Variation of δ18O, δD and 3H in karst springs of south Kashmir,western Himalayas (India)

Water samples were collected from cold and warm karst springs for stable isotopes (δ¹⁸O and δD) and ³H from SE of Kashmir valley (western Himalayas) to distinguish the sources of recharge and infer their recharge areas. The spring water samples were most depleted in heavier isotopes in May (average δ¹⁸O: ?8.87‰ and δD: ?50.3‰) and enriched in September (average δ¹⁸O: ?7.58‰ and δD: ?48.1‰). The depleted ¹⁸O and ²H of spring waters bear the signatures of winter precipitation while as the enriched ¹⁸O and ²H of spring waters bear the signature of summer rainfall. D‐excess and ³H corroborate with the stable isotope results that the spring flow in spring season (May) and autumn (September) is dominantly controlled by the melting of winter snowmelt and summer rainfall, respectively. The results showed that unlike δD, the δ¹⁸O value in the karst spring waters decreases in January suggesting δ¹⁸O shift. The spring water samples also fall above the Local Meteoric Water Line and Global Meteoric Water Line indicating the δ¹⁸O shift due to interaction of groundwater with the host carbonate rocks during its traverse. The mean elevation of the recharge areas of the springs using δ¹⁸O and δD tracers was also estimated. Copyright © 2014 John Wiley & Sons, Ltd.     

A tale of two isotopes: differences in hydrograph separation for a runoff event when using δD versus δ18O

It is often assumed that stable water isotopes (δD and δ¹⁸O) provide redundant information for a given sample of water. In this note we illustrate that the choice of isotope used may influence the resultant hydrograph separation. This is especially true in light of the spatial and temporal variability in the isotopic composition of rainfall water at the catchment scale. We present several possible hydrograph separations based on both δD and δ¹⁸O observed in rainfall for a single runoff event occurring in the southwest USA. This study demonstrates the potential of using both stable water isotopes by showing that δD and δ¹⁸O may provide unique information for catchment hydrologists. We also report on the utility of new technology capable of simultaneous measurements of both δD and δ¹⁸O using off‐axis integrated cavity output spectroscopy (OA‐ICOS) methods. This may be of interest to catchment hydrologists seeking to incorporate this type of equipment into their laboratory. Copyright © 2009 John Wiley & Sons, Ltd.     

Continuous monitoring of stream δ18O and δ2H and stormflow hydrograph separation using laser spectrometry in an agricultural catchment

A portable Wavelength Scanned‐Cavity Ring‐Down Spectrometer (Picarro L2120) fitted with a diffusion sampler (DS‐CRDS) was used for the first time to continuously measure δ¹⁸O and δ²H of stream water. The experiment took place during a storm event in a wet tropical agricultural catchment in north‐eastern Australia. At a temporal resolution of one minute, the DS‐CRDS measured 2160 δ¹⁸O and δ²H values continuously over a period of 36 h with a precision of ±0.08 and 0.5‰ for δ¹⁸O and δ²H, respectively. Four main advantages in using high temporal resolution stream δ¹⁸O and δ²H data during a storm event are highlighted from this study. First, they enabled us to separate components of the hydrograph, which was not possible using high temporal resolution electrical conductivity data that represented changes in solute transfers during the storm event rather than physical hydrological processes. The results from the hydrograph separation confirm fast groundwater contribution to the stream, with the first 5 h of increases in stream discharge comprising over 70% pre‐event water. Second, the high temporal resolution stream δ¹⁸O and δ²H data allowed us to detect a short‐lived reversal in stream isotopic values (δ¹⁸O increase by 0.4‰ over 9 min), which was observed immediately after the heavy rainfall period. Third, δ¹⁸O values were used to calculate a time lag of 20 min between the physical and chemical stream responses during the storm event. Finally, the hydrograph separation highlights the role of event waters in the runoff transfers of herbicides and nutrients from this heavily cultivated catchment to the Great Barrier Reef. Copyright © 2015 John Wiley & Sons, Ltd.     

Isotopic composition (δ18O and δD) of precipitation and groundwater in a semi‐arid,mountainous area (Guadiana Menor basin,Southeast Spain)

We characterize the precipitation and groundwater in a mountainous (peaks slightly above 3000 m a.s.l.), semi‐arid river basin in SE Spain in terms of the isotopes ¹⁸O and ²H. This basin, with an extension of about 7000 km², is an ideal site for such a study because fronts from the Atlantic and the Mediterranean converge here. Much of the land is farmed and irrigated both by groundwater and runoff water collected in reservoirs. A total of approximately 100 water samples from precipitation and 300 from groundwater have been analysed. To sample precipitation we set up a network of 39 stations at different altitudes (800–1700 m a.s.l.), with which we were able to collect the rain and snowfall from 29 separate events between July 2005 and April 2007 and take monthly samples during the periods of maximum recharge of the aquifers. To characterize the groundwater we set up a control network of 43 points (23 springs and 20 wells) to sample every 3 months the main aquifers and both the thermal and non‐thermal groundwater. We also sampled two shallow‐water sites (a reservoir and a river). The isotope composition of the precipitation forms a local meteoric water line (LMWL) characterized by the equation δD = 7·72δ¹⁸O + 9·90, with mean values for δ¹⁸O and δD of − 10·28‰ and − 69·33‰, respectively, and 12·9‰ for the d‐excess value. To correlate the isotope composition of the rainfall water with groundwater we calculated the weighted local meteoric water line (WLMWL), characterized by the equation δD = 7·40δ¹⁸O + 7·24, which takes into account the quantity of water precipitated during each event. These values of (dδD/dδ¹⁸O)< 8 and d‐excess (δD–8δ¹⁸O)< 10 in each curve bear witness to the ‘amount effect’, an effect which is more manifest between May and September, when the ground temperature is higher. Other effects noted in the basin were those of altitude and the continental influence. The isotopic compositions of the groundwater are represented by the equation δD = 4·79δ¹⁸O − 18·64. The groundwater is richer in heavy isotopes than the rainfall, with mean values of − 8·48‰ for δ¹⁸O and − 59·27‰ for δD. The isotope enrichment processes detected include a higher rate of evaporation from detrital aquifers than from carbonate ones, the effects of recharging aquifers from irrigation return flow and/or from reservoirs' leakage and enrichment in δ¹⁸O from thermal water. Copyright © 2010 John Wiley & Sons, Ltd.     

Local vs. Regional Groundwater Flow Delineation from Stable Isotopes at Western North America Springs

The recharge location for many springs is unknown because they can be sourced from proximal, shallow, atmospheric sources or long‐traveled, deep, regional aquifers. The stable isotope (¹⁸O and ²H) geochemistry of springs water can provide cost‐effective indications of relative flow path distance without the expense of drilling boreholes, conducting geophysical studies, or building groundwater flow models. Locally sourced springs generally have an isotopic signature similar to local precipitation for that region and elevation. Springs with a very different isotopic composition than local meteoric inputs likely have non‐local recharge, representing a regional source. We tested this local vs. regional flow derived hypothesis with data from a new, large springs isotopic database from studies across Western North America in Arizona, Nevada, and Alberta. The combination of location‐specific precipitation data with stable isotopic groundwater data provides an effective method for flow path determination at springs. We found springs in Arizona issue from a mix of regional and local recharge sources. These springs have a weak elevation trend across 1588 m of elevation where higher elevation springs are only slightly more depleted than low elevation springs with a δ¹⁸O variation of 5.9‰. Springs sampled in Nevada showed a strong elevation‐isotope relationship with high‐elevation sites discharging depleted waters and lower elevation springs issuing enriched waters; only a 2.6‰ difference exists in ¹⁸O values over an elevation range of more than 1500 m. Alberta's springs are mostly sourced from local flow systems and show a moderate elevation trend of 1200 m, but the largest range in δ¹⁸O, 7.1‰.     

Spatial and temporal variability of stable isotopes (δ18O and δ2H) in surface waters of arid,mountainous Central Asia

Characterization of spatial and temporal variability of stable isotopes (δ¹⁸O and δ²H) of surface waters is essential to interpret hydrological processes and establish modern isotope–elevation gradients across mountainous terrains. Here, we present stable isotope data for river waters across Kyrgyzstan. River water isotopes exhibit substantial spatial heterogeneity among different watersheds in Kyrgyzstan. Higher river water isotope values were found mainly in the Issyk‐Kul Lake watershed, whereas waters in the Son‐Kul Lake watershed display lower values. Results show a close δ¹⁸O–δ²H relation between river water and the local meteoric water line, implying that river water experiences little evaporative enrichment. River water from the high‐elevation regions (e.g., Naryn and Son‐Kul Lake watershed) had the most negative isotope values, implying that river water is dominated by snowmelt. Higher deuterium excess (average d = 13.9‰) in river water probably represents the isotopic signature of combined contributions from direct precipitation and glacier melt in stream discharge across Kyrgyzstan. A significant relationship between river water δ¹⁸O and elevation was observed with a vertical lapse rate of 0.13‰/100 m. These findings provide crucial information about hydrological processes across Kyrgyzstan and contribute to a better understanding of the paleoclimate/elevation reconstruction of this region.     

Environmental isotopes and hydrochemical study applied to surface water and groundwater interaction in the Awash River basin

An environmental isotope and hydrochemical study was carried out to conceptualize the surface water and groundwater interaction and to explore the groundwater flow pattern in relation to the geological setting. More emphasis is given to the Afar Depression where groundwater is a vital source of water supply. Conventional field hydrogeological study and river discharge records support the isotope and hydrochemical analysis. The region is tectonically active, comprising rift volcanic terrain bordered by highlands. The result revealed that recent meteoric water is the major source of recharge. Three distinct groundwater zones were identified associated with the highlands, transitional escarpment and the rift. Towards the rift, the ionic concentration and isotopic enrichment (δ²H and δ^18degO) increases following the groundwater flow paths, which is strongly controlled by axial rift faults. The groundwater flow converges to the seismically active volcano–tectonic depressions with internal drainage and to the Awash River. Within the Afar Depression, at least four groundwater regimen are identified: (1) fresh and shallow groundwater associated with alluvial deposits ultimately recharged by isotopically depleted recent highland rainfall and the evaporated Awash River; (2) cold and relatively younger groundwater within localized fractured volcanics showing mixed origin in axial fault zones; (3) old groundwater with very high ionic concentration and low isotopic signature localized in deep volcanic aquifers; and (4) old and hot saline groundwaters connected to geothermal systems. The study demonstrated that dependable groundwater can only be obtained from the first two aquifer types in aerially restricted zones in flat plains following river courses, local wadis and volcano–tectonic depressions. The conventional hydrogeological survey and discharge records indicate substantial channel losses from the Awash River, which becomes a more dominant source of recharge in central and lower Awash valleys. Copyright © 2007 John Wiley & Sons, Ltd.     

Estimating groundwater recharge from water isotope (δ2H, δ18O) depth profiles in the Densu River basin,Ghana

Abstract

Accurate estimation of groundwater recharge is essential for the proper management of aquifers. A study of water isotope (δ²H, δ¹⁸O) depth profiles was carried out to estimate groundwater recharge in the Densu River basin in Ghana, at three chosen observation sites that differ in their altitude, geology, climate and vegetation. Water isotopes and water contents were analysed with depth to determine water flow in the unsaturated zone. The measured data showed isotope enrichment in the pore water near the soil surface due to evaporation. Seasonal variations in the isotope signal of the pore water were also observed to a depth of 2.75 m. Below that depth, the seasonal variation of the isotope signal was attenuated due to diffusion/dispersion and low water flow velocities. Groundwater recharge rates were determined by numerical modelling of the unsaturated water flow and water isotope transport. Different groundwater recharge rates were computed at the three observation sites and were found to vary between 94 and 182 mm/year (± max. 7%). Further, the approximate peak-shift method was applied to give information about groundwater recharge rates. Although this simple method neglects variations in flow conditions and only considers advective transport, it yielded mean groundwater recharge rates of 110–250 mm/year (± max. 30%), which were in the same order of magnitude as computed numerical modelling values. Integrating these site-specific groundwater recharge rates to the whole catchment indicates that more water is potentially renewed than consumed nowadays. With increases in population and irrigation, more clean water is required, and knowledge about groundwater recharge rates – essential for improving the groundwater management in the Densu River basin – can be easily obtained by measuring water isotope depth profiles and applying a simple peak-shift approach.

Citation Adomako, D., Maloszewski, P., Stumpp, C., Osae, S. & Akiti, T. T. (2010) Estimating groundwater recharge from water isotope (δ²H, δ¹⁸O) depth profiles in the Densu River basin, Ghana. Hydrol. Sci. J. 55(8), 1405–1416.     

Groundwater evolution and mean water age inferred from hydrochemical and isotopic tracers in a tropical confined aquifer

The coastal confined aquifer in the Gulf of Urabá (Colombia) is an important water source for the banana agro‐industry as well as for urban and rural communities. However, the main processes controlling recharge and mixing in the aquifer are still poorly understood. Hydrochemical analyses and stable isotope monitoring were conducted to (a) determine groundwater recharge origin, mean groundwater age, and the main processes governing groundwater chemistry and the potential mixing of marine water and the influence of diffusive processes from the two surrounding aquitard layers. Hydrochemical data indicate that the main processes affecting the dissolved chemical composition include cation exchange, dissolution of carbonated and CO₂, and silicate weathering. δ¹⁸O and δ²H compositions combined with ¹⁴C data highlight the differences in climatic conditions between the recharge zone and the confined section of the aquifer, which is close to the Atlantic Ocean. Groundwater samples with ¹⁴C ages from recent to 28,300 years BP show a depleted isotopic trend ranging from ?6.43‰ to ?9.14‰ in δ¹⁸O and from ?43.2‰ to ?65.7‰ in δ²H. The most depleted δ¹⁸O and δ²H compositions suggest a cooler recharge climate than the current conditions (corresponding to the last glacial period of the late Pleistocene). Depleted δ¹³C values in the total dissolved inorganic carbon indicate the existence of organic material oxidation processes within the geologic formation. These results can be used or transferred to enhance groundwater modelling efforts in other confined coastal aquifers of South America where scarcity of long‐term monitoring data limits water resources planification under a changing climate.     

Characterizing spatial and temporal variation in 18O and 2H content of New Zealand river water for better understanding of hydrologic processes

Time series of hydrogen and oxygen stable isotope ratios (δ²H and δ¹⁸O) in rivers can be used to quantify groundwater contributions to streamflow, and timescales of catchment storage. However, these isotope hydrology techniques rely on distinct spatial or temporal patterns of δ²H and δ¹⁸O within the hydrologic cycle. In New Zealand, lack of understanding of spatial and temporal patterns of δ²H and δ¹⁸O of river water hinders development of regional and national-scale hydrological models. We measured δ²H and δ¹⁸O monthly, together with river flow rates at 58 locations across New Zealand over a two-year period. Results show: (a) general patterns of decreasing δ²H and δ¹⁸O with increasing latitude were altered by New Zealand's major mountain ranges; δ²H and δ¹⁸O were distinctly lower in rivers fed from higher elevation catchments, and in eastern rain-shadow areas of both islands; (b) river water δ²H and δ¹⁸O values were partly controlled by local catchment characteristics (catchment slope, PET, catchment elevation, and upstream lake area) that influence evaporation processes; (c) regional differences in evaporation caused the slope of the river water line (i.e., the relationship between δ²H and δ¹⁸O in river water) for the (warmer) North Island to be lower than that of the (cooler, mountain-dominated) South Island; (d) δ²H seasonal offsets (i.e., the difference between seasonal peak and mean values) for individual sites ranged from 0.50‰ to 5.07‰. Peak values of δ¹⁸O and δ²H were in late summer, but values peaked 1 month later at the South Island sites, likely due to greater snow-melt contributions to streamflow. Strong spatial differences in river water δ²H and δ¹⁸O caused by orographic rainfall effects and evaporation may inform studies of water mixing across landscapes. Generally distinct seasonal isotope cycles, despite the large catchment sizes of rivers studied, are encouraging for transit time analysis applications.     

Tracer hydrology of the data-scarce and heterogeneous Central American Isthmus

Numerous socio-economic activities depend on the seasonal rainfall and groundwater recharge cycle across the Central American Isthmus. Population growth and unregulated land use changes resulted in extensive surface water pollution and a large dependency on groundwater resources. This work combines stable isotope variations in rainfall, surface water, and groundwater of Costa Rica, Nicaragua, El Salvador, and Honduras to develop a regionalized rainfall isoscape, isotopic lapse rates, spatial–temporal isotopic variations, and air mass back trajectories determining potential mean recharge elevations, moisture circulation patterns, and surface water–groundwater interactions. Intra-seasonal rainfall modes resulted in two isotopically depleted incursions (W-shaped isotopic pattern) during the wet season and two enriched pulses during the mid-summer drought and the months of the strongest trade winds. Notable isotopic sub-cloud fractionation and near-surface secondary evaporation were identified as common denominators within the Central American Dry Corridor. Groundwater and surface water isotope ratios depicted the strong orographic separation into the Caribbean and Pacific domains, mainly induced by the governing moisture transport from the Caribbean Sea, complex rainfall producing systems across the N-S mountain range, and the subsequent mixing with local evapotranspiration, and, to a lesser degree, the eastern Pacific Ocean fluxes. Groundwater recharge was characterized by (a) depleted recharge in highland areas (72.3%), (b) rapid recharge via preferential flow paths (13.1%), and enriched recharge due to near-surface secondary fractionation (14.6%). Median recharge elevation ranged from 1,104 to 1,979 m a.s.l. These results are intended to enhance forest conservation practices, inform water protection regulations, and facilitate water security and sustainability planning in the Central American Isthmus.     

Isotope hydrology of the Allt a' Mharcaidh catchment,Cairngorms, Scotland: implications for hydrological pathways and residence times

The hydrology of oxygen‐18 (¹⁸O) isotopes was monitored between 1995 and 1998 in the Allt a' Mharcaidh catchment in the Cairngorm Mountains, Scotland. Precipitation (mean δ¹⁸O=−7·69‰) exhibited strong seasonal variation in δ¹⁸O values over the study period, ranging from −2·47‰ in the summer to −20·93‰ in the winter months. As expected, such variation was substantially damped in stream waters, which had a mean and range of δ¹⁸O of −9·56‰ and −8·45 to −10·44‰, respectively. Despite this, oxygen‐18 proved a useful tracer and streamwater δ¹⁸O variations could be explained in terms of a two‐component mixing model, involving a seasonally variable δ¹⁸O signature in storm runoff, mixing with groundwater characterized by relatively stable δ¹⁸O levels. Variations in soil water δ¹⁸O implied the routing of depleted spring snowmelt and enriched summer rainfall into streamwaters, probably by near‐surface hydrological pathways in peaty soils. The relatively stable isotope composition of baseflows is consistent with effective mixing processes in shallow aquifers at the catchment scale. Examination of the seasonal variation in δ¹⁸O levels in various catchment waters provided a first approximation of mean residence times in the major hydrological stores. Preliminary estimates are 0·2–0·8 years for near‐surface soil water that contributes to storm runoff and 2 and >5 years for shallow and deeper groundwater, respectively. These ¹⁸O data sets provide further evidence that the influence of groundwater on the hydrology and hydrochemistry of upland catchments has been underestimated. Copyright © 2000 John Wiley & Sons, Ltd.     

Recharge and mineralization of groundwater of the Upper Cretaceous aquifer in Orontes basin,Syria

Abstract

Chemical and isotopic data of groundwater of the Upper Cretaceous aquifer in the Orontes basin, Syria, have been used to assess the groundwater geochemistry, the origin of groundwater recharge and groundwater residence time. The chemical data indicate that dissolution of evaporite minerals is the main process controlling groundwater mineralization. The composition of stable isotopes δ¹⁸O and δ²H, together with ¹⁴C activity, reflect the existence of three different groups: (a) groundwater in the Coastal Mountains with δ¹⁸O of –6.65‰, quite similar to modern-day precipitation, and high ¹⁴C (>50 pmC); (b) groundwater in the unconfined aquifer of the Hama Uplift, which has δ¹⁸O of –5.52‰ and ¹⁴C near 20 pmC, and is recharged locally; and (c) groundwater from the confined aquifer of the Homs Depression, which is characterized by more depleted δ¹⁸O,, –8.01‰, and low ¹⁴C (<7 pmC), and might be recharged in the northern piedmont of the Anti-Lebanon Mountains. The distinctive isotope signatures of the latter two groups indicate different recharge elevations and palaeoclimatic effects. The low recharge rate of the groundwater in the Hama Uplift aquifer, and the even slower recharge rate in the Homs Depression aquifer, are reflected by groundwater ¹⁴C residence times of 5 and over 22 Ka BP, respectively.

Editor D. Koutsoyiannis

Citation Al-Charideh, A., 2013. Recharge and mineralization of groundwater of the Upper Cretaceous aquifer in Orontes basin (Syria). Hydrological Sciences Journal, 58 (2), 452–467.     

Temporal and spatial variation of water stable isotopes (18O and 2H) in the Kaidu River basin,Northwestern China

Water resources are the most critical factors to ecology and society in arid basins, such as Kaidu River basin. Isotope technique was convenient to trace this process and reveal the influence from the environment. In this paper, we try to investigate the temporal and spatial characteristics in stable isotope (¹⁸O and ²H) of surface water and groundwater in Kaidu River. Through the water stable isotope composition measurement, spatial and temporal characteristics of deuterium (δ²H) and oxygen 18 (δ¹⁸O) were analysed. It is revealed that (1) comparing the stream water line with the groundwater line and local meteorological water line of Urumqi City, it is found that the contribution of precipitation to surface water in stream runoff is the main source, whereas the surface water is the main source of groundwater. Groundwater is mainly drainage of surface runoff in the river; (2) in the main stream of Kaidu River, the spatial variability of river water showed a ‘heavier‐lighter‐heavier’ change along with the main stream for δ¹⁸O, and temporal variability showed higher in summer and lower in winter; (3) the δ¹⁸O and δ²H values of groundwater samples ranged from ?11.36 to ?7.97‰ and ?73.45 to ?60.05‰, respectively. There is an increasing trend of isotopic values along the groundwater flow path. The seasonal fluctuation of δ¹⁸O is not clear in most samples. Copyright © 2012 John Wiley & Sons, Ltd.     

Characterization of surface and ground water δ18O seasonal variation and its use for estimating groundwater residence times

¹⁸O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. ¹⁸O variations (δ¹⁸O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well‐instrumented research catchment in north‐central Minnesota. SRHA surface waters exhibit δ¹⁸O seasonal variations similar to those of groundwaters, and seasonal δ¹⁸O variations plotted versus time fit seasonal sine functions. These seasonal δ¹⁸O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed‐basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km² from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ¹⁸O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ¹⁸O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments. Copyright © 2005 John Wiley & Sons, Ltd.     

Seasonal connections between meteoric water and streamflow generation along a mountain headwater stream

In snowmelt-driven mountain watersheds, the hydrologic connectivity between meteoric waters and stream flow generation varies strongly with the season, reflecting variable connection to soil and groundwater storage within the watershed. This variable connectivity regulates how streamflow generation mechanisms transform the seasonal and elevational variation in oxygen and hydrogen isotopic composition (δ¹⁸O and δD) of meteoric precipitation. Thus, water isotopes in stream flow can signal immediate connectivity or more prolonged mixing, especially in high-relief mountainous catchments. We characterized δ¹⁸O and δD values in stream water along an elevational gradient in a mountain headwater catchment in southwestern Montana. Stream water isotopic compositions related most strongly to elevation between February and March, exhibiting higher δ¹⁸O and δD values with decreasing elevation. These elevational isotopic lapse rates likely reflect increased connection between stream flow and proximal snow-derived water sources heavily subject to elevational isotopic effects. These patterns disappeared during summer sampling, when consistently lower δ¹⁸O and δD values of stream water reflected contributions from snowmelt or colder rainfall, despite much higher δ¹⁸O and δD values expected in warmer seasonal rainfall. The consistently low isotopic values and absence of a trend with elevation during summer suggest lower connectivity between summer precipitation and stream flow generation as a consequence of drier soils and greater transpiration. As further evidence of intermittent seasonal connectivity between the stream and adjacent groundwaters, we observed a late-winter flush of nitrate into the stream at higher elevations, consistent with increased connection to accumulating mineralized nitrogen in riparian wetlands. This pattern was distinct from mid-summer patterns of nitrate loading at lower elevations that suggested heightened human recreational activity along the stream corridor. These observations provide insights linking stream flow generation and seasonal water storage in high elevation mountainous watersheds. Greater understanding of the connections between surface water, soil water and groundwater in these environments will help predict how the quality and quantity of mountain runoff will respond to changing climate and allow better informed water management decisions.     

Determination of groundwater discharge rates and water residence time of groundwater‐fed lakes by stable isotopes of water (18O, 2H) and radon (222Rn) mass balances

Lacustrine groundwater discharge (LGD) and the related water residence time are crucial parameters for quantifying lake matter budgets and assessing its vulnerability to contaminant input. Our approach utilizes the stable isotopes of water (δ¹⁸O, δ²H) and the radioisotope radon (²²²Rn) for determining long‐term average and short‐term snapshots in LGD. We conducted isotope balances for the 0.5‐km² Lake Ammelshainer See (Germany) based on measurements of lake isotope inventories and groundwater composition accompanied by good quality and comprehensive long‐term meteorological and isotopic data (precipitation) from nearby monitoring stations. The results from the steady‐state annual isotope balances that rely on only two sampling campaigns are consistent for both δ¹⁸O and δ²H and suggested an overall long‐term average LGD rate that was used to infer the water residence time of the lake. These findings were supported by the good agreement of the simulated LGD‐driven annual cycles of δ¹⁸O and δ²H lake inventories with the observed lake isotope inventories. However, radon mass balances revealed lower values that might be the result of seasonal LGD variability. For obtaining further insights into possible seasonal variability of groundwater–lake interaction, stable water isotope and radon mass balances could be conducted more frequently (e.g., monthly) in order to use the derived groundwater discharge rates as input for time‐variant isotope balances.     

Groundwater and surface water connectivity within the recharge area of Guarani aquifer system during El Niño 2014–2016

Recharge areas of the Guarani Aquifer System (GAS) are particularly sensitive and vulnerable to climate variability; therefore, the understanding of infiltration mechanisms for aquifer recharge and surface run‐off generation represent a relevant issue for water resources management in the southeastern portion of the Brazilian territory, particularly in the Jacaré‐Pepira River watershed. The main purpose of this study is to understand the interactions between precipitation, surface water, and groundwater using stable isotopes during the strong 2014–2016 El Niño Southern Oscillation event. The large variation in the isotopic composition of precipitation (from ?9.26‰ to +0.02‰ for δ¹⁸O and from ?63.3‰ to +17.6‰ for δ²H), mainly associated with regional climatic features, was not reflected in the isotopic composition of surface water (from ?7.84‰ to ?5.83‰ for δ¹⁸O and from ?49.7‰ to +33.6‰ for δ²H), mainly due to the monthly sampling frequency, and groundwater (from ?7.04‰ to ?7.76‰ for δ¹⁸O and from ?49.5‰ to ?44.7‰ for δ²H), which exhibited less variation throughout the year. However, variations in deuterium excess (d‐excess) in groundwater and surface water suggest the occurrence of strong secondary evaporation during the infiltration process, corresponding with groundwater level recovery. Similar isotopic composition in groundwater and surface water, as well as the same temporal variations in d‐excess and line‐conditioned excess denote the strong connectivity between these two reservoirs during baseflow recession periods. Isotopic mass balance modelling and hydrograph separation estimate that the groundwater contribution varied between 70% and 80%, however, during peak flows, the isotopic mass balance tends to overestimate the groundwater contribution when compared with the other hydrograph separation methods. Our findings indicate that the application of isotopic mass balance methods for ungauged rivers draining large groundwater reservoirs, such as the GAS outcrop, could provide a powerful tool for hydrological studies in the future, helping in the identification of flow contributions to river discharge draining these areas.     

A Geochemical Approach to Determine Sources and Movement of Saline Groundwater in a Coastal Aquifer

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major‐ions, the chemical composition is classified as Na‐Ca‐Cl‐SO₄, Na‐Cl, or Na‐Ca‐Cl type water. δ²H and δ¹⁸O values range from ?47.7‰ to ?12.8‰ and from ?7.0‰ to ?1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. ⁸⁷Sr/⁸⁶Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. ³H and ¹⁴C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher‐elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest‐to‐southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers.     

Improved understanding of spring and stream water responses in headwaters of the Indian Lesser Himalaya using stable isotopes,conductivity and temperature as tracers

Stable isotope data are presented for precipitation, spring and stream water in a headwater catchments in the Indian Lesser Himalaya. Isotopic contents of phreatic groundwater followed the local meteoric water line and showed minimal alteration by evaporation, suggesting fast recharge. Mean isotopic values for springs and the stream were close to the weighted annual mean for precipitation, indicating recharge was in synchrony with seasonal rainfall distribution. Precipitation exhibited isotopic declines of ?0.6‰ and ?0.2‰ δ¹⁸O per 100 m rise in elevation in July and August (monsoon), respectively. The time lag of one month between rainfall and spring discharge, combined with the isotopic lapse rate indicated a recharge elevation of 70–165 m above the spring outflow point, implying the water originated within the catchment. Time series of electrical conductivity and temperature of spring, seepage and stream waters confirmed the rapid recharge and limited storage capacity of the shallow aquifers.