 8.5 ± 1.2 kbar, respectively. Pressures obtained from the sphalerite-hexagonal pyrrhotite-pyrite barometer average 7.7 ± 1.0 kbar. In consideration of these results, the peak metamorphic conditions at the Bleikvassli deposit are estimated to be 580 °C and 8 kbar. Received: 18 June 1997 / Accepted: 14 May 1998