On the formation of dissolution pipes in Quaternary coastal calcareous arenites in Mediterranean settings

A large number of uniform cone‐shaped dissolution pipes has been observed and studied in Quaternary coastal calcareous arenites in Apulia and Sardinia (Italy) and Tunisia. These cylindrical tubes have a mean diameter of 52·8 cm and are up to 970 cm deep (mean depth for sediment‐free pipes is 1·38 m). They generally have smooth walls along their length, are perfectly vertical and taper out towards their bottoms. Their development is not influenced by bedding nor fractures. Sometimes their walls are coated by a calcrete crust. Their morphology has been studied in detail and their relationships with the surrounding rocks and with the environment have been analysed. The perfectly vertical development is a clear evidence of their genesis controlled by gravity. The depth of the dissolution pipes can be described by an exponential distribution law (the Milanovic distribution), strongly suggesting they developed by a diffusion mechanism from the surface vertically downward. We believe dissolution pipes preferentially form in a covered karst setting. Local patches of soil and vegetation cause infiltration water to be enriched in carbon dioxide enhancing dissolution of carbonate cement and local small‐scale subsidence. This process causes the formation of a depression cone that guides infiltrating waters towards these spots giving rise to the downward growth of gravity‐controlled dissolution pipes. A change of climate from wetter phases to drier and hotter ones causes the formation of a calcrete lining, fossilizing the pipes. When the pipes become exposed to surface agents by erosion of the sediment cover or are laterally breached the loose quartz sand filling them may be transported elsewhere. Copyright © 2010 John Wiley & Sons, Ltd.     

含流体砂岩地震波频散实验研究

为了研究孔隙流体对不同渗透率岩石地震波速度的影响,在实验室利用跨频带岩石弹性参数测试系统得到了应变幅值10-6的2~2000Hz频段下的地震波速度和1 MHz频率下的超声波速度,利用差分共振声谱法得到了频率600Hz岩石干燥和完全饱水情况下岩石声学参数.实验表明,在低饱和度下,致密砂岩在地震和超声频段下没有明显的频散;在高饱和度下纵波速度的频散变得明显.从干燥到完全水饱和条件,不同频率测量的致密砂岩的体积模量随岩石孔隙度增高而降低,且体积模量的变化量受岩石微观孔隙结构的影响较大.高孔、高渗砂岩无论在低含水度下还是在高含水饱和度下频散微弱,并且在地震频段下围压对于岩石纵横波速度的影响要大于频率的影响.高孔、高渗砂岩和致密砂岩不同含水饱和度下的频散差异可应用于储层预测,油气检测等方面,同时该研究可以更好地帮助理解岩石的黏弹性行为,促进岩石物理频散理论的发展,提高地震解释的精度.     

Stress relaxation and attenuation of fluid－saturated sandstone at low frequency

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Brønsted reactions on oxide mineral surfaces and the temperature-dependence of their dissolution rates

The pH-dependence of oxide dissolution rates is controlled by Brønsted acid-base reactions at the mineral surface. These reactions are rapid but depend explicitly on temperature, as do the subsequent slow rates of bond hydrolysis. The net result is that dissolution rates vary in a complicated fashion with temperature and solution pH. The enthalpy changes of acid-base reactions on oxide materials are sufficiently similar, however, that general statements can be made about their contribution. The enthalpy changes from proton adsorption to a hydroxyl functional group (SOH), or to a deprotonated functional group (SO ^–), are generally exothermic. The enthalpy changes become increasingly endothermic, however, as charge accumulates on the mineral surface and the charged species interact electrostatically. The result is that mineral dissolution rates are least sensitive to temperature, as measured with an Arrhenius-like rate law, at pH conditions near the Point of Zero Net Proton Charge.     

The attenuation of stress waves in fluid saturated porous rock

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Experimental sandstone weathering using different wetting and drying moisture amplitudes

Wetting and drying is an acknowledged yet still poorly understood rock weathering process. Previous experiments documented in the literature measure physical changes or mass loss in relation to moisture oscillations but only one study directly compares different moisture amplitudes by using different modes of moisture application. In this experimental study, four sets of sandstone tablets are subjected to 48 h wetting and drying cycles at set moisture content fluctuations of 29, 42, 56 and 63% respectively. A common moisture application, full immersion, is used for all four sets. Mass loss after 52 cycles averaged 0·27%, some three times more than that of the control samples. Average porosity of the samples increased, while water absorption capacities and the saturation coefficients of the samples decreased. No discernable difference in mass loss or change in physical properties was found between the different sample sets. When compared with previous studies, results suggest that the effect of moisture application type may be more of a controlling factor on the weathering effect than actual moisture content achieved. A need to move towards a more standardized approach in wetting and drying experimental studies is emphasized. Copyright © 2007 John Wiley & Sons, Ltd.     

砂岩的热破裂过程

高温环境下,岩石表现为明显的宏观破裂特征. 本实验在细观尺度下观测了不同温度条件下,阜新细砂岩的矿物组分和微结构及其发展变化,以及内部微裂纹的发生和发展. 从实验中观察到,自150℃开始,阜新细砂岩微裂纹数量有剧烈的增加,并达到峰值;当温度超过210℃以后,可见裂纹的数量呈下降趋势并逐渐稳定;当温度达到810℃,细砂岩裂纹数量出现第二个增长峰值. 结果表明随着温度变化,细砂岩存在热破裂阀值.     

Coeval biochemical and biophysical weathering processes on Quaternary sandstone terraces south of Rabat (Temara), northwest Morocco

Despite numerous investigations on substrate‐inhabiting microflora, especially lichens, very little is known about the colonization of coastal escarpments by lithobiontic micro‐organisms, inland of a retreating coastline in Africa. Reported herein are the results of a combined field observation and microscopy study focusing on the connection between microrelief of the substrate, colonies of lithobiontic micro‐organisms (in particular the lichen Xanthoria parietina) and microstructures of putative bacterial origin. The occurrence of weathering pits in which the early stages of the biotic development occurs, and the subsequent disintegration of the rock indicate that lichens, mosses and fungi act synergistically by alternating chemical and mechanical weathering. Penetration of grains by expansion and contraction of the hyphae depletes the rock matrix and contributes to the mechanical breakdown of the rock. Calcite rhombs on the weathered surfaces of the calcite‐cemented sandstones are severely etched with well‐developed rhomb‐shaped etch pits (‘spiky calcite’), holes, or has one or more of the faces removed, and their cores exposed and leached. Nanofilaments (c. 100–700 nm) and ‘nanomicrobial’ fruiting bodies (c. 250 nm) emanating from micropores appear to be common on affected crystalline structures. Weddellite present immediately below the thallus is a strong indicator of biomineralization. Quartz responds differently to chemical weathering by producing peeling structures and microbrecciation features. The dissolution of these crystals appears to be a surface reaction‐controlled process mediated by microbial microfilaments and nanofilaments. A model is proposed, firstly indicating early‐stage biochemical weathering, followed by biophysical weathering. Disintegration of the rock outcrops in due to a complex interplay of several events, probably beginning at the nanoscale with penetration of sites on crystal faces. Copyright © 2006 John Wiley & Sons, Ltd.     

Sandstone response to salt weathering following simulated fire damage: a comparison of the effects of furnace heating and fire

Fire has long been recognized as an agent of rock weathering. Our understanding of the impact of fire on stone comes either from early anecdotal evidence, or from more recent laboratory simulation studies, using furnaces to simulate the effects of fire. This paper suggests that knowledge derived from simulated heating experiments is based on the pre‐conceptions of the experiment designer – when using a furnace to simulate fire, the operator decides on the maximum temperature and the duration of the experiment. These are key factors in determining the response of the stone to fire, and if these are removed from real‐world observations then knowledge based on these simulations must be questioned. To explore the differences between heating sandstone in a furnace and a real fire, sample blocks of Peakmoor Sandstone were subjected to different stress histories in combination (lime rendering and removal, furnace heating or fire, frost and salt weathering). Block response to furnace heating and fire is discussed, with emphasis placed on the non‐uniformity of the fire and of block response to fire in contrast to the uniform response to surface heating in a furnace. Subsequent response to salt weathering (by a 10% solution of sodium chloride and magnesium sulphate) was then monitored by weight loss. Blocks that had experienced fire showed a more unpredictable response to salt weathering than those that had undergone furnace heating – spalling of corners and rapid catastrophic weight loss were evidenced in blocks that had been subjected to fire, after periods of relative quiescence. An important physical side‐effect of the fire was soot accumulation, which created a waxy, relatively impermeable layer on some blocks. This layer repelled water and hindered salt ingress, but eventually detached when salt, able to enter the substrate through more permeable areas, concentrated and crystallized behind it, resulting in rapid weight loss and accelerated decay. Copyright © 2007 John Wiley & Sons, Ltd.     

静水条件下砂岩渗透性的试验研究

在TRIAXIAL CELL V3岩石三轴伺服试验机上进行了砂岩的渗透试验,采用流量法测量不同围压和渗透压作用下的砂岩渗透率,揭示了围压和渗透压对砂岩渗透率的影响规律,并给出了围压与渗透率的拟合关系式。结果表明,在相同围压下,随着渗透压差的增加,砂岩渗透率呈不同程度的增加;围压越小,渗透压差对渗透率的影响越大;当渗透压差相同时,砂岩围压一渗透率曲线变化趋势基本一致,渗透率随围压的增加而减小,显示砂岩内部裂隙的闭合程度受围压的影响较明显。     

陇东黄土塬地区中生界石油砂岩储层预测

在鄂尔多斯盆地陇东黄土源地区地震解释中,采用广义S变换地震层序处理解释技术、三叠系顶部古地貌解释技术,以及各种储层横向预测技术,对比分析了应用效果。研究表明,用广义S变换地层层序处理解释技术可识别出约6m的层序界面,进而确认了陇东地区长8段砂体的展布方向,扩大了陇东地区西峰油田的勘探范围。     

基于储层砂岩微观孔隙结构特征的弹性波频散响应分析

储层砂岩微观孔隙结构特征不仅影响干燥岩石的弹性波传播速度,也决定了岩石介质中与流体流动相关的速度频散与衰减作用.依据储层砂岩微观结构特征及速度随有效压力变化的非线性特征,将其孔隙体系理想化为不同形状的硬孔隙(纵横比α0.01)与软孔隙(纵横比α0.01)的组合(双孔隙结构).基于孔弹性理论,给出软孔隙最小初始纵横比值(一定压力下所有未闭合软孔隙在零压力时的纵横比最小值)的解析表达式,并在此基础上利用岩石速度-压力实验观测结果给出求取介质中两类孔隙纵横比及其含量分布特征的方法.通过逐步迭代加入软孔隙的方法对基于特征纵横比的"喷射流"(squirt fluid)模型进行了扩展,以考虑复杂孔隙分布特征对岩石喷射流作用的影响及其可能引起的速度频散特征.相较于典型的喷射流作用速度频散模式,对于岩石中软孔隙纵横比及其对应含量在较宽的范围呈谱分布的一般情况,其速度频散曲线不存在明显的低频段和中间频段,速度随频率的增大呈递增趋势直至高频极限.这说明即使在地震频段,微观尺度下的喷射流作用仍起一定作用,同样会造成流体饱和岩石介质的地震速度与Gassmann方程预测结果有不可忽略的差异.本文是对现有喷射流模型的重要补充,也为利用实验数据建立不同频段间岩石弹性波传播速度的可能联系提供了理论依据.     

古水文地球化学形迹与地浸砂岩铀成矿的关系

本文以水成铀矿床、地质构造学、沉积学、古水文地质学、铀水文地球化学、同位素地质学等学科理论,从分析伊犁盆地南缘铀成矿大地构造背景人手,初步进行了盆地地质构造、地质演化、含矿岩系沉积特征、地下水中同位素（D、^18O、^3H、^234U／^238U、^230Th／^232Th等）和水文地球化学的研究,基本查明了伊犁盆地南缘区域地下水动力条件,研究了区域水文地球化学条件与铀成矿的关系,探讨古地下水演化与铀成矿作用的关系,为全盲型地浸砂岩铀成矿的水文地球化学及古水文地质预测研究提供理论基础。     

Building sandstone surface modification by biofilm and iron precipitation: emerging block‐scale heterogeneity and system response

Stone surfaces are sensitive to their environment. This means that they will often respond to exposure conditions by manifesting a change in surface characteristics. Such changes can be more than simply aesthetic, creating surface/subsurface heterogeneity in stone at the block scale, promoting stress gradients to be set up as surface response to, for example, temperature fluctuations, can diverge from subsurface response. This paper reports preliminary experiments investigating the potential of biofilms and iron precipitation as surface‐modifiers on stone, exploring the idea of block‐scale surface‐to‐depth heterogeneity, and investigating how physical alteration in the surface and near‐surface zone can have implications for subsurface response and potentially for long‐term decay patterns. Salt weathering simulations on fresh and surface‐modified stone suggest that even subtle surface modification can have significant implications for moisture uptake and retention, salt concentration and distribution from surface to depth, over the period of the experimental run. The accumulation of salt may increase the retention of moisture, by modifying vapour pressure differentials and the rate of evaporation. Temperature fluctuation experiments suggest that the presence of a biofilm can have an impact on energy transfer processes that occur at the stone surface (for example, buffering against temperature fluctuation), affecting surface‐to‐depth stress gradients. Ultimately, fresh and surface‐modified blocks mask different kinds of system, which respond to inputs differently because of different storage mechanisms, encouraging divergent behaviour between fresh and surface‐modified stone over time. Copyright © 2014 John Wiley & Sons, Ltd.     

Effects of fluid displacement pattern on complex electrical impedance in Berea sandstone over frequency range 104–106 Hz

To better understand the effect of fluid distribution on the electric response of rocks saturated with oil and brine, we conducted experimental studies on the complex electrical impedance in a Berea sandstone, together with in situ acquisitions of oil distribution images employing a high‐resolution medical X‐ray computed tomography. We performed two tests of brine displacement by oil under high (10 MPa) and low (5 MPa) pressures, which were accompanied by fingering and stable displacement patterns, respectively. The measured complex impedance data were fitted to the Cole model to obtain the resistance, capacitance, peak frequency of the imaginary impedance, and the exponent α of the rock–fluid system. With increasing oil saturation, the resistance showed an increasing trend, whereas the other three parameters decreased. The fingering displacement exhibited lower resistance and capacitance than the stable displacement. The analysis of the resistance changes using a simple parallel connection model indicates that there are more components of residual brine in parallel connections in the fingering pattern than in the stable displacement pattern at the same saturation. We also interpreted the normalised changes in the capacitance (or apparent dielectric constant) with respect to the oil saturation via an analysis of the shape factor of fluid distribution based on the Maxwell–Wagner–Brugermann–Hanai model. The changes in the shape factor suggest that the pinch‐off of the brine in parallel connection by the oil is a dominant mechanism reducing the capacitance. In the stable displacement, most of the connections in the brine phase are immediately pinched off by oil displacement front at a local oil saturation of 65%. Conversely, in the fingering displacement, there is a transition from the bulk or layered brine to the pinched‐off at a local oil saturation below 60%. The analyses indicate that the difference in the fluid distribution under different fluid conditions is responsible for the non‐Archie behaviour.     

Organic carbon inputs,common ions and degassing: rethinking mixing dissolution in coastal eogenetic carbonate aquifers

Caves deliver freshwater from coastal carbonate landscapes to estuaries but how these caves form and grow remains poorly understood. Models suggest fresh and salt water mixing drives dissolution in eogenetic limestone, but have rarely been validated through sampling of mixing waters. Here we assess controls on carbonate mineral saturation states using new and legacy geochemical data that were collected in vertical profiles through three cenotes and one borehole in the Yucatan Peninsula. Results suggest saturation states are primarily controlled by carbon fluxes rather than mixing. Undersaturation predicted by mixing models that rely on idealized end members is diminished or eliminated when end members are collected from above and below actual mixing zones. Undersaturation due to mixing is limited by CO₂ degassing from fresh water in karst windows, which results in calcite supersaturation. With respect to saline groundwater, controls on capacity for mixing dissolution were more varied. Oxidation of organic carbon increased pCO₂ of saline groundwater in caves (pCO₂ = 10^–2.06 to 10^–0.96 atm) relative to matrix porosity (10^–2.39 atm) and local seawater (10^–3.12 atm). The impact of increased pCO₂ on saturation state, however, depended on the geochemical composition of the saline water and the magnitude of organic carbon oxidation. Carbonate undersaturation due to mixing was limited where gypsum dissolution (Cenote Angelita) or sulfate reduction (Cenote Calica) increased concentrations of common ions (Ca²⁺ or HCO₃^?, respectively). Maximum undersaturation was found to occur in mixtures including saline water that had ion concentrations and ratios similar to seawater, but with moderately elevated pCO₂ (Cenote Eden). Undersaturation, however, was dominated by the initial undersaturation of the saline end member, mixing was irrelevant. Our results add to a growing body of literature that suggests oxidation of organic carbon, and not mixing dissolution, is the dominant control on cave formation and enlargement in coastal eogenetic karst aquifers. Copyright © 2016 John Wiley & Sons, Ltd.     

Petrography, diagenesis and provenance of Eocene Tyee Basin sandstones, southern Oregon Coast Range: New view from sequence stratigraphy

Abstract Sandstone petrography considered within a sequence stratigraphic framework provides a better understanding of the characteristics of the Eocene Tyee Basin, an accretionary and forearc sequence, southern Oregon Coast Range. Detailed comparison of the relative abundance of major framework grains documents a marked difference in the sandstone composition of each depositional sequence. Such a difference is mainly due to an abrupt change in provenance, from a local Klamath Mountains metasedimentary source to a more distant extrabasinal Idaho Batholith‐Clarno volcanic arc source. Furthermore, the composition of framework grains varies systematically from the lowstand systems tract to the highstand systems tract within a depositional sequence. This suggests that relative sea level change in the depositional basin, and tectonics in the source area, can affect the patterns of sedimentation and sandstone composition. In addition, the Eocene Tyee Basin sandstones have a down‐section distribution of authigenic minerals, consisting of early formed zeolites and late‐stage quartz, as well as a change in the abundance of smectite to mixed‐layer chlorite/smectite with increasing burial depth. The down‐section distribution of authigenic minerals is also causally linked to the compositional variation of framework grains in each depositional sequence with increasing burial temperature. Much primary porosity has been filled with these authigenic minerals, which diminishes the permeability of potential reservoir rocks. Reservoir‐quality porosities and permeabilities, however, are present locally in the basin. The development of these reservoir‐quality sandstones within the Eocene Tyee Basin sequence is due to a complex burial diagenesis, which is directly related to temporal and spatial variations in original detrital mineralogy, in sedimentation pattern, and in burial temperature in the basin.     

WEATHERING BY WETTING AND DRYING: SOME EXPERIMENTAL RESULTS

A series of experiments on sandstone and dolerite was undertaken in an attempt to better understand the wetting and drying weathering process. As rock samples are frequently subjected to wet–dry cycles within the simulation of other weathering mechanisms (e.g. freeze–thaw), three common methods of moisture application were used and the influences of these evaluated. It was found that the method of moisture application could affect the nature of the weathering products resulting from wetting and drying. It was also observed that there were changes in the internal properties of the rock (e.g. porosity/microporosity) and that these could influence the synergistic operation of other weathering processes. Although not all of the observations could be explained, it is apparent that wetting and drying has both a direct and an indirect effect on the weathering of rock that has not been taken into account in simulations. Greater cognizance needs to be given to the role of this process both in the field and in laboratory simulations.     

Effects of aspect on weathering: anomalous behaviour of sandstone gravestones in southeast England

Rocks in the humid temperate zone tend to weather more severely on faces exposed to the prevailing winds than on their more sheltered leeward faces. In southeast England, however, gravestones composed of a non‐local, quartz‐rich sandstone exhibit a reverse weathering pattern. The east‐facing, lee sides exhibit a much greater depth and areal extent of weathering than the west sides which face the westerly wind and rain. Possible reasons for the asymmetric pattern of weathering are discussed. Copyright © 2000 John Wiley & Sons, Ltd.     

地震岩石物理研究进展

地震岩石物理(Seismic Rock Physics)是研究岩石物理性质与地震响应之间关系的一门学科,旨在通过研究不同温度压力条件下岩性、孔隙度、孔隙流体等对岩石弹性性质的影响,分析地震波传播规律,建立各岩性参数、物性参数与地震速度、密度等弹性参数之间的关系.本文主要论述了半个多世纪以来,国内外地震岩石物理在岩石、流体基础研究、烃类检测等方面取得的主要进展,并分析目前国内岩石物理的研究现状、存在的问题、最新研究动向及展望.