Chemical condensation sequences in supernova ejecta

The mineralogical composition of grains produced in supernova ejecta is explored via chemical equilibrium condensation computations. These calculations are carried out for chemical compositions characteristic of each of several supernova zones, taking into account the pressure decrease due to adiabatic expansion and condensation. The distributions of the major elements among the various gaseous species and solid phases are graphically displayed. These computations reveal that many of the major condensates from supernova ejecta are also stable against evaporation in a gas of solar composition at high temperatures. This is especially true for minerals containing the elements O, Mg, Al, Si, Ca, Fe and Ti. Grains which form in supernova ejecta are less likely to become homogenized with solar nebular gas than SN gas and are thus potential sources of exotic isotopic compositions in the early solar system. The calculated elemental distributions of supernova condensates are applied to problems concerning isotopic anomalies and large mass-dependent isotopic fractionations discovered in the meteorite Allende. The order in which the major elements become totally condensed is found to be nearly independent of the supernova zone considered, being the same as that for a solar gas. The consequence of this may be that some of the observed depletions of heavy elements in the interstellar gas are due to supernova-produced dust.Paper presented at the Conference on Protostars and Planets, held at the Planetary Science Institute, University of Arizona, Tucson, Arizona, between January 3 and 7, 1978.     

Petrology and origin of amoeboid olivine aggregates in CR chondrites

Abstract— Amoeboid olivine aggregates (AOAs) are irregularly shaped, fine‐grained aggregates of olivine and Ca, Al‐rich minerals and are important primitive components of CR chondrites. The AOAs in CR chondrites contain FeNi metal, and some AOAs contain Mn‐rich forsterite with up to 0.7 MnO and Mn:Fe ratios greater than one. Additionally, AOAs in the CR chondrites do not contain secondary phases (nepheline and fayalitic olivine) that are found in AOAs in some CV chondrites. The AOAs in CR chondrites record a complex petrogenetic history that included nebular gas‐solid condensation, reaction of minerals with the nebular gas, small degrees of melting, and sintering of the assemblage. A condensation origin for the Mn‐rich forsterite is proposed. The Mn‐rich forsterite found in IDPs, unequilibrated ordinary chondrite matrix, and AOAs in CR chondrites may have had a similar origin. A type A calcium, aluminum‐rich inclusion (CAI) with an AOA attached to its Wark‐Lovering rim is also described. This discovery reveals a temporal relationship between AOAs and type A inclusions. Additionally, a thin layer of forsterite is present as part of the Wark‐Lovering rim, revealing the crystallization of olivine at the end stages of Wark‐Lovering rim formation. The Ca, Al‐rich nodules in the AOAs may be petrogenetically related to the Ca, Al‐rich minerals in Wark‐Lovering rims on type A CAIs. AOAs are chondrite components that condensed during the final stage of Wark‐Lovering rim formation but, in general, were temporally, spatially, or kinetically isolated from reacting with the nebula vapor during condensation of the lower temperature minerals that were commonly present as chondrule precursors.     

Microstructural evidence for complex formation histories of amoeboid olivine aggregates from the ALHA77307 CO3.0 chondrite

The microstructures and compositions of olivine and refractory components in six amoeboid olivine aggregates (AOAs) in the Allan Hills A77307 CO3.0 chondrite have been characterized in detail using the focused ion beam sample preparation technique with transmission electron microscopy. In the AOAs, refractory components (perovskite, melilite, spinel, anorthite, and Al‐Ti‐bearing diopside) provide evidence of a high degree of textural and compositional heterogeneity, suggesting that these phases have formed by disequilibrium gas–solid condensation at high temperatures under highly dynamic conditions. We infer different possible reactions of early‐condensed solid minerals (perovskite and spinel) with a nebular gas, forming diopside with wide ranges of Al and Ti contents and/or anorthite. The progressive, incomplete consumption of spinel in these reactions may have resulted in the Cr enrichment in the remaining, unreacted spinel in the AOAs. In contrast to the refractory components, olivines in the AOAs have equilibrated textures with 120° triple junctions, indicating that the AOAs were subjected to high‐temperature annealing after agglomeration of olivine and refractory components. Because the AOAs consist of fine‐grained olivine grains with numerous pores, the annealing is constrained by experimental data to have occurred for a short duration of the order of a few hours to tens of hours depending on the annealing temperature. In comparison, the effects of annealing on the refractory components are minimal, probably due to pinning of grain boundaries in the multiphase assemblages that inhibited grain growth.     

On the diversity of giant planets—Simulating the evolution of solids in protoplanetary disks

We describe a model designed to track simultaneously the evolution of gas and solids in protoplanetary disks from an early stage, when all solids are in the dust form, to the stage when most solids are in the form of a planetesimal swarm. The model is computationally efficient and allows for a global, comprehensive approach to the evolution of solid particles due to gas–solid coupling, coagulation, sedimentation, and evaporation/condensation. We have used it to calculate the co-evolution of gas and solids starting from a comprehensive domain of initial conditions. Then based on the core accretion-gas capture scenario, we have estimated the planet-bearing capability of the environment defined by the final planetesimal swarm and the still evolving gaseous component of the disk. We describe how the disk's capability of formation of giant planets depends on the initial mass and size of a protoplanetary disk, its thermal structure, mass of the central star and properties of the material forming solid grains.     

The condensation origin of zoned metal grains in Queen Alexandra Range 94411: Implications for the formation of the Bencubbin‐like chondrites

Abstract— Thermodynamic analysis of the compositional profiles across large chemically‐zoned Fe, Ni metal grains in the Bencubbin‐like chondrite Queen Alexandra Range (QUE) 94411 suggests that these grains formed by non‐equilibrium gas‐solid condensation under variable oxidizing conditions, isolation degree, and Cr depletion factors. The oxidizing conditions must have resulted from the complete vaporization of nebular regions with enhanced dust/gas ratios (～ 10–40 × solar). Because the origin of each of the metal grains studied requires different condensation parameters (dust/gas ratio, isolation degree, and Cr depletion factor), a high degree of heterogeneity in the formation region of the Bencubbin‐like chondrite metal is required. To preserve compositional zoning of the metal grains and prevent their melting and sulfidization, the grains must have been removed from the hot condensation region into cold regions where the accretion of the Bencubbin‐like asteroidal body took place.     

Microstructural evidence for a disequilibrium condensation origin for hibonite‐spinel inclusions in the ALHA77307 CO3.0 chondrite

Two hibonite‐spinel inclusions (CAIs 03 and 08) in the ALHA77307 CO3.0 chondrite have been characterized in detail using the focused ion beam sample preparation technique combined with transmission electron microscopy. These hibonite‐spinel inclusions are irregularly shaped and porous objects and consist of randomly oriented hibonite laths enclosed by aggregates of spinel with fine‐grained perovskite inclusions finally surrounded by a partial rim of diopside. Melilite is an extremely rare phase in this type of CAI and occurs only in one inclusion (CAI 03) as interstitial grains between hibonite laths and on the exterior of the inclusion. The overall petrologic and mineralogical observations suggest that the hibonite‐spinel inclusions represent high‐temperature condensates from a cooling nebular gas. The textural relationships indicate that hibonite is the first phase to condense, followed by perovskite, spinel, and diopside. Texturally, melilite condensation appears to have occurred after spinel, suggesting that the condensation conditions were far from equilibrium. The crystallographic orientation relationships between hibonite and spinel provide evidence of epitaxial nucleation and growth of spinel on hibonite surfaces, which may have lowered the activation energy for spinel nucleation compared with that of melilite and consequently inhibited melilite condensation. Hibonite contains abundant stacking defects along the (001) plane consisting of different ratios of the spinel and Ca‐containing blocks within the ideal hexagonal hibonite structure. This modification of the stacking sequence is likely the result of accommodation of excess Al in the gas into hibonite due to incomplete condensation of corundum from a cooling gas under disequilibrium conditions. We therefore conclude that these two hibonite‐spinel inclusions in ALHA77307 formed by high‐temperature condensation under disequilibrium conditions.     

Grain formation in the ejecta of a supernova: the nucleation rate of grains heated by radiation

In the ejecta of a supernova, the temperature of the created grains differs from that of the gas due to the radiation from the star. We investigated the grain formation in the supernova using a developed new nucleation rate where the temperature difference between the gas and the grains is taken into account. If the temperature of the grains is higher than that of the gas, the nucleation process does not occur when the gaseous temperature attains the condensation temperature. As a result we found that the temperature difference between the gas and the grains in SN1987A is about 50–200K which leads that the nucleation is delayed for about 20–100 days.     

The solar system evolution

The concepts on the spatially-periodic condensation in the solar system have been considered in the light of the general theory of the evolution of the solar system. It has been shown that as protodisks arise and compress, the role of hydromagnetic effects weakens. After the stage of spatially-periodic condensation and accretion, the concentration of gas in protodisks decreases and the role of hydromagnetic effects increases again. Specific features of the formation of planets near the Sun and satellites near the planets can be explained if these peculiarities of the evolution are taken into account. The corresponding role of the above processes has been evaluated numerically.The accretion of gas molecules both by jet streams arising after spatially-periodic condensation and by planet embryos has also been considered. Characteristic times of these processes have been estimated.The results obtained show that the general concept on the solar system evolution (Alfvén and Arrhenius, 1976) is in good agreement with the mechanism of spatially-periodic condensation, which takes place during the formation of primary rings of the solar and satellite systems (Gladyshev, 1977).     

Primodial retention of carbon by the terrestrial planets

Chemical equilibrium calculations on the stability of pure and dissolved graphite and cohenite (Fe₃C), several other carbides, and several carbonates have been carried out for a system with solar elemental abundances over a very wide range of temperature and pressure. The calculated abundances of condensed carbon compounds are similar to the observed inventories on Earth and Venus, but fully 10 times smaller than the minimum carbon abundance found in ordinary chondrites. The total carbon content of most iron meteorites is compatible with their origin as a cooling FeNiCSP solution which was saturated with dissolved carbon at the solidus, such as would be produced by melting an ordinary chondrite, not by direct condensation from or equilibrium with the primitive solar nebula. It is argued that the carbon content of Mars need not be appreciably greater than that of the Earth. Material with even lower formation temperatures than Mars, such as the primitive material in the asteroid belt, may retain substantially more carbon as disequilibrium polymeric organic matter, possibly by the Fischer-Tropsch mechanism favored by Anders. Carbonates are not found as equilibrium products in a solar-composition system, and are probably secondary alteration products. CaCO₃ might, however, persist in a solar-composition gas at temperatures below 460°K and pressures below 10^?6.6 bar. The most stable condensed carbon compounds are found to be graphite, Fe₃C, and possibly TiC, all in solid solution in the metal phase.     

Silica‐rich igneous rims around magnesian chondrules in CR carbonaceous chondrites: Evidence for condensation origin from fractionated nebular gas

Abstract— The outer portions of many type I chondrules (Fa and Fs <5 mol%) in CR chondrites (except Renazzo and Al Rais) consist of silica‐rich igneous rims (SIRs). The host chondrules are often layered and have a porphyritic core surrounded by a coarse‐grained igneous rim rich in low‐Ca pyroxene. The SIRs are sulfide‐free and consist of igneously‐zoned low‐Ca and high‐Ca pyroxenes, glassy mesostasis, Fe, Ni‐metal nodules, and a nearly pure SiO₂ phase. The high‐Ca pyroxenes in these rims are enriched in Cr (up to 3.5 wt% Cr₂O₃) and Mn (up to 4.4 wt% MnO) and depleted in Al and Ti relative to those in the host chondrules, and contain detectable Na (up to 0.2 wt% Na₂O). Mesostases show systematic compositional variations: Si, Na, K, and Mn contents increase, whereas Ca, Mg, Al, and Cr contents decrease from chondrule core, through pyroxene‐rich igneous rim (PIR), and to SIR; FeO content remains nearly constant. Glass melt inclusions in olivine phenocrysts in the chondrule cores have high Ca and Al, and low Si, with Na, K, and Mn contents that are below electron microprobe detection limits. Fe, Ni‐metal grains in SIRs are depleted in Ni and Co relative to those in the host chondrules. The presence of sulfide‐free, SIRs around sulfide‐free type I chondrules in CR chondrites may indicate that these chondrules formed at high (>800 K) ambient nebular temperatures and escaped remelting at lower ambient temperatures. We suggest that these rims formed either by gas‐solid condensation of silica‐normative materials onto chondrule surfaces and subsequent incomplete melting, or by direct SiO_(gas) condensation into chondrule melts. In either case, the condensation occurred from a fractionated, nebular gas enriched in Si, Na, K, Mn, and Cr relative to Mg. The fractionation of these lithophile elements could be due to isolation (in the chondrules) of the higher temperature condensates from reaction with the nebular gas or to evaporation‐recondensation of these elements during chondrule formation. These mechanisms and the observed increase in pyroxene/olivine ratio toward the peripheries of most type I chondrules in CR, CV, and ordinary chondrites may explain the origin of olivine‐rich and pyroxene‐rich chondrules in general.     

A hibonite‐corundum inclusion from Murchison: A first‐generation condensate from the solar nebula

Abstract— Through freeze‐thaw disaggregation of the Murchison (CM) carbonaceous chondrite, we have recovered a ?90 times 75 μm refractory inclusion that consists of corundum and hibonite with minor perovskite. Corundum occurs as small (?10 μm), rounded grains enclosed in hibonite laths (?10 μm wide and 30–40 μm long) throughout the inclusion. Perovskite predominantly occurs near the edge of the inclusion. The crystallization sequence inferred petrographically‐corundum followed by hibonite followed by perovskite‐is that predicted for the first phases to form by equilibrium condensation from a solar gas for P^tot ≤5 times 10^?3 atm. In addition, the texture of the inclusion, with angular voids between subhedral hibonite laths and plates, is also consistent with formation of the inclusion by condensation. Hibonite has heavy rare earth element (REE) abundances of ?40 × CI chondrites, light REE abundances ?20 × CI chondrites, and negative Eu anomalies. The chondrite‐normalized abundance patterns, especially one for a hibonite‐perovskite spot, are quite similar to the patterns of calculated solid/gas partition coefficients for hibonite and perovskite at 10^?3 atm and are not consistent with formation of the inclusion by closed‐system fractional crystallization. In contrast with the features that are consistent with a condensation origin, there are problems with any model for the formation of this inclusion that includes a molten stage, relic grains, or volatilization. If thermodynamic models of equilibrium condensation are correct, then this inclusion formed at pressures <5 times 10^?3 atm, possibly with enrichments (<1000x) in CI dust relative to gas at low pressures (below 10^?4 atm). Both hibonite and corundum have δ17O ? δ18O ? ?50%, indicating formation from an 16O‐rich source. The inclusion does not contain radiogenic ²⁶Mg and apparently did not contain live ²⁶Al when it formed. If the short‐lived radionuclides were formed in a supernova and injected into the early solar nebula, models of this process suggest that ²⁶Al‐free refractory inclusions such as this one formed within the first ?6 times 10⁵ years of nebular collapse.     

Condensation and vaporization studies of CH3OH and NH3 ices: major implications for astrochemistry

In an extension of previously reported work on ices containing H2O, CO, CO2, SO2, H2S, and H2, we present measurements of the physical and infrared spectral properties of ices containing CH3OH and NH3. The condensation and sublimation behavior of these ice systems is discussed and surface binding energies are presented for all of these molecules. The surface binding energies can be used to calculate the residence times of the molecules on grain surfaces as a function of temperature. It is demonstrated that many of the molecules used to generate radio maps of and probe conditions in dense clouds, for example CO and NH3, will be significantly depleted from the gas phase by condensation onto dust grains. Attempts to derive total column densities solely from radio maps that do not take condensation effects into account may vastly underestimate the true column densities of any given species. Simple CO condensation onto and vaporization off of grains appears to be capable of explaining the observed depletion of gas phase CO in cold, dense molecular cores. This is not the case for NH3, however, where thermal considerations alone predict that all of the NH3 should be condensed onto grains. The fact that some gas phase NH3 is observed indicates that additional desorption processes must be involved. The surface binding energies of CH3OH, in conjunction with this molecule's observed behavior during warm up in H2O-rich ices, is shown to provide an explanation of the large excess of CH3OH seen in many warm, dense molecular cores. The near-infrared spectrum and associated integrated band strengths of CH3OH-containing ice are given, as are middle infrared absorption band strengths for both CH3OH and NH3.     

An imaging,tunable magneto-optical filter

The Imaging, Tunable Magneto-Optical Filter (ITMOF) is a one- or two-cell magnetic birefringence filter designed to measure the Doppler shift of the solar potassium line (770 nm) with respect to a laboratory standard. Two gas vapor cells contain isotopically refined potassium and operate at temperature near 393 K. Hot cell windows are employed in a carefully controlled thermal environment to limit spurious birefringence in the pyrex cell and prevent condensation in the light path. Electromagnets provide a variable strength and direction longitudinal magnetic field of up to 5000 G on each cell. There is no rotating quarter-wave plate or other moving parts. The final image is detected with a CCD camera system.     

The Fountain Hills unique CB chondrite: Insights into thermal processes on the CB parent body

Abstract— We report the results of an extensive study of the Fountain Hills chondritic meteorite. This meteorite is closely related to the CB_a class. Mineral compositions and O‐isotopic ratios are indistinguishable from other members of this group. However, many features of Fountain Hills are distinct from the other CB chondrites. Fountain Hills contains 23 volume percent metal, significantly lower than other members of this class. In addition, Fountain Hills contains porphyritic chondrules, which are extremely rare in other CB_a chondrites. Fountain Hills does not appear to have experienced the extensive shock seen in other CB chondrites. The chondrule textures and lack of fine‐grained matrix suggests that Fountain Hills formed in a dust‐poor region of the early solar system by melting of solid precursors. Refractory siderophiles and lithophile elements are present in near‐CI abundances (within a factor of two, related to the enhancement of metal). Moderately volatile and highly volatile elements are significantly depleted in Fountain Hills. The abundances of refractory siderophile trace elements in metal grains are consistent with condensation from a gas that is reduced relative to solar composition and at relatively high pressures (10^?3bars). Fountain Hills experienced significant thermal metamorphism on its parent asteroid. Combining results from the chemical gradients in an isolated spinel grain with olivine‐spinel geothermometry suggests a peak temperature of metamorphism between 535 °C and 878 °C, similar to type‐4 ordinary chondrites.     

Some aspects of condensation in clouds

Several general features of nucleation characteristics of low density cosmic clouds are discussed. These are: (1) tendency for metastable condensates to form, (2) non-occurrence of nominal refractory molecule in the gas, (3) a strong temperature dependence of condensation at relatively low temperatures, and (4) significant vibrational disequilibrium in cosmic clouds. These support previous analyses by the author which indicate that equilibrium calculations have restricted applicability. A kinetic treatment of condensation is required for cosmic grains and the possibility of formulating such an analysis is pointed out.Invited contribution to the Proceedings of a Workshop onThermodynamics and Kinetics of Dust Formation in the Space Medium, held at the Lunar and Planetary Institute, Houston, 6–8 September, 1978.     

The role of exchange reactions in oxygen isotope fractionation during CAI and chondrule formation

Abstract— The role of oxygen isotope exchange during evaporation and condensation of silicate melt is quantitatively evaluated. Silicate dusts instantaneously heated above liquidus temperature are assumed to cool in gas and experience partial evaporation and subsequent recondensation. The results show that isotopic exchange effectively suppresses mass‐dependent O‐isotope fractionation even if the degree of evaporation is large, which is the fundamental difference from the case without isotopic exchange. The final composition of silicate melt strongly depends on the initial abundance of oxygen in the ambient gas relative to that in silicate dust, but not on the cooling rate of the system. The model was applied to O‐isotope evolution of silicate melts in isotopically distinct gas of the protoplanetary disk. It was found that deviation from a straight mixing line toward the δ¹⁸O‐rich side on the three‐oxygen isotope diagram is inevitable when mass‐dependent fractionation and isotopic exchange take place simultaneously; the degree of deviation depends on the abundance of oxygen in an ambient gas and isotopic exchange efficiency. The model is applied to explain O‐isotopic compositions of igneous CAIs and chondrules.     

Mineralogy and petrography of amoeboid olivine aggregates from the reduced CV3 chondrites Efremovka,Leoville and Vigarano: Products of nebular condensation,accretion and annealing

Abstract— Amoeboid olivine aggregates (AOAs) from the reduced CV chondrites Efremovka, Leoville and Vigarano are irregularly‐shaped objects, up to 5 mm in size, composed of forsteritic olivine (Fa_<10) and a refractory, Ca, Al‐rich component. The AOAs are depleted in moderately volatile elements (Mn, Cr, Na, K), Fe, Ni‐metal and sulfides and contain no low‐Ca pyroxene. The refractory component consists of fine‐grained calcium‐aluminum‐rich inclusions (CAIs) composed of Al‐diopside, anorthite (An₁₀₀), and magnesium‐rich spinel (～1 wt% FeO) or fine‐grained intergrowths of these minerals; secondary nepheline and sodalite are very minor. This indicates that AOAs from the reduced CV chondrites are more pristine than those from the oxidized CV chondrites Allende and Mokoia. Although AOAs from the reduced CV chondrites show evidence for high‐temperature nebular annealing (e.g., forsterite grain boundaries form 120° triple junctions) and possibly a minor degree of melting of Al‐diopside‐anorthite materials, none of the AOAs studied appear to have experienced extensive (>50%) melting. We infer that AOAs are aggregates of high‐temperature nebular condensates, which formed in CAI‐forming regions, and that they were absent from chondrule‐forming regions at the time of chondrule formation. The absence of low‐Ca pyroxene and depletion in moderately volatile elements (Mn, Cr, Na, K) suggest that AOAs were either removed from CAI‐forming regions prior to condensation of these elements and low‐Ca pyroxene or gas‐solid condensation of low‐Ca‐pyroxene was kinetically inhibited.     

Greenhouse models of the atmosphere of titan

The greenhouse effect is calculated for a series of model atmospheres of Titan containing varying proportions of methane, hydrogen, helium, and ammonia. The pressure induced transitions of hydrogen and methane are the major sources of infrared opacity. For each model atmosphere we first computed its temperature structure with a radiative-convective equilibrium computer program and then generated its brightness temperature spectrum to compare with observed values. This comparison indicates that the methane-to-hydrogen ratio is 1_?.67⁺², the surface pressure is at least 0.4atm, and the surface temperature at least 150°K. In addition, except possibly close to the surface, the amount of ammonia is far less than the saturation vapor value. Large amounts of helium may also be present. Many of the successful model atmospheres have methane condensation clouds in the upper troposphere, which help reconcile spectroscopic gas abundances and the observed ultraviolet albedo of Titan with the gas amounts required for the greenhouse effect. The occurrence of large amounts of hydrogen may be a prerequisite for the occurrence of large amounts of methane in the atmosphere and vice versa. This hypothesis may help explain why Titan is the only satellite in our solar system known to have an atmosphere.     

Structural clues to the origin of refractory metal alloys as condensates of the solar nebula

Abstract– Alloys of the refractory metals Re, Os, W, Ir, Ru, Mo, Pt, and Rh with small amounts of Fe and Ni are predicted to be one of the very first high‐temperature condensates in a cooling gas of solar composition. Recently, such alloy grains were found in acid‐resistant residues of the Murchison CM2 chondrite. We used focused ion beam (FIB) preparation to obtain electron‐transparent sections of 15 submicrometer‐sized refractory metal nuggets (RMNs) from the original Murchison residue. We studied their crystallography, microstructures, and internal compositional variations using transmission electron microscopy (TEM). Our results show that all RMNs studied have hexagonal close‐packed (hcp) crystal structures despite considerable variations of their bulk compositions. Crystallographic superstructures or signs of spinodal decomposition are absent and defect microstructures are scarce. Internally, RMNs are compositionally homogeneous, with no evidence for zoning patterns or heterogeneities due to exsolution. Many RMNs show well‐defined euhedral crystal shapes and all are nearly perfect single crystal. Our findings are consistent with a direct (near‐) equilibrium condensation of refractory metals into a single alloy at high temperature in the solar nebula as predicted by current condensation models. We suggest that this alloy is generally hcp structured due to an extended ε‐phase field in the relevant multicomponent alloy system. The high degree of structural perfection and compositional homogeneity is attributed to high defect energies, high formation temperatures, slow cooling rates, small grain sizes, and rapid internal diffusion.