The Effect of Water Dynamics on the Hydrochemical Structure in the Northeastern Black Sea

The results of hydrophysical and hydrochemical monitoring in the northeastern Black Sea and the results of Black Sea-99 expedition conducted in the autumn of 1999 are discussed. Examination was made to analyze the basic features of the climatic vertical hydrochemical structure, seasonal variations in the fields using the data of sections from the shore to the center of the sea, and the vortex-related variations assessed based on the data of area surveys.     

Ra in the Black Sea and Sea of Marmara

Water column distributions of²²⁶Ra were determined at stations in the Sea of Marmara and the Black Sea as part of the 1988 Joint U.S.—Turkish Black Sea Expedition. Black Sea surface water²²⁶Ra concentrations were a factor of three to four lower than measurements made 20 years earlier. The most likely cause is increased removal of²²⁶Ra and Ba [35] due to increased surface biological activity; a secondary effect is decreased fluvial discharge and related dimunition of inputs by desorption from fluvial suspended sediments. The amount of²²⁶Ra missing from the surface waters of the Black Sea over this period is accounted for in the high-porosity surficial “fluff” sediment layer.

Throughout the Black Sea, depth profiles of²²⁶Ra exhibited pronounced maxima of approximately 25 dpm/100 L at aboutσ_θ = 16.2–16.3, in the vicinity of a bacterial maximum, but slightly shallower than the total dissolved Mn and Fe maxima (σ_θ = 16.4–16.5) reported by Lewis and Landing [38]. While the²²⁶Ra maximum may, in part, be linked to the cycling of Mn and Fe oxyhydroxides near theO₂H₂S interface, its distribution appears to be more plausibly explained as a result of the microbial breakdown of particulate organic matter and the subsequent release and partial dissolution of associated barite in this region.

A simple steady-state two-☐ model has been used to obtain a semiquantitative understanding of the behavior of²²⁶Ra in the Black Sea. By incorporating reasonable estimates for the input and removal of²²⁶Ra in the Black Sea, an excellent agreement between predicted and observed (1988)²²⁶Ra concentrations was achieved. The model suggests that the dominant variables controlling the distribution of²²⁶Ra in the Black Sea are riverine input and cycling with Ba.     

Particle Size Distribution Analysis of Chemical Oxygen Demand Fractions with Different Biodegradation Characteristics in Black Water and Gray Water

The study investigated the particle size distribution of major organic pollutants in black water and gray water fractions of domestic sewage. Particle size distribution was assessed by means of a filtration/ultrafiltration sequence together with laser diffraction. Emphasis was placed upon the correlation between the size distribution of chemical oxygen demand (COD) and its biodegradation characteristics obtained by respirometric analysis. Particle size distribution analysis provided specific fingerprints for COD, total organic carbon (TOC), carbohydrates, proteins, and color for black water and gray water: Aside from significant difference between COD contents, the more concentrated COD was predominantly in particulate form in black water, whereas soluble COD accounted for nearly 60% of the total in gray water. TOC and carbohydrate exhibited a similar pattern. Size distribution of particulate matter yielded different characteristics for the two fractions and indicated that settleable matter should be considered as a significant portion in assessing biodegradation. Particle size distribution of COD, although not directly related, gave an accurate image of biodegradation, indicating that particle size was basically the main parameter for differentiating and predicting major COD fractions with different biodegradation characteristics. It explained the dual hydrolysis mechanism associated with the black water based on the existence of a significant settleable COD fraction.     

Remediation of Sea Water Intrusion: A Case Study

Sea water intrusion and remediation in the Upper Floridan Aquifer in South Carolina is simulated using the finite-element model SUTRA developed by the U.S. Geological Survey. A sensitivity analysis of the effect of the hydrogeologic parameters on the sea water recharge and seepage velocities is performed. An increase in confining unit and/or in aquifer conductivity results in an increase of the sea water recharge. An increase in aquifer porosity results in a decrease of the sea water recharge. Among the three remedial techniques simulated—reduced aquifer withdrawals, an injection well, and a combined injection and capture well—the reduced aquifer withdrawals and injection well are the best methods for preventing sea water intrusion.     

Water intrusions and particle signatures in the Black Sea: a Biogeochemical-Argo float investigation

Continuous observations during 3 years with a vertical resolution of 1 dbar from two Bio-Argo floats in the Black Sea that were equipped with oxygen optodes, chlorophyll fluorometers, and backscattering sensors are analyzed. The particle backscattering coefficient, b _bp provides a proxy for the concentration of suspended particles. The observations clearly identify thermal and b _bp intrusions down to ~700–800 m in the Bosporus inflow area. In this area, b _bp is more than five times larger than elsewhere, which could indicate bacterial abundance and possible biological involvement in the precipitation of Mn-containing particles. The b _bp anomalies become much shallower than the temperature anomalies with increasing distance to the east of the strait. Their maxima are located between the onset of the suboxic zone and the upper part of the anoxic layer. Unlike well-known intrusions that are caused by inflow, open ocean intrusions are shallower and often characterized by multiple layers of backscatter maxima with thicknesses of only 15–20 m. The ratio between backscattering coefficients measured at two wavelengths, which gives a proxy for particle size, shows that the relative amount of larger size particles in the anoxic layer increases with depth. The particle concentrations and their size distribution display different vertical variability, which indicates the complex transformation of biological matter. The lower concentration of particles and lower chlorophyll-a during the extremely warm 2016 reveals an overall positive correlation between the two properties. The trends in the particle backscattering coefficient in the suboxic zone during 2013–2016 could indirectly reveal a biogeochemical response to temperature changes.     

Paleohydrology of the Black Sea Pleistocene Basins

The history of the Black Sea Pleistocene basins, whose paleohydrologic and faunistic characteristics markedly differ, is discussed. A distinct hierarchy of rhythms is established in the variations in the levels of the water bodies.     

Hydrodynamic modelling of mesoscale eddies in the Black Sea

A three dimensional structure of mesoscale circulation in the Black Sea is simulated using the Proudman Oceanographic Laboratory Coastal Ocean Modelling System. A number of sensitivity tests reveal the response of the model to changes in the horizontal resolution, time steps, and diffusion coefficients. Three numerical grids are examined with x-fine (3.2 km), fine (6.7 km) and coarse (25 km) resolution. It is found that the coarse grid significantly overestimates the energy of the currents and is not adequate even for the study of basin-scale circulation. The x-fine grid, on the other hand, does not give significant advantages compared to the fine grid, and the latter is used for the bulk of simulations. The most adequate parameters are chosen from the sensitivity study and used to model both the basin-scale circulation and day-to-day variability of mesoscale currents for the months of May and June of 2000. The model is forced with actual wind data every 6 h and monthly climatic data for evaporation, precipitation, heat fluxes and river run-off. The results of the fine grid model are compared favourably against the satellite imagery. The model adequately reproduces the general circulation and many mesoscale features including cyclonic and anticyclonic eddies, jets and filaments in different parts of the Black Sea. The model gives a realistic geographical distribution and parameters of mesoscale currents, such as size, shape and evolution of the eddies.     

The Effect of Plunging Water of Waves on the Entrainment of Spilled Oil at Sea

Water Resources - The study of oil entrainment mechanism is the basis of the vertical process modeling of spilled oil at sea. In order to reveal the effect of plunging breaking waves, a dripping...     

Petroleum and PAH contamination of the Black Sea

Concern has been expressed regarding the extent of contamination of the Black Sea. Analyses of coastal sediments taken from throughout the region indicate, however, that levels of petroleum hydrocarbons (2-300 microg g(-1) dry wt total hydrocarbons) are generally comparable to those encountered in the Mediterranean and are lower than concentrations reported for highly contaminated areas such as the Gulf, Hong Kong, Taiwan and New York Bight. Highest concentrations of total hydrocarbons (>100 microg g(-1) dry wt) were associated with discharges from Odessa, Sochi and the River Danube. Chronic/degraded petroleum was the major contributor at these sites. Samples from the Ukrainian coastline were comparatively clean (<10 microg g(-1) dry wt total hydrocarbons). Major contributions of fresh oil (as indicated by sigma n-C14-34) occur through the River Danube. Concerning total PAH, concentrations (7-638 ng g(-1) dry wt) compare to relatively unpolluted locations in the Mediterranean and are much lower than levels reported for polluted UK estuaries (e.g. Mersey, Tyne, Thames). Both pyrolytic and petrogenic PAH are present in most samples, although petroleum derived PAH are dominant at Sochi and pyrolytic sources are prevalent in the Bosphorus region. The absence of a correlation between total hydrocarbons and PAH (R2 = 0.04) indicates different primary sources for the two.     

Persistent organochlorine residues in sediments from the Black Sea

The extent of contamination of the Black Sea by selected organochlorine compounds has been assessed through the analysis of surficial sediments taken from throughout the region. Concentrations of HCHs at sites influenced by the Danube delta are among the highest recorded on a global basis (up to 40 ng g(-1) dry wt). The ratio between the alpha- and gamma-isomers was relatively low indicating contamination through the use of lindane. Concentrations of DDTs (0.06-72 ng g(-1) dry wt) and PCBs (0.06-72 ng g(-1) dry wt) were not especially high in comparison to levels reported from throughout the world. The DDE/DDT ratio was, however, low indicating fresh inputs and hence current usage of DDT within the Black Sea region.     

Biomonitoring of the coastal waters of the Black Sea

Morpho-physiological and biochemical parameters were determined in Scorpion fish Scorpaena porcus L. from two bays in the area of Sevastopol, which experience a high anthropogenic load. The effect of natural and anthropogenic factors on the size, weight, and age composition, as well as on the sex ratio of the fish from both populations, was studied. The relationships between the concentrations of chlororganic substances in the water of the bays, their accumulation in the liver and gonads of the fish, the activity of antioxidant enzymes in the blood, and the fractional composition of serum proteins were determined. A possibility for the use of the Scorpion fish as a indicator species for the biomonitoring and assessment of the environmental conditions in the coastal waters of the Black Sea was considered.Translated from Vodnye Resursy, Vol. 32, No. 2, 2005, pp. 238–246.Original Russian Text Copyright © 2005 by Rudneva, Shevchenko, Zalevskaya, Zherko.     

Landscape mapping of the Russian Black Sea coast

The purpose of this investigation is to study structure, evolution and present ecological state of background and anthropogenically modified landscapes of the Abrau Peninsula. This region has been recommended as one of the main conservation sites on the Russian Black Sea coast due to its relatively low anthropogenic transformation and its historical importance. The ecological situation is aggravated today by the construction of a pipe-line and oil terminal near Novorossiysk and by an increase in unregulated recreation activity within the peninsula's narrow coastal zone. A special landscape-ecological map has been compiled for the model area. All ecosystems shown on the map can be grouped into four main categories based on changes of landscape structure resulting from direct impact of human activity and indirect impact mainly from chemical pollution. Ecosystems exhibiting a high degree of transformation are more typical for regions characterized by settlements, vineyards and the coastal recreation zone. Ecosystems with moderate changes also exist in the coastal area, including, for example, some unique ecosystems with pine-tree forests, pistachio-juniper and juniper open-lands. Nearly 50% of pine-tree (Pinus pithyusa) forests are in the fourth and fifth stages of recreation degradation. Some protection measures are suggested to maintain biodiversity and sustainable development of these coastal landscapes and to improve their current condition.     

The Khvalynian transgression of the Caspian Sea and the New-Euxinian basin of the Black Sea

The Late Pleistocene history of the Caspian and Black seas is considered. It is suggested that the New-Euxinian basin was to a great degree due to the penetration of the Caspian water through the Manych depression into the Black Sea during the Caspian-Early Khvalynian transgression.     

Modelling the impact of Black Sea water inflow on the North Aegean Sea hydrodynamics

The impact of the Black Sea Water (BSW) inflow on the circulation and the water mass characteristics of the North Aegean Sea is investigated using a high-resolution 3D numerical model. Four climatological numerical experiments are performed exploring the effects of the exchange amplitude at the Dardanelles Straits in terms of the mean annual volume exchanged and the amplitude of its seasonal cycle. Larger inflow of low salinity BSW influences the water characteristics of the whole basin. The largest salinity reduction is encountered in the upper layers of the water column, and the most affected region is the northeastern part of the basin. The winter insulation character of the BSW layer (low-salinity layer) is reduced by the seasonal cycle of the inflow (minimum during winter). The maximum atmospheric cooling coincides with the minimum BSW inflow rate, weakening the vertical density gradients close to the surface and thus facilitating the vertical mixing. The inflow rate of BSW into the North Aegean Sea constitutes an essential factor for the circulation in the basin. Increased inflow rate results into considerably higher kinetic energy, stronger circulation and reinforcement of the mesoscale circulation features. Although the position of the front between BSW and waters of Levantine origin does not vary significantly with the intensity of the BSW inflow rate, the flow along the front becomes stronger and more unstable as the inflow rate increases, forming meanders and rings. The changes in the intensity of BSW inflow rate overpower the wind and thermohaline forcing and largely determine the general circulation of the North Aegean Sea.     

Inundatios on the Black Sea coast of Krasnodar krai

Inundatios on the Black Sea coast of Krasnodar krai between 1945 and 2013 have been analyzed. The main genetic types of inundations on the coast have been identified. The specific features and regularities of inundation wave transformation along the rivers and over time have been studied. Seasonal and maximal runoff of Black Sea rivers has been analyzed over a long-term period. Regularities in the variations of the number of inundatios and their characteristics over the coastal area have been revealed both at the annual and long-term scales. Quantitative estimates are given to the hazard and damage to the population and economic activity due to inundations in the valleys of Black Sea rivers.     

Cenozoic evolution of the eastern Black Sea: A test of depth-dependent stretching models

Subsidence analysis of the eastern Black Sea basin suggests that the stratigraphy of this deep, extensional basin can be explained by a predominantly pure-shear stretching history. A strain-rate inversion method that assumes pure-shear extension obtains good fits between observed and predicted stratigraphy. A relatively pure-shear strain distribution is also obtained when a strain-rate inversion algorithm is applied that allows extension to vary with depth without assuming its existence or form. The timing of opening of the eastern Black Sea, which occupied a back-arc position during the closure of the Tethys Ocean, has also been a subject of intense debate; competing theories called for basin opening during the Jurassic, Cretaceous or Paleocene/Eocene. Our work suggests that extension likely continued into the early Cenozoic, in agreement with stratigraphic relationships onshore and with estimates for the timing of arc magmatism. Further basin deepening also appears to have occurred in the last ～ 20 myr. This anomalous subsidence event is focused in the northern part of the basin and reaches its peak at ～ 15–10 Ma. We suggest that this comparatively localized shortening is associated with the northward movement of the Arabian plate. We also explore the effects of paleowater depth and elastic thickness on the results. These parameters are controversial, particularly for deep-water basins and margins, but their estimation is a necessary step in any analysis of the tectonic subsidence record stored in stratigraphy.     

Characteristics of the frequency spectra of wind-waves in Eastern Black Sea

Spectral information for wind-waves in the Black Sea is extremely limited. Knowledge on spectral characteristics of wind-waves would contribute to scientific, engineering, and operational coastal and marine activities in the Black Sea, and would allow a better understanding of the nature of the waves occurring in this enclosed basin. Frequency spectra obtained from the directional buoys deployed offshore Sinop and Hopa in Turkey, and Gelendzhik in Russia were utilized as the three sets of data to investigate characteristics of wind-waves frequency spectra for the Eastern Black Sea. Records were firstly analyzed to identify them as uni-modal or multi-modal spectra. Single-peaked spectra were then identified as belonging to fully arisen or developing sea states. Parameters of the JONSWAP and PM model spectra were estimated for the corresponding sea state by using a least square error method. Finally, the records of developing seas were further analyzed to select the ones belonging to stable wind conditions. ECMWF analysis wind fields were utilized as the wind information corresponding to the wave records. Fetch dependencies of non-dimensional spectral variables (variance and peak frequency) and α parameter of the JONSWAP model spectrum were investigated for this data sub-set.