DISTRIBUTION OF DISSOLVED AND PARTICULATE TRACE METALS IN ANOXIC SEAWATER, SAANICH INLET, B . C. CANADA

This paper discusses the spatial and seasonal distribution character of dissolved and paniculate trace metals in the anoxic seawater of Saanich Inlet, B.C., Canada. The study showed that concentration of dissolved and paniculate trace metals in anoxic seawater is closely related to (1) the concentration of H2S and the depth of the O2-H2S interface, (2) the exchange of seawater in Saanich Inlet with outside seawater, (3) biotic action, and (4) the flushing event. The study was based in part on the ratio between trace metals and nutrients. There was a steep change in the concentration of dissolved trace metals at the O2-H2S interface. The concentration of dissolved trace metals in the H2S-controlled zone was dependent on the H2S there. The suspended matter in Saanich Inlet comes from the Hero Strait seawater, phytoplankton production and resuspension of flushed-up sediments. The concentration of particulate trace metals was rather low in Saanich Inlet and tended to increase with depth. The total concentra     

Investigation on the interaction between trace metals and humic acid in seawater

The interactions between trace metals and humic acid in seawater influence the metal species distribution and the various geochemical pathways. An approach for investigating these interactions based on stripping polarography is proposed. The basic principle is that the half-wave potentials of the stripping polarogram shift negatively with the increase of concentrations of humic acid. From the results of calculation, it may be concluded that the species of Pb-HA complex is less than 5% of total lead in seawater but has significant percentage in estuary, and that Pb-HA complex exists mainly as 1∶1 form. Contribution No. 1509 from the Institute of Oceanology, Academia Sinica     

Study on Dissolved Trace Metals in Sea Surface Microlayer in Daya Bay

Glass-plate sampling during 1988- 1999 in Daya Bay and suitable corresponding analytical methods were used for the measurement of dissolved trace metals, dissolved organic carbon, biological oxygen demand, chemical oxygen demand, salinity of the sea surface mierolayer and subsurface water. Apparent enrichment mechanism and diurnal variation have been revealed for dissolved trace metals in the microlayer in Daya Bay. The more dissolved organic matter was enriched in the sea surface microlayer, the more dissolved trace metals were enriched in the layer. The organic matter played an important role in the enrichment process. The diurnal variations of dissolved trace metals showed that their concentration was apparently inversely related to the tide activity that the concentration was low during rising tide, but high during falling tide. The behavior of dissolved trace metals expressed by the diurnal variation was clearly opposite to that of salinity.     

Partitioning of grain-size components of estuarine sediments and implications for sediment transport in southwestern Laizhou Bay, China

Sediment transport in estuarine systems has been of increasing interest for scientists during the past few decades. However, the mechanisms for sediment redistribution remain unclear. We characterized in detail sediment transport in the Xiaoqing River estuary using the mathematical Weibull function to partitiongrain-size components of surface sediments in the southwestern Laizhou Bay, Northeast China. Four partitioned components: finer than 4, 4.6–12.5, 23.4–63.3, and 67.1–132.6 μm were interpreted in terms of hydrodynamic conditions. During sediment transport, silt grains were suspended and moved seaward from three depositional centers, whereas fine-grained sands moved generally landward. Overall, sediments are transported clockwise in a generally NNE direction near shore and then turn eastward offshore. The mathematical partitioning method showed a great potential for future estuarine environmental studies.     

Ecological risk assessment of heavy metals in surface seawater and sediment near the outlet of a zinc factory in Huludao City,Liaoning Province,China

At present, the methods widely applied to assess ecological risk of heavy metals are essentially single-point estimates in which exposure and toxicity data cannot be fully used and probabilities of adverse biological eff ects cannot be achieved. In this study, based on investigation of concentrations of six heavy metals (As, Hg, Pb, Cd, Cu, and Zn) in the surface seawater and sediment near the outlet of a zinc factory, located in Huludao City, Liaoning Province, China, a tiered approach consisting of several probabilistic options was used to refine ecological risk assessment for the individuals. A mixture of various heavy metals was detected in the surface seawater, and potential ecological risk index (PERI) was adopted to assess the potential ecological risk of heavy metals in the surface sediment. The results from all levels of aquatic ecological risk assessment in the tiered framework, ranging from comparison of single eff ects and exposure values to the use of distribution-based Hazard Quotient obtained through Monte Carlo simulation, are consistent with each other. Briefly, aquatic Zn and Cu posed a clear ecological risk, while Cd, Pb, Hg, and As in the water column posed potential risk. As expected, combined ecological risk of heavy metal mixture in the surface seawater was proved significantly higher than the risk caused by any individual heavy metal, calculated using the concept of total equivalent concentration. According to PERI, the severity of pollution by the six heavy metals in the surface sediment decreased in the following sequence: Cd>Hg>As>Pb>Cu>Zn, and the total heavy metals in the sediment posed a very high risk to the marine environment. This study provides a useful mathematical framework for ecological risk assessment of heavy metals.     

Estimation of extreme marine hydrodynamic variables in western Laizhou Bay

Laizhou Bay and its adjacent waters are of great importance to China's marine oil and gas development. It is therefore crucial to estimate return-period values of marine environmental variables in this region to ensure the safety and success of maritime engineering and maritime exploration. In this study, we used numerical simulations to estimate extreme wave height, sea current velocity and sea-level height in western Laizhou Bay. The results show that the sea-level rise starts at the mouth of the bay, increases toward west/southwest, and reaches its maximum in the deepest basin of the bay. The 100-year return-period values of sea level rise can reach 3.4–4.0 m in the western bay. The elevation of the western part of the Qingdong Oil Field would remain above the sea surface during extreme low sea level, while the rest of the oil field would be 1.6–2.4 m below the sea surface. The return-period value of wave height is strongly affected by water depth; in fact, its spatial distribution is similar to the isobath's. The 100-year return-period values of effective wave height can be 6 m or higher in the central bay and be more than 1 m in the shallow water near shore. The 100-year return-period values of current velocity is about 1.2–1.8 m s-1 in the Qingdong Oil Field. These results provide scientific basis for ensuring construction safety and reducing construction cost.     

A model study on dynamical processes of phytoplankton in Laizhou Bay

A three-dimensional ecosystem model, using a PIC (Particle-In-Cell) method, is developed to reproduce the annual cycle and seasonal variation of nutrients and phytoplankton biomass in Laizhou Bay. Eight state variables, i.e., DIN (dissolved inorganic nitrogen), phosphate, DON (dissolved organic nitrogen), DOP (dissolved organic phosphorus), COD (chemical oxygen demand), chlorophyll-a (Chl-a), detritus and the zooplankton biomass, are included in the model. The model successfully reproduces the observed temporal and spatial variations of nutrients and Chl-a biomass distributions in the bay. The nutrient concentrations are at high level in winter and at low level in summer. Double-peak structure of the phytoplankton (PPT) biomass exists in Laizhou Bay, corresponding to a spring and an autumn bloom respectively. Several numerical experiments are carried out to examine the nutrient limitation, and the importance of the discharges of the Yellow River and Xiaoqinghe River. Both DIN limitation and phosphate limitation exist in some areas of the bay, with the former being more significant than the latter. The Yellow River and Xiaoqinghe River are the main pollution sources of nutrients in Laizhou Bay. During the flood season, the algal growth is inhibited in the bay with the Yellow River discharges being excluded in the experiment, while in spring, the algal growth is enhanced with the Xiaoqinghe River excluded.     

SEAWATER INTRUSION TYPES AND REGIONAL DIVISIONS IN THE SOUTHERN COAST OF LAIZHOU BAY

The southern coast of Laizhou Bay, Bohai Sea, is one of the areas in China most seriously impacted by seawater intrusion. Based on the sources of intruding waterbedies, seawater intrusion can be divided into two types: intrusion of saline water derived from modern seawater, and intrusion of subsurface brine and saline water derived from paleo-seawater in shallow Quaternary sediments. There are some distinct differences in their formation, mechanism and damage. The subsurface brine intrusion is a special type, which can cause very serious disaster. The coastal landform and the Quaternary hydrogeological environment are predominant factors in the classification of seawater intrusion types. Various coastal environments in different coastal sections result in three types of intrusion: seawater intrusion, saline groundwater intrusion, and mixed seawater and saline water intrusion, in the southern coast of Laizhou Bay, which can be divided into four areas: the sea-water intrusion area in the northern Laizhou City coast, the mixed seawater and saline groundwater intrusion area in the Baisha River-Jiaolai River mouth plain area, the mixed seawater and saline groundwater intrusion area in the Weihe River mouth plain area northern Changyi county coast, and the saline ground-water intrusion area in the northern Shouguang plains.     

Spatial variations in depth-distribution of trace metals in coastal wetland sediments from Quanzhou Bay, Fujian Province, China

Four short cores were obtained from the coastal wetland of the Quanzhou Bay, Fujian Province, China, and sediment samples were analyzed with a Mastersizer 2000 for grain size analysis and an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) for trace metal analysis. The results of grain size analysis show that the wetland sediments are mainly composed of silt and clay, and the distribution of median grain size is affected by human activities obviously. The results of trace metal analysis show that the wetland sediments mainly originate from terrestrial materials in the Luoyangjiang River estuary and from contaminants discharged from adjacent rivers in Shuitou area. The heavy metal contamination in Luoyangjiang estuary decreased from 1984 to 2004 due to industry transformation, but has increased since 2004 because of the discharge of contaminants to the Jinjiang River and much living sewerage to the bay, and a large number of trace metals are trapped within Spartina alterniflora marsh.     

Macrobenthic community in the Xiaoqing River Estuary in Laizhou Bay, China

The macrobenthic community of the Xiaoqing River Estuary and the adjacent sea waters was investigated in May and November 2008, August 2009, and May and September 2010, respectively. A total of 95 species of macrobenthos were identified in the five cruises and most of them were polychaetes (46.39%), mollusks (28.86%) and crustaceans (20.62%). The Shannon-Wiener index of macrobenthos was lower than 2 in 67% sites. Along the stream channel, estuary and the coastal waters, the species of polychaetes reduced gradually, while the abundance increased at first and then decreased. The abundance was the biggest at regions with salinity of 5–20 in the estuary. The species and abundance of mollusks and crustaceans increased gradually. As for seasonal distribution, the species, abundance and biomass were higher in spring and lower in summer and autumn. Contemporaneously compared with Laizhou Bay and Yellow River Estuary, the species of macrobenthos appeared in the Xiaoqing River Estuary were much less, while the percentage of polychaetes was higher. Abundance and biomass were higher in Xiaoqing River estuary, then consequently followed by Laizhou Bay and Yellow River Estuary. The dominant species in Xiaoqing River Estuary was polychaete, and Layzhou Bay mollusk. The community structure characteristics of macrobenthos in the Xiaoqing River Estuary revealed a significant pollution status in this region.     

莱州湾滨海地区饱和液化砂土特征及液化评价

通过对区内257个钻孔(工程地质孔及第四纪地质孔)资料分析,划分了莱州湾滨海地区地貌单元,阐述了全新世砂体特征;利用三角洲平原区砂性土层非饱和砂土和饱和砂土静探数据和标贯数据的对比分析,采用数理统计方法,建立了非饱和砂土对饱和砂土的静探锥尖阻力与锥尖阻力、标贯击数与标贯击数的相关关系式,研究了地下水对静探锥尖阻力和标贯击数的影响;依据《建筑抗震设计规范》(GB50011-2010),采用标准贯入和静力触探综合判别法,对全新世砂体进行现状条件下和未来地下水限采条件下砂土液化判别;并针对液化区不同液化条件提出相应砂土液化防御措施。     

莱洲湾南岸滨海湿地生物多样性及生态地质环境

莱州湾南岸滨海湿地作为环渤海滨海湿地的一部分,具有海洋与河口交互性、海陆过渡性和生态脆弱性等特点,湿地面积广阔、资源丰富,是东北亚环西太平洋鸟类迁徙的重要“中转站”及越冬、栖息和繁殖地。湿地总面积为1150．079km^2,湿地维管束植物区系包括维管束植物53科144属217种。近年来,在对滨海湿地的开发中,虾池、盐田等人工湿地面积不断扩大,造成自然湿地面积减小、植被退化、地貌和水文条件改变、生物多样性下降,改变了原始的滨海湿地自然景观,破坏了珍稀鸟类的生存环境。     

Zinc and copper bioaccumulation in fish from Laizhou Bay,the Bohai Sea

Abstract Zinc （Zn） and copper （Cu） concentrations were determined in the tissues （muscle, stomach, liver, gills, skin, and gonads） of five commercial fish species （mullet Liza haematocheilus, flathead Platycephalus indicus, mackerel Scomberomorus niphonius, silver pomfret Pampus argenteus, and sea bass Lateolabrax japonicus） from Laizhou Bay in the Bohai Sea. Metal bioaccumulation was highest in the metabolically active tissues of the gonads and liver. Bioconcentration factors for Zn were higher in all tissues （gonads 44.35, stomach 7.73, gills 7.72, liver 5.61, skin 4.88, and muscle 1.63） than the corresponding values for Cu （gonads 3.50, stomach 3.00, gills 1.60, liver 5.43, skin 1.50, and muscle 0.93）. Mackerel tissues accumulated metal to higher concentrations than did other fish species, but bioaccumulation levels were not significantly correlated with the trophic levels of the fish. Zn and Cu concentrations in the tissues were generally negatively correlated with fish length, except for a few tissues of sea bass. Risk assessment based on national and international permissible limits and provisional tolerances for weekly intake of Zn and Cu revealed that the concentrations of these two metals in muscle were relatively low and would not pose hazards to human health.     

Three tropical seagrasses as potential bio-indicators to trace metals in Xincun Bay, Hainan Island, South China

Concentrations of the trace metals Cu,Cd,Pb,and Zn were measured in seawater,rhizosphere sediments,interstitial water,and the tissues of three tropical species of seagrasses (Thalassia hemprichii,Enhalus acoroides and Cymodocea rotundata) from Xincun Bay of Hainan Island,South China.We analyzed different environmental compartments and the highest concentrations of Pb and Zn were found in the interstitial and seawater.The concentrations of Cd and Zn were significantly higher in blades compared with roots or rhizomes in T.hemprichii and E.acoroides,respectively.A metal pollution index (MPI) demonstrated that sediment,interstitial water,and seagrasses in the sites located nearest anthropogenic sources of pollution had the most abundant metal concentrations.There was obvious seasonal variation of these metals in the three seagrasses with higher concentrations of Cu,Pb and Zn in January and Cd in July.Furthermore,the relationships between metal concentrations in seagrasses and environmental compartments were positively correlated significantly.The bioconcentration factors (BCF) demonstrated that Cd from the tissues of the three seagrasses might be absorbed from the sediment by the roots.However,for C.rotundata,Zn is likely to be derived from the seawater through its blades.Therefore,the blades of T.hemprichii,E.acoroides and C.rotundata are potential bio-indicators to Cd content in sediment,and additionally Zn content (C.rotundata only) in seawater.     

Taxonomic distinctness of macrofauna as an ecological indicator in Laizhou Bay and adjacent waters

In this paper, we assessed the ecological and biodiversity status in the Bohai Sea through a quantitative survey on mac-rofaunal community at 25 stations in Laizhou Bay and adjacent waters in the autumn of 2006.We tested the robustness and effectiveness of taxonomic distinctness as an ecological indictor by analyzing its correlation with species richness and natural environmental variables and by analyzing other ecological indicators (Shannon-Wiener H' and W statistics from Abundance Biomass Comparison curve).Results so obtained indicated that the benthic environment of the study waters in general is not under major impact of anthropogenic disturbance, but some stations in Laizhou Bay and along the coast of the Shandong Peninsula and even in the central Bohai Sea might be moderately disturbed and showed signs of ecological degradation.The taxonomic distinctness measures △+ and Λ+ were independent of sampling effort and natural environment factors and were compliant to other ecological indicators.Further application of the taxonomic distinctness indicator to assess marine biodiversity and ecosystem health on a larger regional scale with historical data seems promising.     

Estimates of autumntime benthic secondary production in Laizhou Bay and adjacent Bohai Sea waters

The whole metazoan community inhabiting Laizhou Bay and adjacent Bohai Sea waters were sampled in late autumn,2006.Secondary production estimates for macrofauna and meiofauna were made separately.Total benthic secondary production was as high as 8.38 ± 4.08 g ash-free dry weight(AFDW) m-2 a-1,which represented the autumn production level.In general,macrofaunal secondary production in Laizhou Bay was much lower than that in adjacent Bohai Sea areas.In contrast,meiofaunal secondary production in Laizhou Bay was higher than that in adjacent Bohai Sea areas.Macrofauna contributed 61% to benthic secondary production(5.09 ± 3.26 g AFDW m-2 a-1),lower than the value in previous studies in Bohai Sea.Sediment granulometric characteristics and bottom-water salinity could explain the substantial variability in the macrofauna biomass and production.Meiofaunal production was an important component of benthic production and exceeded macrofauna production under exceptional conditions,e.g.in Laizhou Bay,where macrofauna was restricted.Chlorophyll pigments(Chl-a) concentrations in sediment explained the general meiofaunal biomass and production distribution here.     

莱州湾凹陷东部走滑带盐相关构造特征

通过对盐相关构造变形样式的探讨,证明莱州湾凹陷东部走滑带盐相关构造的形成受到走滑作用和重力流动作用控制,以盐层沿层流动为主要特征,由南至北,盐层逐渐由过成熟底辟向盐枕过渡。莱州湾凹陷东部走滑带盐上构造有盐上断裂背斜、盐撤凹陷、龟背构造、翼部地层超覆和盐体遮挡构造;盐层构造有枕状底辟、盐株和外来盐席;推测盐下构造有早期古隆起。盐相关构造经历了发育-调整-成熟-再活动4个主要阶段。盐上构造圈闭控制了莱州湾凹陷东部走滑带的油气聚集。     

The land-sourced pollution in the Jiaozhou Bay

In recent years, natural environment of the Jiaozhou Bay has been changed largely by fast developing industry and agriculture of the cities around, from which wastewaters were generated. The size of the bay has been continuously shrunk with reduced river flows, resulting in serious contamination to the marine lives in the bay. After analyzing the basic historical data, the authors put forward a suggestion of how to protect the bay ecology for sustaining the resources in the Jiaozhou Bay.     

Modelling nitrogen and phosphorus dynamics in a mesocosm pelagic ecosystem in Laizhou Bay in China

A model of nitrogen and phosphorus dynamics in mesocosm experiments was established on the basis of a summary and synthesis of the existing models. The established model comprised seven state variables(DIN,PO4-P,DON,DOP,phytoplankton,zooplankton and detritus) and five modules - phytoplankton,zooplankton,dissolved inorganic nutrients,dissolved organic nutrients and detritus. Comparison with the in situ experimental data in Laizhou Bay at the end of August 2002 showed that this model could properly simulate t...