The Sabzevar blueschists of the North-Central Iranian micro-continent as remnants of the Neotethys-related oceanic crust subduction

The Sabzevar ophiolites mark the Neotethys suture in east-north-central Iran. The Sabzevar metamorphic rocks, as part of the Cretaceous Sabzevar ophiolitic complex, consist of blueschist, amphibolite and greenschist. The Sabzevar blueschists contain sodic amphibole, epidote, phengite, calcite ± omphacite ± quartz. The epidote amphibolite is composed of sodic-calcic amphibole, epidote, albite, phengite, quartz ± omphacite, ilmenite and titanite. The greenschist contains chlorite, plagioclase and pyrite, as main minerals. Thermobarometry of a blueschist yields a pressure of 13–15.5 kbar at temperatures of 420–500 °C. Peak metamorphic temperature/depth ratios were low (~12 °C/km), consistent with metamorphism in a subduction zone. The presence of epidote in the blueschist shows that the rocks were metamorphosed entirely within the epidote stability field. Amphibole schist samples experienced pressures of 5–7 kbar and temperatures between 450 and 550 °C. The presence of chlorite, actinolite, biotite and titanite indicate greenschist facies metamorphism. Chlorite, albite and biotite replacing garnet or glaucophane suggests temperatures of >300 °C for greenschist facies. The formation of high-pressure metamorphic rocks is related to north-east-dipping subduction of the Neotethys oceanic crust and subsequent closure during lower Eocene between the Central Iranian Micro-continent and Eurasia (North Iran).     

Pacific superplume-related oceanic basalts hosted by accretionary complexes of Central Asia, Russian Far East and Japan

Plume-related oceanic magmatism form oceanic islands, seamounts and plateaus (hereafter “seamounts” or “paleoseamounts”), which are important features in geological history. The accretion of oceanic seamounts to active continental margins significantly contributed to the formation of the continental crust. This paper reviews occurrences of Late Neoproterozoic–Mesozoic seamounts of the Paleo-Asian and Paleo-Pacific oceans, which are hosted by accretionary complexes (ACs) of Russian Altai, East Kazakhstan, Mongolia, Russian Far East and Japan. The paleoseamounts commonly consist of Ti–LREE–Nb-enriched plume-related basalts (OIB-type or intraplate basalts) capped with massive limestone and associated with other units of oceanic plate stratigraphy (OPS): oceanic floor basalts (MORB), pelagic chert, epiclastic slope facies, etc. The paper presents available geochemical data on the plume-related basalts including the first geochemical data on the Middle Paleozoic OIB-type basalts of the Paleo-Asian Ocean hosted by the Ulaanbaatar AC of Mongolia. An emphasis is made for the structural setting of OPS units, specific geochemical features of intraplate basalts, problems of their identification, and distinguishing from magmatic units of a different origin such as MORB, island-arc and back-arc basalts. Finally, we propose a continuous, though periodical, evolution of the Pacific superplume-related magmatism, which can be more reliably proved by studying Middle Paleozoic OPS units hosted by ACs of Mongolia and Tien Shan, and discuss prospects of future studies.     

Triassic blueschists and eclogites from northwest Turkey: vestiges of the Paleo-Tethyan subduction

Triassic eclogite and blueschist facies rocks occur as a thrust sheet, 25-km long and over 2-km thick, in an Eocene fold-and-thrust belt in northwest Turkey along the zmir–Ankara suture. The thrust sheet consists mainly of metabasites with minor marble, phyllite and metachert, and rare lenses of serpentinite. The common blueschist facies mineral assemblage in the metabasites is sodic amphibole+epidote+albite+chlorite+phengite±garnet. Sodic amphibole commonly shows replacement by barroisite, and there is continuous petrographic transition from blueschist–metabasites to barroisite-bearing epidote–amphibolites. Eclogite with the mineral assemblage of garnet+sodic pyroxene+sodic–calcic amphibole+epidote is found only in one locality. P–T conditions of the epidote–blueschist facies metamorphism are estimated as 450±50 °C and 11±2 kbar. The blueschist formation was followed by a decrease in pressure and increase in temperature, leading to the development of barroisite-bearing epidote–amphibolites. Phengite, sodic amphibole and barroisite Ar/Ar ages from three metabasic rocks range between 215 and 205 Ma, and indicate Late Triassic high-pressure metamorphism. The Triassic blueschists in northwest Turkey constitute part of a much larger allochthonous tectonic unit of Triassic mafic volcanic rocks. They probably represent the upper layers of a Triassic oceanic plateau, which was accreted to the Laurasian margin during the latest Triassic. The close spatial association of the Triassic and Cretaceous blueschists along the zmir–Ankara suture suggests that the suture represents a long-lived plate boundary of Late Palaeozoic to early Tertiary age.     

SOME TRENDS IN THE STUDY OF CARBONATE SEDIMENTS IN THE FEDERAL REPUBLIC OF GERMANY

A stratigraphically coherent blueschist terrane near Aksu in northwestern China is unconformably overlain by unmetamorphosed sedimentary rocks of Sinian age (～600 to 800 Ma). The pre-Sinian metamorphic rocks, termed the Aksu Group, were derived from shales, sandstones, basaltic volcanic rocks, and minor cherty sediments. They have undergone multi-stage deformation and transitional blueschist/greenschist-facies metamorphism, and consist of strongly foliated chlorite-stilpnomelane-graphite schist, stilpnomelane-phengite psammitic schist, greenschist, blueschist, and minor quartzite, metachert, and meta-ironstone. Metamorphic minerals of basaltic blueschists include crossitic amphibole, epidote, chlorite, albite, quartz, and actinolite. Mineral parageneses and compositions of sodic amphibole suggest blueschist facies recrystallization at about 4 to 6 kbar and 300 to 400° C. Many thin diabasic dikes cut the Aksu Group; they are characterized by high alkali, TiO₂, and P₂O₅ contents and possess geochemical characteristics of within-plate basalts; some of these diabasic rocks contain sodic clinopyroxene and amphibole as primary phases and have minor pumpellyite, albite, epidote, chlorite, and calcite as the prehnite/pumpellyite-facies metamorphic assemblage. This prehnite/pumpellyite-facies overprint did not affect the host rocks of the blueschist-facies lithologies.

K-Ar and Rb-Sr ages of phengite and whole rocks from pelitic schists are ～690 to 728 Ma, and a ⁴⁰Ar/³⁹Ar age of crossite from the blueschist is 754 Ma. The basal conglomerate of the overlying Sinian to Eocambrian sedimentary succession contains clasts of both the blueschist and cross-cutting dike rocks, clearly demonstrating that conditions required for blueschist-facies metamorphism were attained and ceased at least 700 Ma. The northward-increasing metamorphic grade of the small blueschist terrane may reflect northward subduction of an accretionary complex beyond the northern edge of the Tarim craton. Abundant subparallel diabasic dikes indicate a subsequent period of Pre-Sinian rifting and diabasic intrusion along the northern margin of Tarim; a Sinian siliciclastic and carbonate sequence was deposited unconformably atop the Aksu Group and associated diabase dikes.     

内蒙古头道桥地区蓝闪石片岩和相关变质岩石岩石学特征及其构造意义

内蒙古头道桥地区出露了一套经高压变质形成的岩石组合。本次研究通过岩相学和矿物化学分析,根据矿物组合的不同,识别出蓝片岩、绿片岩两种不同类型的岩石类型。其中,蓝片岩的矿物组合为角闪石（蓝闪石、蓝透闪石）+绿帘石+钠长石+绿泥石+石英+赤铁矿±多硅白云母±方解石±榍石;绿片岩的矿物组合为绿泥石+钠长石+石英±绿帘石±角闪石（阳起石、镁角闪石、蓝透闪石、冻蓝闪石等）±多硅白云母±赤铁矿。确定了蓝片岩的峰期变质级别为绿帘-蓝闪片岩相,峰期变质温度为400~600℃,压力为1.2~1.4 GPa。绿片岩的峰期变质级别为绿帘-角闪岩相。结合前人研究成果,认为蓝片岩和绿片岩的形成与额尔古纳地块和兴安地块的碰撞拼合有关。     

Lawsonite zone blueschists and a sodic amphibole producing reaction in the Tavşanli Region,Northwest Turkey

The petrology and mineralogy of lawsonite zone metabasites have been studied northeast of town of Tav?anli, NW Turkey. In the field the metabasites are characteristically green and lack foliation; the essential mineral assemblage being sodic pyroxene+ lawsonite+chlorite+quartz±sodic amphibole. Sodic pyroxene of aegirine-jadeite composition occurs as pseudomorphs after magmatic augite. Lawsonite and chlorite are the other two dominant minerals. Sodic amphibole forms progressively from a reaction between sodic pyroxene, chlorite and quartz, and an isograd representing the first abundant occurrence of sodic amphibole in basic rocks has been mapped. The widespread occurrence of sodic pyroxene pseudomorphs in other blueschist terrains indicates that the inferred sodic amphibole producing reaction is of general significance for blueschist metabasites.The conversion of greenstones with the assemblage albite+chlorite+actinolite directly into glaucophane-lawsonite blueschists without any intervening lawsonite zone illustrates the influence of the initial mineral assemblage on the reaction path.     

ON PRINCIPAL RULES IN THE OCCURRENCE OF OIL AND GAS ACCUMULATIONS IN THE WORLD

Anomalous coarse-crystalline garnet amphibolites and possible retrograded eclogites in varying stages of replacement by sodic amphibole + epidote assemblages compose exotic boulders (tectonic blocks) resting unconformably on serpentinite and finergrained, lower-greenschist-grade metabasites and metapelites in the Coastal Range of Chile (41° S Lat.). Major-and trace-elemental compositions of the tectonic blocks are similar to metapillow basalts and metavolcaniclastics within the underlying, in situ, metamorphic complex. Phase compatibilities and mineral compositions within the coarse blueschist/amphibolite suggest both a higher maximum pressure (greater burial depth) and higher P-T retrograde path for the tectonic blocks than for the in situ greenschists, suggesting an inversion of their relative structural position after metamorphism.

Coarse amphibolite-grade metabasites forming the lower portion of a primitive arc system may have been detached from the upper plate and subducted to deeper levels within a zone of distributed shear, resulting in the formation of high-P/T blueschist minerals. A K-Ar age of 304 + 9 Ma on white mica from one of the blueschist blocks is similar to previous ages from the regional metamorphic complex, and suggests that ascent of the tectonic blocks marginal to or within serpentinite diapirs occurred during an early stage of late Paleozoic orogenesis along the Gondwanide margin. Post-orogenic static uplift, sedimentation, and differential erosion then resulted in the present surficial distribution of the blueschist boulders.     

Geochemical discrimination of metabasalt rocks of the Fan–Karategin transitional blueschist/greenschist belt, South Tianshan, Tajikistan: seamount volcanism and accretionary tectonics

The Fan–Karategin metamorphic belt, South Tianshan, Tajikistan, is regarded to be an ancient subduction–accretionary complex and is composed of three tectonostratigraphic units which display lithologies consistent with different tectonic settings. The mafic schists, which make up the major part of the older unit of the belt, contain both alkali and tholeiitic metabasalts. On the basis of rare-earth and other immobile element characteristics, the alkali metabasalts are akin to within-plate ocean island basalts, whereas the tholeiitic metabasalts resemble E-type MORB. The association is interpreted to have been formed on seamount-like structures under a within-plate plume. Bedded cherts and marbles in the unit are regarded as ancient pelagic sediments and carbonate caps developed upon basaltic seamounts, respectively. Dismemberment of the seamount-related basalts and pelagic sediments and the high-P/low-T prograde metamorphism of the unit rocks up to transitional blueschist/greenschist facies was the result of paleoseamount submergence into a subduction zone. This unit is tectonically overlain by arc-derived metavolcanic unit and a disrupted, mainly clastic unit of Upper Ordovician–Lower Silurian age. Metavolcanic and metasedimentary rocks of the two upper units have geochemical characteristics compatible with subduction-related origin. The lithological assemblages of the individual units and their juxtaposition suggest an origin involving collision–accretionary processes. The Fan–Karategin belt is a subduction–accretionary complex which formed during subduction of oceanic crust under a volcanic arc and was subjected to tectonic juxtaposition and imbrication of seamount, deep-sea, trench and volcanic arc sequences.     

Glaucophane-bearing assemblage overprinted by greenschist-facies metamorphism in the Variscan Kaczawa complex, Sudetes, Poland

An Early Palaeozoic (Ordovician ?) metamudstone sequence near Wojcieszow, Kaczawa Mts, Western Sudetes, Poland, contains numerous metabasite sills, up to 50 m thick. These subvolcanic rocks are of within-plate alkali basalt type. Primary igneous phases in the metabasites, clinopyroxene (salite) and kaersutite, are veined and partly replaced by complex metamorphic mineral assemblages. Particularly, the kaersutite is corroded and rimmed by zoned sodic, sodic–calcic and calcic amphiboles. The matrix is composed of actinolite, pycnochlorite, albite (An ≤ 0.5%), epidote (Ps 27–33), titanite, calcite, opaques and, occasionally, biotite, phengite and stilpnomelane. The sodic amphiboles are glaucophane to crossite in composition with Na^B from 1.9 to 1.6. They are rimmed successively by sodic–calcic and calcic amphiboles with compositions ranging from magnesioferri-winchite to actinolite. No compositions between Na^B= 0.92 and Na^B= 1.56 have been ascertained. The textures may be interpreted as representing a greenschist facies overprint on an earlier blueschist (or blueschist–greenschist transitional) assemblage. The presence of glaucophane and no traces of a jadeitic pyroxene + quartz association indicate pressures between 6 and 12 kbar during the high-pressure episode. Temperature is difficult to assess in this metamorphic event. The replacement of glaucophane by actinolite + chlorite + albite, with associated epidote, allows restriction of the upper pressure limit of the greenschist recrystallization to <8 kbar, between 350 and 450°C. The mineral assemblage representing the greenschist episode suggests the P–T conditions of the high-pressure part of the chlorite or lower biotite zone. The latest metamorphic recrystallization, under the greenschist facies, may have taken place in the Viséan.     

Amphibole compositions and metamorphic history of the Rand Schist and the greenschist unit of the Catalina Schist,Southern California

The Catalina Schist and Rand Schist are two high P/T terranes in southern California. The Catalina Schist is correlated with the Franciscan Complex and occurs in the continental borderland. It consists of a blueschist-facies melange tectonically overlain by a greenschist unit, which, in turn, is overthrust by an amphibolite unit. The greenschist unit itself is inversely zoned from epidote-amphibolite fades at the top through greenschist facies in the center to transitional blueschist-greenschist facies at the base. The Rand Schist is part of the eugeoclinal Pelona-Orocopia Schist terrane, which lies interior to the present continental margin, structurally beneath Precambrian to Mesozoic sialic basement. The Rand Schist is inversely zoned from epidote-amphibolite facies to transitional blueschist-greenschist facies, similar to the greenschist unit of the Catalina Schist.Two trends in amphibole composition, one from actinolite to hornblende in greenschists and epidote amphibolites (calcic series) and the other from actinolite through winchite to crossite in glaucophanic greenschists (sodic-calcic series), are present in both the Rand Schist and the greenschist unit of the Catalina Schist. The transition from actinolite to hornblende in the calcic series is defined by increases in tschermakite, edenite, and glaucophane substitution. Amphiboles of the sodic-calcic series differ mainly in the degree of glaucophanic substitution. The similarity of amphibole trends in the two terranes indicates that they were metamorphosed at approximately the same pressures and temperatures, and is evidence that the Rand Schist originated in a subduction zone, despite its present intracontinental setting.Most glaucophanic greenschists in the Rand and Catalina Schists contain both a sodic and a calcic member of the sodic-calcic series. Textural relations indicate that calcic members generally developed after the sodic ones. This implies that sodic amphibole formerly may have been present in many of the structurally higher greenschists and epidote amphibolites. Preservation of the inverted zonations, as well as microstructural evidence for the syntectonic development of calcic and sodic-calcic amphiboles, suggest that glaucophanic greenschists, greenschists, and epidote amphibolites all formed during underthrusting (subduction). This contrasts with many orogenic belts, where replacement of blueschists by greenschists to amphibolites is attributed to thermal reequilibration during erosional unroofing.     

Geochemistry of metamorphic rocks of the Kurai block (Gorny Altai)

We consider the primary nature and sources of the protoliths of metamorphic rocks of the Kurai block located in the large Teletskoe-Kurai system of deep faults separating the Gorny Altai and West Sayan structures. It has been established that the protoliths of the Kurai block metapelites were deposits of transitional crust: They lack typical rocks of mature continental crust (arkoses, litharenites) and have reduced (relative to the upper continental crust) contents of lithophile elements and elevated contents of transition elements. The average Nd model age of the protoliths of the metapelites of the Kurai complex corresponds to the Middle Riphean (1.4-1.6 Ga). The metabasites of the Kurai complex are similar in petrologic composition to metamorphic products of oceanic basalts. It is shown that the formation of metamorphic associations of the Kurai block was caused by tectonometamorphic transformations of a compositionally heterogeneous rock unit (basalts, aluminous and volcanomict sediments), which were, most likely, a fragment of Middle Cambrian-Early Ordovician turbidite basin with an oceanic basement.     

Blueschists of the Amassia-Stepanavan Suture Zone (Armenia): linking Tethys subduction history from E-Turkey to W-Iran

The Amassia–Stepanavan blueschist-ophiolite complex of the Lesser Caucasus in NW Armenia is part of an Upper Cretaceous-Cenozoic belt, which presents similar metamorphic features as other suture zones from Turkey to Iran. The blueschists include calcschists, metaconglomerates, quartzites, gneisses and metabasites, suggesting a tectonic mélange within an accretionary prism. This blueschist mélange is tectonically overlain by a low-metamorphic grade ophiolite sequence composed of serpentinites, gabbro-norite pods, plagiogranites, basalts and radiolarites. The metabasites include high-P assemblages (glaucophane–aegirine–clinozoisite–phengite), which indicate maximal burial pressure of ∼1.2 GPa at ∼550°C. Most blueschists show evidence of greenschist retrogression (chlorite—epidote, actinolite), but locally epidote-amphibolite conditions were attained (garnet—epidote, Ca/Na amphibole) at a pressure of ∼0.6 GPa and a temperature of ∼500°C. This LP–MT retrogression is coeval with exhumation and nappe-stacking of lower grade units over higher grade ones. ⁴⁰Ar/³⁹Ar phengite ages obtained on the high-P assemblages range between 95 and 90 Ma, while ages obtained for epidote-amphibolite retrogression assemblages range within 73.5–71 Ma. These two metamorphic phases are significant of (1) HP metamorphism during a phase of subduction in the Cenomanian–Turonian times followed by (2) exhumation in the greenschist to epidote-amphibolite facies conditions during the Upper Campanian/Maastrichtian due to the onset of continental subduction of the South Armenian block below Eurasia.     

Neoproterozoic zirconium-depleted boninite and tholeiitic series rocks from Adola, southern Ethiopia

In Adola, southern Ethiopia, mafic and ultramafic igneous rocks occur in narrow, 4–10 km wide, north-south-trending belts bounded by high-grade gneisses and migmatites. The mafic/ultramafic rocks are complexly deformed and metamorphosed in greenschist to lower amphibolite facies and are thought to be tectonically dismembered parts of an ophiolite complex. Preliminary geochemical and geochronological data highlight that the high-grade rocks in southern Ethiopia and northern Kenya include a significant portion of juvenile rocks that were accreted at the same time as ophiolitic rocks at 885-765 Ma. This is also the time of widespread oceanic magmatism and closure in the Arabian-Nubian Shield to the north.The Adola mafic rocks were previously described as island arc tholeiites and mid-ocean ridge basalts (MORB). New chemical analyses on the Megado belt rocks reveal the presence of boninites and related dacites interspersed with tholeiitic rocks. The Adola boninites are similar to the Cambrian boninites in western Tasmania in having relatively low Zr/Sm (≤32). Boninites with similarly low ratios have not been reported from elsewhere.The Adola tholeiites have high Ti/Zr (150–300). Mixing between tholeiite and boninite magmas may have resulted in elevated Ti/Zr (80–126) in some Adola boninites. Otherwise, Ti/Zr in the latter is low (20–40). Low Ti/Zr is characteristic of Tertiary boninites in the west Pacific. The fact that both Ti/Eu and Zr/Sm increase from the Adola and Tasmania type to the Tertiary boninites at constant Ti/Zr suggests that Ti might be an element that is also metasomatically added to the source of boninites and raises doubts about the role of amphibole in boninite petrogenesis.     

Lawsonite zone blueschists and a sodic amphibole producing reaction in the Tavşanli Region,Northwest Turkey

The petrology and mineralogy of lawsonite zone metabasites have been studied northeast of town of Tavanli, NW Turkey. In the field the metabasites are characteristically green and lack foliation; the essential mineral assemblage being sodic pyroxene+ lawsonite+chlorite+quartz±sodic amphibole. Sodic pyroxene of aegirine-jadeite composition occurs as pseudomorphs after magmatic augite. Lawsonite and chlorite are the other two dominant minerals. Sodic amphibole forms progressively from a reaction between sodic pyroxene, chlorite and quartz, and an isograd representing the first abundant occurrence of sodic amphibole in basic rocks has been mapped. The widespread occurrence of sodic pyroxene pseudomorphs in other blueschist terrains indicates that the inferred sodic amphibole producing reaction is of general significance for blueschist metabasites.The conversion of greenstones with the assemblage albite+chlorite+actinolite directly into glaucophane-lawsonite blueschists without any intervening lawsonite zone illustrates the influence of the initial mineral assemblage on the reaction path.     

Parageneses and compositions of amphiboles from Franciscan jadeite–glaucophane type facies series metabasites at Cazadero, California

Abstract Sodic amphiboles are common in Franciscan type II and type III metabasites from Cazadero, California. They occur as (1) vein-fillings, (2) overgrowths on relict augites, (3) discrete tiny crystals in the groundmass, and (4) composite crystals with metamorphic Ca–Na pyroxenes in low-grade rocks. They become coarse-grained and show strong preferred orientation in schistose high-grade rocks. In the lowest grade, only riebeckite to crossite appears; with increasing grade, sodic amphibole becomes, first, enriched in glaucophane component, later coexists with actinolite, and finally, at even higher grade, becomes winchite. Actinolite first appears in foliated blueschists of the upper pumpellyite zone. It occurs (1) interlayered on a millimetre scale with glaucophane prisms and (2) as segments of composite amphibole crystals. Actinolite is considered to be in equilibrium with other high-pressure phases on the basis of its restricted occurrence in higher grade rocks, textural and compositional characteristics, and Fe/Mg distribution coefficient between actinolite and chlorite. Detailed analyses delineate a compositional gap for coexisting sodic and calcic amphiboles. At the highest grade, winchite appears at the expense of the actinolite–glaucophane pair. Compositional characteristics of Franciscan amphiboles from Ward Creek are compared with those of other high P/T facies series. The amphibole trend in terms of major components is very sensitive to the metamorphic field gradient. Na-amphibole appears at lower grade than actinolite along the higher P/T facies series (e.g. Franciscan and New Caledonia), whereas reverse relations occur in the lower P/T facies series (e.g. Sanbagawa and New Zealand). Available data also indicate that at low-temperature conditions, such as those of the blueschist and pumpellyite–actinolite facies, large compositional gaps exist between Ca- and Na-amphiboles, and between actinolite and hornblende, whereas at higher temperatures such as in the epidote–amphibolite, greenschist and eclogite facies, the gaps become very restricted. Common occurrence of both sodic and calcic amphiboles and Ca–Na pyroxene together with albite + quartz in the Ward Creek metabasites and their compositional trends are characteristic of the jadeite–glaucophane type facies series. In New Caledonia blueschists, Ca–Na pyroxenes are also common; Na-amphiboles do not appear alone at low grade in metabasites, instead, Na-amphiboles coexist with Ca-amphiboles throughout the progressive sequence. However, for metabasites of the intermediate pressure facies series, such as those of the Sanbagawa belt, Japan and South Island, New Zealand, Ca–Na pyroxene and glaucophane are not common; sodic amphiboles are restricted to crossite and riebeckite in composition and clinopyroxenes to acmite and sodic augite, and occur only in Fe₂O₃-rich metabasites. The glaucophane component of Na-amphibole systematically decreases from Ward Creek, New Caledonia, through Sanbagawa to New Zealand. This relation is consistent with estimated pressure decrease employing the geobarometer of Maruyama et al. (1986). Similarly, the decrease in tschermakite content and increase in NaM₄ of Ca-amphiboles from New Zealand, through Sanbagawa to New Caledonia is consistent with the geobarometry of Brown (1977b). Therefore, the difference in compositional trends of amphiboles can be used as a guide for P–T detail within the metamorphic facies series.     

Pressure–temperature evolution of lawsonite eclogite in Sivrihisar; Tavşanlı Zone–Turkey

The Cretaceous blueschist belt, Tavşanlı Zone, representing the subducted and exhumed northern continental margin of the Anatolide–Tauride platform is exposed in Western Anatolia. The Sivrihisar area east of Tavşanlı is made up of tectonic units consisting of i) metaclastics and conformably overlying massive marbles (coherent blueschist unit), ii) blueschist-eclogite unit, iii) marble–calcschist intercalation and iv) metaperidotite slab. The metaclastics are composed of jadeite–lawsonite–glaucophane and jadeite–glaucophane–chloritoid schists, phengite phyllites, and calcschists with glaucophane–lawsonite metabasite layers. The blueschist-eclogite unit representing strongly sheared, deeply buried and imbricated tectonic slices of accreted uppermost levels of the oceanic crust with minor metamorphosed serpentinite bodies consists of lawsonite-bearing eclogitic metabasites (approximately 90% of the field), lawsonite eclogites, metagabbros, serpentinites, pelagic marbles, omphacite–glaucophane–lawsonite metapelites and metacherts. The mineral assemblage of the lawsonite eclogite (garnet + omphacite > 70%) is omphacite, garnet, lawsonite, glaucophane, phengite and rutile. Lawsonite eclogite lenses are enclosed by garnet–lawsonite blueschist envelopes.Textural evidence from lawsonite eclogites and country rocks reveals that they did not leave the stability field of lawsonite during subduction and exhumation. The widespread preservation of lawsonite in eclogitic metabasites and eclogites can be attributed to rapid subduction and subsequent exhumation in a low geothermal gradient of the oceanic crust material without experiencing a thermal relaxation. Peak P–T conditions of lawsonite eclogites are estimated at 24 ± 1 kbar and 460 ± 25 °C. These P–T conditions indicate a remarkably low geotherm of 6.2 °C/km corresponding to a burial depth of 74 km.     

Oceanic ridge metamorphism of the East Taiwan Ophiolite

Brecciated mafic+ultramafic plutonic rocks of the East Taiwan Ophiolite occur as detritus and slide blocks in the Pliocene Lichi Mélange. These plutonic rocks have been subjected to two stages of post-magmatic recrystallization: (I) pre-brecciation ridge-type metamorphism attended by high-grade greenschist and rare amphibolite facies physical conditions; and (II) later off-axis metamorphism under zeolite to lowest greenschist facies conditions that postdated brecciation, submarine talus accumulation and deposition of associated pelagic sediments. The effects of the earlier ridge metamorphism are the main concern of this paper. (I) Dominant antigorite together with chlorite and talc in some ultramafics suggests that these rocks recrystallized at T>350 ° C. The primary compositions of gabbroic calcic plagioclase have been modified from An 45–70 to An 13–38, and the igneous clinopyroxenes and hornblendes partly replaced by actinolite+chlorite. Stable mineral assemblages in the metagabbros are thus ∼oligoclase+actinolite+chlorite±very rare epidote+sphene, and intermediate plagioclase +actinolite+chlorite+sphene. Amphibolites are less common and consist of more calcic plagioclase (An 25–49)+hornblende. The presence of assemblages transitional between greenschist and amphibolite facies for basaltic compositions is suggestive of very low-pressure thermal metamorphism such as would be appropriate to the crustal portions of an oceanic spreading center. (II) The occurrence of vein albite+actinolite+ chlorite near the base of the brecciated plutonic sequence and vein prehnite+laumontite in the upper part suggests that the brecciated plutonic rocks were later feebly retrograded under conditions of the greenschist and zeolite facies respectively-probably some distance removed from the thermal regime of a mid-oceanic ridge. The East Taiwan Ophiolite probably represents the western termination of the Philippine Sea lithospheric plate. Portions of this oceanic crust and underlying mantle were incorporated in the Lichi Mélange of the Coastal Range of eastern Taiwan as a consequence of antithetic faulting and erosion. This process evidently accompanied east-directed underflow of the Asiatic (South China Sea) plate.     

闽中马面山群变质火山岩微量元素地球化学特征及其构造意义

闽中地区元古宙马面山群变质火山岩沿政和-大埔断裂带分布,根据其主要化学成分特征,应为－套“双峰式”火山岩。稀土元素地球化学特征表明：本区绿片岩及钠长变粒岩LREE富集,Eu含量基本正常,微量元素MORB标准化蛛网图和微量元素构造判别图显示样品具大陆拉斑玄武岩特征,并呈大陆裂谷性质;斜长角闪岩没有明显的Eu负异常,MORB标准化蛛网图曲线前部呈小的隆起,Nb-Ta亏损较为明显,其岩石特征具有过渡性的钙碱性玄武岩及T－MORB的地球化学属性,原始地幔及Nb标准化蛛网图显示其可能来源于亏损地幔或有陆壳物质的混染。说明本区由大陆裂谷演化发展成为初始洋盆,有岩浆喷发,并可能发生板内俯冲。因此,这些变质火山岩应形成于裂谷－初始洋盆－板内俯冲的构造环境。     

Metamorphism of the Bikou Group in the Shanxi-Gausu-Sichuan Border Region1

Abstract The Bikou Group on the Shaanxi-Gansu-Sichuan border is composed of Mid-Late Proterozoic metamorphosed bimodal volcanic rocks and flysch sediments. Its metamorphism may be divided into the blueschist and greenschist facies. Three metamorphic zones, i.e. zones A, B, and C, may be distinguished on the basis of the field distribution of metamorphic rocks and the variation of b₀ values of muscovite. Blueschists are characterized by coexistence of sodic amphiboles and epidote and occur as stripes or relict patches in extensive greenschists of zone A. Studies of metamorphic minerals such as amphiboles, chlorite, epidote and muscovite and their textural relationships indicate that blueschists and greenschists were not formed under the same metamorphic physico-chemical conditions. The blueschist facies was formed at temperatures of 300-400°C and pressures of 0.5–0.6 GPa. The greenschist facies in zones A and B has similar temperatures but its pressure is only 0.4 GPa or so. The transition from the blueschist to greenschist facies is a nearly isothermal uplift process. The rock and mineral assemblages of the Bikou Group indicate that the blueschist facies metamorphism of the group might be related to crustal thickening or A-subduction accompanying the closure of an intracontinental small ocean basin.     

The geochemistry of mafic metavolcanics: implications for the origin of the Devonian massive sulfide deposits at Zlaté Hory,Czechoslovakia

Mafic metavolcanic rocks in the area of the Zlaté Hory massive sulfide deposits are interpreted as convergent plate-margin basalts and basaltic andesites metamorphosed to the greenschist facies. According to the major- and trace-element compositions the metabasites exhibit island-arc tholeiitic to low-K, calc-alkaline composition.Approximately 50% of samples of maifc metavolcanics studied have a salient negative anomaly of Ce in chondrite-normalized REE patterns. The Ce-depleted greenschists are thought to represent hydrothermally altered equivalents of metabasites of island-arc tholeiitic composition. The alteration was accompanied by the sulfide mineralization. That is indicated by enrichment in Ba and S together with correlation of the Ce/Ce* values and CO₂ abundances in the Ce-depleted rocks. The Ce anomaly may be caused by alteraton of ore-forming, seawaterderived solutions. The occurrence of Ce-depleted greenschists supports the hypothesis of the volcanogenic origin of the ore deposits in the Zlaté Hory area.