Occurrence of phthalate esters in the Seine River estuary (France)

The rigin and fate of six phthalate esters (dimethyl phthalate (DMP), diethyl phthalate (DEP), di‐n‐butyl phthalate (DnBP), butyl benzyl phthalate (BBP), di (2‐ethylhexyl) phthalate (DEHP) and di‐n‐octyl phthalate (DnOP)), were investigated during 2005 and 2006 in the densely populated Seine river estuary. Four compounds, DMP, DEP, DnBP and DEHP were detected at all the stations with DEHP (160–314 ng L^?1), followed by DEP (71–181 ng L^?1) and next DnBP (67–319 ng L^?1), except at la Bouille, where DnBP was the second most important compound. BBP and DnOP concentrations remained low and were not found at all the stations. Considering all six phthalates, Caudebec‐en‐Caux (beginning of the salinity gradient) was the least polluted station (464 ng L^?1), whereas Honfleur (771 ng L^?1) and La Bouille (716 ng L^?1) displayed the highest contamination levels, probably related to important industrial plants. From Caudebec‐en‐Caux to Honfleur (maximum turbidity), variation of DEHP concentration was related to that of suspended matter. In addition, the salinity rise in that area might have facilitated DEHP sorption upon particles. A significant correlation between flow magnitude and DEHP concentration was found (P < 0·01, n = 12), supporting the influence of the hydrological cycle upon contamination. Runoff contribution (56·9 kg d^?1) to river contamination was confirmed by the annual evolution of phthalate concentrations in the Seine river at Poses. Concentrations of DEHP in the tributaries were in the same range as those of the Seine River (100–350 ng L^?1), except for two in densely populated and industrialized areas: Robec (800 ng L^?1) and Cailly (970 ng L^?1). The treatment plant discharge fluxes were in the same range as those of tributaries (30·4–250 g d^?1). During high flow periods, the influence of tributaries and of treatment plants seemed to play a minor part in the contamination level of the Seine river estuary. Copyright © 2009 John Wiley & Sons, Ltd.     

Importance of soil surface characteristics on water erosion in a small grazed Sahelian catchment

This study concerns the problem of water erosion in the Sahel. Surface water and sediment yields (suspended matter and bedload) were monitored for 3 years (1998–2000) at the outlet of a small grazed catchment (1·4 ha) in the northern part of Burkina Faso. The catchment consists of about 64% sandy deposits (DRY soil surface type), which support most of the vegetation, and about 34% of crusted bare soils (ERO soil surface type). The annual solid‐matter export is more than 90% suspended sediment, varying between 4·0 and 8·4 t ha^?1. The bedload represents less than 10% of soil losses. In a single flood event (10 year return period), the sediment yield can reach 4·2 t ha^?1. During the period studied, a small proportion (20 to 32%) of the floods was thus responsible for a large proportion (80%) of the solid transport. Seasonal variation of the suspended‐matter content was also observed: high mean values (9 g l^?1) in June, decreasing in July and stabilizing in August (between 2 and 4 g l^?1). This behaviour may be a consequence of a reorganization of the soil surfaces that have been destroyed by trampling animals during the previous long dry season, vegetation growth (increase in the protecting effect of the herbaceous cover) and, to a lesser extent, particle‐supply limitation (exhaustion of dust deposits during July). The particle‐size distribution in the suspended matter collected at the catchment outlet is 60% made up of clay: fraction ≤2 µ m. The contribution of this clay is maximum when the water rises and its kaolinite/quartz ratio is then close to that of the ERO‐type surfaces. This indicates that these surfaces are the main source of clay within the catchment. Copyright © 2003 John Wiley & Sons, Ltd.     

Hydrological heterogeneity of an alpine stream–lake network in Switzerland

Water source and lake landscape position can strongly influence the physico‐chemical characteristics of flowing waters over space and time. We examined the physico‐chemical heterogeneity in surface waters of an alpine stream‐lake network (>2600 m a.s.l.) in Switzerland. The catchment comprises two basins interspersed with 26 cirque lakes. The larger lakes in each basin are interconnected by streams that converge in a lowermost lake with an outlet stream. The north basin is primarily fed by precipitation and groundwater, whereas the south basin is fed mostly by glacial melt from rock glaciers. Surface flow of the entire channel network contracted by ～60% in early autumn, when snowmelt runoff ceased and cold temperatures reduced glacial outputs, particularly in the south basin. Average water temperatures were ～4 °C cooler in the south basin, and temperatures increased by about 4–6 °C along the longitudinal gradient within each basin. Although overall water conductivity was low (<27 µS cm^?1) because of bedrock geology (ortho‐gneiss), the south basin had two times higher conductivity values than the north basin. Phosphate‐phosphorus levels were below analytical detection limits, but particulate phosphorus was about four times higher in the north basin (seasonal average: 9 µg l^?1) than in the south basin (seasonal average: 2 µg l^?1). Dissolved nitrogen constituents were around two times higher in the south basin than in the north basin, with highest values averaging > 300 µg l^?1 (nitrite + nitrate‐nitrogen), whereas particulate nitrogen was approximately nine times greater in the north basin (seasonal average: 97 µg l^?1) than in the south basin (seasonal average: 12 µg l^?1). Total inorganic carbon was low (usually <0·8 mg l^?1), silica was sufficient for algal growth, and particulate organic carbon was 4·5 times higher in the north basin (average: 0·9 mg l^?1) than in the south basin (average: 0·2 mg l^?1). North‐basin streams showed strong seasonality in turbidity, particulate‐nitrogen and ‐phosphorus, and particulate organic carbon, whereas strong seasonality in south‐basin streams was observed in conductivity and dissolved nitrogen. Lake position influenced the seasonal dynamics in stream temperatures and nutrients, particularly in the groundwater/precipitation‐fed north‐basin network. Copyright © 2007 John Wiley & Sons, Ltd.     

The solute budget of a forest catchment and solute fluxes within a Pinus radiata and a secondary native forest site,southern Chile

Solute concentrations and fluxes in rainfall, throughfall and stemflow in two forest types, and stream flow in a 90 ha catchment in southern Chile (39°44′S, 73°10′W) were measured. Bulk precipitation pH was 6·1 and conductivity was low. Cation concentrations in rainfall were low (0·58 mg Ca²⁺ l^?1, 0·13 mg K⁺ l^?1, 0·11 mg Mg²⁺ l^?1 and <0·08 mg NH₄–N l^?1), except for sodium (1·10 mg l^?1). Unexpected high levels of nitrate deposition in rainfall (mean concentration 0·38 mg NO₃–N l^?1, total flux 6·3 kg NO₃–N ha^?1) were measured. Concentrations of soluble phosphorous in bulk precipitation and stream flow were below detection limits (<0·09 mg l^?1) for all events. Stream‐flow pH was 6·3 and conductivity was 28·3 μs. Stream‐water chemistry was also dominated by sodium (2·70 mg l^?1) followed by Ca, Mg and K (1·31, 0·70 and 0·36 mg l^?1). The solute budget indicated a net loss of 3·8 kg Na⁺ ha^?1 year^?1, 5·4 kg Mg²⁺ ha^?1 year^?1, 1·5 kg Ca²⁺ ha^?1 year^?1 and 0·9 kg K⁺ ha^?1 year^?1, while 4·9 kg NO₃–N ha^?1 year^?1 was retained by the ecosystem. Stream water is not suitable for domestic use owing to high manganese and, especially, iron concentrations. Throughfall and stemflow chemistry at a pine stand (Pinus radiata D. Don) and a native forest site (Siempreverde type), both located within the catchment, were compared. Nitrate fluxes within both forest sites were similar (1·3 kg NO₃–N ha^?1 year^?1 as throughfall). Cation fluxes in net rainfall (throughfall plus stemflow) at the pine stand generally were higher (34·8 kg Na⁺ ha^?1 year^?1, 21·5 kg K⁺ ha^?1 year^?1, 5·1 kg Mg²⁺ ha^?1 year^?1) compared with the secondary native forest site (24·7 kg Na⁺ ha^?1 year^?1, 18·9 kg K⁺ ha^?1 year^?1 and 4·4 kg Mg²⁺ ha^?1 year^?1). However, calcium deposition beneath the native forest stand was higher (15·9 kg Ca²⁺ ha^?1 year^?1) compared with the pine stand (12·6 kg Ca²⁺ ha^?1 year^?1). Copyright © 2002 John Wiley & Sons, Ltd.     

Sediment concentration in interrill flow: interactions between soil surface conditions,vegetation and rainfall

A database composed of 673 natural rainfall events with sediment concentration measurements at the field or plot scale was analysed. Measurements were conducted on similar soil type (loess soils prone to sealing phenomenon) to apprehend the variability and complexity involved in interrill erosion processes attributable to soil surface conditions. The effects of the dominant controlling factors are not described by means of equations; rather, we established a classification of potential sediment concentration domain according to combination of the dominant parameters. Thereby, significant differences and evolution trends of mean sediment concentration between the different parameter categories are identified. Further, when parameter influences interact, it allows us to discern the relative effects of factors according to their respective degree of expression. It was shown that crop cover had a major influence on mean sediment concentration, particularly when soil surface roughness is low and when maximum 6‐min intensity of rainfall events exceeds 10 mm h^?1: mean sediment concentration decreases from 8·93 g l^?1 for 0–20 per cent of coverage to 0·97 g l^?1 for 21–60 per cent of coverage. The established classification also indicates that the increase of the maximum 6‐min intensity of the rainfall factor leads to a linear increase of mean sediment concentration for crop cover over 21 per cent (e.g. from 2·96 g l^?1 to 14·44 g l^?1 for the 1–5 cm roughness class) and to an exponential increase for low crop cover (e.g. from 3·92 g l^?1 to 58·76 g l^?1 for the 1–5 cm roughness class). The implication of this work may bring perspective for erosion prediction modelling and give references for the development of interrill erosion equation. Copyright © 2002 John Wiley & Sons, Ltd.     

Flood frequency analysis of Turkey using L‐moments method

The index flood procedure coupled with the L‐moments method is applied to the annual flood peaks data taken at all stream‐gauging stations in Turkey having at least 15‐year‐long records. First, screening of the data is done based on the discordancy measure (D_i) in terms of the L‐moments. Homogeneity of the total geographical area of Turkey is tested using the L‐moments based heterogeneity measure, H, computed on 500 simulations generated using the four parameter Kappa distribution. The L‐moments analysis of the recorded annual flood peaks data at 543 gauged sites indicates that Turkey as a whole is hydrologically heterogeneous, and 45 of 543 gauged sites are discordant which are discarded from further analyses. The catchment areas of these 543 sites vary from 9·9 to 75121 km² and their mean annual peak floods vary from 1·72 to 3739·5 m³ s^?1. The probability distributions used in the analyses, whose parameters are computed by the L‐moments method are the general extreme values (GEV), generalized logistic (GLO), generalized normal (GNO), Pearson type III (PE3), generalized Pareto (GPA), and five‐parameter Wakeby (WAK). Based on the L‐moment ratio diagrams and the |Z_dist|‐statistic criteria, the GEV distribution is identified as the robust distribution for the study area (498 gauged sites). Hence, for estimation of flood magnitudes of various return periods in Turkey, a regional flood frequency relationship is developed using the GEV distribution. Next, the quantiles computed at all of 543 gauged sites by the GEV and the Wakeby distributions are compared with the observed values of the same probability based on two criteria, mean absolute relative error and determination coefficient. Results of these comparisons indicate that both distributions of GEV and Wakeby, whose parameters are computed by the L‐moments method, are adequate in predicting quantile estimates. Copyright © 2011 John Wiley & Sons, Ltd.     

Some aspects of the hydroclimatology of the Quesnel River Basin,British Columbia,Canada

In conjunction with available climate data, surface runoff is investigated at 12 gauges in the Quesnel watershed of British Columbia to develop its long‐term (1926–2004) hydroclimatology. At Quesnel itself, annual mean values of air temperature, precipitation and runoff are 4·6 °C, 517 and 648 mm, respectively. Climate data reveal increases in precipitation, no significant trend in mean annual air temperature, but an increasing trend in mean minimum temperatures that is greatest in winter. There is some evidence of decreases in winter snow depth. On the water year scale (October–September), a strong positive correlation is found between discharge and precipitation (r = 0·70, p < 0·01) and a weak negative correlation is found between precipitation and temperature (r = ? 0·36, p < 0·01). Long‐term trends using the Mann‐Kendall test indicate increasing annual discharge amounts that vary from 8 to 14% (12% for the Quesnel River, p = 0·03), and also a tendency toward an earlier spring freshet. River runoff increases at a rate of 1·26 mm yr^?1 m^?1 of elevation from west to east along the strong elevation gradient in the basin. Discharge, temperature and precipitation are correlated with the large‐scale climate indices of the Pacific Decadal Oscillation (PDO) and El‐Niño Southern Oscillation (ENSO). Copyright © 2009 John Wiley & Sons, Ltd.     

Heavy metal concentrations during storm events in a rehabilitated industrialized catchment

Water quality data collected on a fortnightly or monthly basis are inadequate for assessment and modelling of many water quality problems as storm event samples are underrepresented or missed. This paper examines the stormflow dynamics of heavy metals (Pb, Cu, Cd and Zn) in the Nant‐y‐Fendrod stream, South Wales, which has been affected by 250 years of metal smelting, followed by 35 years of landscape rehabilitation measures. For storm events of contrasting (very dry and very wet) antecedent conditions in May 2000 and February 2001, respectively, temporal changes in streamwater heavy metal concentrations above and below an in‐line flood detention lake are analysed. At the upstream site, peaks in total metal concentration were recorded on the rising limb for Pb (0·150 mg l^?1) and Cu (0·038 mg l^?1) but on the falling limb for Zn (1·660 mg l^?1) and Cd (0·006 mg l^?1) in the summer 2000 storm event, yielding clockwise and anticlockwise hysteretic loops respectively. In contrast, metal concentrations, although high throughout the winter storm event, were diluted somewhat during the storm peak itself. The Pb and Cu appear to be supplied by quickflow processes and transported in close association with fine sediment, whereas Zn and Cd are delivered to the channel and lake by slower subsurface seepage in dissolved form. In the winter 2001 event, antecedent soil moisture and shallow groundwater levels were anomalously high and seepage sources of dissolved metals dominated. Downstream of the lake, Pb and Cu levels and suspended sediment were high in the summer storm, but low in the winter storm, suggesting retention with deposition of fine sediment in the lake during the latter. In the winter storm, Zn and Cd levels were higher downstream than upstream of the lake, perhaps because of additional seepage inputs from the surrounding slopes, which failed to have an impact during summer. An understanding of the complex interplay of antecedent soil moisture and the dynamics of subsurface seepage pathways in relation to the three‐dimensional distribution of sources is important in modelling heavy metal fluxes and levels in contaminated urban catchments. Copyright © 2003 John Wiley & Sons, Ltd.     

Measuring effectiveness of three postfire hillslope erosion barrier treatments,western Montana,USA

After the Valley Complex Fire burned 86 000 ha in western Montana in 2000, two studies were conducted to determine the effectiveness of contour‐felled log, straw wattle, and hand‐dug contour trench erosion barriers in mitigating postfire runoff and erosion. Sixteen plots were located across a steep, severely burned slope, with a single barrier installed in 12 plots (four per treatment) and four plots left untreated as controls. In a rainfall‐plus‐inflow simulation, 26 mm h^?1 rainfall was applied to each plot for 1 h and 48 L min^?1 of overland flow was added for the last 15 min. Total runoff from the contour‐felled log (0·58 mm) and straw wattle (0·40 mm) plots was significantly less than from the control plots (2·0 mm), but the contour trench plots (1·3 mm) showed no difference. The total sediment yield from the straw wattle plots (0·21 Mg ha^?1) was significantly less than the control plots (2·2 Mg ha^?1); the sediment yields in the contour‐felled log plots (0·58 Mg ha^?1) and the contour trench plots (2·5 Mg ha^?1) were not significantly different. After the simulations, sediment fences were installed to trap sediment eroded by natural rainfall. During the subsequent 3 years, sediment yields from individual events increased significantly with increasing 10 min maximum intensity and rainfall amounts. High‐intensity rainfall occurred early in the study and the erosion barriers were filled with sediment. There were no significant differences in event or annual sediment yields among treated and control plots. In 2001, the overall mean annual sediment yield was 21 Mg ha^?1; this value declined significantly to 0·6 Mg ha^?1 in 2002 and 0·2 Mg ha^?1 in 2003. The erosion barrier sediment storage used was less than the total available storage capacity; runoff and sediment were observed going over the top and around the ends of the barriers even when the barriers were less than half filled. Published in 2007 by John Wiley & Sons, Ltd.     

Transfer of carbon dioxide and methane through the soil‐water‐atmosphere system at Mer Bleue peatland,Canada

Surface waters associated with peatlands, supersaturated with CO₂ and CH₄ with respect to the atmosphere, act as important pathways linking a large and potentially unstable global repository of C to the atmosphere. Understanding the drivers and mechanisms which control C release from peatland systems to the atmosphere will contribute to better management and modelling of terrestrial C pools. We used non‐dispersive infra‐red (NDIR) CO₂ sensors to continuously measure gas concentrations in a beaver pond at Mer Bleue peatland (Canada); measurements were made between July and August 2007. Concentrations of CO₂ in the surface water (10 cm) reached 13 mg C l^?1 (epCO₂ 72), and 26 mg C l^?1 (epCO₂ 133) at depth (60 cm). The study also showed large diurnal fluctuations in dissolved CO₂ which ranged in amplitude from ～1·6 mg C l^?1 at 10 cm to ～0·2 mg C l^?1 at 60 cm depth. CH₄ concentration and supersaturation (epCH₄) measured using headspace analysis averaged 1·47 mg C l^?1 and 3252, respectively; diurnal cycling was also evident in CH₄ concentrations. Mean estimated evasion rates of CO₂ and CH₄ over the summer period were 44·92 ± 7·86 and 0·44 ± 0·25 µg C m^?2s^?1, respectively. Open water at Mer Bleue is a significant summer hotspot for greenhouse gas emissions within the catchment. Our results suggest that CO₂ concentrations during the summer in beaver ponds at Mer Bleue are strongly influenced by biological processes within the water column involving aquatic plants and algae (in situ photosynthesis and respiration). In terms of carbon cycling, soil‐stream connectivity at this time of year is therefore relatively weak. Copyright © 2008 John Wiley & Sons, Ltd.     

Sediment transport in a highly regulated fluvial system during two consecutive floods (lower Ebro River,NE Iberian Peninsula)

The transfer of sediment through a highly regulated large fluvial system (lower Ebro River) was analysed during two consecutive floods by means of sediment sampling. Suspended sediment and bedload transport were measured upstream and downstream of large reservoirs. The dams substantially altered flood timing, particularly the peaks, which were advanced downstream from the dams for flood control purposes. The suspended sediment yield upstream from the dams was 1 700 000 tonnes, which represented nearly 99 per cent of the total solid yield. The mean concentrations were close to 0·5 g l^?1. The sediment yield downstream from the dams was an order of magnitude lower (173 000 tonnes), showing a mean concentration of 0·05 g l^?1. The dams captured up to 95 per cent of the fine sediment carried in suspension in the river channel, preventing it from reaching the lowermost reaches of the river and the delta plain. Total bedload transport upstream from the dams was estimated to be about 25 000 tonnes, only 1·5 per cent of the total load. The median bedload rate was 100 gms^?1. Below the dams, the river carried 178 000 tonnes, around 51 per cent of the total load, at a mean rate of 250 g ms^?1. The results of sediment transport upstream and downstream from the large dams illustrate the magnitude of the sediment deficit in the lower Ebro River. The river mobilized a total of 350 000 tonnes in the downstream reaches, which were not replaced by sediment from upstream. Therefore, sediment was necessarily entrained from the riverbed and channel banks, causing a mean incision of 33 mm over the 27 km long study reach, altogether a significant step towards the long‐term degradation of the lower Ebro River. Copyright © 2005 John Wiley & Sons, Ltd.     

Quantifying periglacial erosion: insights on a glacial sediment budget,Matanuska Glacier,Alaska

Glacial erosion rates are estimated to be among the highest in the world. Few studies have attempted, however, to quantify the flux of sediment from the periglacial landscape to a glacier. Here, erosion rates from the nonglacial landscape above the Matanuska Glacier, Alaska are presented and compare with an 8‐yr record of proglacial suspended sediment yield. Non‐glacial lowering rates range from 1·8 ± 0·5 mm yr^?1 to 8·5 ± 3·4 mm yr^?1 from estimates of rock fall and debris‐flow fan volumes. An average erosion rate of 0·08 ± 0·04 mm yr^?1 from eight convex‐up ridge crests was determined using in situ produced cosmogenic ¹⁰Be. Extrapolating these rates, based on landscape morphometry, to the Matanuska basin (58% ice‐cover), it was found that nonglacial processes account for an annual sediment flux of 2·3 ± 1·0 × 10⁶ t. Suspended sediment data for 8 years and an assumed bedload to estimate the annual sediment yield at the Matanuska terminus to be 2·9 ± 1·0 × 10⁶ t, corresponding to an erosion rate of 1·8 ± 0·6 mm yr^?1: nonglacial sources therefore account for 80 ± 45% of the proglacial yield. A similar set of analyses were used for a small tributary sub‐basin (32% ice‐cover) to determine an erosion rate of 12·1 ± 6·9 mm yr^?1, based on proglacial sediment yield, with the nonglacial sediment flux equal to 10 ± 7% of the proglacial yield. It is suggested that erosion rates by nonglacial processes are similar to inferred subglacial rates, such that the ice‐free regions of a glaciated landscape contribute significantly to the glacial sediment budget. The similar magnitude of nonglacial and glacial rates implies that partially glaciated landscapes will respond rapidly to changes in climate and base level through a rapid nonglacial response to glacially driven incision. Copyright © 2009 John Wiley & Sons, Ltd.     

Using GIS and a digital elevation model to assess the effectiveness of variable grade flow diversion terraces in reducing soil erosion in northwestern New Brunswick,Canada

Flow diversion terraces (FDT) are commonly used beneficial management practice (BMP) for soil conservation on sloped terrain susceptible to water erosion. A simple GIS‐based soil erosion model was designed to assess the effectiveness of the FDT system under different climatic, topographic, and soil conditions at a sub‐basin level. The model was used to estimate the soil conservation support practice factor (P‐factor), which inherently considered two major outcomes with its implementation, namely (1) reduced slope length, and (2) sediment deposition in terraced channels. A benchmark site, the agriculture‐dominated watershed in northwestern New Brunswick (NB), was selected to test the performance of the model and estimated P‐factors. The estimated P‐factors ranged from 0·38–1·0 for soil conservation planning objectives and ranged from 0·001 to 0·45 in sediment yield calculations for water‐quality assessment. The model estimated that the average annual sediment yield was 773 kg ha^?1 yr ^?1 compared with a measured value of 641 kg ha^?1 yr^?1. The P‐factors estimated in this study were comparable with predicted values obtained with the revised universal soil loss equation (RUSLE2). The P‐factors from this study have the potential to be directly used as input in hydrological models, such as the soil and water assessment tool (SWAT), or in soil conservation planning where only conventional digital elevation models (DEMs) are available. Copyright © 2009 John Wiley & Sons, Ltd.     

Estimates of spatial variation in evaporation using satellite‐derived surface temperature and a water balance model

Evaporation dominates the water balance in arid and semi‐arid areas. The estimation of evaporation by land‐cover type is important for proper management of scarce water resources. Here, we present a method to assess spatial and temporal patterns of actual evaporation by relating water balance evaporation estimates to satellite‐derived radiometric surface temperature. The method is applied to a heterogeneous landscape in the Krishna River basin in south India using 10‐day composites of NOAA advanced very high‐resolution radiometer satellite imagery. The surface temperature predicts the difference between reference evaporation and modelled actual evaporation well in the four catchments (r² = 0·85 to r² = 0·88). Spatial and temporal variations in evaporation are linked to vegetation type and irrigation. During the monsoon season (June–September), evaporation occurs quite uniformly over the case‐study area (1·7–2·1 mm day^?1), since precipitation is in excess of soil moisture holding capacity, but it is higher in irrigated areas (2·2–2·7 mm day^?1). In the post‐monsoon season (December–March) evaporation is highest in irrigated areas (2·4 mm day^?1). A seemingly reasonable estimate of temporal and spatial patterns of evaporation can be made without the use of more complex and data‐intensive methods; the method also constrains satellite estimates of evaporation by the annual water balance, thereby assuring accuracy at the seasonal and annual time‐scales. Copyright © 2007 John Wiley & Sons, Ltd.     

Hydro‐climatic variability and trends in Washington State for the last 50 years

Historical records of monthly streamflow and precipitation coupled with mean, minimum, and maximum air temperatures for Washington State were used to study the variation and the trend characteristics that occurred over the last 50 years (1952–2002). Results indicate that the 1967 statewide water resource assessment needs to be updated because all of the stations used in that study exhibited a decreasing trend in annual streamflow ranging from ?0·9% to ?49·3%, with an arithmetic mean of ?11·7% and a median value of ?9·8%. Furthermore, a slightly decreasing trend in annual streamflow, although not statistically significant, was detected. The decreasing streamflow magnitude was about ?1·178 mm year^?2, or 4·88 m³ s^?1 year^?1, which caused a decrease in annual streamflow in the state of about 58·9 mm, or 244 m³ s^?1. This magnitude was about 9·6% of the average annual streamflow for the entire state from 1952 to 2002. Contrastingly, the overall annual precipitation in the entire state increased 1·375 mm year^?2. Overall the annual means of daily mean, maximum, and minimum temperature increased by 0·122, 0·048, and 0·185 °C/10 years, respectively, during the study period. Thus the corresponding annual means of daily mean, maximum, and minimum temperatures increased by 0·61, 0·24, and 0·93 °C, respectively. All of these trends and magnitudes were found to vary considerably from station to station and month to month. The possible reasons resulting in these detected trends include, but are not limited to, human activities, climate variability and changes, and land use and land cover changes. Copyright © 2009 John Wiley & Sons, Ltd.     

The role of perched aquifers in hydrological connectivity and biogeochemical processes in vernal pool landscapes,Central Valley,California

Relatively little is known about the role of perched aquifers in hydrological, biogeochemical, and biological processes of vernal pool landscapes. The objectives of this study are to introduce a perched aquifer concept for vernal pool formation and maintenance and to examine the resulting hydrological and biogeochemical phenomena in a representative catchment with three vernal pools connected to one another and to a seasonal stream by swales. A combined hydrometric and geochemical approach was used. Annual rainfall infiltrated but perched on a claypan/duripan, and this perched groundwater flowed downgradient toward the seasonal stream. The upper layer of soil above the claypan/duripan is ～0·6 m in thickness in the uplands and ～0·1 m in thickness in the vernal pools. Some groundwater flowed through the vernal pools when heads in the perched aquifer exceeded ～0·1 m above the claypan/duripan. Perched groundwater discharge accounted for 30–60% of the inflow to the vernal pools during and immediately following storm events. However, most perched groundwater flowed under or around the vernal pools or was recharged by annual rainfall downgradient of the vernal pools. Most of the perched groundwater was discharged to the outlet swale immediately upgradient of the seasonal stream, and most water discharging from the outlet swale to the seasonal stream was perched groundwater that had not flowed through the vernal pools. Therefore, nitrate‐nitrogen concentrations were lower (e.g. 0·17 to 0·39 mg l^?1) and dissolved organic carbon concentrations were higher (e.g. 5·97 to 3·24 mg l^?1) in vernal pool water than in outlet swale water discharging to the seasonal stream. Though the uplands, vernal pools, and seasonal stream are part of a single surface‐water and perched groundwater system, the vernal pools apparently play a limited role in controlling landscape‐scale water quality. Copyright © 2005 John Wiley & Sons, Ltd.     

Groundwater quality in Mesogea basin in eastern Attica (Greece)

Studies on the hydrogeological conditions of the Mesogea basin in east Attica reveal that the aquifers developed on the post‐alpine formations at the inner part of the coastal brackish zone exhibit positive hydraulic head. These Neogene and Quaternary deposits present high salt concentrations. Selected points were sampled (total 85: 51 wells and 34 boreholes) in order to obtain hydrogeological and hydrochemical data for a better understanding of the structure, operation and dynamics of the aquifer of the area. Statistical methods, R‐mode factor analysis and scatter‐plot diagrams were used for the hydrochemical analysis and presentation of the data. The groundwater resources are relatively weak and there is significant quality degradation due to the geological structure of the greater area, as well as the bad management of the aquifer and anthropogenic activities. Groundwater is characterized by high salt concentrations. Electrical conductivity values range between 260 and 6970 µS cm^?1. High salt concentrations at the coastal aquifers are due to sea intrusion, whereas they are attributed to the dissolution of minerals of the geological environment in the inland area. The groundwaters of the study area can be classified into five water types: Ca–HCO₃, Mg–HCO₃, Na–HCO₃, Na–Cl and Mg–Cl. They are saturated in dolomite and calcite, whereas they are unsaturated in anhydrite. High ion concentrations, e.g. ] (0‐221 mg l^?1), ] (0·01‐1·88 mg l^?1), ] (0·01‐6·75 mg l^?1), as well as high heavy metals concentrations are attributed to anthropogenic impacts. Copyright © 2006 John Wiley & Sons, Ltd.     

The Accumulation of Crimidin in Some Fish Organs

The accumulation of crimidin in total samples and in some organs of five fish species was studied under experimental conditions. The species were Cyprinus carpio, Carassius carassius, Tinca tinca, Scardinus erythrophthalmus and Leucaspius delineatus. Fish were exposed to concentrations of 10 mg · l^?l and 50 mg · l^?1. During short-term experiments water and fish samples were taken at intervals of t = 0, 6, 12, 24, 48 and 72 hours, during the long-term experiment sampling was performed weekly for six weeks. Total samples were analysed for C. carassius, T. tinca, S. erythrophthalmus and L. delineatus. Samples of individual organs and tissues were taken as follows: C. carpio – gills, digestive tract, muscular tissue, kidneys, gonads; C. carassius – gills, digestive tract, muscular tissue, ovaries, testes. Crimidin was determined by gas chromatography. In samples from the short-term experiments at a concentration of 10 mg · l^?1 in the water the amount was roughly 10¹–10 mg · kg^?1, at a concentration of 50 mg · l^?1 in the water roughly 10¹ mg · kg^?1. In most cases the accumulation coefficient was lower than 1.0. The accumulation capacity of individual fish species did not differ greatly. Of the internal organs only the kidneys had a high accumulation capacity, otherwise the highest values were found in muscular tissue and the gills. After one – three weeks the amount of crimidin in most organs falls, and after transfer to clean water there is a general sharp decline. Thus crimidin is not firmly bound in the body.     

Impact of redox and transport processes in a riparian wetland on stream water quality in the Fichtelgebirge region,southern Germany

Biologically mediated redox processes in the riparian zone, like denitrification, can have substantially beneficial impacts on stream water quality. The extent of these effects, however, depends greatly on the hydrological boundary conditions. The impact of hydrological processes on a wetland's nitrogen sink capacity was investigated in a forested riparian fen which is drained by a first‐order perennial stream. Here, we analysed the frequency distributions and time‐series of pH and nitrogen, silica, organic carbon and oxygen concentrations in throughfall, soil solution, groundwater and stream water, and the groundwater levels and stream discharges from a 3‐year period. During baseflow conditions, the stream was fed by discharging shallow, anoxic groundwater and by deep, oxic groundwater. Whereas the latter delivered considerable amounts of nitrogen (～0·37 mg l^?1) to the stream, the former was almost entirely depleted of nitrogen. During stormflow, near‐surface runoff in the upper 30 cm soil layer bypassed the denitrifying zone and added significant amounts to the nitrogen load of the stream. Nitrate‐nitrogen was close to 100% of deep groundwater and stream‐water nitrogen concentration. Stream‐water baseflow concentrations of nitrate, dissolved carbon and silica were about 1·6 mg l^?1, 4 mg l^?1 and 7·5 mg l^?1 respectively, and >3 mg l^?1, >10 mg l^?1 and <4 mg l^?1 respectively during discharge peaks. In addition to that macroscale bypassing effect, there was evidence for a corresponding microscale effect: Shallow groundwater sampled by soil suction cups indicated complete denitrification and lacked any seasonal signal of solute concentration, which was in contrast to piezometer samples from the same depth. Moreover, mean solute concentration in the piezometer samples resembled more that of suction‐cup samples from shallower depth than that of the same depth. We conclude that the soil solution cups sampled to a large extent the immobile soil‐water fraction. In contrast, the mobile fraction that was sampled by the piezometers exhibited substantially shorter residence time, thus being less exposed to denitrification, but predominating discharge of that layer to the stream. Consequently, assessing the nitrogen budget based on suction‐cup data tended to overestimate the nitrogen consumption in the riparian wetland. These effects are likely to become more important with the increased frequency and intensity of rainstorms that are expected due to climate change. Copyright © 2006 John Wiley & Sons, Ltd.