Spinel inclusions in olivine and plagioclase crystals in a layered gabbro: a marker and a tracer for primary phenocrysts in a differentiating magma reservoir

The problem of whether cumulate rocks were formed by crystal settling or by in situ crystallization after magma emplacement is an important issue concerning the mechanisms of magmatic differentiation. However, it is hard to distinguish these two processes for plutonic rocks because the primary texture and chemical composition have generally been modified by postcumulus processes. To contribute this problem, we studied the distribution and compositions of Cr-spinel inclusions hosted in olivine and plagioclase in the Murotomisaki Gabbroic Intrusion (MGI), SW Japan. It is shown that the olivine-hosted inclusions are restricted to specific horizons where accumulation of olivine phenocrysts is thought to have occurred and that the compositional variations of the Cr-spinel are explained by a secondary compositional modification that probably took place after the magma emplacement. It is also shown that the Cr-spinel inclusions in a chilled margin have suffered the least compositional modification and nearly retains the primary composition. Those in the interior of the intrusion, on the contrary, have been significantly modified by re-equilibration with residual melt driven by cation diffusions through the host phases. Those in plagioclase have been less modified. It is shown that all the spinel inclusions had primarily the same and common composition at the time of magma emplacement. This implies that all the inclusion-bearing crystals, olivine and plagioclase, represent primary phenocrysts that had already existed in the emplaced magma. In this way, spinel inclusion in the MGI may be regarded to be a useful petrographic “marker” for identifying intratelluric phenocrysts and also as a “tracer” to trace the motion of the primary phenocrysts after the magma emplacement.     

Trace metal occurrence in a mineralised and a non-mineralised spodosol in northern Sweden

In order to determine the metal-bearing phases with special emphasis on Cu, a sequential extraction has been carried out on seven soil samples from a sulphide-bearing spodosol profile in Liikavaara Östra, close to the Aitik Copper Mine in northern Sweden. A reference spodosol profile with very low abundances of sulphides located far from anthropogenic emissions was also studied. Five fractions were selected for the extraction: (I) CH₃COONa-extractable (exchangeable/adsorbed/carbonate); (II) Na₄P₂O₇-extractable (labile organics); (III) 0.25 M NH₂OH·HCl-extractable (amorphous Fe oxyhydroxides/Mn oxides); (IV) 1 M NH₂OH·HCl-extractable (crystalline Fe oxides); and (V) KClO₃/HCl-extractable (organics and sulphides). The distribution of trace elements (Co, Cr, Cu, Ni, Pb and Zn) in the profile in Liikavaara Östra is different from that in the reference profile. Possible explanations for these differences are (i) the presence of sulphides in the soil, (ii) atmospheric deposition of dust derived from mining activities at the Aitik Copper Mine, and (iii) mineralogical heterogeneities inherited from the deposition of the till. There is no straightforward correlation between the amount of the extracted phases and the metal extractability in the soils. This fact indicates that other factors are important for the retention of trace metals as well. The data presented in this study suggest that Co, Cr and Ni, to a fairly large extent, are associated with the organic matter in the B-horizon in both profiles, while in the C-horizon in Liikavaara Östra, sulphides are probably the more important carriers of these elements. For Co and Ni, Fe oxyhydroxides seem to be important. Most of the Cr occurred in the residual remaining after the leaching procedure. Copper and Zn seem to be associated with the organic matter to some extent in the B-horizon. The concentration of Cu in the C-horizon in Liikavaara Östra is high (2310 ppm), but only a very small fraction is likely to be hosted by sulphides. It is concluded that the major part of Cu in the C-horizon and a prominent fraction in the B-horizon in Liikavaara Östra are associated with some secondary phase that is extractable during extractions III and IV. Possible candidates for this phase are goethite and inclusions of native Cu in weathered biotite.     

Microfracturing and faulting in a limestone

Two fundamentally distinct types of microfractures are present in an experimentally deformed limestone: subaxial microfractures and microfaults. Macroscopic faults are composed of coalesced microfaults and are not related to the subaxial microfractures. A high-temperature mechanical instability occurs at temperatures of 200° C and above when the confining pressure is 600 bars or less.     

Between a rock and a hard place: Vulnerability and precarity in rural Nepal

Drawing on a local study on Nepal’s Terai, this paper explores the nature of livelihood exposure to shocks and stresses among rural households in two Village Development Committees in Sunsari District. The primary data are derived from a 117 household survey supplemented by 19 purposefully sampled follow-up interviews. The paper opens with a discussion of the changing nature of exposure in the global South, distinguishing between inherited vulnerability and produced precarity. We then provide background to the research site and the research methods. In the core empirical part of the paper we unravel and distinguish between the livelihood threats and opportunities faced by households in the area and use these to reflect on the nature of ’exposure’, its historical origins and contemporary (re)production. The final part of the paper uses the Nepal case to build a more general argument, proposing that if we are to understand the puzzle of continued livelihood exposure and uncertainty in the context of aggregate economic expansion we need to identify and interrogate the processes that may, at the same time, produce wealth and reduce vulnerability, while also generating precarity.     

Seasonal patterns of nitrification and denitrification in a natural and a restored salt marsh

Seasonal patterns of microbially-mediated nitrogen cycling via the nitrification-denitrification pathway were compared between a natural and a restored salt marsh. Sedimentary denitrification rates, measured with a modification of the acetylene block technique, were approximately 44 times greater in the natural marsh relative to an adjacent transplanted marsh. Nitrification rates were similar at both sites. The difference in denitrification rates was attributed to oxygen inhibition at low tide and tidal flushing of porewater nutrients at high tide in the coarse sediments of the restored marsh. Denitrification was positively correlated with nitrification throughout the year in the natural marsh with a seasonal fall peak in denitrification corresponding to a maximum in porewater ammonia concentration. A weak correlation existed between the two processes in the restored marsh, where nitrification rates exceeded denitrification rates by a factor of 20. Transplanted marsh denitrification rates exhibited a spring peak, corresponding to elevated porewater ammonia concentrations. Our findings demonstrate functional differences in microbial nitrogen dynamics of a young (0–3 yr) restored marsh relative to a mature (>50 yr) salt-marsh system. *** DIRECT SUPPORT *** A01BY070 00008     

folding and slumping in a layered gabbro

The layered gabbroic intrusion of Sarqata qaqa, Ubekendt Ejland, West Greenland contains numerous xenoliths of thermally metamorphosed picrite-basalt. Folding and slumping of the layering occurs adjacent to some of these blocks. It is postulated that the structures were formed by sloped lava xenoliths hitting the unconsolidated layers of crystals forming the floor of the magma chamber during the cooling history of the intrusion. The settling velocities of the xenoliths, and thickness and viscosity of the crystal mush are estimated and discussed.     

Strain and rotation in a multilayered fold

Strain was estimated in a fold of Cambrian interlayered siltstones and pelites by determining the preferred orientation of chlorite grains with an X-ray goniometer. Strains so obtained and the postulate that continuity be preserved allowed unfolding of the fold and the determination of rigid body rotations that accompanied the strain. Petrologic investigation showed no sign of major differential volume changes in the siltstones, and this in conjunction with measured strains led to the conclusion that one of the silty layers making up the fold was not, originally, a bed of uniform thickness but a lenticular body, probably representing a single ripple on a ripple-marked tidal flat.Unfolding by piecemeal fitting of unstrained domains shows that none of the principal axes of strain lie consistently parallel to or at right angles to the fold axis. Rock material was displaced with components orthogonal to the profile plane as well as parallel to it. Strain due to compaction during an early history of increasing sediment overburden cannot be separated from strain during tectonic deformation. Its influence is most clearly seen in differential volume change between siltstones and pelites. Additional differential volume changes within pelite beds could have occurred at any time of the deformational history.A comparison of the orientation of strain and rotation axes in the two limbs of the fold, and also comparison of the same orientations in Eulerian coordinates (Cartesian coordinates in the observed fold) and in Lagrangean coordinates (Cartesian in the unfolded fold) make it probable that episodes of relatively uniform strain both preceded and followed the buckling episode that produced the sharp hinge in the competent silt-stone. The siltstone may have been less indurated and thus no more competent than the pelite during early deformation.     

Shear Strength Anisotropy in a Bedded Pyritic Shale and a Siliceous Dolomite

SummaryShear Strength Anisotropy in a Bedded Pyritic Shale and a Siliceous Dolomite The orientation, frequency and extent of joint and bedding plane fractures were measured in bedded pyritic shale and siliceous dolomite, host rocks of the lead-zinc and copper orebodies at Mount Isa, Queensland, Australia. The measurements, carried out in openings 10 by 10 feet, bring out the marked difference between the two rock types in regard to frequency and extent of the geologie discontinuities. Friction tests on joint and bedding planes, together with the continuity measurements, provide information on the shear strength anisotropy in the rock mass.It was found that an increase of the fracture frequency parallel to bedding planes is related to an increase in joint frequency, although not a proportional one, and that fractures of higher frequency show a tendency to have greater continuity.

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ZusammenfassungScherfestigkeits-Anisotropie in einem pyritischen Tonschiefer und einem Quarzdolomit Die Orientierung, Häufigkeit und die Ausdehnung von Bruchflächen parallel zu Kluft und Schichtebenen wurden im pyritischen Tonschiefer und im Quarzdolomit gemessen. Diese Gesteine enthalten die Blei-, Zink- und Kupfererze in Mount Isa, Queensland, Australien. Die Messungen wurden in Stollen mit einem Querschnitt von 3 × 3 m durchgeführt und weisen auf die großen Unterschiede hin, die hinsichtlich der Häufigkeit und Ausdehnung der Bruchflächen in beiden Gesteinsarten bestehen. Laborscherversuche zusammen mit den Kontinuitätswerten erlauben die Bestimmung der Unterschiede der Scherfestigkeit. Es wurde beobachtet, daß mit der Zunahme der Bruchflächenhäufigkeit entlang von Schichtebenen eine Zunahme der Klufthäufigkeit verbunden ist, und daß Bruchflächen mit zunehmender Häufigkeit eine größere Kontinuität aufweisen.

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RésuméAnisotropie de la résistance au cisaillement dans une Bedded Pyritic Shale et une Dolomite siliceuse L'orientation, la fréquence et l'étendue des fissures géologiques dans la Bedded Pyritic Shale et la Dolomite siliceuse ont été mesurés dans les dépôts de cuivre et plomb/zinc du Mt. Isa, Queensland, Australie. Les mesures, obtenues dans des tunnels de 3 × 3 m, montrent une différence marquée entre les deux types de roches en regard de la fréquence et de l'étendue de la discontinuité géologique. Des études du cisaillement sur les fissures parallèles aux strates géologiques et aux joints ainsique les mesures d'étendue ont donnés des informations sur l'anisotropie de la résistance au cisaillement dans le massif rocheux.

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With 4 Figures     

Cryptoperthites and cooling rate in a layered syenite pluton: a chemical and TEM study

Alkali feldspars in the Klokken layered syenite (South Greenland) are optically either coarse, turbid, deuteric patch perthites or clear, unaltered, fine braid microor cryptoperthites. Irregular, clear volumes can be found in most turbid grains. Electron microscopy shows that all clear crystals or volumes are cryptoperthites in which the periodicity of the exsolution lamellae increases systematically with distance from the roof of the intrusion, from 40 nm to 300nm. They are composed of low albite and diagonally associated maximum microcline. A secondary coarsening is responsible for optically visible braid microperthites.The layered series consists of interleaved, granular syenites and coarser grained, laminated syenites with mineral layering. Microprobe analyses show a downward decrease in Ca and Ba in the granular syenite feldspars consistent with chilling from the roof inwards. Most laminated syenite feldspars contain 1% An increasing to 5% in mafic layers.The periodicity of the exsolution lamellae in the laminated syenite feldspars is consistently up to twice that in adjacent granular syenites. Periodicity is not influenced by Ab:Or or An content, but high-An feldspars have continuous zig-zag intergrowths, while others are more lozengeshaped. Lamellar periodicities largely reflect cooling rate in the pluton. Cooling times in the exsolution interval were probably about 10³–10⁴ years at the top of the series, whereas existing experimental data suggest that the periodicities would be reached in a few days or years. The periodicities at the top of the granular series are only slightly greater than experimentally determined initial wavelengths for spinodal decomposition, suggesting that little or no coarsening occurred despite the long cooling times. Coarsening did occur lower in the pile. Framework ordering and twinning must slow or stop coarsening.The difference in periodicity between the granular and laminated syenite series may be caused by differences in amount of water incorporated in the feldspar structure from the magma. The exsolution of this water at low temperatures could be the cause of the deuteric unmixed patch perthites. Small volumes of cryptoperthite which have escaped deuteric unmixing may be common in igneous rocks in general and may be useful relative indicators of cooling rate.     

Fracture Initiation and Propagation in a Brazilian Disc with a Plane Interface: a Numerical Study

In the present study, fracture initiation and propagation from a pre-existing plane interface in a Brazilian disc is investigated using a finite-discrete element combined method. Different fracture patterns, depending on the frictional resistance of the pre-existing crack or interface, are observed from the numerical simulation. It is found that when there is no or very little frictional resistance on the surfaces of the pre-existing crack, the primary fractures (wing cracks), which are tensile in nature and are at roughly right angles to the pre-existing crack, start from the tips of the pre-existing crack. As the friction coefficient increases, the wing cracks’ initiation locations deviate from the crack tips and move toward the disc center. Secondary fractures, which are also tensile in nature, initiate from the disc boundary and occur only when the length of the pre-existing crack is sufficiently long. The secondary fractures are roughly sub-parallel to the pre-existing crack. The failure load is found to be influenced by the friction coefficient of the pre-existing crack. A 38 % failure load increase can result when the friction coefficient changes from 0 to 1. A good understanding of the fracture initiation and propagation in the forms of primary and secondary fractures provides insight into explaining some fracture patterns observed underground.     

Reconstruction and post-event analysis of a flash flood in a small ungauged basin: a case study in Slovak territory

Flash floods are one of the major natural hazards occurring in small streams with a negative effect on the country as well as on human lives. Heavy rainfall occurred on July 20, 2014 and July 21, 2014 and caused severe surface water flooding and a flash flood in the Malá Fatra National Park (Slovakia). The most affected was Vrátna Valley with the Varínka stream. This study presents a reconstruction and post-event analysis of a flash flood on small ungauged basin located in this protected area of Slovakia. The reconstruction included hydraulic terrain measurements on estimating the flood’s culmination and documenting the flood’s development. The measurements were taken at three cross sections of the Varínka stream. This paper is focused mainly on post-event analysis of the Varínka stream in two profiles: Strá?a (gauged profile) and Tiesňavy (ungauged cross section). Subsequently, the extremeness of the flash flood was preliminary evaluated. Results of the post-event analysis showed that the July 2014 flood was not the highest flood in this area despite its catastrophic consequences. By studying historical materials, we came to the conclusion that in the past (e.g. in 1848 or 1939) some devastating floods in this area had occurred, which had disastrous consequences for the population. The second part of the study is focused on comparing this flash flood with three major floods which have occurred in Slovak territory since 1998. The first flood occurred on the 20th of July, 1998 on the Malá Svinka stream, and the two others are floods which occurred on the 7th of June, 2011 in the Small Carpathian Mountains: on the Gidra stream in Píla village and on the Parná stream in Horné Ore?any village. Such comparison of flash floods from different geographical regions and different rainfall events can provide comprehensive information about their regimes, threats and disastrous effects.     

Results of a study of co-migration of trace elements and organic matter in a river flow in a boreal zone

This work describes the evolution of migration forms of true dissolved compounds and colloidal entities using an integrated approach with molecular mass distribution and differences in the association of trace elements with organic matter and Fe-oxide colloids in the soil water-bog-river-lake system. One major problem is obtaining reliable information on the processes of redistribution deposited forms and trace element complexes during the phase transformation of organic humic compounds in a series of high-molecular-weight organic matter of bog soils to colloidal and truly dissolved forms, as well as to the river and lake fine sediment (suspension) as a transit zone and deposit region.     

Geochemistry of a Rapakivi Granite Suite in a Proterozoic Rift Trough in Beijing and Its Vicinity

Controlled by E-W-trending faults, a Proterozoic (1.4-1.8 Ga old) rapakivi granite suite was intruded inBeijing and the area to its east (within Hebei Province), forming three parallel belts of igneous rocks. Theisotopic, trace element and rare earth element geochemical data of a bimodal rock association made up ofanorthosite, gabbro and alkali basalt and olivine-bearing quartz-syenite, rapakivi granite and trachyte as wellas potassic A-type granites and anorogenic granites—— all suggest that there exists an incipient rift in thestudy area. Fractional crystallization of a mixed magma formed by the magma derived from the upper mantleand the magma derived by small degrees of fusion of the lower crust produced anorthosite cumulates. Thewater-deficient granitic magma was differentiated into a subalkaline series. When the fractional crystallizationwas incomplete, rhythmic eruptions took place.     

Petrography and decay of a marly limestone in the cloister of a medieval cathedral in Sicily

This paper deals with a significant process of decohesion of a marly limestone, taking place in the cloister of the medieval Cathedral of Cefalù, a pleasant town on the northern coast of Sicily. After desalination with deionised water and consolidation with ethyl silicate, the decay of the stone became faster. The aim of our study is to characterise the stony material and investigate the observed decay phenomena. The stone, that is a poor building material indeed, is characterised by means of petrographical, chemical and physical analyses on samples taken from the monument. Furthermore, experimental tests are performed in the laboratory in order to highlight the causes of incompatibility between the stone and the applied treatments.     

福建闽侯某小区滑坡特征及成因机制分析

通过对福建闽侯某小区滑坡的地质调绘、探井及钻孔勘察等综合方法应用,结合深部位移监测,充分论证了滑面的位置,分析研究滑坡的基本特征及影响因素。研究表明,该滑坡是推移式土质滑坡,破坏模式为蠕滑-拉裂-弯曲型式,结合小区建设实际,提出切合实际且有效的锚索抗滑桩的治理方案。     

Distribution and abundance of hydrobiid snails in a mixed estuary and a coastal lagoon,Argentina

This study examined the environmental factors influencing the distribution and abundance of hydrobiid snails in two estuaries on the northeastern coast of Argentina in a coastal lagoon (Mar Chiquita, 37°40′S, 57°20′W) and a partially mixed estuary (Quequén Grande, 38°30′S, 58°45′W). Five intertidal study sites in each estuary represented a gradient in environmental conditions. Variations in the main environmental factors and in the abundance of hydrobiids were assessed both spatially and seasonally. The three species wereHeleobia australis, Heleobia conexa, andHeleobia parchappii, and they were primarily distributed across a salinity gradient. This pattern was clearly recognizable in the partially mixed estuary, where the abundance ofH. australis decreased as salinity decreased, and the abundance ofH. conexa gradually increased towards the inner reaches of the estuary.H. parchappii was restricted to areas far away from the influence of the tide. Slight differences in the distribution patterns of these species between Quequén Grande and Mar Chiquita were refated to the different dynamics of environmental factors in each estuary.     

Characterization of natural colloids from a river and spring in a karstic basin

 Colloids are known to transport contaminants over long distances in natural media. Despite this potentially harmful effect, very few studies have been undertaken in subsurface aquifers. This paper presents the first results of a study of natural colloids and particles in a karstic aquifer. The site was chosen for its coverage by clay layers and peat which deliver various and numerous particle types in water. The methodological part describes three methods used for size determination and sample fractionation of surface water and spring water. These methods have been adapted for the treatment of multiple samples due to the rapid discharge variation typical of karstic aquifers. The analysis of many particle size distributions (PSD) shows that they can be described by a Pareto law. The variation of the slope of the PSD at the spring is mainly dependent on discharge. This behavior is interpreted as a washing of the karstic drains during the first phase of high flow events. Fractionation of the samples allowed application of various characterization techniques to particle size classes. X-ray diffraction (XRD) patterns showed that most of the mineral particles originated from Quaternary deposits and limestones. However the use of scanning electron micrsocopy with energy-dispersive spectrometer (SEM-EDS) detailed the composition of individual particles and revealed particles not found by XRD. These techniques also showed the high complexity of the natural particles and the important place of coprecipitation in their formation. Consequences on the fluxes of particulate matter and its potential role as a carrier of contaminants are discussed. Received: 28 October 1996 · Accepted: 7 July 1997     

IR photometry and a model of a dust shell in V2108 Ophiuchi

We present the results of JHKLM photometry of the oxygen Mira variable V2108 Oph acquired in 2000–2004. The period of brightness variations is refined (570 ± 3 days), and light and color curves in the near-IR are presented. The mean fluxes, color temperatures, and sizes for two blackbodies representing the combined radiation of the star and dust shell at minimum and maximum brightness are estimated. Additional IRAS data were used to compute a model with a spherically symmetric dust shell of silicate grains; the best-fit model has a radius for its inner boundary of 2.4 × 10¹⁴ cm, a dust temperature at this boundary of 1150 K, an optical depth of the shell at 0.55 μm of 16.8, and implies a distance to the star of 980 pc. We estimate the mass-loss rate for V2108 Oph to be 1.2 × 10⁻⁵ M _⊙/yr. Original Russian Text ? M.B. Bogdanov, O.G. Taranova, V.I. Shenavrin, 2006, published in Astronomicheskiĭ Zhurnal, 2006, Vol. 83, No. 5, pp. 437–442.     

Emotion and politics in a mediated public sphere: Questioning democracy,responsibility and ethics in a computer mediated world

This article debates the extent to which particular forums of the internet enable democratic discussions around social and political issues, developing the interest in cyber-geographies from the late 1990s and early 2000s. The paper investigates discussions around abortion in the UK media, and public response(s) to such discussions. The analysis originates from an article written for the Huffington post by political editor Medhi Hasan and deconstructs subsequent reactions to this through mainstream media and news sites, comments pages on these sites, and reactions on Twitter. We assess the democratic potential of these types of media, developing Habermasian notions of the public sphere by analyzing the extent to which specific forums within the internet sphere play a role in facilitating emotions in political discussions. We also discuss the impact of individual narrative and personal perspective and its role within this quasi-political space. In so doing, we question the extent to which these types of ‘new media’, as a forum for public discussion and interaction, enable democratic deliberation by assessing the engagement between users of this sphere, and the nature of those discussions. This presents an assessment of computer mediated communication as a new way of ‘doing’ politics through its absence and presence(s) and through ideas of distance, moral responsibility, and an understanding of ethics and care at-a-distance, presenting a holistic account of how we might envision these debates playing out.