Water quality model establishment for middle and lower reaches of Hanshui River,China

With the development of industry and agriculture,nitrogen,phosphorus and other nutrients in the Hanshui River greatly increase and eutrophication has become an important threat to the water quality of the Hanshui River,especially in the middle and lower reaches.The primary objective of this study was to establish the water quality model for the middle and lower reaches of the Hanshui River based on the model of MIKE 11.The main pollutants migration and transformation process could be simulated using the water quality model.The rainfall-runoff model,hy-drodynamic model and water quality model were established using MIKE 11.The pollutants,such as chemical oxygen demand(COD),biochemical oxygen demand(BOD),ammonia nitrogen,nitrate nitrogen,phosphorus,dissolved oxy-gen(DO),were simulated and predicted using the above three models.A set of methods computing non-point source pollution load of the Hanshui River Basin was proposed in this study.The simulated and observed values of COD,BOD5,ammonia,nitrate,DO,and total phosphorus were compared after the parameter calibration of the water quality model.The simulated and observed results match better,thus the model can be used to predict water quality in the fu-ture for the Hanshui River.The pollution trend could be predicted using the water quality model according pollution load generation.It is helpful for government to take effective measures to prevent the water bloom and protect water quality in the river.     

Benthic nutrient recycling in shallow coastal waters of the Bohai Sea

Sediment-water fluxes of N and P species in the Bohai Sea were investigated in September-October 1998 and April-May 1999. The benthic fluxes of nutrient species were determined by incubating sediment core samples with bottom seawater bubbled with air or nitrogen. NO^-2,NH4, dissolved organic nitrogen (DON) and phosphorus (DOP), total dissolved nitrogen (TDN) and phosphorus (TDP), and PO4^3- showed a net exchange flux from seawater to sediment, while NO^-3, dissolved inorganic nitrogen (DIN) and SiO3^2- were released from sediment to seawater in the Bohai Sea. Sediment-water nutrient exchange increases DIN and reduces the phosphorus load in the Bohai Sea. The release of silicate from sediment to overlying seawater reduces potential silicate limitation of primary production resulted from decrease of riverine discharge.The exchange flux of nutrients showed no obvious seasonal variation. The present study showed that the concentrations and composition of nutrients in the water column were affected by suspended sediment, and that not all the exchangeable phosphate in sediment could be released via sediment resuspension.     

Identifying key environmental factors influencing spatial variation of water quality in upper Shitoukoumen Reservoir Basin in Jilin Province, China

Based on the observed data in monitored drainage areas and GIS spatial analysis tools, watershed basic database of Shitoukoumen Reservoir Basin was built. The multivariate analysis and redundancy analysis (RDA) were used to analyze the spatial and temporal variations of water quality, identify the key environmental factors and their patterns influencing the spatial variation of water quality, and determine the main types and forms of the non-point source (NPS) pollutant export controlled by the key environmental factors. The results show that different patterns of environmental factors lead to great changes in water quality at spatial and seasonal scales. All selected environmental factors explain 64.5% and 68.2% of the spatial variation of water quality over dry season and rainy season, respectively, which shows clear seasonal difference. Over dry season, residential land is the most important environmental factor, which possesses 35.4% of the spatial variation, and drainage area is the second key environmental factor, which possesses 17.0% of spatial variation in the total variance. Over rainy season, slope length and drainage area are the key environmental factors, which possess 29.3% of the spatial variation together. Residential land influences nitrogen export by changing NH₄ ⁺-N and particulate organic nitrogen (PON) discharge over dry season, and drainage area controls phosphorus export by regulating dissolved phosphorus (DP) drainage over dry season and phosphorus associated particulate (PAP) loss over rainy season, respectively. Although slope length is an important environmental factor, it does not influence NPS pollutant export. It is interesting that soil organic matter, as a minor environmental factor, highly determines phosphorus and nitrogen export by enhancing the DP, PAP and PON loss.     

A model study on dynamical processes of phytoplankton in Laizhou Bay

A three-dimensional ecosystem model, using a PIC (Particle-In-Cell) method, is developed to reproduce the annual cycle and seasonal variation of nutrients and phytoplankton biomass in Laizhou Bay. Eight state variables, i.e., DIN (dissolved inorganic nitrogen), phosphate, DON (dissolved organic nitrogen), DOP (dissolved organic phosphorus), COD (chemical oxygen demand), chlorophyll-a (Chl-a), detritus and the zooplankton biomass, are included in the model. The model successfully reproduces the observed temporal and spatial variations of nutrients and Chl-a biomass distributions in the bay. The nutrient concentrations are at high level in winter and at low level in summer. Double-peak structure of the phytoplankton (PPT) biomass exists in Laizhou Bay, corresponding to a spring and an autumn bloom respectively. Several numerical experiments are carried out to examine the nutrient limitation, and the importance of the discharges of the Yellow River and Xiaoqinghe River. Both DIN limitation and phosphate limitation exist in some areas of the bay, with the former being more significant than the latter. The Yellow River and Xiaoqinghe River are the main pollution sources of nutrients in Laizhou Bay. During the flood season, the algal growth is inhibited in the bay with the Yellow River discharges being excluded in the experiment, while in spring, the algal growth is enhanced with the Xiaoqinghe River excluded.     

Forms and Balance of Nitrogen and Phosphorus in Cage Culture Waters in Guangdong Province, China

In order to approach the characteristics of nitrogen and phosphorus pollution caused by cage culture and the balance of nitrogen and phosphorus during the process of cage culture, a monitoring was conducted in Daya Bay of Guangdong Province, China from April 2002 to Jane 2003. The results show that the concentrations of total nitrogen (TN) in the waters at the sites with five and ten years of cage culture history are 1.8 and 2.3 times of that at control site respectively. Ammonium (NH3-N) is the main form of nitrogen in spring while nitrate ( NO3 -) in winter. The concentrations of TN, total dissolved nitrogen (TDN) and dissolved organic nitrogen (DON) are highest in autumn. The concentration of phosphorus increases with the increasing of the culturing time, among which phosphate ( PO 34-) increases most obviously. The concentrations of total phosphorus (TP) and total dissolved phosphorus (TDP) are highest in autumn. The nitrogen and phosphorus are accumulated significantly in the sediment of cage culture area. The model of N balance in the cage culture area: bait (70.62%) fry (0.28%) input by tide (14.8%) release from sediment (14.3%) = harvest of adult fish (12.07%) deposition into sediment (28.75%) output by tide (56.18%) others (3.00%). The model of P balance: bait (83.11%) fry (0.17%) input by tide (12.23%) release from sediment (4.49%) = harvest of adult fish (8.43%) deposition into sediment (48.59%) output by tide (41.94%) others (1.04%). In one fish growth year, the contents of nitrogen and phosphorus in harvest of adult fish are only 17.0% and 10.1% of the contents of nitrogen and phosphorus in fish bait and fry, wherein 83% of nitrogen and more than 89% of phosphorus in fish bait became marine pollutants.     

Numerical simulation of nutrient and phytoplankton dynamics in Guangxi coastal bays,China

The increasing riverine pollutants have resulted in nutrient enrichment and deterioration of water quality in the coastal water of Guangxi Province, China. However, the quantitative relationship between nutrient loads and water quality responses, which is crucial for developing eutrophication control strategies, is not well studied. In this study, the riverine fluxes of nutrients were quantified and integrated with nutrient cycling and phytoplankton dynamics by using box models for Guangxi coastal bays. The model concepts and biogeochemical equations were the same; while most model parameters were specific for each bay. The parameters were calibrated with seasonal observations during 2006–2007, and validated with yearly averaged measurements in 2009. The general features of nutrient and phytoplankton dynamics were reproduced, and the models were proved feasible under a wide range of bay conditions. Dissolved inorganic nitrogen was depleted during the spring algal bloom in Zhenzhu Bay and Fangcheng Bay with relatively less nutrient inputs. Phosphorus concentration was high in spring, which decreased then due to continuous phytoplankton consumption. Chlorophyll-a concentration reached its annual maximum in summer, but was the minimum in winter. Eutrophication was characterized by both an increase in nutrient concentrations and phytoplankton biomass in Lianzhou Bay. Either about 80% reduction of nitrogen or 70% reduction of phosphorus was required to control the algal bloom in Lianzhou Bay. Defects of the models were discussed and suggestions to the environmental protection of Guangxi coastal bays were proposed.     

Water quality evaluation in Tidal River reaches of Liaohe River Estuary, China using a revised QUAL2K model

Rivers in the Liaohe River Estuary area have been seriously polluted by discharges of wastewater containing petroleum pollutants and nutrients. In this paper, The Enhanced Stream Water Quality Model (QUAL2K) and its revised model as well as One-dimensional Tide Mean Model (1D model) were applied to predict and assess the water quality of the tidal river reach of the Liaohe River Estuary. Dissolved oxygen (DO), biochemical oxygen demand (BOD₅), ammonia nitrogen (NH₃-N) and total phosphorus (TP) were chosen as water quality indices in the two model simulations. The modelled results show that the major reasons for degraded rivers remain petroleum and non-point source pollution. Tidal water also has a critical effect on the variation of water quality. The sensitivity analysis identifies that flow rate, point load and diffuse load are the most sensitive parameters for the four water quality indices in the revised QUAL2K simulation. Uncertainty analysis based on a Monte Carlo simulation gives the probability distribution of the four water quality indices at two locations (6.50 km and 44.84 km from the river mouth). The statistical outcomes indicate that the observed data fall within the 90% confidence intervals at all sites measured, and show that the revised QUAL2K gives better results in simulating the water quality of a tidal river.     

粤西近岸环流研究进展

粤西近岸环流对粤西乃至北部湾海域的物质输送、水质环境、渔业养殖等都具有重要影响.本研究就粤西沿岸环流(尤其是夏季环流)的基本特征、驱动机制、及其与琼州海峡流关系等方面的研究进展进行了概述,并对存在的问题进行了探讨.前人对粤西沿岸流终年向西以及夏季沿岸流外侧存在气旋式环流等定性特征已达成共识,然而,对环流的主要影响机制以及与琼州海峡流的关系尚有争议,关于环流的定量结果也较为缺乏,还需进行长时间的连续观测以及适合近岸海域的数值模拟.     

2010-2017年嵊泗马鞍列岛保护区海域水质调查与评价

【目的】分析评价2010-2017年嵊泗马鞍列岛保护区海域的水质状况。【方法】采用水质有机污染指数(A)法进行水质有机污染评价,采用富营养化指数(E)法和营养状态质量指数(INQ)法进行水质富营养化评价。【结果】该保护区海域水质化学需氧量(COD)和溶解氧(DO)符合第一类海水水质标准,无机磷(DIP)含量有3个年份符合第一类海水水质标准,其余年份超过第一类但符合第二类海水水质标准,无机氮(DIN)质量浓度超标严重,2015年达到0.674 mg/L;叶绿素a(Chl-a)本底含量较高,适宜条件下使得浮游植物大量繁殖,Chl-a含量急剧上升,并容易诱发赤潮;有机污染指数评价显示,2012-2015年水质有机污染状况达到中度污染以上,并且有3年达到严重污染级别,最大A值为2014年和2015年的4.10,2016年污染最轻,为开始受到污染级别;富营养化指数和营养状态质量指数评价显示,最大E值和INQ值分别为2012年的4.29和2010年的8.59,DIN含量高是富营养化的主要贡献因子。【结论】该保护区海域水质主要污染因子为DIN,水质有机污染状况呈现年度波动状态,水质富营养化较严重。     

Modelling nitrogen and phosphorus dynamics in a mesocosm pelagic ecosystem in Laizhou Bay in China

A model of nitrogen and phosphorus dynamics in mesocosm experiments was established on the basis of a summary and synthesis of the existing models. The established model comprised seven state variables(DIN,PO4-P,DON,DOP,phytoplankton,zooplankton and detritus) and five modules - phytoplankton,zooplankton,dissolved inorganic nutrients,dissolved organic nutrients and detritus. Comparison with the in situ experimental data in Laizhou Bay at the end of August 2002 showed that this model could properly simulate t...     

The environmental implication of diatom fossils in the surface sediment of the Changjiang River estuary(CRE) and its adjacent area

In order to depict the distribution of diatom fossils in surface sediments and to establish a reliable reference data for further paleoenvironmental study in the Changjiang(Yangtze) River estuary and its adjacent waters, the diatom fossils from 34 surface sediment samples and their relationship with environmental variables were analyzed by principal component analysis and redundancy correspondence analysis. The diversity and abundance of diatom fossils were analyzed. Some annual average parameters of the overlying water(salinity, temperature, turbidity, dissolved oxygen, depth, dissolved inorganic nitrogen,dissolved inorganic phosphate and dissolved inorganic silicate) were measured at each sampling site. A total of 113 diatom taxa and one silicoflagellate species were identified in the investigation area. Diatom fossils were better preserved in fine sediments. The absolute abundance of diatom fossils did not significantly dif fer between inshore and of fshore areas, the species diversity decreased from inshore to of fshore. This may be because high nutrients and low salinity promoted the growth of more brackish species in coastal waters. The diatom taxa were divided into three groups, on the basis of their response and indication to environmental changes. For example, Actinocyclus ehrenbergii and Cyclotella stylorum were dominant in coastal waters(Group 1 and Group 3) with high nutrients and low salinity; the relative abundances of Paralia sulcata and Podosira stelliger were significantly higher in of fshore sites(Group 2, average 39.5%),which were characterized by high salinity and deep water. Four environmental variables(salinity, dissolved inorganic nitrogen, temperature and water depth) explained the composition and distribution of diatom taxa independently( P 0.05), this finding can be applied in further paleoenvironmental reconstruction research in this area.     

Occurrence and distribution of dissolved tellurium in Changjiang River estuary

With the implementation of the GEOTRACES program, the biogeochemical cycle and distribution of tellurium （Te） in marine environments are becoming increasing environmental concerns. In this study, the concentration of dissolved Te in the Changjiang （Yangtze） River estuary and nearby waters was determined in May 2009 by hydride-generation atomic fluorescence spectrometry to elucidate the abundance, dominant species, distribution, and relationship with environmental factors. Results show that： （1） dissolved Te was low owing to its low abundance in the Earth＇s crust, high insolubility in water, and strong affinity to particulate matter; （2） Te（IV） and Te（VI） predominated in surface water. Te（VI） was the dominant species in bottom water, and Te（IV） was the minor species; （3） Horizontally, resulting from low phytoplankton metabolism and the weak reduction from Te（VI） to Te（IV） in the shore, Te（IV） was concentrated in the central zone instead of the coastal region. However, Te（VI） was abundant near the mouth of the Changjiang River where the Changjiang water is diluted and in the area to the south where the Taiwan Warm Current invaded. In the adsorption-desorption process, Te（IV） was negatively related to suspended paniculate matter （SPM）, indicating that it was adsorbed by particulate matter. While for Te（VI）, the positive correlation with SPM suggested that it was desorbed from the solid phase. In the estuary, dissolved Te had a negative correlation to salinity. However, it deviated from the dilution line in high-salinity regions due to the invasion of the Taiwan Warm Current and the mineralization of organic matter. The relationship between Te（IV） and SPM nutrients indicated that it was more bioavailable and more related to phosphorus than to nitrogen. Progress in the field is slow and more research is needed to quantify the input of Te to the estuary and evaluate the biochemical role of organisms.     

Geochemical characteristics of phosphorus near the Huanghe River estuary

INTRODUCTIONPhosphorus (P)isanimportantlimitingelementinglobaloceanicproductivity (Holland ,1 978) ,soknowledgeofPisakeytobetterunderstandingofthecyclingofcarbon ,nitrogen,sulfur,andothernu trientelements.Inasimplemassbalancemodel,thelevelofdissolvedPintheoceanisafunctionoftherateofinputviarivers,andtherateofoutputviadepositioninsediments.Inthepresentstudy,thefocusisontheriverinePinputbytheHuangheRiver (YellowRiver)totheBohaiSea,andespeciallyontheamountofPsolubilizedfromsolidphasesupo…     

Nitrogen and phosphorus budgets of the Changjiang River estuary

Eutrophication has emerged as a key environmental problem in Chinese coastal waters, especially in the Changjiang (Yangtze) River estuary. In this area, large nutrient inputs result in frequent harmful algal blooms and serious hypoxia in bottom waters. Four cruises were made in the estuary in 2006 to assess the concentration and distribution of dissolved inorganic nitrogen (DIN) and phosphorus (DIP). The concentration of DIN decreased gradually in a linear relationship with salinity from the river mouth to ...     

Numerical hydrodynamics study around turbine array of tidal stream farm in Zhoushan,China

In recent decades, great efforts have been made to efficiently explore tidal stream energy due to its unique advantages of easy prediction and great potential. China recently launched a national tidal stream farm demonstration project in the waterway between Putuoshan and Hulu Islands in the Zhoushan area. Before deployment of the turbine array, it is necessary to understand the hydrodynamic changes associated with the construction of a turbine array. In this study, we developed a depth-averaged hydrodynamics model that solves the shallow water governing equations to simulate the tidal hydrodynamics around the Zhoushan Archipelago. The simulation results agree with field data in terms of the water elevation and stream velocity. We considered two types of turbine arrays in this study and investigated their impacts on the local hydrodynamics. In general, the stream velocity in the northern and southern areas is reduced due to the power take-off of the turbine array, whereas stream velocity in the western and eastern areas is slightly increased due to the blockage impact of the turbine array.     

Characteristics of diffuse pollution of nitrogen and phosphorous from a small town in the hilly area of the central Sichuan Basin,China

Hydrological and hydro-chemical monitoring of nitrogen (N) and phosphorus (P) in a small urbanized catchment was conducted in the hilly area of the central Sichuan Basin, China, from 2010 through 2011. The diffuse N and P loadings in different forms of total nitrogen (TN) and phosphorus (TP), dissolved nitrogen (DN) and phosphorus (DP), as well as particulate nitrogen (PN) and phosphorus (PP) were calculated based on runoff discharges and chemical analyses. The results revealed that the diffuse pollution concentrations of TN, DN, PN, TP, DP and PP exhibited large variations during rainfall events, with peak concentrations occurring during the initial period. For all of the measured parameters, the event mean concentrations (EMCs) were observed to clearly vary among rainfall events. The EMCs of TN, DN, PN, TP, DP and PP (for all of the observed rainfall events) were 10.04, 6.62, 3.42, 1.30, 0.47 and 0.83 mg/L, respectively. The losses of diffuse N and P exhibited clear seasonal patterns and mainly occurred during the period from July through September, when the losses totaled 99.3 and 9.6 kg/ha for TN and TP, respectively, accounting for 75% and 74% of the total annual loadings. The mean annual loadings of TN and TP were 124.6 and 12.9 kg/ha, respectively. The results indicate that residential areas in the hilly area of the central Sichuan Basin are subject to high diffuse N and P loadings, posing a serious risk to the receiving water quality. Ecological buffering belts are recommended to incorporate into the urbanized catchment to reduce diffuse pollution.     

The baroclinic residual circulation in shallow seas

There are two different modeling approaches which have been proposed and utilized to derive residual currents: the first approach is equivalent to deducing residual currents from current-meter records using filtering techniques or time averages of time-series records to remove tidal variations; in the second approach, filters or time averages over several tidal cycles are applied to the hydrodynamic equations to generate the governing equations for residual circulation. Based on the latter, both the baroclinic dynamic models of residual circulation are proposed, of which one is a two-dimensional transport model and the other is a three-dimensional model with variable eddy viscosity. The two-dimensional transport model is a direct generalization from the barotropic model of residual circulation presented by Nihoul and Randy (1975) and Heaps (1978) to the baroclinic model. In the three-dimensional model with variable eddy viscosity, using a Sturm-Liouville system adopted in the reference [5], the nondimensional problem for residual circulation reduces to the nondimensional problem of the elevation and the expression of residual currents. It should be pointed out that both the baroclinic models developed in the present paper are confined to describe the Eulerian residual circulation only.     

THE CHARACTERISTIC OF MARINE ENVIRONMENT IN LINGDINGYANG ESTUARY

1 HYDROLOGIC FEATURES Lingdingyang Estuary, located at the middle south of Guangdong Province, is a bell-shaped estuary with a north-south direction. Its area is about 2100km2. The north of Qi′ao Island and Inner-Lingding Island, and the south of Humen are grouped as Neilingdingyang Estuary, having an area of 1041km2. Affected by topography, runoff and tide, its dynamic condition is very complicated. Different water areas have different hydrologic features. The topography under …     

黄河三角洲海岸冲淤及泥沙输运模型数值模拟分析

黄河三角洲是陆海交界地带,陆地海洋相互作用显著,泥沙所引起的岸滩演变、港口航道的淤积、水动力环境的改变等问题比较复杂。该文采用三维HEM-3D数值模型对黄河三角洲海域流场变化、盐度、悬浮泥沙浓度及海岸冲淤分布进行了潮流周期内的数值模拟分析。结果表明,黄河三角洲海域的悬浮泥沙浓度分布与潮流场变化和河口泥沙输入有密切的关系,在三角洲北部受五号桩外强潮流区的影响,近岸海底的泥沙发生明显的再悬浮,并在涨潮流向南输送,含沙量达1.5 g/L左右。在三角洲南部(现行河口区域和莱州湾区域),受现行河口入海泥沙扩散的影响显著。海域年冲淤分布,在北部废弃三角洲区域,由于海洋动力作用强烈,浅水冲刷,海底侵蚀显著,形成了明显呈沿岸展布的侵蚀中心,在侵蚀中心以外,侵蚀快速减弱。在现行河口区域,以淤积为主,在羽状流扩散的控制下,泥沙入海后向南输运,至莱州湾区域逐渐减弱。数值模拟的结果与卫星遥感解译的岸线变化基本一致,效果良好。     

Numerical simulation of the hydrodynamics within octagonal tanks in recirculating aquaculture systems

A three-dimensional numerical model was established to simulate the hydrodynamics within an octagonal tank of a recirculating aquaculture system.The realizable k-s turbulence model was applied to describe the flow,the discrete phase model(DPM) was applied to generate particle trajectories,and the governing equations are solved using the finite volume method.To validate this model,the numerical results were compared with data obtained from a full-scale physical model.The results show that:(1) the realizable k-e model applied for turbulence modeling describes well the flow pattern in octagonal tanks,giving an average relative error of velocities between simulated and measured values of 18%from contour maps of velocity magnitudes;(2) the DPM was applied to obtain particle trajectories and to simulate the rate of particle removal from the tank.The average relative error of the removal rates between simulated and measured values was 11%.The DPM can be used to assess the self-cleaning capability of an octagonal tank;(3) a comprehensive account of the hydrodynamics within an octagonal tank can be assessed from simulations.The velocity distribution was uniform with an average velocity of 15 cm/s;the velocity reached0.8 m/s near the inlet pipe,which can result in energy losses and cause wall abrasion;the velocity in tank corners was more than 15 cm/s,which suggests good water mixing,and there was no particle sedimentation.The percentage of particle removal for octagonal tanks was 90%with the exception of a little accumulation of 5 mm particle in the area between the inlet pipe and the wall.This study demonstrated a consistent numerical model of the hydrodynamics within octagonal tanks that can be further used in their design and optimization as well as promote the wide use of computational fluid dynamics in aquaculture engineering.