An Integrated Ground Water Monitoring Program Using Multilevel Gas-Driven Samplers and Conventional Monitoring Wells

Hydrogeologic and ground water quality data obtained from a gas-driven multilevel sampler system and a polyvinyl chloride (PVC) monitoring well nest with the same aquifer communication intervals are compared. All monitoring points are in close proximity to each other. The study was conducted at an eight-acre uncontrolled hazardous waste site. The site is located in an alluvial valley composed of approximately 40 feet of alluvium overlying shale bedrock. The ground water at the site is contaminated with various organic constituents. A ground water monitoring network consisting of 26 conventional monitoring wells, nine observation well points, and six multilevel gas-driven samplers was established to characterize the hydrogeologic regime and define the vertical and horizontal extent of contamination in the vicinity of the abandoned chemical plant. As part of this study, a multilevel monitoring system was installed adjacent to a well nest. The communication zones of the multilevel samplers were placed at the same elevation as the sand packs of the well nest. The multilevel sampler system and well nest are located in a contaminated area directly downgradient of the site. A comparison of the vertical head distribution and ground water quality was performed between the well nest and the multilevel sampling system. The gas-driven multilevel sampling system consists of three gas-driven samplers that monitor separate intervals in the unconsolidated materials. The well nest, composed of two PVC monitoring wells in separate boreholes, has the same communication interval as the other two gas-driven samplers. Hydraulic head information for each multilevel sampler was obtained using capillary tubing. This was compared with heads obtained from the well nest utilizing an electric water level indicator. Chemical analyses from the PVC and multilevel sampler wells were performed and compared with one another. The analyses included organic acids, base neutrals, pesticides, PCBs, metals, volatile organics, TOX, TOC, CN, pH and specific conductance.     

A New Multilevel Ground Water Monitoring System Using Multichannel Tubing

A new multilevel ground water monitoring system has been developed that uses custom-extruded flexible 1.6-inch (4.1 cm) outside-diameter (O.D.) multichannel HOPE tubing (referred to as Continuous Multichannel Tubing or CMT) to monitor as many as seven discrete zones within a single borehole in either unconsolidated sediments or bedrock. Prior to inserting the tubing in the borehole, ports are created that allow ground water to enter six outer pie-shaped channels (nominal diameter = 0.5 inch [1.3 cm]) and a central hexagonal center channel (nominal diameter = 0.4 inch [1 cm]) at different depths, facilitating the measurement of depth-discrete piezometric heads and the collection of depth-discrete ground water samples. Sand packs and annular seals between the various monitored zones can be installed using conventional tremie methods. Alternatively, bentonite packers and prepacked sand packs have been developed that are attached to the tubing at the ground surface, facilitating precise positioning of annular seals and sand packs. Inflatable rubber packers for permanent or temporary installations in bedrock aquifers are currently undergoing site trials. Hydraulic heads are measured with conventional water-level meters or electronic pressure transducers to generate vertical profiles of hydraulic head. Ground water samples are collected using peristaltic pumps, small-diameter bailers, inertial lift pumps, or small-diameter canister samplers. For monitoring hydrophobic organic compounds, the CMT tubing is susceptible to both positive and negative biases caused by sorption, desorption, and diffusion. These biases can be minimized by: (1) purging the channels prior to sampling, (2) collecting samples from separate 0.25-inch (0.64 cm) O.D. Teflon sampling tubing inserted to the bottom of each sampling channel, or (3) collecting the samples downhole using sampling devices positioned next to the intake ports. More than 1000 CMT multilevel wells have been installed in North America and Europe to depths up to 260 feet (79 m) below ground surface. These wells have been installed in boreholes created in unconsolidated sediments and bedrock using a wide range of drilling equipment, including sonic, air rotary, diamond-bit coring, hollow-stem auger, and direct push. This paper presents a discussion of three field trials of the system, demonstrating its versatility and illustrating the type of depth-discrete data that can be collected with the system.     

Progressive Packer/Zone Sampling Method for VOC Plume Delineation in Consolidated Aquifers

The progressive packer/zone sampling method was used to identify the bottom of a plume of volatile organic compounds (VOCs) in the parts-per-million (ppm) range using one well in each of three separate locations. The method involves progressively drilling a 20-foot length of borehole through casing, setting an inflatable packer at the top of the drilled zone, purging the zone of three volumes of water using the airlift method, sampling the zone in situ through the packer string using a bailer, then repeating the procedure.
A plume consisting of chlorinated VOCs, alcohols, and vinyl chloride occurs in a low-yielding fractured bedrock aquifer located in the Passaic Formation at a site in central New Jersey. The thickness of the plume in total VOC concentrations exceeding 1 ppm was determined using the progressive packer/zone sampling method to a depth of 200 feet. The first borehole was completed as a monitoring well in the "hottest" zone encountered during testing. Additional wells were then clustered with this exploratory well to delineate the plume in the parts-per-billion (ppb) range. Cross contamination from previously sampled zones was not a problem as long as total VOCs in the ppm range were targeted and the sample interval was properly purged.
Instead of using a multiple well cluster consisting of an indefinite number of wells to determine the bulk thickness of a plume at a specific location, information from one borehole may suffice during the exploratory phase. Costs to the client and cross contamination potential to the aquifer can be minimized by limiting the number of boreholes needed for vertical delineation.     

Remediation of the Wells G & H Superfund Site,Woburn, Massachusetts

Remediation of ground water and soil contamination at the Wells G & H Superfund Site, Woburn, Massachusetts, uses technologies that reflect differences in hydrogeologic settings, concentrations of volatile organic compounds (VOCs), and costs of treatment. The poorly permeable glacial materials that overlie fractured bedrock at the W.R. Grace property necessitate use of closely spaced recovery wells. Contaminated ground water is treated with hydrogen peroxide and ultraviolet (UV) oxidation. At UniFirst, a deep well completed in fractured bedrock removes contaminated ground water, which is treated by hydrogen peroxide, UV oxidation, and granular activated carbon (GAC). The remediation system at Wildwood integrates air sparging, soil-vapor extraction, and ground water pumping. Air stripping and GAC are used to treat contaminated water; GAC is used to treat contaminated air. New England Plastics (NEP) uses air sparging and soil-vapor extraction to remove VOCs from the unsaturated zone and shallow ground water. Contaminated air and water are treated using separate GAC systems. After nine years of operation at W.R. Grace and UniFirst, 30 and 786 kg, respectively, of VOCs have been removed. In three years of operation, 866 kg of VOCs have been removed at Wildwood. In 15 months of operation, 36 kg of VOCs were removed at NEP. Characterization work continues at the Olympia Nominee Trust, Whitney Barrel, Murphy Waste Oil, and Aberjona Auto Parts properties. Risk assessments are being finalized that address heavy metals in the floodplain sediments along the Aberjona River that are mobilized from the Industri-Plex Superfund Site located a few miles upstream.     

Bedrock Depth Estimates from Ground Magnetometer Profiles

Bedrock depths can be calculated readily from ground magnetic profiles using either Werner deconvolution or Fourier spectral analysis. For crystalline basement rocks of New England and eastern Canada, a vertical dike is a useful magnetic source model. Formulae for these methods are presented along with some practical guidelines for implementing them. Six field examples from metamorphic and igneous areas in New Hampshire show that bedrock depths from spectral analysis agree well with estimates from seismic refraction, from wells and from outcrops. The Werner estimates are much more variable but commonly bracket the others. At several of these sites, measurements by other geophysical methods would be impractical, more expensive, or restricted to certain times of the year.     

Vertical Contaminant Profiling of Volatile Organic* in a Deep Fractured Basalt Aquifer

Volatile organic compounds delected in ground water from wells at Test Area North (TAN) at the Idaho National Engineering Laboratory (INEL) prompted RCRA facility investigations in 1989 and 1990 and a CERCLA-driven RI/FS in 1992. In order to address ground water treatment feasibility, one of the main objectives, of the 1992 remedial investigation was to determine the vertical extent of ground water contamination, where the principle contaminant, of concern is trichloroethylene (TCE). It was hypothesized that a sedimentary interbed at depth in the fractured basalt aquifer could be inhibiting vertical migration of contaminants to lower aquifers. Due to the high cost of drilling and installation of ground water monitoring wells at this facility (greater than $100,000 per well), a real time method was proposed for obtaining and analyzing ground water samples during drilling to allow accurate placement of well screens in zones of predicted VOC contamination. This method utilized an inflatable pump packer pressure transducer system interfaced with a datalogger and PC at land surface. This arrangement allowed for real lime monitoring of hydraulic head above and below the packer to detect leakage around the packer during pumping and enabled collection of head data during pumping for estimating hydrologic properties. Analytical results were obtained in about an hour from an on-site mobile laboratory equipped with a gas chromalograplvmass spectrometer (GC/MS). With the hydrologic and analytical results in hand, a decision was made to either complete the well or continue drilling to the next test zone. In almost every case, analytical results of ground water samples taken from the newly installed wells closely replicated the water quality of ground water samples obtained through the pump packer system.     

A Dry Injection System for the Emplacement of Filter Packs and Annular Seals in Ground Water Monitoring Wells

The reliability of filter pack and annular seal emplacements, and the degree of integrity of installed seals, are two of the most important factors to be considered when both installing and later utilizing ground water monitoring wells.
Numerous, and often costly, problems of using existing methods of installing filter packs and annular seals during the construction of ground water monitoring wells have led to the development of a technique of installing these monitoring well components using a dry injection system.
The dry injection system has been used to construct monitoring wells in extremely complex overburden/bedrock environments with a variety of drilling techniques. The system has shown that a high degree of reliability in the, construction of monitoring wells and greater confidence in obtaining representative ground water samples can be achieved over existing methods of filter pack and annular seal emplacement. The system has also been more cost effective than existing methods, especially for deep boreholes and multilevel monitoring system installations.     

Performance Assessments of a Novel Well Design for Reducing Exposure to Bedrock‐Derived Arsenic

Arsenic in groundwater is a serious problem in New England, particularly for domestic well owners drawing water from bedrock aquifers. The overlying glacial aquifer generally has waters with low arsenic concentrations but is less used because of frequent loss of well water during dry periods and the vulnerability to surface‐sourced bacterial contamination. An alternative, novel design for shallow wells in glacial aquifers is intended to draw water primarily from unconsolidated glacial deposits, while being resistant to drought conditions and surface contamination. Its use could greatly reduce exposure to arsenic through drinking water for domestic use. Hypothetical numerical models were used to investigate the potential hydraulic performance of the new well design in reducing arsenic exposure. The aquifer system was divided into two parts, an upper section representing the glacial sediments and a lower section representing the bedrock. The location of the well, recharge conditions, and hydraulic properties were systematically varied in a series of simulations and the potential for arsenic contamination was quantified by analyzing groundwater flow paths to the well. The greatest risk of arsenic contamination occurred when the hydraulic conductivity of the bedrock aquifer was high, or where there was upward flow from the bedrock aquifer because of the position of the well in the flow system.     

Screened Auger Sampling: The Technique and Two Case Studies

The screened auger is a laser-slotted, hollow-stem auger through which a representative sample of ground water is pumped from an aquifer and tested for water-quality parameters by appropriate field-screening methods. Screened auger sampling can be applied to ground water quality remedial investigations, providing:(1) a mechanism for determining a monitoring well's optimal screen placement in a contaminant plume; and (2) data to define the three-dimensional configuration of the contaminant plume.
Screened auger sampling has provided an efficient method for investigating hexavalent chromium and volatile organic compound contamination in two sandy aquifers in Cadillac, Michigan. The aquifers approach 200 feet in thickness and more than 1 square mile in area. A series of screened auger borings and monitoring wells was installed, and ground water was collected at 10-foot intervals as the boreholes were advanced to define the horizontal and vertical distribution of the contaminant plumes. The ability of the screened auger to obtain representative ground water samples was supported by the statistical comparison of field screening results and subsequent laboratory analysis of ground water from installed monitoring wells.     

Modeling effects of multinode wells on solute transport

Long-screen wells or long open boreholes with intraborehole flow potentially provide pathways for contaminants to move from one location to another in a ground water flow system. Such wells also can perturb a flow field so that the well will not provide water samples that are representative of ground water quality a short distance away from the well. A methodology is presented to accurately and efficiently simulate solute transport in ground water systems that include wells longer than the grid spacing used in a simulation model of the system and hence are connected to multiple nodes of the grid. The methods are implemented in a MODFLOW-compatible solute-transport model and use MODFLOW's Multi-Node Well Package but are generic and can be readily implemented in other solute-transport models. For nonpumping multinode wells (used to simulate open boreholes or observation wells, for example) and for low-rate pumping wells (in which the flow between the well and the ground water system is not unidirectional), a simple routing and local mixing model was developed to calculate nodal concentrations within the borehole. For high-rate pumping multinode wells (either withdrawal or injection, in which flow between the well and the ground water system is in the same direction at all well nodes), complete and instantaneous mixing in the wellbore of all inflows is assumed.     

A Tracer Test for Detecting Cross Contamination Along a Monitoring Well Column

A tracer test was used to evaluate whether cross contamination exists along a monitoring well completed through a shallow ground water system in fractured clay and screened in a sand and gravel aquifer. The fractured clay is separated from the sand and gravel deposit by a layer of highly plastic unfractured clay. A natural vertical downward hydraulic gradient of approximately 0.5 exists between the shallow system and the sand and gravel aquifer. Ground water contamination was detected in an adjacent monitoring well screened in the fractured clay and in the monitoring well screened in the sand and gravel deposit. No ground water contamination was apparent in an intermediate well screened in the unfractured clay layer. A tracer of sodium bromide was injected into a shallow boring near the monitoring wells. The tracer was detected in the monitoring well in the sand and gravel aquifer after three to seven days. The bromide concentration continued to increase in this well with time while the concentration in the shallow boring declined. This trend of tracer concentration indicates the tracer has in fact migrated downward and possibly traveled along the well column.     

Monitoring Hydrogeologlcal Conditions in Fractured Rock at the Site of Canada's Underground Research Laboratory

Atomic Energy of Canada Limited is constructing an Underground Research Laboratory (URL) at a depth of 250m in a plutonic rock body near Lac du Bonnet, Manitoba. The facility is being constructed to carry out a variety of in situ geotechnical experiments as part of the Canadian Nuclear Fuel Waste Management Program. A unique feature of the URL, in comparison to other similar facilities such as the Stripa Mine in Sweden, is that it is to be constructed below the ground water table in a previously undisturbed plutonic rock body. One of the main research objectives of the project is to develop and validate comprehensive three-dimensional models of the hydrogeology of the rock mass encompassing the URL site. These models will be used, before excavation of the URL shaft begins, to predict the hydrogeological perturbation that will be created by the excavation of the shaft and the horizontal working levels below the ground water table. As a model-validation exercise, these drawdown predictions will be compared with actual hydrogeological perturbations that will be monitored at the study area over the next several years by an extensive network of instrumented boreholes. Measurements made in an array of boreholes extending to depths of 1,000m on the 4.8 km² study area have established that the permeability distribution in three major extensive subhorizontal fracture zones controls the movement of ground water within the rock mass. Several types of multiple-interval completion systems have been installed in the boreholes to monitor the three-dimensional, physico-chemical hydrogeological conditions within the fractured rock mass. These include conventional piezometer nests and water-table wells that have been installed in shallow holes (less than 30m deep), and multiple-packer/ multiple-standpipe piezometers and multiple-interval casing systems installed in deeper holes (30 to 1,000m deep). An automated, electronic, piezometric pressure-monitoring system has been designed to collect continuous measurements from 75 isolated hydrogeological monitoring positions within the rock mass. Another 200 positions are being monitored frequently using a variety of techniques. Piezometric data have been collected from this monitoring network to establish baseline conditions prior to any excavation into the rock mass. These data have also been used to determine the steady-state, three-dimensional ground water flow regimes that exist at the URL site under natural conditions.     

Vertical cross contamination of trichloroethylene in a borehole in fractured sandstone

Boreholes drilled through contaminated zones in fractured rock create the potential for vertical movement of contaminated ground water between fractures. The usual assumption is that purging eliminates cross contamination; however, the results of a field study conducted in a trichloroethylene (TCE) plume in fractured sandstone with a mean matrix porosity of 13% demonstrates that matrix-diffusion effects can be strong and persistent. A deep borehole was drilled to 110 m below ground surface (mbgs) near a shallow bedrock well containing high TCE concentrations. The borehole was cored continuously to collect closely spaced samples of rock for analysis of TCE concentrations. Geophysical logging and flowmetering were conducted in the open borehole, and a removable multilevel monitoring system was installed to provide hydraulic-head and ground water samples from discrete fracture zones. The borehole was later reamed to complete a well screened from 89 to 100 mbgs; persistent TCE concentrations at this depth ranged from 2100 to 33,000 microg/L. Rock-core analyses, combined with the other types of borehole information, show that nearly all of this deep contamination was due to the lingering effects of the downward flow of dissolved TCE from shallower depths during the few days of open-hole conditions that existed prior to installation of the multilevel system. This study demonstrates that transfer of contaminant mass to the matrix by diffusion can cause severe cross contamination effects in sedimentary rocks, but these effects generally are not identified from information normally obtained in fractured-rock investigations, resulting in potential misinterpretation of site conditions.     

Long-Term Confidence in Ground Water Monitoring Systems

State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.     

Investigation of Ground Water Contamination by Fenamiphos and Atrazine in a Residential Area: Source and Distribution of Contamination

Ground water in a residential area of Perth. Western Australia, was contaminated with fenamiphos and atrazine. probably as a result of the storage and handling of these chemicals at a residential properly. Sampling of existing wells indicated that atrazine and fenamiphos concentrations in ground water beneath a neighboring property were 2000 μg/L and 1000 μg/L, respectively. Fenamiphos concentrations were sufficiently high to be toxic on prolonged skin contact, and contamination posed a public health threat to nearby residents with private wells. Management of the contamination problem included restricting ground water use in the area and using a recovery well to pump contaminated ground water.     

POSSIBILITIES OF USING VERTICAL GEOPHONE ARRAYS (CVA) IN REFLECTION SEISMOLOGY*

Vertical geophone arrays in boreholes have been used for many years to study seismic velocities by investigating the first arrivals of records. The development of the vertical seismic profiling (VSP) technique shows possibilities of using the reflected events to close the gap between interpretation of conventional seismic data and physical observations made in the well. Reflected events recorded by vertical arrays (as in VSP) generally have higher signal-to-noise ratio, larger bandwidth and can easily be separated from multiples. The new Continuous Vertical Array (CVA) technique combines vertical arrays in several boreholes with a line of source points near the surface. The result is a multi-covered seismic line similar to that of a conventional seismic survey, but it retains the benefits of observations with vertical arrays. The possibilities of the new technique are discussed with the aid of theoretical considerations, model studies, and a first field case using nine boreholes 500 m apart with depths of 400 m. New data acquisition and processing techniques (mainly migration before stack) have been developed. The CVA-seismic method is still in the development stage but promises new possibilities for detailed surveys in difficult areas.     

Contamination from Sand-Bentonite Seal in Monitoring Wells Installed in Aquitards

A six year field experiment has shown that a sand-bentonite mixture used to seal monitoring wells in aquitards contributes solutes to the ground water sampled from these wells. Monitoring wells were installed at field sites with hydraulic conductivity (K) ranging from 5 × 10 ^-9 m/s to 3 × 10¹¹ m/s. In most cases the boreholes remained dry during installation which allowed the placement of a dry powdered bentonite/sand mixture tagged with potassium bromide (KBr) to seal and separate sampling points. Over six years, wells were sampled periodically and ground-water samples were analyzed for Br and Cl and other major ions. Typical Br results ranged from 10 mg/1 to 35 mg/1 in the first 700 days, as compared to an estimated initial concentration in the seal material of about 75 mg/1. After six years the bromide concentrations had decreased to between 3 mg/1 and 5 mg/1. The total mass of Br removed in six years is less than 50% of that placed; therefore the contamination effects, although considerably diminished, persist. The trends of Br, Cl, Na, and SO₄ indicate that varying degrees of contamination occur. These data show that the materials used to seal monitoring wells in aquitards can have a significant and long-lasting impact on the chemistry of the water in the wells.     

Design, Installation, and Uses of Combination Ground Water and Gas Sampling Wells

Waste disposal sites with volatile organic compounds (VOCs) frequently contain contaminants that are present in both the ground water and vadose zone. Vertical sampling is useful where transport of VOCs in the vadose zone may effect ground water and where steep vertical gradients in chemical concentrations are anticipated. Designs for combination ground water and gas sampling wells place the tubing inside the casing with the sample port penetrating the casing for sampling. This physically interferes with pump or sampler placement. This paper describes a well design that combines a ground water well with gas sampling ports by attaching the gas sampling tubing and ports to the exterior of the casing. Placement of the tubing on the exterior of the casing allows exact definition of gas port depth, reduces physical interference between the various monitoring equipment, and allows simultaneous remediation and monitoring in a single well. The usefulness and versatility of this design was demonstrated at the Idaho National Engineering and Environmental Laboratory (INEEL) with the installation of seven wells with 53 gas ports, in a geologic formation consisting of deep basalt with sedimentary interbeds at depths from 7.2 to 178 m below land surface. The INEEL combination well design is easy to construct, install, and operate.     

Delineation of Ground Water Flow in Fractured Rock in the Southwestern Part of Manhattan, New York, Through Use of Advanced Borehole Geophysical Methods

Advanced borehole-geophysical methods were used to assess the geohydrology of fractured crystalline bedrock at five test boreholes in southwestern Manhattan Island, New York, in preparation for construction of a third water tunnel for New York City. The boreholes penetrated gneiss and other crystalline bedrock that has an overall southwest to northwest dipping foliation with a 60° dip. Most of the fractures encountered are either nearly horizontal or have moderate northwest dip azimuths. Fracture indexes range from 0.25 to 0.44 fracture per foot (0.3 m) of borehole.
Electromagnetic (EM) and heat-pulse flowmeter logs obtained under ambient and pumping conditions, together with other geophysical logs, indicate transmissive fracture zones in each borehole. Pumping tests of each borehole indicated transmissivity ranges from <2 to 360 ft²/day (0.2 to 33 m²/day). Ground water appears to flow within an interconnected fracture network toward the south and west within the study area. No correlation was indicated between the fracture index and the total borehole transmissivity.     

A Single Packer Method for Characterizing Water Contributing Fractures in Crystalline Bedrock Wells

Water levels and water quality of open borehole wells in fractured bedrock are flow-weighted averages that are a function of the hydraulic heads and transmissivities of water contributing fractures, properties that are rarely known. Without such knowledge using water levels and water quality data from fractured bedrock wells to assess groundwater flow and contaminant conditions can be highly misleading. This study demonstrates a cost-effective single packer method to determine the hydraulic heads and transmissivities of water contributing fracture zones in crystalline bedrock wells. The method entails inflating a pipe plug to isolate sections of an open borehole at different depths and monitoring changes in the water level with time. At each depth, the change in water level with time was used to determine the sum of fracture transmissivities above the packer and then to solve for individual fracture transmissivity. Steady-state wellbore heads along with the transmissivities were used to determine individual fracture heads using the weighted average head equation. The method was tested in five wells in crystalline bedrock located at the University of Connecticut in Storrs. The single packer head and transmissivity results were found to agree closely with those determined using conventional logging methods and the dissolved oxygen alteration method. The method appears to be a simple and cost-effective alternative in obtaining important information on flow conditions in fractured crystalline bedrock wells.