Subsidence hazard avoidance based on geomorphological mapping in the Ebro River valley mantled evaporite karst terrain (NE Spain)

In the valley of the Ebro River to the southeast of the city of Zaragoza (NE Spain), the dissolution of evaporite sediments (gypsum, halite and Na-sulphates) which underlie alluvial deposits gives rise to numerous sinkholes. These sinkholes are a potential hazard to human safety, particularly where they develop in a catastrophic way. Even slow-developing sinkholes are problematic, as they damage urban and agricultural infrastructure, necessitating costly repairs and vigilant maintenance. To assist in developing avoidance strategies for these hazards, the factors controlling sinkhole occurrence have been assessed using geomorphological maps produced from aerial photographs for 1956 and 1981. Important controls on sinkhole development are found to include underlying geological structure (manifest in preferred orientations of sinkholes on the azimuths N130-150E and N30-40E), and the presence of glauberite in the groundwater flow path, which apparently promotes accelerated gypsum dissolution. Perhaps surprisingly, alluvium thickness does not appear to significantly correlate with the density of sinkholes on the floodplain in this area. The maps for 1956 and 1981 reveal that both human activity and natural processes can serve to obscure the true density of sinkhole development. For instance, a large number of sinkholes which were conspicuous in 1956 have since been back-filled by farmers. In the most fluvially active zone of the Ebro valley (the meander belt), the relatively low density of sinkholes compared with adjoining zones suggests that subsidence is being masked by morpho-sedimentary dynamic processes (aggradation and erosion). Careful geomorphological mapping for different time periods yields a much more accurate impression of the frequency of sinkhole development than would be gained from surveying currently visible sinkholes in the area of interest.     

GIS and ANN coupling model: an innovative approach to evaluate vulnerability of karst water inrush in coalmines of north China

Evaporites, including rock salt (halite) and gypsum (or anhydrite), are the most soluble among common rocks; they dissolve readily to form the same types of karst features that commonly are found in limestones and dolomites. Evaporites are present in 32 of the 48 contiguous states in USA, and they underlie about 40% of the land area. Typical evaporite-karst features observed in outcrops include sinkholes, caves, disappearing streams, and springs, whereas other evidence of active evaporite karst includes surface-collapse structures and saline springs or saline plumes that result from salt dissolution. Many evaporites also contain evidence of paleokarst, such as dissolution breccias, breccia pipes, slumped beds, and collapse structures. All these natural karst phenomena can be sources of engineering or environmental problems. Dangerous sinkholes and caves can form rapidly in evaporite rocks, or pre-existing karst features can be reactivated and open up (collapse) under certain hydrologic conditions or when the land is put to new uses. Many karst features also propagate upward through overlying surficial deposits. Human activities also have caused development of evaporite karst, primarily in salt deposits. Boreholes (petroleum tests or solution-mining operations) or underground mines may enable unsaturated water to flow through or against salt deposits, either intentionally or accidentally, thus allowing development of small to large dissolution cavities. If the dissolution cavity is large enough and shallow enough, successive roof failures can cause land subsidence and/or catastrophic collapse. Evaporite karst, natural and human-induced, is far more prevalent than is commonly believed.     

Identification, prediction, and mitigation of sinkhole hazards in evaporite karst areas

Sinkholes usually have a higher probability of occurrence and a greater genetic diversity in evaporite terrains than in carbonate karst areas. This is because evaporites have a higher solubility and, commonly, a lower mechanical strength. Subsidence damage resulting from evaporite dissolution generates substantial losses throughout the world, but the causes are only well understood in a few areas. To deal with these hazards, a phased approach is needed for sinkhole identification, investigation, prediction, and mitigation. Identification techniques include field surveys and geomorphological mapping combined with accounts from local people and historical sources. Detailed sinkhole maps can be constructed from sequential historical maps, recent topographical maps, and digital elevation models (DEMs) complemented with building-damage surveying, remote sensing, and high-resolution geodetic surveys. On a more detailed level, information from exposed paleosubsidence features (paleokarst), speleological explorations, geophysical investigations, trenching, dating techniques, and boreholes may help in investigating dissolution and subsidence features. Information on the hydrogeological pathways including caves, springs, and swallow holes are particularly important especially when corroborated by tracer tests. These diverse data sources make a valuable database—the karst inventory. From this dataset, sinkhole susceptibility zonations (relative probability) may be produced based on the spatial distribution of the features and good knowledge of the local geology. Sinkhole distribution can be investigated by spatial distribution analysis techniques including studies of preferential elongation, alignment, and nearest neighbor analysis. More objective susceptibility models may be obtained by analyzing the statistical relationships between the known sinkholes and the conditioning factors. Chronological information on sinkhole formation is required to estimate the probability of occurrence of sinkholes (number of sinkholes/km² year). Such spatial and temporal predictions, frequently derived from limited records and based on the assumption that past sinkhole activity may be extrapolated to the future, are non-corroborated hypotheses. Validation methods allow us to assess the predictive capability of the susceptibility maps and to transform them into probability maps. Avoiding the most hazardous areas by preventive planning is the safest strategy for development in sinkhole-prone areas. Corrective measures could be applied to reduce the dissolution activity and subsidence processes. A more practical solution for safe development is to reduce the vulnerability of the structures by using subsidence-proof designs.     

A genetic classification of sinkholes illustrated from evaporite paleokarst exposures in Spain

This contribution analyses the processes involved in the generation of sinkholes from the study of paleokarst features exposed in four Spanish Tertiary basins. Bedrock strata are subhorizontal evaporites, and in three of the basins they include halite and glauberite in the subsurface. Our studies suggest that formation of dolines in these areas results from a wider range of subsidence processes than those included in the most recently published sinkhole classifications; a new genetic classification of sinkholes applicable to both carbonate and evaporite karst areas is thus proposed. With the exception of solution dolines, it defines the main sinkhole types by use of two terms that refer to the material affected by downward gravitational movements (cover, bedrock or caprock) and the main type of process involved (collapse, suffosion or sagging). Sinkholes that result from the combination of several subsidence processes and affect more than one type of material are described by combinations of the different terms with the dominant material or process followed by the secondary one (e.g. bedrock sagging and collapse sinkhole). The mechanism of collapse includes any brittle gravitational deformation of cover and bedrock material, such as upward stoping of cavities by roof failure, development of well-defined failure planes and rock brecciation. Suffosion is the downward migration of cover deposits through dissolutional conduits accompanied with ductile settling. Sagging is the ductile flexure of sediments caused by differential corrosional lowering of the rockhead or interstratal karstification of the soluble bedrock. The paleokarsts we analysed suggest that the sagging mechanism (not included in previous genetic classifications) plays an important role in the generation of sinkholes in evaporites. Moreover, collapse processes are more significant in extent and rate in areas underlain by evaporites than in carbonate karst, primarily due to the greater solubility of the evaporites and the lower mechanical strength and ductile rheology of gypsum and salt rocks.     

Paleosubsidence and active subsidence due to evaporite dissolution in the Zaragoza area (Huerva River valley, NE Spain): processes, spatial distribution and protection measures for transport routes

The lowest 17-km long reach of the Huerva River valley, down to its confluence with the Ebro River in Zaragoza city, flows across salt-bearing evaporites of the Ebro Tertiary Basin (NE Spain). Upstream, the horizontally lying Miocene evaporites are interfingered with non-soluble distal alluvial fan facies (shales and sandstones). The proportion of soluble facies in the Huerva River valley increases in a downstream direction towards the basin depocenter. On the basis of the type and magnitude of the paleosubsidence features, the valley has been divided into four reaches. Along reach I, undeformed terrace deposits less than 4 m thick rest on insoluble detrital bedrock. In reaches II and III, dissolution at the alluvium–bedrock boundary has generated local thickening, deformation and paleocollapse structures, which only affect the alluvial mantle. In reach IV, terrace deposits thicken to over 60 m resulting from a large-scale synsedimentary subsidence. In this sector, subsidence locally affects to both the alluvium and the underlying bedrock. This indicates that dissolution acts at the rockhead beneath the alluvial cover (alluvial karst) and within the evaporitic substratum (interstratal karst). The development of an intraevaporitic karst in reach IV is attributed to gypsum and salt dissolution. Irregular terrace gravel bodies (gravel pockets) embedded in a fine-grained matrix associated with paleocollapse structures have been interpreted as liquefaction–fluidization structures resulting from ground acceleration and suction induced by catastrophic collapses. Subsidence is currently active in the region affecting areas with a thin alluvial cover in reaches III and IV. The low subsidence activity in most of Zaragoza city is explained by the presence of thickened (around 50 m) and indurated alluvial deposits. In the surrounding area, numerous buildings in Cadrete and Santa Fe villages have been severely damaged by subsidence. Natural and human-induced subsidence favours the development of slope movements in the gypsum scarp overlooking Cadrete village. Several transport routes including the Imperial Canal (irrigation canal) and the recently completed Madrid–Barcelona high-speed railway are affected by human-induced sinkholes. The paleocollapse structures exposed in the trenches of this railway and a ring road under construction point to hazardous locations underlain by cavities and collapse structures where special protection measures should be applied. Rigid structures are recommended beneath the high-speed railway with sufficient strength to span the larger sinkholes with no deformation. Electronic monitoring devices linked to a warning system can detect subtle subsidence-induced deformations in carriageways or railways. This research demonstrates that the study of the paleokarst helps to understand the processes involved in the present-day subsidence phenomena and their general spatial distribution.     

Geological and environmental implications of the evaporite karst in Spain

In Spain, evaporite outcrops cover approximately 7% of the total area of the country. Most of the evaporitic formations are made up of Ca-sulfates (gypsum/anhydrite) or Ca-sulfates and halite. Certain Paleogene marine evaporites also contain K-Mg-chlorides, and some Tertiary continental formations bear substantial amounts of Na-sulfates in the subsurface (glauberite and thenardite). Mesozoic evaporitic formations commonly wedge out towards the ground surface, passing into condensed sequences and dissolution-collapse breccias. Some of these highly porous breccias constitute major regional aquifers. In several areas, interstratal karstification of the evaporites has given rise to gravitational deformations such as basin structures, monoclines, and collapse structures covering several square kilometers that record a cumulative subsidence in excess of 200 m (Teruel and Calatayud Grabens). A widespread consequence of evaporite dissolution processes in Spain is the hydrochemical degradation of surface waters. Some of the largest and most outstanding lake systems, from an environmental perspective, occur in karstic depressions developed in evaporitic formations (Fuente de Piedra, Gallocanta, Bujaraloz, and Bañolas lakes). Sinkhole activity is a major geohazard in several evaporite karst areas. The sinkhole risk has a particularly high impact in sectors where Tertiary evaporites are overlain by Quaternary alluvial aquifers (Calatayud, Zaragoza, and Madrid areas). Some of the detrimental effects of subsidence include severe damage to historical monuments (Calatayud), the demolition of a whole village (Puilatos), or the derailment of a freight train (Zaragoza area). The deepest gypsum caves are found in Triassic diapiric structures (El Sumidor Cave, 210 m deep), and the longest ones are developed in horizontally lying Neogene sequences (Sorbas caves, and Estremera maze cave). The Cardona diapir hosts salt caves up to 4,300 m long whose genesis is related to flooding of mine galleries caused by the interception of a phreatic conduit. The main anthropogenic impacts on the endokarstic systems are related to the disposal of wastewaters and the destruction of caves by quarrying. The fluvial valleys that cross Tertiary evaporitic outcrops commonly show peculiar geological characteristics related to dissolution-induced synsedimentary subsidence phenomena: (1) Thickened alluvium filling dissolution basins up to several tens of kilometers long and more than 100 m deep. The largest thickenings are found in areas where the bedrock contains halite and glauberite. (2) Superimposed alluvial units locally bounded by angular unconformities. (3) Abundant deformational structures and paleosinkholes related to the rockhead and/or interstratal karstification of the substratum. These fluvial valleys typically are flanked by a prominent gypsum escarpment. Rock-falls favored by the dissolutional enlargement of joints derived from these scarps are the type of mass movement which has caused the highest number of casualties in Spain.     

Gypsum-karst problems in constructing dams in the USA

Gypsum is a highly soluble rock and is dissolved readily to form caves, sinkholes, disappearing streams, and other karst features that typically are also present in limestones and dolomites. Gypsum karst is widespread in the USA and has caused problems at several sites where dams were built, or where dam construction was considered. Gypsum karst is present (at least locally) in most areas where gypsum crops out, or is less than 30–60 m below the land surface. These karst features can compromise on the ability of a dam to hold water in a reservoir, and can even cause collapse of a dam. Gypsum karst in the abutments or foundation of a dam can allow water to pass through, around, or under a dam, and solution channels can enlarge quickly, once water starts flowing through such a karst system. The common procedure for controlling gypsum karst beneath the dam is a deep cut-off trench, backfilled with impermeable material, or a close-spaced grout curtain that hopefully will fill all cavities. In Oklahoma, the proposed Upper Mangum Dam was abandoned before construction, because of extensive gypsum karst in the abutments and impoundment area. Catastrophic failure of the Quail Creek Dike in southwest Utah in 1989 was due to flow of water through an undetected karstified gypsum unit beneath the earth-fill embankment. The dike was rebuilt, at a cost of US $12 million, with construction of a cut-off trench 600 m long and 25 m deep. Other dams in the USA with severe gypsum-karst leakage problems in recent years are Horsetooth and Carter Lake Dams, in Colorado, and Anchor Dam, in Wyoming.     

Spatial distribution, morphometry and activity of La Puebla de Alfindén sinkhole field in the Ebro river valley (NE Spain): applied aspects for hazard zonation

A highly active collapse sinkhole field in the evaporitic mantled karst of the Ebro river valley is studied (NE Spain). The subsidence is controlled by a NW-SE trending joint system and accelerated by the discharge of waste water from a nearby industrial state. The morphometry, spatial distribution and temporal evolution of the sinkholes have been analysed. The volume of the sinkholes yields a minimum estimate of average lowering of the surface by collapse subsidence of 46 cm. The clustering of the sinkholes and the tendency to form elongated uvalas and linear belts, in a NW–SE direction have a predictive utility and allow the establishment of criteria for a hazard zonation. With the precipitation record supplied by a pluviograph and periodic cartographic and photographic surveys the influence of heavy rainfall events on the triggering of collapses has been studied.     

Environmental problems and geological implications derived from evaporite dissolution in the Barbastro salt anticline (NE Spain)

The halite-bearing Barbastro Formation crops out in the core of the Barbastro Anticline (Ebro Tertiary Basin). This anticline is traversed perpendicularly by some of the most important Pyrenean drainages such as the Cinca and Noguera-Ribagorzana Rivers. The terrace sequences of these fluvial systems have been used as markers to identify and assess dissolution-induced subsidence and salt tectonics. In the limbs of the anticline, terrace deposits underlain by detrital bedrock do not show any evidence of deformation and have a consistent thickness of less than 10 m. The deposits of certain terrace levels of the Noguera-Ribagorzana River and its tributary, the Lo Reguer Creek, are locally thickened filling basins generated by dissolution-induced synsedimentary subsidence up to several kilometers long and more than 100 m deep. Conversely, terraces of the Cinca River do not show anomalously high thicknesses, but local uplifts related to differential upward flow of the halite-bearing bedrock. Locally, a minimum uplift rate of 0.3 mm/year has been estimated from a 64-ka terrace tilted away from the valley. The subsidence hazards occur chiefly in areas where the ground receives artificial water recharge. Serviceability of some canals has been notoriously affected by evaporite karstification. The problem has been mitigated to acceptable levels by grouting. Numerous buildings of Ivars de Noguera are severely damaged by dissolution subsidence, and possibly, by hydrocompaction of gypsiferous silts. The pipe network has been replaced to ameliorate the subsidence risk. In the Cinca River valley, cavities with a total volume of about 180,500 m³ have been created by solution mining at depths greater than 500 m. No investigation methods are applied in the brine field to monitor the distribution and evolution of artificial voids. Substantial increase in salinity of the Cinca River is another evidence of subjacent evaporite dissolution.     

Development and validation of sinkhole susceptibility models in mantled karst settings. A case study from the Ebro valley evaporite karst (NE Spain)

A preliminary sinkhole susceptibility analysis has been carried out in a stretch 50 km² in area of the Ebro valley alluvial evaporite karst (NE Spain). A spatial database consisting of a sinkhole layer and 27 thematic layers related to causal factors was constructed and implemented in a GIS. Three types of sinkholes were differentiated on the basis of their markedly different morphometry and geomorphic distribution: large subsidence depressions (24), large collapse sinkholes (23), and small cover-collapse sinkholes (447). The susceptibility models were produced analysing the statistical relationships between the mapped sinkholes and a set of conditioning factors using the Favourability Functions approach. The statistical analyses indicate that the best models are obtained with 6 conditioning factors out of the 27 available ones and that different factors and processes are involved in the generation of each type of sinkhole. The validation of two models by means of a random-split strategy shows that reasonably good predictions on the spatial distribution of future dolines may be produced with this approach; around 75% of the sinkholes of the validation sample occur on the 10% of the pixels with the highest susceptibility and about 45% of the area can be considered as safe.     

Monitoring ground subsidence induced by salt mining in the city of Tuzla (Bosnia and Herzegovina)

Salt mining induced ground subsidence is a major hazard in the city of Tuzla (Northeastern sector of Bosnia and Herzegovina) and its surroundings since 1950, when solution mining of salt deposits by boreholes began. An analysis of the large (and never before processed) amount of topographical data collected during two periods: from 1956 to the Balkan War, and from 1992 to 2003 has been made. The analysis reveals a cumulative subsidence as high as 12 m during the whole period, causing damage to buildings and infrastructures within an area that includes a large portion of the historical town. Human-induced subsidence, (with rates up to 40 cm/year in the most developed area), has been investigated to recognize the areas affected by the sinking phenomenon and to produce a subsidence hazard. The time series of topographical observations have been enlarged by conducting new surveys in the urban area by modern space-geodesy methodologies, such as static relative GPS (Global Positioning System) and high resolution satellite imageries. The GPS monitoring started in 2004 and detected a decrease in the subsidence rates to 20 cm/year related to the reduction of salt exploitation. There is close correlation between the average subsidence rate and the annual amount of salt extracted.     

柴达木盆地土壤积盐与盐胀溶陷灾害对工程建设的影响

西北干旱荒漠区盐胀溶陷灾害对工程建设的影响较大,但由于技术、资金等原因,对该类型灾害的研究还非常欠缺。文章在分析地处青海省干进中心的柴达木盆地土壤积盐类型分布特点及成因的基础上,客观地阐述了柴达木盆地土壤成盐环境及盐胀溶陷灾害形成演化对工程建设的影响,进而提出了相应的防护治理对策。     

Subsidence-sinkhole development in light of mud infiltrate structures within interstratal karst of the Coastal Plain,southeast United States

Mud infiltrate structures (MIS) are a class of clastic sedimentary structures that have formed by high-angle gravitational sedimentation in vadose cavernous limestones beneath the Miocene Hawthorn Group. Observations of MIS in caves beneath the Pelham Escarpment, southwest Georgia, suggest three main types occurring either beneath, within, or contiguous to subvertical feeder pipes in the ceiling: (1) rubbly, conical masses; (2) polished, striated, cylindrical masses; and, (3) mud-flow, -drape, and-splash forms. MIS abundance suggests gravitative deposits are a major component to the total volume of cave mud. The muds apparently do not include soil-mantle materials; rather, their sources are poorly cemented clay-rich layers within the overlying Hawthorn Group. In cases where an individual MIS volume is large in proportion to the clastic-cover thickness, but no surface depression is found, the MIS location hypothetically predicts a directly overlying site of potential cover-collapse sinkhole development. Smaller-volume and/or shallower MIS predict the location of potential cover-subsidence sinkholes. The MIS forms suggest plastic and fluid behavior of the sediments occurs during displacements. The capacity for subsurface voids to accept mobile sediments depends on several factors that influence sinkhole development: (1) void size and interconnectedness; (2) spacing and size of subvertical solution pipes which can act as MIS feeders; (3) depth beneath the sediment source of any main horizontal cave development; (4) thickness of the cover sediments; and (5) the presence and depth of any breakout domes. The Hawthorn is present over more than 50 percent of the area underlain by the Floridan Aquifer system and is the system's major upper confining unit. MIS-forming processes are likely to be widely distributed within this stratigraphic setting, promoting ground subsidence and subsurface porosity obliteration. Given the existence of feeder pipes, MIS also are expected to form within the phreatic zone.     

Quaternary tectonic faulting in the Eastern United States

Paleoseismological study of geologic features thought to result from Quaternary tectonic faulting can characterize the frequencies and sizes of large prehistoric and historical earthquakes, thereby improving the accuracy and precision of seismic-hazard assessments. Greater accuracy and precision can reduce the likelihood of both underprotection and unnecessary design and construction costs. Published studies proposed Quaternary tectonic faulting at 31 faults, folds, seismic zones, and fields of earthquake-induced liquefaction phenomena in the Appalachian Mountains and Coastal Plain. Of the 31 features, seven are of known origin. Four of the seven have nontectonic origins and the other three features are liquefaction fields caused by moderate to large historical and Holocene earthquakes in coastal South Carolina, including Charleston; the Central Virginia Seismic Zone; and the Newbury, Massachusetts, area. However, the causal faults of the three liquefaction fields remain unclear. Charleston has the highest hazard because of large Holocene earthquakes in that area, but the hazard is highly uncertain because the earthquakes are uncertainly located.Of the 31 features, the remaining 24 are of uncertain origin. They require additional work before they can be clearly attributed either to Quaternary tectonic faulting or to nontectonic causes. Of these 24, 14 features, most of them faults, have little or no published geologic evidence of Quaternary tectonic faulting that could indicate the likely occurrence of earthquakes larger than those observed historically. Three more features of the 24 were suggested to have had Quaternary tectonic faulting, but paleoseismological and other studies of them found no evidence of large prehistoric earthquakes. The final seven features of uncertain origin require further examination because all seven are in or near urban areas. They are the Moodus Seismic Zone (Hartford, Connecticut), Dobbs Ferry fault zone and Mosholu fault (New York City), Lancaster Seismic Zone and the epicenter of the shallow Cacoosing Valley earthquake (Lancaster and Reading, Pennsylvania), Kingston fault (central New Jersey between New York and Philadelphia), and Everona fault-Mountain Run fault zone (Washington, D.C., and Arlington and Alexandria, Virginia).     

Utilising seasonal variations in hydrogeochemistry and excitation-emission fluorescence to develop a conceptual groundwater flow model with implications for subsidence hazards: an example from Co. Durham, UK

Groundwaters were sampled from four research boreholes, a private supply well and a natural karst resurgence in southern County Durham, England. Time series data sets of piezometric levels, groundwater major ions, and fluorescence of dissolved organic matter (DOM) were interpreted in the light of new geological mapping to assess the movement of groundwater and its potential for the dissolution of gypsum. Three distinct groundwater facies were identified representing contact with gypsiferous strata, dolomitic limestone and Quaternary Till. Piezometric data indicated time varying transverse flow across the gypsifeorus strata, which was confirmed from gradational mixing of groundwater types and cation ratios. Fluorescence of dissolved DOM identified variations in protein and fulvic-like acid fluorescence. The former was taken to represent surface derived, short-lived material. Spatial and temporal variations in protein fluorescence offered a means to trace groundwater movement along the regional groundwater gradient and indicated rapid lateral movement of groundwater. It was concluded that gypsum dissolution is occurring beneath the town of Darlington, however, the presence of a thick deposit of Quaternary till effectively confines the small head differences of approximately 1 m, across the gypsum strata beneath the town. Further to the south, the lowering of the ground surface results in a greater upwards flow of water across the gypsum and is used to explain the presence of historic collapse sinkholes.     

Natural and human-induced dissolution and subsidence processes in the salt outcrop of the Cardona Diapir (NE Spain)

The Cardona Diapir in NE Spain, with a salt outcrop about 0.9 km² in area, has a well-developed endokarstic system that used to discharge into the Cardener River. Underground mining for potassium salt carried out from 1930 to 1990 caused significant changes in the topography and hydrology of the diapir. The accumulation of two halite slag heaps, totalling around 10 million tons, locally dammed the surface drainage, creating closed depressions and preferential zones of water recharge. The waters that infiltrated in one of these depressions, largely derived from uncontrolled sewage disposal, led to the generation of a 335-m-long human-induced cave excavated in one of the slag heaps. Moreover, the inflow of freshwater from the surrounding sandstone aquifer, caused by the excavation of a ventilation gallery, resulted in the generation of a 280-m-long cave. In March 1998, the interception of a phreatic conduit by a halite mine gallery 50 m deep caused dramatic changes in the hydrology and geomorphology of the diapir, including: (a) a sudden decline in the piezometric level of the karstic aquifer; (b) the inflow of freshwater and debris from the Cardener River into the endokarstic system and the mine galleries. A tunnel had to be constructed to divert the river flow from the salt outcrop; (c) massive dissolution of salt, creating new cavities and enlarging the pre-existing ones, including both mine galleries or cave passages. The 4,300-m-long Salt Meanders Cave was largely generated by the inrush of water from the Cardener River into the mine galleries; and (d) the generation of a large number of sinkholes in the vicinity of the Cardener River. An inventory of 178 sinkholes has allowed us to estimate minimum probability values of 4.7 and 8 sinkholes/km²·year for time intervals previous and subsequent to the 1998 mine flood event, respectively.     

雄安新区蓟县系雾迷山组地层水对白云岩溶蚀的模拟实验研究

为了研究雄安新区雾迷山组地层水对白云岩的溶蚀作用,文章以雾迷山组白云岩为研究对象,以井下雾迷山组地层水为实验流体,开展高温高压条件下溶蚀模拟实验。实验结果表明：（1）样品在地层水中的溶蚀速率随温度增加总体呈下降趋势,具有快速下降—缓慢增加—快速下降的特征,在100~140 ℃范围内明显增加。样品在地层水中的溶蚀速率随压力增加明显增大。反应溶液的Ca²⁺、Mg²⁺浓度增加量随温度、压力变化特征与样品溶蚀速率随温度、压力变化特征一致;（2）孔隙、微裂隙欠发育的样品仅在样品表面发生溶蚀,使得样品表面变模糊。孔隙、微裂隙发育的样品,沿粒间、晶间孔隙及各类裂隙溶蚀、扩展,最终呈一定程度连通;（3）埋藏成岩环境下,在100~140 ℃范围存在一个保持较高溶蚀能力的温度窗口,这可能是研究区雾迷山组白云岩岩溶储层形成的有利温度区间。     

青海马海盐湖低品位固体钾矿室内溶矿实验研究

柴达木盆地马海盐湖浅部赋存有储量可观的低品位固体钾盐资源,通过水溶开采即固液转化的方法为企业10万吨/年的钾肥生产提供了资源保障。随着水溶开采工作的持续进行,目前马海钾矿区北部浅部固体钾矿的品位进一步降低,给盐田和选矿工艺的调整带来极大挑战。为使这部分资源得以充分利用,本文以马海盐湖钻孔9-13和9-3附近埋深0～3m的固体钾矿样品为研究对象,系统开展了室内溶矿模拟实验。实验结果表明:(1)在固体钾矿KCl品位较低时,适当提高溶剂的波美度,有利于K⁺的溶出,提高溶出液中K⁺的浓度。(2)溶剂中Na⁺的浓度太低会溶解盐层骨架,而Na⁺的浓度太高会导致结盐,生产中应根据钾矿层的实际情况,以满足溶出液K⁺浓度含量达标为准调整溶剂的波美度。(3)随着马海矿区固体钾矿品位持续降低,当K⁺的浓度达到盐田生产要求时,钠盐池卤水中Na⁺的浓度会明显增加,卤水中SO₄^2-相对浓度也相应增加,钠盐池阶段析出的石...     

重庆中梁山碳酸盐岩溶蚀速率对季节的响应研究

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