Spatial–temporal variability in water quality and macro-invertebrate assemblages in the Upper Mara River basin,Kenya

Tropical rivers display profound temporal and spatial heterogeneity in terms of environmental conditions. This aspect needs to be considered when designing a monitoring program for water quality in rivers. Therefore, the physico-chemical composition and the nutrient loading of the Upper Mara River and its two main tributaries, the Amala and Nyangores were monitored. Initial daily, and later a weekly monitoring schedule for 4 months spanning through the wet and dry seasons was adopted. Benthic macro-invertebrates were also collected during the initial sampling to be used as indicators of water quality. The aim of the current study was to investigate the physico-chemical status and biological integrity of the Upper Mara River basin. This was achieved by examining trends in nutrient concentrations and analyzing the structure, diversity and abundance of benthic macro-invertebrates in relation to varying land use patterns. Sampling sites were selected based on catchment land use and the level of human disturbance, and using historical records of previous water quality studies. River water pH, dissolved oxygen, electrical conductivity (EC), temperature, and turbidity were determined in situ. All investigated parameters except iron and manganese had concentration values within allowable limits according to Kenyan and international standards for drinking water. The Amala tributary is more mineralized and also shows higher levels of pH and EC than water from the Nyangores tributary. The latter, however, has a higher variability in both the total phosphorus (TP) and total nitrogen (TN) concentrations. The variability in TP and TN concentrations increases downstream for both tributaries and is more pronounced for TN than for TP. Macro-invertebrate assemblages responded to the changes in land use and water quality in terms of community composition and diversity. The study recommends detailed continuous monitoring of the water quality at shorter time intervals and to identify key macro-invertebrate taxa that can be used to monitor changes of the water quality in rivers of the Mara basin as a result of anthropogenic changes.     

Longitudinal and temporal thermal patterns of the French Rh?ne River using Landsat ETM+ thermal infrared images

Understanding the thermal regime of rivers is a key issue for predicting ecosystem change in the context of global warming. However, water temperature is not only influenced by air temperature. To better highlight relative contribution of factors controlling water temperature, we used satellite thermal infrared (TIR) images from Landsat ETM+ to investigate longitudinal and temporal variations in thermal patterns of the French Rh?ne River. Because satellite TIR remote sensing is limited to large rivers, we used an automated water extraction technique to remove pixels contaminated by terrestrial surfaces. We calculated water surface temperatures of the 500?km long reach for 83 dates between 1999 and 2009. The average accuracy and uncertainty of our data, ±1.1 and ±0.4°C for reaches with more than 3?pixels across and ±1.4 and ±0.5°C for reaches with one to 3?pixels across, are comparable to other satellite TIR studies of rivers. Our results confirmed previous studies on the thermal impacts of tributaries and nuclear power plants on the Rh?ne, providing an understanding of their seasonal pattern and their longitudinal impact. We showed temperature differences of 0?C2°C within the largest hydroelectric bypass facilities between the bypass section and the canal, with Montélimar and Caderousse showing the most pronounced differences. Discussion points concern the potential impacts of tributaries and nuclear power plants on the spatio-temporal thermal patterns, as well as the factors responsible for thermal differences in the bypass facilities: length and minimum flow of the bypass section, and tributaries coming into this reach.     

Phosphorus forms and bioavailability of lake sediments in the middle and lower reaches of Yangtze River

Forms of phosphorus in sediments from 25 lakes in the middle and lower reaches of Yangtze River were analyzed by the sequential extraction procedure. Contents and spatial distrubution of algal available phosphorus (AAP) in sediments of Lake Taihu, the third largest freshwater lake of China, were also studied. Relationships between phosphorus forms in sediment and macrophytes coverage in sample sites, as well as phosphorus forms in sediments and chlorophyal contents in lake water were discussed. Exchangeable form of phosphorus (Ex-P) in surface sediments was significantly positive correlative to total phosphorus (IP), dissolved total phosphorus (DTP) and soluble reactive phosphorus (SRP) contents in the lake water. Bioavailable phosphorus (Bio-P) contents in sediments from macrophytes dominant sites were significantly lower than that in no macrophyte sites. In Lake Taihu, Ex-P content in top 3 cm sediment was highest. However, content of ferric fraction phosphorus (Fe-P) was highest in 4 - 10 cm. Bioavalilble phosphorus (Bio-P) contents in surface sediments positively correlated to Chlorophyll a contents in water of Lake Taihu with significant difference. Therefore, contents of Bio-P and AAP could be acted as the indicators of risks of internal release of phosphorus in the shallow lakes. It was estimated that there were 268.6 ton AAP in top 1 cm sediments in Lake Taihu. Sediment suspension caused by strong wind-induced wave disturbance could carry plenty of AAP into water in large shallow lakes like Lake Taihu.     

Variations in sediment runoff in the lower reaches and the delta of the Kuban River in the XX–XXI centuries

Data of network and expedition measurements and information about water management arrangements were used to study in detail the peculiarities of along-channel and long-term variations in the major characteristics of suspended sediment runoff in the lower reach and the delta of the Kuban River. For characteristics periods, the annual volumes of actual and estimated sediment runoff and the contribution of economic activity in its variations are evaluated and possible changes in sediment runoff characteristics in the XXI century are forecasted. The specific features, values, and causes of sediment runoff transformation in Kuban delta in the past and the present are analyzed; sediment balance in the delta is calculated.     

Changes in the patterns of inorganic nitrogen and TN/TP ratio and the associated mechanism of biological regulation in the shallow lakes of the middle and lower reaches of the Yangtze River

The changes of NH3-N, NO3-N, NO2-N and TN/TP were studied during growth and non-growth season in 33 subtropical shallow lakes in the middle and lower reaches of the Yangtze River. There were significant positive correlations among all nutrient concentrations, and the correlations were better in growth season than in non-growth season. When TP>0.1 mgL-1, NH3-N increased sharply in non-growth season with increasing TP, and NO3-N increased in growth season but decreased in non-growth season with TP. These might be attributed to lower dissolved oxygen and low temperature in non-growth season of the hypereutrophic lakes, since nitrification is more sensitive to dissolved oxygen and temperature than antinitrification. When 0.1 mgL-1>TP>0.035 mgL-1, TN and all kinds of inorganic nitrogen were lower in growth season than in non-growth season, and phytoplank-ton might be the vital regulating factor. When TP<0.035 mgL-1, inorganic nitrogen concentrations were relatively low and NH3-N, NO2-N had significant correlations with phytoplankton, indicating that NH3-N and NO2-N might be limiting factors to phytoplankton. In addition, TN/TP went down with decline in TP concentration, and TN and inorganic nitrogen concentrations were obviously lower in growth season than in non-growth season, suggesting that decreasing nitrogen (especially NH3-N and NO3-N) was an important reason for the decreasing TN/TP in growth season. The ranges of TN/TP were closely related to trophic level in both growth and non-growth seasons, and it is apparent that in the eutrophic and hypertrophic state the TN/TP ratio was obviously lower in growth season than in non-growth season. The changes of the TN/TP ratio were closely correlated with trophic levels, and both declines of TN in the water column and TP release from the sediment were important factors for the decline of the TN/TP ratio in growth season.     

Spatial and temporal variations in rainfall erosivity during 1960–2005 in the Yangtze River basin

Water resources and soil erosion are the most important environmental concerns in the Yangtze River basin, where soil erosion and sediment yield are closely related to rainfall erosivity. The present study explores the spatial and temporal changing patterns of the rainfall erosivity in the Yangtze River basin of China during 1960–2005 at annual, seasonal and monthly scales. The Mann–Kendall test is employed to detect the trends during 1960–2005, and the T test is applied to investigate possible changes between 1991–2005 and 1960–1990. Meanwhile the Rescaled Range Analysis is used for exploring future trend of rainfall erosivity. Moreover the continuous wavelet transform technique is using studying the periodicity of the rainfall erosivity. The results show that: (1) The Yangtze River basin is an area characterized by uneven spatial distribution of rainfall erosivity in China, with the annual average rainfall erosivity range from 131.21 to 16842 MJ mm ha^?1 h^?1. (2) Although the directions of trends in annual rainfall erosivity at most stations are upward, only 22 stations have significant trends at the 90 % confidence level, and these stations are mainly located in the Jinshajiang River basin and Boyang Lake basin. Winter and summer are the seasons showing strong upward trends. For the monthly series, significant increasing trends are mainly found during January, June and July. (3) Generally speaking, the results detected by the T test are quite consistent with those detected by the Mann–Kendall test. (4) The rainfall erosivity of Yangtze River basin during winter and summer will maintain a detected significant increasing trend in the near future, which may bring greater risks to soil erosion. (5) The annual and seasonal erosivity of Yangtze River basin all have one significant periodicity of 2–4 years.     

Characteristics of vertical ozone distribution in the lower troposphere in the Yangtze River Delta at Lin’an in the spring of 2001

Deterioration of air quality as a result of rapid eco- nomic development in the Yangtze River Delta (YRD) has attracted much scientific and public attention[1―7]. To explore the air quality of a region, measurement of pollutants in locations reflecting the “background” atmospheric conditions of the region is essential. The Regional Baseline Air Quality Monitoring Station of the Chinese Academy of Meteorological Sciences (CAMS) at Lin’an is located in such an area in Zhe- jiang Pro…     

The nutrient forms, cycling and exchange flux in the sediment and overlying water system in lakes from the middle and lower reaches of Yangtze River

This paper is a review of research works concerning the nutrient transportation, transformation and exchange between water, sediment and biota in the lakes from the middle and lower reaches of the Yangtze River conducted in the context of project entitled "The Processes and Mechanism of Lake Eutrophication in Middle and Lower Reaches of Yangtze River". All the lakes from this area are shallow lakes. According to the typical lake site research, the lakes from the middle and lower reaches of Yangtze River have a higher baseline of nutrition in the history. Normally the trophic status of these lakes can be categorized into medium-trophic or eutrophic. Human activities have been enhanced during the last decades, which speed up the lake eutrophic process. Lake eutrophication control needs to reduce not only the external nutrient inputs from watershed but also the internal loading from the sediments. Investigations revealed that the lake sediments in this area are considerablly high in nutrition in which at most about 30% of phosphorus exists in the form of bio-available in the sediment. The surface sediment will exert great effects on the nutrient exchange between water-sediment interface via adsorption and release of nutrient. The nutrient release from the sediment in these shallow lakes is mainly in two ways, i.e. in the undisturbed condition the nutrient is released through diffusion created by the nutrient gradient from sediment to overlying water; whereas in disturbed condition, the nutrient release is determined by the hydrodynamic forcing intensity and the sediment resuspension. Metallic elements such as the iron, manganese and aluminium and the aerobic-anaerobic ambience will affect the release of nutrients. The disturbed release will increase the total nutrients in the water column significantly in the short period. At the beginning of sediment resuspension, the dissolved nutrient concentration will increase. This increase will be damped if the ferric oxide and aluminium are rich in sediment because of the adsorption and flocculation. This means that the lakes have capability of eliminating the nutrient loadings. Investigations for the lakes from middle and down stream of Yangtze River have suggested that most lakes have the self-cleaning capability. Dredging the control of the internal loading, therefore, is only applicable to the small lakes or undisturbed bays which normally are situated nearby the city or town and rich in organic materials in the sediment. In addition, the strong reduction condition and weak aeration of these lakes and bays make these small lakes and bays release much more bio-available nutrient and without much self-eliminating capability. Moreover, eutrophication induced algal bloom in these lakes will change the pH of water, which further induces the increase in the nutrient release. In turn, the increase in nutrient release promotes the growth of phytoplankton and results in severe algal bloom. For the heavily polluted water, research suggests that the biomass of bacteria and alkaline phosphatase activity will be higher corresponding to the higher concentration of nutrients, which accelerates the nutrient recycling between water, sediment and biota. Quick recycling of nutrient, in turn, promotes the production and biomass growth of microorganism and leads to more severe eutrophication. Further research work should focus on the nutrient transformation mechanism and the effects of microbial loop on the eutrophication.     

Spatial and temporal characteristics of changes in precipitation during 1957�C2007 in the Haihe River basin, China

The present study explores the spatial and temporal changing patterns of the precipitation in the Haihe River basin of North China during 1957–2007 at annual, seasonal and monthly scales. The Mann–Kendall and Sen’s T tests are employed to detect the trends, and the segmented regression is applied to investigate possible change points. Meanwhile, Sen’s slope estimator is computed to represent the magnitudes of the temporal trends. The regional precipitation trends are also discussed based on the regional index series of four sub-basins in the basin. Serial correlation of the precipitation series is checked prior to the application of the statistical test to ensure the validity of trend detection. Moreover, moisture flux variations based on the NCEP/NCAR reanalysis dataset are investigated to further reveal the possible causes behind the changes in precipitation. The results show that: (1) Although the directions of annual precipitation trends at all stations are downward, only seven stations have significant trends at the 90% confidence level, and these stations are mainly located in the western and southeastern Haihe River basin. (2) Summer is the only season showing a strong downward trend. For the monthly series, significant decreasing trends are mainly found during July, August and November, while significant increasing trends are mostly observed during May and December. In comparison with the annual series, more intensive changes can be found in the monthly series, which may indicate a shift in the precipitation regime. (3) Most shifts from increasing trends to decreasing trends occurred in May–June, July, August and December series, while opposed shifts mainly occurred in November. Summer is the only season displaying strong shift trends and the change points mostly emerged during the late 1970s to early 1980s. (4) An obvious decrease in moisture flux is observed after 1980 in comparison with the observations before 1980. The results of similar changing patterns between monthly moisture budget and precipitation confirmed that large-scale atmospheric circulation may be responsible for the shift in the annual cycle of precipitation in the Haihe River basin. These findings are expected to contribute to providing more accurate results of regional changing precipitation patterns and understanding the underlying linkages between climate change and alterations of hydrological cycles in the Haihe River basin.     

Poly-aromatic hydrocarbon (PAH) inputs from the Rhône River to the Mediterranean Sea in relation with the hydrological cycle: impact of floods

The concentrations of dissolved and particulate polycyclic aromatic hydrocarbons (PAHs) were monitored in waters of the Rhône River (France) every fortnight for a full calendar year, from June 1994 to May 1995. All flood events occurring over the course of the experiment were sampled at higher frequency to better quantify the impact of these extreme hydrological episodes on the annual export of PAHs to the Mediterranean Sea. This time-series indicates that more than 90% of the annual load of particulate PAHs is transported during flood episodes, with 77% discharged during the course of only one extreme flood event occurring in November 1994. During these intense events, riverine particles are depleted in PAHs while at low river discharge particles are PAH-enriched. Dissolved PAHs were less variable and less abundant than adsorbed PAHs, consistently with the low solubility of these compounds.     

Comparison of River Terraces in the Middle Reach Valleys of the Yellow River and Analysis on the Multi-Gradational Features of Tectonism in the Formation of Terrace Series

Where the Yellow River flows through the Haiyuan-Tongxin arc-form tectonic region on the northeastern side of the Qinghai-Xizang (Tibet) Plateau, as many as 10～21 basis and erosion terraces have been produced, among which the biggest altitude above river level is 401m and the formation age of the highest terrace is 1.57 Ma B.P. Based on comparative analysis of the Yellow River terraces located separately in the Mijiashan mountain, the Chemuxia gorge, the Heishanxia gorge and the other river terraces in the vast extent of the northern part of China, it has been found that the tectonic processes resulting in the formation of the terrace series is one of multi-gradational features, i.e., a terrace series can include the various terraces produced by tectonic uplifts of different scopes or scales and different ranks. The Yellow River terrace series in the study region can be divided into three grades. Among them, in the first grade there are 6 terraces which were formed separately at the same time in the vast extent of the northern part of China and represent the number and magnitude of uplift of the Qinghai-Xizang Plateau since 1.6 Ma B. P. ; in the second grade there are 5 terraces which were separately and simultaneously developed within the Haiyuan-Tianjingshan tectonic region and represent the number and magnitude of uplift of this tectonic region itself since 1.6Ma B. P.; in the third grade there are 10 terraces which developed on the eastern slope of the Mijiashan mountain and represent the number and amplitude of uplift of the Haiyuan tectonic belt itself since 1.6Ma B.P. Comparison of the terrace ages with loess-paleosoil sequence has also showed that the first grade terraces reflecting the vast scope uplifts of the Qinghai-Xizang Plateau are very comparable with climatic changes and their formation ages all correspond to the interglacial epochs during which paleosoils were formed. This implies that the vast extent tectonic uplifts resulting in river down-cutting are closely related to the warm-humid climatic periods which can also resnit in river downward erosion after strong dry and cold climatic periods, and they have jointly formed the tectonic-climatic cycles. There exists no unanimous and specific relationship between the formation ages of the second and third grade terraces and climatic changes and it is shown that the formation of those terraces was most mainly controlled by tectonic uplifts of the Tianjingshan block and the Haiyuan belt. The river terraces in the study region, therefore, may belong to 2 kinds of formation cause. One is a tectonic-climatic cyclical terrace produced jointly by vast extent tectonic uplifts and climatic changes, and the terraces of this kind are extensively distributed and can be well compared with each other among regions. Another is a pulse-tectonic cyclical terrace produced by local tectonic uplifts as dominant elements, and their distribution is restricted within an active belt and can not be compared with among regions.     

Secondary flows induced by wind forcing in the Rhône region of freshwater influence

Secondary flows induced by the blocking effect of a river plume on a transverse upwelling are investigated in a microtidal region of freshwater influence (ROFI). A nested version of the SYMPHONIE primitive-equation free-surface model for 3-D baroclinic coastal flows has been developed for the Rhône ROFI. The main characteristics of the model are a generalized sigma coordinate system in finite differences, using a time splitting for external and internal modes and high-order numerical advection schemes for density fields in combination with an modified turbulence closure scheme. The nesting system consists of two grids forced by the high-resolution ALADIN model atmospheric data. The coarse grid of 3 km resolution for the whole Gulf of Lions allows the forcing of the Liguro-Provençal large-scale current when the fine mesh of 1-km resolution is centred on the river mouth of the Grand Rhône. Documented field experiments from the Biodypar 3 field campaign performed during March 1999 are used for validation. Numerical results, CTD profiles and a SPOT TSM visible image are in good agreement concerning the shape and structure of the river plume. Other coastal flow features can be observed from satellite imagery. Computations of realistic situations recover these main secondary structures. Complementary process-oriented runs give an explanation of how the coastal upwelling induced by an inhomogeneous offshore wind is destabilized by the combination of the river plume and along-shelf current-blocking effects. In the end, a factor-separation analysis provides evidence that the locally non-linear effects in momentum contribute to the occurrence of secondary vortices.Responsible Editor: Phil Dyke     

Spatial distribution and temporal variation of reference evapotranspiration during 1961–2006 in the Yellow River Basin,China

Abstract

To explore the spatial and temporal variations of the reference evapotranspiration (ET_ref) is helpful to understand the response of hydrological processes to climate changes. In this study, ET_ref was calculated by the Penman-Monteith method (P-M method) using air temperature, wind speed, relative humidity and sunshine hours at 89 meteorological stations during 1961–2006 in the Yellow River Basin (YRB), China. The spatial distribution and temporal variations of ET_ref were explored by means of the kriging method, the Mann-Kendall (M-K) method and the linear regression model, and the causes for the variations discussed. The contribution of main meteorological variables to the variations of ET_ref was explored. From the results we found that: (1) the spatial distributions of ET_ref display seasonal variation, with similar spatial patterns in spring, summer and autumn; (2) temporal trends for ET_ref showed large variation in the upper, middle and lower regions of the basin, most of the significant trends (P?=?0.05) were detected in the middle and lower regions, and, in particular, the upward and downward trends were mainly detected in the middle region and lower region of the basin, respectively; and (3) sensitivity analysis identified the most sensitive variable for ET_ref as relative humidity, followed by air temperature, sunshine hours and wind speed at the basin scale.

Citation Yang, Zhifeng, Liu, Qiang & Cui, Baoshan (2011) Spatial distribution and temporal variation of reference evapotranspiration during 1961–2006 in the Yellow River Basin, China. Hydrol. Sci. J. 56(6), 1015–1026.     

Spatial and temporal variation of gravity field in the capital region

Ｓｐａｔｉａｌａｎｄｔｅｍｐｏｒａｌｖａｒｉａｔｉｏｎｏｆ　ｇｒａｖｉｔｙ　ｆｉｅｌｄｉｎｔｈｅｃａｐｉｔａｌｒｅｇｉｏｎＣｈａｎｇ－ＣａｉＨＵＡ；（华昌才）ＹｏｎｇＧＵＯ；（果勇）Ｄｕａｎ－ＦａＬＩＵ；（刘瑞法）ＧａｎｇＸＩＡＯ；（肖钢），Ｊ．Ｔ．...     

Effect of sediment resuspension on underwater light field in shallow lakes in the middle and lower reaches of the Yangtze River: A case study in Longgan Lake and Taihu Lake

Based on three continuous in situ underwater light field measurement under different wind waves conditions in Longgan Lake, Meiliang Bay of Taihu Lake in July 2003 and littoral zone near TLLER in July 2004, respectively, the effects of sediment resuspension caused by wind waves on PAR diffuse attenuation, absorption coefficients and euphotic depths are analyzed. In Longgan Lake, PAR diffuse attenuation coefficients during small, middle and large wind waves were 1.74, 2.02 and 2.45 m-1, respectively, and the corresponding PAR spectral diffuse attenuations ranged from 0.98 to 2.97, 1.34 to 3.95 and 1.80 to 5.40 m-1, respectively. In Meiliang Bay, PAR diffuse attenuation coefficients were 2.63, 3.72, 4.37 m-1 during small, middle and large wind waves. PAR diffuse attenuation coefficients increased by 41% and 66% from small to middle, large wind waves, respectively. Absorption coefficients integrated over the range of PAR of CDOM, phytoplankton were 0.26, 0.28 m-1; 0.76, 0.49 m-1, respectively during middle and large wind waves. Absorption coefficients integrated over the range of PAR of non-algal particulate matter and total suspended particulate matter increased from 0.94 to 1.73 m-1, and from 1.70 to 2.22 m-1, respectively during middle and large wind waves. Relative contributions of absorption coefficients of non-algal particulate matter to total absorption coefficient integrated over the range of PAR were 44.14%, 65.05%, respectively, during middle and large wind waves. PAR euphotic depths decreased by 0.40, 0.19, 0.20 m from middle to large wind waves in Longganhu Lake, Meliang Bay and littoral zone near TLLER. Significant correlations were found between transparency, PAR diffuse attenuation coefficients, euphotic depths and total suspended paniculate matter, wind velocity, wave height. Most significant correlations were found between transparency, PAR diffuse attenuation coefficients, euphotic depths and inorganic suspended paniculate matter but low correlations for chlorophyll a, dissolved organic carbon. Increase of total suspended paniculate matter, especially inorganic suspended paniculate matter caused by wind waves was the dominant factor affecting underwater light field in shallow lakes in the middle and lower reaches of the Yangtze River based on observations at three stations.     

Assessment of heavy metal contamination in the sur?cial sediments from the lower Meghna River estuary,Noakhali coast,Bangladesh

Sediment samples were collected from ten selected sites of the lower Meghna River estuary, and six heavy metals were analyzed with Atomic Absorption Spectrophotometry(AAS) to assess the contamination level and the metals' association with sediment grain size. The current results revealed that the mean concentrations of the studied metals were ranked in descending order of iron(Fe)(1.29 ? 103 mg/kg) zinc(Zn)(42.41 mg/kg) lead(Pb)(12.48 mg/kg) chromium(Cr)(10.59 mg/kg) copper(Cu)(6.22 mg/kg) cadmium(Cd)(0.28 mg/kg). The geo-accumulation, contamination, and pollution load indexes suggested that the lower Meghna river estuary was not contaminated by Fe, Zn, Pb, Cr, and Cu.The mean size of the sediment ranged from 28.92 to 126.2 mm, and the Pearson correlation coefficient showed a significant association between Fe and Pb(coefficient of determination, r2? 0.836; p 0.05),and no significant correlation was found between individual metals and grain size, indicating no or low influence on the metals distribution.     

Comparison of Pb(Ⅱ) and Cd(Ⅱ) micro-interfacial adsorption on ?ne sediment in the Pearl River Basin,China

The complex micro-interfacial interaction theories of heavy metal ions such as Pb(II) and Cd(II)adsorption on fine sediment in aqueous solution were not systematically investigated. The aim of this work was to reflect the micro-interfacial adsorption characteristics. Sediment samples were collected from an estuary. The Isothermal and kinetics adsorption experiment were done to acquire the data.Isothermal, kinetics, film diffusion and intraparticle diffusion models were adopted to fit the adsorption experimental data. The results indicated that the Langmuir, Freundlich and Temkin models were suitable for analyzing the isothermal experimental data. The maximum adsorption capacities of Pb(II) and Cd(II)on the sediment were 1.1377 and 0.9821 mg·g_(-1), respectively. The q_m and K_L of the Langmuir model, K_f and n_F of the Freundlich model, and b and A of the Temkin model all exhibited a power function relationship with the initial adsorbate concentration. The pseudo-second-order model provided a better fit for the experimental kinetics data compared with the fit of the pseudo-first-order and Elovich models.The pseudo-second-order parameters k_2 and q_e of Pb(II) and q_e of Cd(II) both had a power function relationship with adsorption time, additionally, the k_2 of Cd(II) had an exponential function relationship with adsorption time. The liquid-film diffusion parameters k_(fd) of Pb(II) and Cd(II) were 0.0569 and 0.1806 min_(-1), respectively. The intraparticle diffusion parameter k_(id) values of Pb(II) and Cd(II) were0.0055 mg·g_(-1)·min_(1/2) and 0.0049 mg·g_(-1)min_(1/2), respectively. The physical significance of the model parameters showed that Pb(II) adsorption on sediment was stronger than Cd(II). The results of this study provided a theoretical reference for the micro-interfacial mechanism of heavy metal ion adsorption on sediment.     

The 20―30-day oscillation of the global circulation and heavy precipitation over the lower reaches of the Yangtze River valley

Based on the observational data in summer, the variations of intraseasonal oscillation (ISO) of the daily rainfall over the lower reaches of the Yangtze River valley (LYRV) were studied by using the non-integer spectrum analysis. The NCEP/NCAR reanalysis data for the period of 1979―2005 were analyzed by principal oscillation pattern analysis (POP) to investigate the spatial and temporal characteristics of principal ISO patterns of the global circulation. The relationships of these ISO patterns to the rainfa...