Graphite of the Turgenevskoe and Tamginskoe deposits of the Lesozavodsk area in the Primor’e region

The regional carbonization of the Riphean metamorphic complexes is discussed using as an example the Tamginskoe and Turgenevskoe graphite deposits located in the northern part of the Khanka terrane. It is shown that the noble metal mineralization associates closely with the graphitization. Isotopic, X-ray, and thermal analyses and Raman spectroscopy were first used for investigating the structural state of the graphite with defining its two varieties. The first of them is represented by nanocrystalline fluidogenic graphite that was formed during gas condensate crystallization from deep-seated reduced ore-bearing fluid. The second variety (large-flake graphite) represents a product of metamorphic recrystallization of carbonaceous terrigenous protoliths. The recrystallization was accompanied by the granitization of the sedimentary protolith, mobilization, and the transfer of the carbonaceous and ore matter of the host rocks. It is inferred that the graphitization associated with noble metal mineralization is a polygenic process. The graphite of the first generation associates closely with amorphous diamond-like carbon. This unexpected find may bear genetic information useful for geological and geochemical reconstructions.     

Formation of PGM-Cu-Ni deposits in the process of evolution of flood-basalt magmatism in the Noril’sk region

The timing of the emplacement of ore-bearing melts in the process of evolution of flood-basalt magmatism in the Noril’sk District is discussed. The current models of ore formation consider the emplacement of ore-bearing intrusions either under the conditions of a closed magmatic system as a product of a self-dependent magmatic event, or under the conditions of an open magmatic system, where intrusions are parts of the conduits feeding lava flows. In both cases, the composition of the initial magma, the content of volatile components therein, and the contribution of country rock assimilation are important for the development of a genetic model. The relationships between lavas and intrusions are exemplified in the South Maslov intrusion, which cuts through the rocks of the Nadezhdinsky Formation. No geological evidence for links of lavas to intrusions has been established. Substantial difference in geochemistry (Ti contents, Gd/Yb and La/Sm ratios, etc.) of the tuff and lava sequence on the northern shore of Lake Lama and the Maslov intrusions are demonstrated. It is concluded that the Noril’sk deposits were formed as products of emplacement of self-dependent portion of magma in the post-lower Nadezhdinsky time. The melt composition determined from melt inclusions in olivine corresponds to high-Mg tholeiitic basalt (up to 7–8 wt % MgO) containing up to 1 wt % H₂O and 0.3 wt % Cl and undersaturated with sulfur. The fluid regime of flood-basalt volcanism had no anomalous features—the fluid was aqueous-carbon dioxide. The melts of ore-bearing and barren intrusions had similar concentrations of volatile components. The distribution of major and trace elements in intrusive rocks of the contact zone with the lower part of the Nadezhdinsky Formation characterized by high (La/Sm)_N ratio in comparison with gabbroic rocks (2.8–2.3 and 1.3–1.6, respectively), indicates that contamination of the initial melt only took place in a narrow (1 m) contact zone or did not develop at all. New data on isotopic compositions of Sr (⁸⁷Sr/⁸⁶Sr)₂₅₁ = 0.7089 and Pb (²⁰⁶Pb/²⁰⁴Pb = 20.877–24.528 in anhydrite confirm that local assimilation did not play a substantial role in the formation of rock and ores. On the basis of chemical composition of ore-forming intrusions, their isotopic characteristics, and the composition of melt inclusions in olivine, it is suggested that the lower crustal rocks were a major source of ore-bearing magmas.     

Age of titanium deposits of the northeastern part of the eastern European Platform: Rb—Sr data

Doklady Earth Sciences -     

A new assessment of the Noril’sk type deposits origin

The origin of the Noril’sk and Talnakh sulfide PGE-Cu-Ni deposits that are associated with Triassic basaltic traps of Siberia is considered. It has been shown that ore elements of these deposits (with the probable exception of iron) are of a crustal origin rather than a mantle one. They entered the basalts owing to the remobilization (recycling) of ore elements from Early Proterozoic sediments and rocks that are presented in the basement of the Siberian Craton. The criteria for prospecting for analogous deposits are given.     

The dilemma of the Jiaodong gold deposits: Are they unique?

The ca. 126e120 Ma Au deposits of the Jiaodong Peninsula, eastern China, define the country＇s largest gold province with an overall endowment estimated as＆gt;3000 t Au. The vein and disseminated ores are hosted by NE-to NNE-trending brittle normal faults that parallel the margins of ca. 165e150 Ma, deeply emplaced, lower crustal melt granites. The deposits are sited along the faults for many tens of kilometers and the larger orebodies are associated with dilatational jogs. Country rocks to the granites are Pre-cambrian high-grade metamorphic rocks located on both sides of a Triassic suture between the North and South China blocks. During early Mesozoic convergent deformation, the ore-hosting structures developed as ductile thrust faults that were subsequently reactivated during Early Cretaceous ＂Yan-shanian＂intracontinental extensional deformation and associated gold formation. 〈br〉 Classification of the gold deposits remains problematic. Many features resemble those typical of orogenic Au including the linear structural distribution of the deposits, mineralization style, ore and alteration assemblages, and ore fluid chemistry. However, Phanerozoic orogenic Au deposits are formed by prograde metamorphism of accreted oceanic rocks in Cordilleran-style orogens. The Jiaodong de-posits, in contrast, formed within two Precambrian blocks approximately 2 billion years after devolati-lization of the country rocks, and thus require a model that involves alternative fluid and metal sources for the ores. A widespread suite of ca. 130e123 Ma granodiorites overlaps temporally with the ores, but shows a poor spatial association with the deposits. Furthermore, the deposit distribution and mineral-ization style is atypical of ores formed from nearby magmas. The ore concentration requires fluid focusing during some type of sub-crustal thermal event, which could be broadly related to a combination of coeval lithospheric thinning, asthenospheric upwelling, paleo-Pacific plate subduction, and seismicity along the continental-scale Tan-Lu fault. Possible ore genesis scenarios include those where ore fluids were produced directly by the metamorphism of oceanic lithosphere and overlying sediment on the subducting paleo-Pacific slab, or by devolatilization of an enriched mantle wedge above the slab. Both the sulfur and gold could be sourced from either the oceanic sediments or the serpentinized mantle. A better understanding of the architecture of the paleo-Pacific slab during Early Cretaceous below the eastern margin of China is essential to determination of the validity of possible models.     

In-bearing potential of tin‒sulfide mineralization in ore deposits of the Russian Far East

The increased demand for indium has made it necessary to revise prospects of In-bearing tin ore deposits in the Russian Far East on the basis of geological data and results of recent analytical methods (X-ray fluorescence with synchrotron radiation, atomic absorption, and ICP-MS). The average In contents in ores of the Tigrinoe and Pravourmiiskoe deposits vary from 55 to 70 ppm, which allows tin ore deposits with Sn?sulfide mineralization to be considered as quite promising with respect to In production from ores of Russian deposits. By their estimated In reserves, the Tigrinoe and Pravourmiiskoe deposits may be attributed to large ore objects.     

Extent of underthrusting of the Indian plate beneath Tibet controlled the distribution of Miocene porphyry Cu–Mo ± Au deposits

Miocene igneous rocks in the 1,600 km-long E–W Gangdese belt of southern Tibet form two groups separated at longitude ～89° E. The eastern group is characterized by mainly intermediate–felsic calc-alkaline plutons with relatively high Sr/Y ratios (23 to 342), low (⁸⁷Sr/⁸⁶Sr)_i ratios (0.705 to 0.708), and high εNd_i values (+5.5 to ?6.1). In contrast, the western group is characterized by mainly potassic to ultrapotassic volcanic rocks with relatively high Th and K₂O contents, low Sr/Y ratios (11 to 163), high (⁸⁷Sr/⁸⁶Sr)_i ratios (0.707 to 0.740), and low εNd_i values (?4.1 to ?17.5). The eastern plutonic group is associated with several large porphyry Cu–Mo ± Au deposits, whereas the western group is largely barren. We propose that the sharp longitudinal distinction between magmatism and metallogenic potential in the Miocene Gangdese belt reflects the breakoff of the Greater India slab and the extent of underthrusting by the Indian continental lithosphere at that time. Magmas to the east of ～89° E were derived by partial melting of subduction-modified Tibetan lithosphere (mostly lower crust) triggered by heating of hot asthenospheric melt following slab breakoff. These magmas remobilized metals and volatile residual in the crustal roots from prior arc magmatism and generated porphyry Cu–Mo ± Au deposits upon emplacement in the upper crust. In contrast, magmas to the west of ～89° E were formed by smaller volume partial melting of Tibetan lithospheric mantle metasomatized by fluids and melts released from the underthrust Indian plate. They are less hydrous and oxidized and did not have the capacity to transport significant amounts of metals into the upper crust.     

Radiolarians,foraminifers, and biostratigraphy of the Coniacian–Campanian deposits of the Alan-Kyr Section,Crimean Mountains

Data on the distribution of radiolarians and planktonic and benthic foraminifers are obtained for the first time from the Alan-Kyr Section (Coniacian–Campanian), in the central regions of the Crimean Mountains. Radiolarian biostrata, previously established from Ak-Kaya Mountain (central regions of the Crimean Mountains) were traced: Alievium praegallowayi–Crucella plana (upper Coniacian–lower Santonian), Alievium gallowayi–Crucella espartoensis (upper Santonian without the topmost part), and Dictyocephalus (Dictyocryphalus) (?) legumen–Spongosaturninus parvulus (upper part of the upper Santonian). Radiolarians from the Santonian–Campanian boundary beds of the Crimean Mountains are studied for the first time, and Prunobrachium sp. ex gr. crassum–Diacanthocapsa acanthica Beds (uppermost Santonian–lower Campanian) are recognized. Bolivinoides strigillatus Beds (upper Santonian) and Stensioeina pommerana–Anomalinoides (?) insignis Beds (upper part of the upper Santonian–lower part of the lower Campanian) are recognized. Eouvigerina aspera denticulocarinata Beds (middle and upper parts of the lower Campanian) and Angulogavelinella gracilis Beds (upper part of the upper Campanian are recognized on the basis of benthic foraminifers. These beds correspond to the synchronous biostrata of the East European Platform and Mangyshlak. Marginotruncana coronata-Concavatotruncana concavata Beds (Coniacian–upper Santonian), Globotruncanita elevata Beds (terminal Santonian), and Globotruncana arca Beds (lower Campanian) are recognized on the basis of planktonic foraminifers. Radiolarian and planktonic and benthic foraminiferal data agree with one another. The position of the Santonian–Campanian boundary in the Alan-Kyr Section, which is located stratigraphically above the levels of the latest occurrence of Concavatotruncana concavata and representatives of the genus Marginotruncana, is refined, i.e., at the level of the first appearance of Globotruncana arca. A gap in the Middle Campanian–lower part of the upper Campanian is established on the basis of planktonic and benthic foraminifers. The Santonian–Campanian beds of the Alan-Kyr Section, on the basis of planktonic foraminifers and radiolarians, positively correlate with synchronous beds of the Crimean-Caucasian region, and beyond. Benthic foraminifers suggest a connection with the basins of the East European Platform.     

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

Erratum:Chin. J. of Geochem. DOI: 10.1007/s11631-006-0354-y Table 3 on page 360 is incorrect and should be replaced by the table below.Table 3. The results of analysis of trace elements for the sandstone-type uranium deposit samples from the Ordos Basin (…     

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin

1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen…     

Tectonic controls of the onset of aeolian deposits in Chinese Loess Plateau – a preliminary hypothesis

Previous studies show that the thick aeolian dust deposits in the Chinese Loess Plateau (CLP) have accumulated since the early Miocene or even late Oligocene. They are considered to provide the best terrestrial record for the onset of Asian interior aridification and the evolutionary history of the Asian Monsoon. However, large variability in the basal ages of aeolian deposits makes the aeolian dust depositional history and the controlling dynamics controversial. Here, we present a preliminary hypothesis for the tectonic controls of aeolian dust deposition in the CLP by connecting the two main uplift events of the Tibetan Plateau and the regional tectonic events with the aeolian dust accumulation history. Regional tectonic events in the Ordos Block (the basement of the CLP) during the late Cenozoic are less recognized as controlling aeolian dust accumulation by sculpting the surface landscape. The stable tectonic environment of the Ordos Block since the late Miocene might have been the main controlling factor that enabled the widespread deposition of the aeolian red clay after ~8 Ma. Here, we hypothesize that because the large-scale monsoon system and central Asian aridity had existed since at least the early Miocene, the accumulation and preservation of aeolian deposits within the CLP are actually largely controlled by the regional tectonic environment and less by climatic factors.     

Tourmaline from deposits of the Birgil’da-Tomino ore cluster, South Urals

Tourmalines from the Kalinovka porphyry copper deposit with epithermal bismuth-gold-basemetal mineralization and the Michurino gold-silver-base-metal prospect have been studied in the South Urals. Tourmaline from the Kalinovka deposit occurs as pockets and veinlets in quartz-sericite metasomatic rock and propylite. The early schorl-“oxy-schorl” [Fe_tot/(Fe_tot + Mg) = 0.66?0.81] enriched in Fe³⁺ is characterized by the homovalent isomorphic substitution of Fe³⁺ for Al typical of propylites at porphyry copper deposits. The overgrowing tourmalines of the second and third generations from propylite and quartz-sericite metasomatic rock are intermediate members of the dravite-magnesio-foitite solid solution series [Fe_tot/(Fe_tot + Mg) = 0.05?0.46] with homovalent substitution of Mg for Fe²⁺ and coupled substitution of ^X _? + ^YAl for ^XNa + ^YMg. These substitutions differ from the coupled substitution of ^YAl + ^WO^2? for ^YFe²⁺ + ^WOH^? in tourmaline from quartz-sericite rocks at porphyry copper deposits. At the Michurino prospect, the tourmaline hosted in the chlorite-pyrite-quartz veins and veinlets with Ag-Au-Cu-Pb-Zn mineralization is an intermediate member of the dravite-magnesio-foitite solid solution series [Fe_tot/(Fe_tot + Mg) = 0.20?0.31] with homovalent substitution of Mg for Fe²⁺ and coupled substitutions of ^X _? + ^YAl for ^XNa + ^YMg identical to that of late tourmaline at the Kalinovka deposit. Thus, tourmalines of the porphyry and epithermal stages are different in isomorphic substitutions, which allow us to consider tourmaline as an indicator of super- or juxtaposed mineralization.     

Seismic stratigraphy of the Upper Quaternary deposits on the northeastern slope of the Ceará Rise (Central Atlantic)

This study is focused on interpretation of ultrahigh-resolution seismoacoustic data from the northeastern slope of the Ceará Rise (Central Atlantic) acquired using the SES 2000 deep parametric narrow-beam subbottom profiler during cruise 35 of RV Akademik Ioffe in 2011. The geologic nature of most of the detected reflectors is constrained by correlation of the results of seismoacoustic profiling with core data collected in frame of the Ocean Drilling Program (ODP site 929A-E). Detailed seismostratigraphic study of the Upper Quaternary deposits in the study area has implications for better understanding of the role of gravity flows and bottom currents in sedimentation on the NE slope of the rise for the past 1.2 Myr.     

Particle size composition of Holocene–Pleistocene deposits of the Laptev Sea (Buor-Khaya Bay)

New data on the particle size composition of the Laptev Sea shelf deposits were obtained on the basis of results of low-angle laser light-scattering of core samples from the columns studied. It was revealed that the sand fraction dominates. The results of comparative analysis of the particle size composition of deposits show that the Laptev Sea shelf zone was characterized by highly variable spatial–temporal conditions and settings of sedimentation in the Quaternary, a polygenic character of deposits, and a pulsating influence of fluvial and slope processes on the conditions of sedimentation. A tendency of coarsening in the vertical sequence that contributes to thawing of the permafrost was revealed in the Ivashkina lagoon.     

Formation of magnesite and siderite deposits in the Southern Urals—evidence of inclusion fluid chemistry

World-class deposits of magnesite and siderite occur in Riphean strata of the Southern Urals, Russia. Field evidence, inclusion fluid chemistry, and stable isotope data presented in this study clearly proof that the replacement and precipitation processes leading to the formation of the epigenetic dolomite, magnesite and hydrothermal siderite were genetically related to evaporitic fluids affecting already lithified rocks. There is, however, a systematic succession of events leading to the formation of magnesite in a first stage. After burial and diagenesis the same brines were modified to hot and reducing hydrothermal fluids and were the source for the formation of hydrothermal siderite. The magnesites of the Satka Formation as well as the magnesites and the siderites of the Bakal Formation exhibit low Na/Br (106 to 222) and Cl/Br (162 to 280) ratios plotting on the seawater evaporation trend, indicating that the fluids acquired their salinity by evaporation processes of seawater. Temperature calculations based on cation exchange thermometers indicate a formation temperature of the magnesites of?~?130 °C. Considering the fractionation at this temperature stable isotope evidence shows that the magnesite forming brines had δ¹⁸O_SMOW values of?~?+1 ‰ thus indicating a seawater origin of the original fluid. Furthermore it proves that these fluids were not yet affected by appreciable fluid-rock interaction, which again implies magnesite formation in relatively high crustal levels. In contrast to the magnesites, the siderite mineralization was caused by hydrothermal fluids that underwent more intense reactions with their host rocks in deeper crustal levels compared to the magnesite. The values of ⁸⁷Sr ^/86Sr in the siderites are substantially higher compared to the host rock slates. They also exceed the ⁸⁷Sr ^/86Sr ratios of the magnesites and the host rock limestones indicating these slates as the source of iron as a consequence of water-rock interaction. The siderites were formed at temperatures of?~?250 °C indicating a relatively heavy fluid in equilibrium with siderite of 13 ‰ δ¹⁸O_SMOW, which is in the range of diagenetic/metamorphic fluids and reflects the?±?complete equilibration with the host rocks. Carbon isotope evidence shows that the fluid forming the siderites underwent a much higher interaction with the host rocks resulting in a lowering of the δ¹³C numbers (?3,3 to ?3,7 ‰). The light carbon was most probably derived from decaying hydrocarbons in the Riphean sediments. In a very early stage after sedimentation of the Satka Formation (~1,550 Ma) magnesite was formed by seepage reflux of evaporitic bittern brines at the stage of riftogenic activity in the region (1,380–1,350 Ma). Sedimentation of the Bakal Formation (~1,430 Ma) and intrusion of diabase dykes (1,386?±?1,4 Ma) followed. Diagenetic/epigenetic mobilization of these buried fluids at?~?1,100 Ma resulted in the formation of hydrothermal siderite bodies.     

Geophysical properties of zinc‐bearing deposits

At present, most, if not all zinc is being produced from the mineral sphalerite. With the exception of its piezoelectricity and in some cases its density, sphalerite has no salient physical properties to routinely allow its direct detection by geophysical methods. Although the mineral usually occurs with other sulfides, which do respond to various geophysical techniques, detection of zinc‐bearing deposits is often difficult. In this paper, physical property measurements from numerous, mainly Australian, deposits are presented, together with examples from various geophysical surveys. The results are used to suggest the most effective geophysical technique for the direct detection of the different types of zinc‐bearing deposits. Induced polarisation is probably the most effective technique for unmetamorphosed sediment‐hosted deposits and for carbonate‐hosted deposits, whereas electromagnetics is usually the most appropriate method to use for volcanic‐hosted deposits and for sediment‐hosted deposits that have been strongly metamorphosed. Magnetics is the best technique for skarn and ‘Cobar‐style’ deposits. However, it must be emphasised that usually more than one geophysical technique is required before a prospect can be considered to have been thoroughly explored.     

A comparative study of uranium–thorium accumulation at the western edge of the Arabian Peninsula and mineral deposits worldwide

Jordan, located at the western edge of the Arabian Plate, stands out from the remaining part of the Arabian Peninsula by its abundance in radioactive elements, mainly uranium, in a way so far not found elsewhere on the Arabian Peninsula. Uranium (U) and thorium in Jordan are concentrated in eight different types of ore mineralization: (1) intrusive-related (intramagmatic), (2) vein-type, (3) superficial, (4) sandstone-hosted (5) limestone-hosted, (6) U-Th-REE placer-type, (7) black shales, and (8) phosphorites. The major concentration of radioactive elements are synsedimentary and diagenetic in nature, mainly in near-shore marine depositional environments where uranium contents are abnormally high in the late Cretaceous to Paleogene phosphorites and increasing towards the mobile shelf of the Tethys ocean. These uraniferous phosphorites form the source of uranium that was redeposited within terrigenous chemical residues of lacustrine-fluvial depositional systems in Central Jordan (calcretes). Faultbound radiometric anomalies are caused by hot brines being vented along with the Jordan-Dead-Sea rifting. Presumably, low-grade U accumulation in (hot) black shales and marls of Silurian age are responsible for these radiometric anomalies. In the present paper, the Jordanian uranium concentrations are compared with reference types of uranium deposits elsewhere in the world to get an idea if the geological, chemical, and mineralogical features of analogue uranium mineralization in Jordan are indicative of economic targets. The uranium concentration in Jordanian phosphorites has been tracked beyond the border into Syria, Iraq, Israel, and Saudi Arabia. The uranium potential in neighboring countries is assessed based on the current geological data available for the Mediterranean Phosphorite Belt which is poised to become a another string to the bow with respect to energy supply on the Arabian Peninsula.     

The Bagassi gold deposits on the eastern margin of the Houndé greenstone belt,Burkina Faso

The Bagassi gold deposits are situated on the West African craton and hosted in Palaeoproterozoic rocks of the Houndé greenstone belt, southwest Burkina Faso. High-grade gold mineralisation is hosted in quartz–gold ± pyrite veins-lodes (V_1A), in dilational zones and narrow shears in the Bagassi granitoid, and forms the majority of the resource–reserve portfolio in the Bagassi exploration permits, with gold grades of 18–21 g/t. Shear hosted gold-pyrite mineralisation in quartz veins in dilational jogs (V_1B) occurs along narrow discontinuous shear zones that trend north-northwest in Birimian-aged metabasaltic units, and forms a secondary gold resource. Gold mineralisation is restricted to formation in the late Eburnean Orogeny and formed during a change from east-west to transcurrent compression and shearing. The Bagassi deposits demonstrate that granitoids emplaced prior to onset of the Eburnean Orogeny represent viable gold mineralisation in host rocks that are increasingly seen to be associated with significant gold resources.     

Geochemical features and sources of clastic material in Paleozoic terrigenous deposits of the northeastern flank of the South Mongolia–Khingan orogenic belt

The results of geological and geochemical studies of terrigenous rocks of the main stratigraphic subdivisions in the northeastern flank of the South Mongolia–Khingan orogenic belt and also the results of U-Pb (LА-ICP-MS) geochronological studies of detrital zircons from these deposits are presented. It is demonstrated that the studied rocks differ significantly in the nature of distribution of detrital zircon ages and, consequently, they cannot be members of a single sedimentary sequence. The data obtained confirm the standpoint according to which the northeastern flank of the South Mongolia–Khingan orogenic belt represents a “joint” zone separating the Argun and the Bureya-Jiamusi Superterranes. This joint zone was formed as the result of closure of the oceanic basin separating the specified continental massifs in the Paleozoic era. The geochemical features of the studied rocks indicate their formation in the conditions of the island arc or the active continental margin. Lack of zircon generations younger than Ordovician age in the studied samples allows assuming that the sedimentary sequences identified within the northeastern flank of the studied belt as the Necla, Dagmara, siltstone-sandstone, and Gramatukha sequences that formed from the end of the Vendian (?) to the Devonian correspond to the youngest stages of belt formation. These sediments in the current structural plan evidently represent fragments of accretion complexes cropping out in fragments among the Cenozoic sequences of the Amur-Zeya Depression.