Multivariate statistical analysis of underground gas storage caverns on groundwater chemistry in Korea

An understanding of groundwater flow and chemistry is important to operate underground storage caverns. Groundwater flow is mainly affected by cavern operating conditions. Groundwater chemistry is modified by disinfection activities for removing possible biological clogging and by mixing with cement pore water. It is important to discern these two effects, because wells affected by the disinfection activities may have hydrological connections with water curtains used to inject the disinfectant. However, it is difficult to separate these two effects using graphical methods because of their similar chemical characteristics. Instead, multivariate statistical analysis, such as principal component analysis (PCA) and factor analysis (FA), can be used. Groundwater samples for chemical analysis were obtained from four surveys in 1999–2000. Based on the results from PCA and FA, it appears that there were temporal variations of seepage water into the propane area when the cavern operation fluctuated, but we could not observe such variation in the butane area. These changes may occur mainly at depth, where water flow is slow and water renewal in the cavern surrounding is limited. Copyright © 2008 John Wiley & Sons, Ltd.     

Modeling spatially correlated spectral accelerations at multiple periods using principal component analysis and geostatistics

Regional seismic risk assessments and quantification of portfolio losses often require simulation of spatially distributed ground motions at multiple intensity measures. For a given earthquake, distributed ground motions are characterized by spatial correlation and correlation between different intensity measures, known as cross‐correlation. This study proposes a new spatial cross‐correlation model for within‐event spectral acceleration residuals that uses a combination of principal component analysis (PCA) and geostatistics. Records from 45 earthquakes are used to investigate earthquake‐to‐earthquake trends in application of PCA to spectral acceleration residuals. Based on the findings, PCA is used to determine coefficients that linearly transform cross‐correlated residuals to independent principal components. Nested semivariogram models are then fit to empirical semivariograms to quantify the spatial correlation of principal components. The resultant PCA spatial cross‐correlation model is shown to be accurate and computationally efficient. A step‐by‐step procedure and an example are presented to illustrate the use of the predictive model for rapid simulation of spatially cross‐correlated spectral accelerations at multiple periods.     

Optimizing Ground Water Observation Networks in Irrigation Areas Using Principal Component Analysis

Ground water monitoring networks can provide vital information for sustainable water resources management. This involves the measurement of ground water level, solute concentration, or both. This article deals with the former. It optimizes network distribution of piezometer or data sampling wells to effectively monitor ground water levels under an irrigation region while retaining adequate overall measurement accuracy. This article presents a structured process for applying principal component analysis (PCA) in optimizing a ground water monitoring network in an irrigation area of Australia. The PCA functions, distributed with the MATLAB package, were used to determine relative contributions of individual piezometers in capturing the spatiotemporal variation of ground water levels. Kriging gridding interpolation algorithm was used to render the data surface presentations and determine spatial differences in piezometeric surfaces using different number of data sets. The results show that the overall difference of ground water level between the original piezometer network and the optimized networks after the PCA process was applied is less than 20%, while the total number of piezometers in the optimized network is reduced by 63%, which will save the time and cost to monitor ground water levels in the irrigation area.     

Use of temperature profiles and stable isotopes to trace flow lines: Nagaoka area, Japan

In this study, we use borehole temperature data and stable isotopes to delineate the flow system and estimate the effect of urbanization in the Nagaoka area of Japan. Temperature profiles were measured four times in observation wells during the period 2000-2001 and compared with those measured in the same wells during the period 1977-1983 (Taniguchi 1986). Water was sampled in both observation and pumping wells during the same period. The temporal and spatial variability in temperature indicate clearly the effect of urban warming and heavy pumping on the ground water system. Urban warming caused higher temperatures recently as compared to the older values, and pumping caused induced recharge from the river to the ground water. The stable isotope data show the ground water flow system is divided into shallow, intermediate, and deep systems, and that land use and infiltration rate are affecting the shallow flow system.     

Hydrogeochemical Evolution Along Groundwater Flow Paths in the Manas River Basin,Northwest China

The impacts of long-term pumping on groundwater chemistry remain unclear in the Manas River Basin, Northwest China. In this study, major ions within five surface water and 105 groundwater samples were analyzed to identify hydrogeochemical processes affecting groundwater composition and evolution along the regional-scale groundwater flow paths using the multivariate techniques of hierarchical cluster analysis (HCA) and principal components analysis (PCA) and traditional graphical methods for analyzing groundwater geochemistry. HCA classified the groundwater samples into four clusters (C1 to C4). PCA reduced the dimensionality of geochemical data into three PCs, which explained 86% of the total variance. The results of HCA and PCA were used to identify three zones: “recharge,” “transition,” and “discharge.” In the recharge zone the groundwater type is Ca-HCO₃-SO₄ and is primarily impacted by the dissolution of calcite and silicate weathering. In the transition zone the groundwater type is Ca-HCO₃-SO₄-Cl and is impacted by rock dissolution and reverse ion exchange. In the discharge zone the groundwater type is Na-Cl and is impacted by evaporation and reverse ion exchange. In addition, anthropogenic activities impact the groundwater chemistry in the study area. The groundwater type generally changes from Ca-HCO₃-SO₄ in the recharge area to Na-Cl in the discharge area along the regional-scale groundwater flow paths. This study provides a process-based knowledge for understanding the interaction of groundwater flow patterns and geochemical evolution within the Manas River Basin.     

山西流体观测井水位与气压相关性分析

分析了山西省流体观测井水位动态特征,利用高阶差分、回归分析方法计算了2008年山西省各观测井水位与气压相关系数,得到了气压系数的背景值,进而对气压干扰因素进行定量化的排除,并对各井的气压系数进行对比分析。结果表明,不同的观测井孔水位受气压影响程度不同,对于某一个观测井孔而言,气压系数及相关系数的变化是有一定规律的。     

An analytical study on three‐dimensional versus two‐dimensional water table‐induced flow patterns in a Tóthian basin

Although it has been increasingly acknowledged that groundwater flow pattern is complicated in the three‐dimensional (3‐D) domain, two‐dimensional (2‐D) water table‐induced flow models are still widely used to delineate basin‐scale groundwater circulation. However, the validity of 2‐D cross‐sectional flow field induced by water table has been seldom examined. Here, we derive the analytical solution of 3‐D water table‐induced hydraulic head in a Tóthian basin and then examine the validity of 2‐D cross‐sectional models by comparing the flow fields of selected cross sections calculated by the 2‐D cross‐sectional model with those by the 3‐D model, which represents the “true” cases. For cross sections in the recharge or discharge area of the 3‐D basin, even if head difference is not significant, the 2‐D cross‐sectional models result in flow patterns absolutely different from the true ones. For the cross section following the principal direction of groundwater flow, although 2‐D cross‐sectional models would overestimate the penetrating depth of local flow systems and underestimate the recharge/discharge flux, the flow pattern from the cross‐sectional model is similar to the true one and could be close enough to the true one by adjusting the decay exponent and anisotropy ratio of permeability. Consequently, to determine whether a 2‐D cross‐sectional model is applicable, a comparison of hydraulic head difference between 2‐D and 3‐D solutions is not enough. Instead, the similarity of flow pattern should be considered to determine whether a cross‐sectional model is applicable. This study improves understanding of groundwater flow induced by more natural water table undulations in the 3‐D domain and the limitations of 2‐D models accounting for cross‐sectional water table undulation only.     

Hydrogeochemistry and environmental isotopes of ground water in Jeju volcanic island,Korea: implications for nitrate contamination

Ground water from springs and public supply wells was investigated for hydrochemistry and environmental isotopes of ³H, ¹⁸O and D in Jeju volcanic island, Korea. The wells are completed in a basaltic aquifer and the upper part of hydrovolcanic sedimentary formation. Nitrate contamination is conspicuous in the coastal area where most of the samples have nitrate concentrations well above 1 mg NO₃ N/l. Agricultural land use seems to have a strong influence on the distribution of nitrate in ground water. Comparison of stable isotopic compositions of precipitation and ground water show that ground water mostly originates from rainy season precipitation without significant secondary modification and that local recharge is dominant. ³H concentration of ground water ranged from nearly zero to 5 TU and is poorly correlated with vertical location of well screens. The occurrence of the ³H‐free, old ground water is due to the presence of low permeability layers near the boundary of the basaltic aquifer and the hydrovolcanic sedimentary formation, which significantly limits ground water flow from the upper basaltic aquifer. The old ground water exhibited background‐level nitrate concentrations despite high nitrate loadings, whereas young ground water had considerably higher nitrate concentrations. This correlation of ³H and nitrate concentration may be ascribed to the history of fertilizer use that has increased dramatically since the early 1960s in the island. This suggests that ³H can be used as a qualitative indicator for aquifer vulnerability to nitrate contamination. Copyright © 2005 John Wiley & Sons, Ltd.     

Frequency‐dependent principal component analysis of multicomponent earthquake ground motions

Stochastic ground motion simulation techniques are becoming increasingly popular because of enhanced computation power enabling direct simulation of complex response quantities. Priestley process assumption is the most general approach for stochastic modeling of earthquake ground motion. However, a framework for multicomponent ground motion simulation using the general Priestley process assumption is not available. Multicomponent motions are useful especially when the correlation structure between them significantly influences the response. The present study proposes a framework for frequency‐dependent principal component analysis (PCA), which facilitates Priestley process–based simulation of multicomponent ground motions. The study focuses only on the frequency‐dependent PCA part, and the results show high dependency of the principal components/directions on the frequency bands of the signals. The present work also advocates that the frequency‐dependent PCA should be preferred to the conventional PCA as the former can address the issues related to the frequency‐independent uniform modulation associated with the latter.     

Hydrogeochemistry and its relation to groundwater level fluctuation in the Palar and Cheyyar river basins,southern India

An investigation was carried out to understand the role of water level fluctuation on major‐ion chemistry of groundwater in the Palar and Cheyyar river basins, southern India. As groundwater is the only major source of water for agricultural and drinking purposes in this area, it is important to know the effect of geological formations and agricultural activities on groundwater chemistry. Groundwater samples were collected once a month from 43 wells (641 samples in total), from January 1998 to June 1999, and analysed for major ions. The results indicate that the major‐ion chemistry of the groundwater varies with respect to space. Groundwater occurring near the River Palar has a high concentration of major ions except calcium, due to the absence of any recharge from the river, whereas lower concentrations of major ions were observed in the central part of the study area due to the recharge of fresh water from a number of surface reservoirs. The major‐ion chemistry of the study region is controlled by both mineral dissolution and anthropogenic activities. The relative contributions of mineral dissolution and anthropogenic contamination are estimated by a stoichiometric approach, which suggests that mineral dissolution is the dominant process in both the formations. The relation between water level fluctuations and major‐ion chemistry indicates that major‐ion chemistry is also greatly influenced by the water level fluctuations in different geological formations. Thus, the major‐ion chemistry of groundwater in this region is greatly influenced by mineral dissolution, anthropogenic activities and water level fluctuations in different geological formations. Copyright © 2006 John Wiley & Sons, Ltd.     

Time series analysis for evaluating hydrological responses of pore-water pressure to rainfall in a slope

Characterization of pore-water pressure at the soil–atmosphere interface is a major requirement in relation to slope instability. A rain-gauge and five piezometers (BH1–BH5) were installed on a slope located in a Korean military base. The upper slope (BH4, BH5) was covered with plastic sheets to prevent rainwater from percolating into the slope due to safety issues. Rainfall is matched by prompt changes in the pore-water pressure except at BH5. Due to the plastic cover, the pore water does not show any significant change in the early period by evapotranspiration. From correlation analysis, two wells (BH3, BH5) have longer memory effects due to matrix flow of past precipitation. Two principal components show hydrological responses of pore water to rainfall during intense rainfall, but PC2 does not indicate any important changes in low or no rainfall. This study suggests that correlation analysis with PCA can be a valuable tool for interpreting datasets consisting only of pore-water pressure.     

海原甘盐池地震观测井水位动态特征分析

影响因素及埋藏类型是地下水观测数据前兆分析的重要资料.通过海原甘盐池拉分盆地内两口地震水位观测井(GYC 和 GYCN 井)的气压、降雨与水位资料,综合分析水位变化的影响因素,并分别利用阶跃响应函数、频谱分析法、潮汐波群相位超前或滞后法分析地下水埋藏类型.结果表明:(1)气压和降雨是影响海原甘盐池两口地震观测井水位动态变化的主要因素.(2)GYC井地下水埋藏类型为混合水,与该井成井时的判定资料不一致(承压水),可能与其时间较长、长年失修、存在破损现象有关,或受地表水影响较大 ;GYCN 井地下水埋藏类型为承压水.该研究结果为该地区地震水位观测井的准入(退出)机制、今后观测井点的勘选等提供科学依据,对今后异常识别和震情跟踪具有重要意义.     

Genesis of arsenic in groundwater of North Bengal Plain using PCA: A case study of English Bazar Block,Malda District,West Bengal,India

The study area is located on the western part of the alluvium‐filled gap between the Rajmahal hills on the west and the Garo hills on the east. Groundwater occurs under unconfined condition in a thick zone of saturation within the Quaternary alluvial sediments. Three hydrochemical facies with distinct characteristics have been identified which are dominated in general by alkaline earths and weak acids. The major‐ion chemistry of the area is controlled by weathering of silicate minerals, rainfall recharge, ion‐exchange processes and anthropogenic activities such as irrigation return flow and the application of inorganic fertilizers and pesticides. A stoichiometric approach suggests that mineral dissolution and anthropogenic activities contribute 79% and 21% of the total cations dissolved in groundwater. Principal component analysis (PCA) of 42 groundwater samples using 13 chemical parameters indicates that the combined processes of recharge of groundwater from rainfall, sediment water interaction, groundwater flow, infiltration of irrigation return water (which is arsenic rich due to the use of arsenic‐bearing pesticides, wood preservatives, etc. and the pumping of arsenic‐rich groundwater for agriculture purpose), oxidation of natural or anthropogenic organic matter and the reductive dissolution of ferric iron and manganese oxides play a key role in the evolution of groundwater in the study area. Factor 2 scores, associated with the infiltration of irrigation return water and spatial distribution of arsenic concentration reveal that the groundwater of the municipal area will not be affected by arsenic in the future in spite of heavy groundwater abstraction. Another PCA with geologic, geomorphic, anthropogenic, geochemical and landuse factors indicates that arsenic concentration in groundwater increases with increasing area of mango orchards, sand lithofacies and nitrate and decreases with increasing distance of paleochannel from the monitored well and depth of bore wells. High loading on nitrate may be attributed to the use of fertilizer, pesticides, etc. in mango orchards and agricultural land. High loadings on log pCO₂, mango orchards (with negative sign) and phosphate (with positive sign) indicate that mango orchards provide the organic waste material which is decomposed to form organic carbon. The organic carbon undergoes oxidative carbon degeneration by different oxidants and increases the concentration of CO₂ in the aquifer. The reducing condition thus developed in the aquifer helps to dissolve the arsenic adsorbed on iron hydroxide or oxy‐hydroxide coated margins of sand, iron rich heavy mineral grain margins, clay minerals and Fe–Mn concretions present in the aquifer matrix. Copyright © 2007 John Wiley & Sons, Ltd.     

A Simple Method for Measuring the Vertically of Small-Diameter Driven Wells

The presence of stones, solid waste, and other obstructions can deflect small-diameter driven wells during installation, leading to deviations of the well from its intended position. This could lead to erroneous results, especially for measurements of ground water levels by water level meters. A simple method was developed to measure deviations from the intended positions of well screens and determine correction factors required for proper measurement of ground water levels in nonvertical wells. The method is based upon measurement of the hydrostatic pressure in the bottom of a water column, which is established in the well lube. The method was used to correct water level measurement in wells driven through a landfill site. Errors of up to 27 cm in water level were observed at the landfill site. The correction of the water level measurements had a significant effect on estimated local ground water flow directions.     

Modeling effects of multinode wells on solute transport

Long-screen wells or long open boreholes with intraborehole flow potentially provide pathways for contaminants to move from one location to another in a ground water flow system. Such wells also can perturb a flow field so that the well will not provide water samples that are representative of ground water quality a short distance away from the well. A methodology is presented to accurately and efficiently simulate solute transport in ground water systems that include wells longer than the grid spacing used in a simulation model of the system and hence are connected to multiple nodes of the grid. The methods are implemented in a MODFLOW-compatible solute-transport model and use MODFLOW's Multi-Node Well Package but are generic and can be readily implemented in other solute-transport models. For nonpumping multinode wells (used to simulate open boreholes or observation wells, for example) and for low-rate pumping wells (in which the flow between the well and the ground water system is not unidirectional), a simple routing and local mixing model was developed to calculate nodal concentrations within the borehole. For high-rate pumping multinode wells (either withdrawal or injection, in which flow between the well and the ground water system is in the same direction at all well nodes), complete and instantaneous mixing in the wellbore of all inflows is assumed.     

Assessment of Water Quality After 10 Years of Reclaimed Water Injection: The Nardò Fractured Aquifer (Southern Italy)

Experimental studies have been carried out in a fractured coastal aquifer of the Salento region (Nardò, Italy), which has been subjected to 12,000 m³/day of treated municipal waste water injected into a natural sinkhole since 1991. The analytical parameters of ground water sampled in 30 monitoring wells in the area down gradient from the sinkhole, taking into account the direction of ground water flow, have been compared before and after injection. The water table mound (1.5 m), the reduction of sea water extent (2 km), and the spreading of injected pollutants were evaluated by means of a mathematical model. The predicted values in the monitoring wells were adjusted to inorganic nitrogen biodegradation using transformation rates developed in laboratory tests. After 10 years, the injection has increased the volume of the available resource for agricultural and drinking water use, without any notable decrease in the preexisting ground water quality. Moreover, to preserve water resources from pollution, the mathematical model allowed the maximum constituent concentrations (standards) in waste water reclamation for recharge to be identified. A precautionary area around the sinkhole was also defined so that withdrawal prohibition could be implemented to avoid risks to human health.     

Controls on Ground Water Chemistry in the Central Couloir Sud Rifain,Morocco

Irrigation, urbanization, and drought pose challenges for the sustainable use of ground water in the central Couloir sud rifain, a major agricultural region in north-central Morocco, which includes the cities of Fès and Meknès. The central Couloir is underlain by unconfined and confined carbonate aquifers that have suffered declines in hydraulic head and reductions in spring flow in recent decades. Previous studies have surveyed ground water flow and water quality in wells and springs but have not comprehensively addressed the chemistry of the regional aquifer system. Using graphical techniques and saturation index calculations, we infer that major ion chemistry is controlled (1) in the surficial aquifer by cation exchange, calcite dissolution, mixing with deep ground water, and possibly calcite precipitation and (2) in the confined aquifer and warm springs by calcite dissolution, dolomite dissolution, mixing with water that has dissolved gypsum and halite, and calcite precipitation. Analyses of ²H and ¹⁸O indicate that shallow ground water is affected by evaporation during recharge (either of infiltrating precipitation or return flow), whereas deep ground water is sustained by meteoric recharge with little evaporation. Mechanisms of recharge and hydrochemical evolution are broadly consistent with those delineated for similar regional aquifer systems elsewhere in Morocco and in southern Spain.     

Hydrochemistry of groundwaters in a spa area of Korea: an implication for water quality degradation by intensive pumping

A geochemical study was carried out in a small spa area (Onyang Spa, Korea) where intensive pumping of deep thermal groundwater (1 300 000 m³ year⁻¹) is taking place. This has caused the deep fractures to lose their artesian pressure and the upper shallow fractures have been encroached by shallow, cold waters. To quantify the influence of long‐term heavy pumping on the quality of the geothermal water, groundwater sampling and chemical analysis, water‐level measurement, and well loggings were performed for the selected deep thermal wells and shallow cold wells. Chemical analysis results indicate a big contrast in water chemistry and origins between the two water types. Shallow groundwater shows a wider concentration ranges in solutes that are closely related to human activity, illustrating the water's vulnerability to contamination near the land surface. Plots of water chemistry as a function of fluoride reveal that the quality of the thermal water was greatly influenced by the shallow, cold groundwater and that intensive pumping of the deep thermal groundwater has caused the introduction of shallow groundwater into the deeper fractures. Although the deep and the shallow fractures were piezometrically separated to some extent, a mixing model based on fluoride and nitrate indicated that the cold‐water fractions in the thermal wells are up to 50%. This suggests that the thermal water is faced with water quality degradation by the downward flow of the shallow, cold water. Restriction on the total of all the pumpage permits per unit area is suggested to restore the artesian pressure of the deep thermal aquifer and to prevent cold‐water intrusion in the study area. Copyright © 2004 John Wiley & Sons, Ltd.     

Geochemistry of the Springfield Plateau aquifer of the Ozark Plateaus Province in Arkansas,Kansas, Missouri and Oklahoma,USA

Geochemical data indicate that the Springfield Plateau aquifer, a carbonate aquifer of the Ozark Plateaus Province in central USA, has two distinct hydrochemical zones. Within each hydrochemical zone, water from springs is geochemically and isotopically different than water from wells. Geochemical data indicate that spring water generally interacts less with the surrounding rock and has a shorter residence time, probably as a result of flowing along discrete fractures and solution openings, than water from wells. Water type throughout most of the aquifer was calcium bicarbonate, indicating that carbonate‐rock dissolution is the primary geochemical process occurring in the aquifer. Concentrations of calcium, bicarbonate, dissolved oxygen and tritium indicate that most ground water in the aquifer recharged rapidly and is relatively young (less than 40 years). In general, field‐measured properties, concentrations of many chemical constituents, and calcite saturation indices were greater in samples from the northern part of the aquifer (hydrochemical zone A) than in samples from the southern part of the aquifer (hydrochemical zone B). Factors affecting differences in the geochemical composition of ground water between the two zones are difficult to identify, but could be related to differences in chert content and possibly primary porosity, solubility of the limestone, and amount and type of cementation between zone A than in zone B. In addition, specific conductance, pH, alkalinity, concentrations of many chemical constituents and calcite saturation indices were greater in samples from wells than in samples from springs in each hydrochemical zone. In contrast, concentrations of dissolved oxygen, nitrite plus nitrate, and chloride generally were greater in samples from springs than in samples from wells. Water from springs generally flows rapidly through large conduits with minimum water–rock interactions. Water from wells flow through small fractures, which restrict flow and increase water–rock interactions. As a result, springs tend to be more susceptible to surface contamination than wells. The results of this study have important implications for the geochemical and hydrogeological processes of similar carbonate aquifers in other geographical locations. Copyright © 2000 John Wiley & Sons, Ltd.     

丹东地区地下水位微动态信息初探

丹东地区现有四口地下水位观测井,分别是东港汤池井、四道沟滨江井、同兴乡变电井、宽甸明安井。本文利用多年的观测资料对这四口井进行了对比分析,着重分析了气压、降雨对地下水位的影响,从前震效应、震后效应、同震响应方面对四口井加以分析,找出了四口观测井的微动态信息,并对丹东地区地下水井点的分布及所反应的微动态信息优劣进行了对比...