Weathering of volcanic tuff rocks caused by moisture expansion

Moisture expansion in natural building stones is considered one of the most important factors affecting their weathering and deterioration. The processes that may be responsible for the expansion under determinate relative humidity (hygric dilatation) and water-saturated conditions (hydric dilatation) are generally attributed to the presence of swellable clay minerals. In contrast to this assumption, our investigations show that moisture expansion also takes place in volcanic tuff building stones almost free from clay minerals. To provide a deeper understanding of the processes, swelling and deterioration were performed on 14 volcanic tuffs used as important building stones of different ages, compositions and weathering stages from Mexico, Germany and Hungary. The investigations undertaken include extensive chemical, petrophysical and fabric analyses. The samples show a wide range of effective porosity, microporosity, capillary water absorption, moisture expansion, and CEC values. High moisture expansion does not seem to depend on clay mineral content alone. We also observed that there is no significant effect on dilatation if clay minerals are present but only form a thin coat on the outer shell of bigger pores. Moreover, we identified a correlation between microporosity, average pore radius and moisture expansion. The investigations highlight the fact that moisture expansion cannot only be attributed to swellable clay minerals, and suggest that the presence and accumulation of micropores and their average radius and distribution play an important role for non-clay associated swelling intensity, which can most probably be attributed to the disjoining pressure.     

Petrographical and petrophysical properties of sandstones: statistical analysis as an approach to predict material behaviour and construction suitability

Most studies dealing with material properties of sandstones are based on a small data set. The present study utilizes petrographical and petrophysical data from 22 selected sandstones and ~300 sandstones from the literature to estimate/predict the material and weathering behaviour of characteristic sandstones. Composition and fabric properties were determined from detailed thin section analyses. Statistical methods applied consist of data distributions with whisker plots and linear regression with confidence regions for the petrophysical and weathering properties. To identify similarities between individual sandstones and to define groups of specific sandstone types, principal component and cluster analyses were applied. The results confirm an interaction between the composition, depositional environment, stratigraphic association and diagenesis, which leads to a particular material behaviour of sandstones. Three different types of pore radii distributions are observed, whereby each is derived from different pore space modifications during diagenesis and is associated with specific sandstone types: (1) bimodal with a maximum in capillary and micropores, (2) unimodal unequal with a maximum in smaller capillary pores and (3) unimodal equable with a maximum in larger capillary pores. Each distribution shows specific dependencies to water absorption, salt loading and hygric dilatation. The strength–porosity relationship shows dependence on the content of unstable lithic fragments, grain contact and type of pore radii distribution, cementation and degree of alteration. Sandstones showing a maximum of capillary pores and micropores (bimodal) exhibit a distinct hygric dilatation and low salt resistance. These sandstones are highly immature sublitharenites–litharenites, characterized by altered unstable rock fragments, which show pointed-elongated grain contacts, and some pseudomatrix. Quartz arenites and sublitharenites–litharenites which are strongly compacted and cemented, show unimodal unequal pore radii distributions, low porosity, high strength and a high salt resistance. The presence of swellable clay minerals in sublitharenites–litharenites leads to a medium to high hygric dilatation, whereas quartz arenites show little hygric dilatation. Sandstones with unimodal equal pore radii distribution mostly belong to weakly compacted and cemented mature quartz arenites. These are characterized by high water absorption and high porosity, low to medium strength and a low salt resistance. The data compiled in this study are used to create a sandstone quality catalogue. Since material properties are dependent on many different parameters of influence, the transition between different lithotypes is fluent.     

Thermal expansion on volcanic tuff rocks used as building stones: examples from Mexico

Three cities in the center of Mexico, declared as cultural heritage, were erected mainly of volcanic tuffs as main construction element. Many of the historic buildings of these cities show significant damage and deterioration. One of the causes of these damages can be attributed to a phenomenon poorly studied in volcanic tuffs, the thermal expansion. To understand the response of volcanic tuffs to thermal expansion, as well as to know their thermal expansion coefficient, thermal expansion test was performed on 12 representative tuffs of these localities. In the same way and to know which of their petrographic, petrophysical, mineralogical, and geochemical properties influence this phenomenon, several laboratory studies were carried out to determine which of these plays an important role in the expansion. The results of our tests showed that volcanic tuffs rocks have very varied thermal expansion values, ranging from 0.7 mm/m at their maximum expansion to even contraction in the order of ??0.5 mm/m. Equally varied were the thermal expansion coefficient values ranging from 10.1 to ??7.2 10^?6/K. The most dominant behavior type is the “anisotropic no residual strain behavior”. In general, the behavior of the tuffs in practically all the tests carried out showed a very important heterogeneity in the rocks; however, in spite of the non-homogeneous behavior of the tuffs, three main factors could be identified that play an important role in the thermal expansion of the studied rocks, the chemical composition, e.g., acid volcanic tuff rocks (rhyolitic composition) had greater expansions, while the more basic rocks (basaltic composition) expanded less, the textural and fabrics homogeneity, e.g., the most homogeneous rocks texturally have higher expansion values and the degree of crystallinity, and, e.g., the tuff rocks with the largest amount of glass showed smaller thermal expansions than the tuffs composed of microcrystals.     

Deterioration mechanisms of tuffs in Midas monument

Slightly weathered white and pink tuffs of the Midas monument have deterioration problems. In this study, depths and characteristics of the weathering zones developed within the tuffs are investigated through optical microscopy, X-ray diffractometry (XRD), chemical analyses, scanning electron microscopy (SEM) and some index parameters. Accelerated weathering tests including wetting–drying, freezing–thawing and salt crystallization are performed, and durability assessment methods are used to predict the durabilities of the tuffs. The findings are compared with field observations. By examining quantitative weathering indices and comparing them with thin section studies, it is found that thin section analyses of the crystals, LoI, and WPI are good indicators to quantify the depth of weathering for the tuffs. However, thin section studies have limited value for fine-grained tuffaceous matrix. The chemical weathering of the tuffs produces weathered zones that are 4.5-cm thick within the white tuff and 2.5-cm thick within the pink tuff. Physical weathering causes scaling of outer layers of the tuffs and fracturing of feldspars along their cleavage planes. However, variations of the index properties of the tuffs due to weathering are not so significant to quantify the weathering depths in the tuffs. Among the accelerated weathering tests, salt crystallization is found to be the most destructive environmental condition. Pigeon droppings rich in NO₃¹⁻ are found to be the main source of soluble salt at the Midas monument. The salt transported up by capillary rise due to surface water causes spalling of the tuffs in the capillary zone. Surface water and salt of any kind in the close vicinity of the monument should be totally eliminated for the purpose of conservation. Field observations and the durability equations reveal that the white tuff is less durable than the pink tuff. Wet-to-dry strength ratio yields a better stone durability assessment among various durability methods used in this study.     

Stress-strain behaviour of reconstituted illitic clay at different temperatures

Tests on specimens of reconstituted illitic clay have examined the influence of temperature on the mechanical behaviour of clay soils. The program involved consolidation to effective confining pressures up to 1.5 MPa, heating to 100°C, and tests on normally consolidated and overconsolidated specimens with OCR = 2. The tests included isotropic consolidation, undrained triaxial compression with pore water pressure measurement, drained tests along controlled stress paths to investigate yielding behaviour, and undrained tests which involved heating and measurement of the resulting induced pore water pressures. The large strain strength envelope is independent of temperature. However, peak undrained strengths increase with temperature because smaller pore water pressures are generated during shearing. An important contribution from the study is a series of results for the yielding of illitic clay at three different temperatures. For the first time, there is clear evidence of yield loci decreasing in size with increasing temperature. An associated flow rule can be assumed without serious error. The results contribute to the confirmation of a thermal elastic-plastic soil model developed by the authors from cam clay following the addition of a small number of extra assumptions. Depending on the initial stress state, heating under undrained conditions may produce shear failure.     

往返荷载下粘性土的强度及取值标准试验研究

通过对粘性土进行一系列动三轴试验，测定并分析了动荷载作用下为粘性土的动剪应力，轴向应变及超孔隙水压力随时间的变化规律，分析了破坏时不同固结比的粘性土对静，动剪强度和孔隙水压力影响规律，得出了粘性土的动剪强度随固结比变化的关系式，并对粘性土的动剪强度判别方法的标准进行探讨，得出了有益的结果。     

Dehumidification property of Eskisehir–Derbent Ciftligi white tuffs in Turkey

In Anatolia, throughout the centuries, caverns in tuffs have been used for food storage. The aim of this study is to investigate experimentally the dehumidification property of tuffs, and to confirm whether tuffs play any part in the humidity of the ecosystem in storage. According to tests carried out on the Eskisehir?CDerbent Ciftligi white tuffs and six different rock types from Turkey, it was found that the atmospheric moisture absorption ability of tuffs is relatively higher than those of other tested rocks. This suggests that the dehumidification property is a unique characteristic of tuffs. It may allow for the tuff walls to work as an air dehumidifier for storing food.     

Melilitite-carbonatite tuffs in the Laetolil Beds of Tanzania

The upper unit of the Laetolil Beds, 45 to 60 m thick, is about 80% wind worked or eolian tuff and 20% air-fall tuff. The air-fall tuffs comprise a phonolitic tuff and numerous thin tuffs of original melilitite-carbonatite composition. Most of the melilitite-carbonatite tuffs consist largely of sand-sized lava globules and crystals cemented by calcite. Evidence of former carbonatite ash is provided by calcite globules, fenestral textures, and high contents of Ba and Sr in early-deposited calcite. These air-fall tuffs were produced by volatile-rich eruptions of highly fluid magma. In a typical eruptive cycle, lava droplets were followed by crystals which increased in size during the eruption. Commonly the final event was an eruption of fine ash and carbonatite globules. Particularly violent explosions ejected blocks of lava and plutonic rock 10 to 15 cm in diameter for distances of 20 km.The climate was semiarid, and melilitite-carbonatite ash layers were first cemented by soluble salts such as trona resulting from incongruent solution of the carbonatite ash by rainfall. Repeated solution and crystallization of salts resulted in a polygonal fracture pattern in the thinner tuffs. Ash layers not cemented by soluble salts were eroded and redeposited by wind to form eolian tuffs. Subsequently both the air-fall and eolian tuffs were modified by several diagenetic stages, mostly in the vadose zone, to form rocks consisting principally of montmorillonite, phillipsite, and calcite. At an early stage calcium carbonate derived from carbonatite ash was precipitated as micrite both as a cement and replacement of organic matter. Glass, nepheline, and melilite were now weathered to clay, releasing components to form phillipsite. Calcite spar was precipitated last, as a replacement, cement, and pore filling. Unaltered glass, preserved in some of the eolian tuffs, has an unusually high content of Na, K, and Fe for a melilitite composition.These beds contain a rich fauna, notable for the excellent preservation of delicate fossils such as bovid dung, land snails, and bird eggs. This preservation is attributed, at least in part, to carbonatite ash. Carbonatite ash was also responsible for the preservation of footprints in one of the tuffs.     

Water absorption process effect on strength of Ayazini tuff,such as the uniaxial compressive strength (UCS), flexural strength and freeze and thaw effect

Tuffs have been used as a construction material possibly since ancient times. In Afyonkarahisar, Turkey, there are numerous buildings constructed by tuff. Tuff has been a local construction material, during the Roman, Seljuk and Ottoman periods. Even though tuffs have relatively low durability and low strength values compared to marble, etc., they have survived with no major deterioration failures on many historical buildings. It has also been preferred because of its high porous texture, lightweight and easy shaping and process properties in the building sector. Naturally, it would be easily affected by water and humidity because of its porous structure. However, having this kind of structure leads to poor durability properties due to keeping water in it. The main objective of this study was to evaluate the physical and mechanical properties of the tuff quarried from the region and possible water effect, which may lead to degradation of its strength and durability of the material, thereby shortening the life span of the building structure used. Samples, which were tested after exposing to water and the freeze and thaw effects, were measured at a certain time. In this study, uniaxial compressive strength and flexural strength tests were conducted on test samples. The test results indicate that water may deteriorate the tuff’s strength properties and durability of the materials in due time.     

Petrophysical behaviour and durability of the Miocene sandstones used in the architectural heritage of Tunisia (Roman aqueduct of Oued Miliane and Uthina Roman site)

In the present work, the relationship between intrinsic factors, mechanical properties and durability of Miocene sandstones used in the architectural heritage of Tunisia, specifically in the Roman aqueduct of Oued Miliane and Uthina site, are studied. The petrographic study and the characterisation of porous network have been carried out using optical microscopy, mercury intrusion porosimetry and laser scanner confocal microscopy (LSCM). The hygric behaviour has also been determined from water absorption under vacuum, drying, capillary water absorption and water vapour permeability. The mechanical properties have been assessed from compressive strength and abrasion tests. Rock durability has been evaluated from salt crystallization (sodium sulphate) accelerated aging tests. The results show good hygric behaviour characterised by a high evaporation rate and almost no retention of water; due to the macroporous character of the rock and the good connectivity of the pore network. Because of the poor lithification, the stone has a very low mechanical strength which makes it very vulnerable to the salt crystallization effects. The absence of chemically unstable minerals preserves the rock from chemical alteration. The durability of the building stone is mainly conditioned by salt loading of the monument.     

软土在不同应力路径下的力学特性分析

通过固结不排水剪应力路径试验对广州南沙典型软土在不同固结条件的力学特性进行了系统研究。分析了初始固结状态对软黏土应力路径依赖性的影响,比较了不同应力路径下土的应力-应变关系特征和孔隙水压力变化规律,探讨了孔压分布与土体变形特征的关系,认为侧向卸荷会造成剪应力增加、体应力减小,从而使土体产生剪胀趋势。研究结果还表明,不排水条件下的有效应力路径主要与土样初始固结状态有关,因而同一固结状态下的有效应力路径具有唯一性。另外,试验中的剪切控制方式对有效应力路径有明显影响,但对土体抗剪强度的影响可以忽略。     

The Hianana Volcanics: Remnants of a Late Permian tuff ring and lava flow,Coombadjha Volcanic Complex,northeastern New South Wales

The Hianana Volcanics consist of bedded tuff and dacitic lava that form a locally mappable unit within the extensive, Late Permian silicic volcanic sequence of northeastern New South Wales. Principal components of the bedded tuff are crystal and volcanic lithic fragments ranging from coarse ash to lapilli, accompanied by variable amounts of fine ash matrix. Well denned plane parallel thin bedding is characteristic. Sandwave bed forms, including low‐angle cross‐beds and wavy beds, are confined to an area of 2–3 km² coinciding with the thickest sections (70 m) of bedded tuff. A high‐aspect ratio flow of porphyritic dacitic lava overlies the bedded tuff in the same area. The setting, lithofacies, extent and geometry of the bedded tuffs of the Hianana Volcanics are comparable with modern tuff rings which are composed of the deposits from base surges generated by explosive phreatomagmatic eruptions at primary volcanic vents. Many of these have also discharged lava late in their activity. Proximal parts of the Hianana tuff ring were buried by the porphyritic lava after the phreatomagmatic eruptions had ceased. In more distal sections, the bedded tuff is less than 10 m thick and dominantly comprises fine grained, plane parallel, very thin beds and laminae; these features suggest an origin by fallout from ash clouds that accompanied the phreatomagmatic eruptions. The distal ash was covered and preserved from erosion by a layer of welded ignimbrite, the source of which is unknown.     

Heulandite and mordenite-rich tuffs from Greece: a potential source for pozzolanic materials

The microcystalline mass of the Pliocene tuffs of Santorini and Polyegos islands, in the South Aegean Volcanic Arc, Greece, is very rich in zeolite minerals, more specifically heulandite type 3, i.e. clinoptilolite, and mordenite. In Santorini, clinoptilolite is the dominant authigenic phase and it was formed in a semi-closed system, by the activity of interstitial water within the volcaniclastic sequence. In Polyegos, mordenite dominates and it was formed by hydrothermal alteration of pyroclastics. Experiments described in this work show that the presence of the zeolite minerals has created materials with excellent pozzolanic properties. Tuffs from the two areas were calcined at 760 °C and for 12 h and then mixed with lime in a constant ratio of 1 part lime to 3 parts calcined tuff. As a result, the free lime content of the lime-calcined tuff mixtures was reduced from 25% to 2.05% (Santorini) and 1.31 % (Polyegos). Compressive strength tests were carried out on concrete cubes made with 100% Portland cement as the cementitious agent, to be used as reference cubes, and concrete cubes in which the Portland cement has been replaced in 4% and 7% proportions by the calcined tuff as pozzolans. The free lime estimation and the compressive strength tests were all carried out in accordance with the British Standards Institution (BS 4550 and BS 1881) guidelines. Early stage measurements of the compressive strength showed that pozzolan-bearing concrete cubes reached values as high as 140% of the reference cubes. The pozzolan-bearing concrete cubes maintained this superior strength throughout the entire one year period of the experiments. After 360 days, they finally maintained 107% of the compressive strength of the reference cubes.     

The Mechanical Behaviour of a Pyroclastic Rock: Yield Strength and “Destructuration” Effects

Summary   A research programme on the mechanical behaviour of a homogenous volcanic tuff found in the centre of the city of Naples (Italy) was carried out at the University of Naples a few years ago. Isotropic and drained triaxial tests were performed in a very wide range of confining pressures (up to 60 MPa). After presenting the stress-strain curve pattern and the mean stress influence on the shear behaviour, the paper focuses on the definition of a strength criterion and of the yield surface for this material. Some tuff samples were subjected to isotropic compression tests up to a confining pressure approximately twice as high as the isotropic yield stress; they were subsequently unloaded and subjected to drained triaxial tests. Partial loosening of the interparticle bonds (“destructuration”) was observed. The paper also compares the mechanical behaviour of intact and “destructured” samples, emphasising the effects of the structure on strength and yield.     

新型三轴剪切试验试样排水固结装置的研制与应用

三轴剪切试验是岩土工程中常见的室内试验,其目的主要是为了获得土的抗剪强度指标和土中孔隙水压力的变化情况。三轴的固结不排水剪（CU）和固结排水（CD）剪试验可以获得土的总应力抗剪强度指标和有效应力抗剪强度指标,因此具有其它剪切试验无法替代的优势。但因试验过程中排水固结的时间很长,影响了试验进度,从而影响到整个工程的进度和经济效益。通过对三轴剪切试样排水固结过程的机理分析,介绍了制作一种可以大大缩短大量试样排水固结时间的装置及该装置的研制方法。采用该装置,可使CU试验的效率提高6～12倍,可使CD试验的效率提高3～6倍。可节约大量的生产成本,提高工作效率,经济效益明显。     

Aspects of sand behaviour by modified constant shear drained tests

Constant shear drained tests (CSD) are probably the most suitable to simulate the strength and deformation behaviour of soils in slopes under water infiltration conditions or lateral stress relief. This is significant because soil behaviour following a CSD stress path could differ from that of traditional compression triaxial tests. In this paper, CSD tests on sand following an alternative procedure are presented and discussed. The modified CSD tests were conducted by increasing the pore water pressure at a constant rate from one end of the specimen with water free to drain from the opposite end. Among the results from specimens consolidated at variable initial void ratios and principal stress ratios it was revealed that specimens showed a tendency to dilate even for loose sands; failure was reached at low axial strains; and a pre-failure type of instability could be identified. The modified procedure has the potential to provide new insights into the failure mechanisms of slopes under a water infiltration condition.     

Undrained Triaxial Behavior of Cement Treated Marine Clay

Clays treated with lower cement contents often exhibit behaviour similar to stiff clays with planar failure surface under triaxial compression. In the present work the behaviour of a marine clay treated with 5 % cement, subjected to undrained triaxial compression tests is studied. The pre-consolidation pressure of the cemented clay due to the cementation bonding is observed to be very high. It is attempted to model the behaviour of cement treated clay using a bounding surface plasticity formulation as the plastic behaviour of the cemented clays within the yield surface has to be considered. The effect of cementation is included in the model as the pre-consolidation pressure obtained from consolidation tests. The tensile strength due to cementation bonds is included in the equation of the bounding surface. Simulations of the undrained triaxial compression tests on cemented clays are carried out and the results are validated with the experimental results.     

Quantification of weathering depths in slightly weathered tuffs

Slightly weathered white and pink tuffs of Midas monument have deterioration problems. In this study, depths of the weathering zones developed in the tuffs are investigated through optical microscopy, XRD, chemical analyses, SEM and some index parameters. By examining quantitative weathering indices and comparing them with thin section studies, it is found that thin section analyses of the phenocrysts, LoI and WPI are good indicators to quantify the depth of weathering for the tuffs. However, thin section studies have limited value for fine-grained tuffaceous matrix. The chemical weathering of the tuffs produces weathered zones that are 4.5 cm thick within the white tuff and 2.5 cm thick within the pink tuff. Physical weathering causes fracturing of feldspars along their cleavage planes. Variations of the index properties of the tuffs caused by weathering are not significant enough to quantify the weathering depths in the tuffs.