Estimation of mean water transit time on a steep hillslope in South Korea using soil moisture measurements and deuterium excess

A method for estimating daily mean transit time (DMTT) within a soil layer was proposed using field measurements of soil moisture. Vertical profiles of soil moisture time series were used for storage estimation. Water fluxes were evaluated through matrix and bypass flow. Variations in soil moisture and soil thickness were used to evaluate matrix flow. Exponential decay in depth of macropores was also used for bypass flow approximation. DMTT evaluation was compared to results obtained from a stable water isotope model using two years of data acquired on a steep granite hillslope in the Sulmachun watershed, South Korea. Various uncertainties in transit time evaluation such as model structure, non‐stationary assumption and data acquisition of existing approaches can be accounted for in the proposed methodology, and the flowpath contribution can be further configured in conjunction with hydrometric measurements. Probability density functions of isotope analyses were partially explained by transit time distributions that were based on soil moisture measurements. Supplementary sensitivity analyses for uncertainty configurations indicate that matrix flow is the primary process in determining transit time distribution while the impact of bypass flow is minor. The feasibility of a DMTT approach over isotope‐based methodologies highlights not only the strength of this proposed method, both in cost and time, but also its further application potential for existing soil moisture measurements. Copyright © 2013 John Wiley & Sons, Ltd.     

Effects of hillslope topography on runoff response in a small catchment in the Fudoji Experimental Watershed,central Japan

We investigated the role of different hillslope units with different topographic characteristics on runoff generation processes based on field observations at two types of hillslopes (0·1 ha): a valley‐head (a convergent hillslope) and a side slope (a planar hillslope), as well as at three small catchments having two types of slopes with different drainage areas ranging from 1·9 to 49·7 ha in the Tanakami Mountains, central Japan. We found that the contribution of the hillslope unit type to small catchment runoff varied with the magnitude of rainfall. When the total amount of rainfall for a single storm event was < 35 mm, runoff in the small catchment was predominantly generated from the side slope. As the amount of rainfall increased (>35 mm), the valley‐head also began to contribute to the catchment runoff, adding to runoff from the side slope. Although the direct runoff from the valley‐head was greater than that from the side slope, the contribution from the side slope was quantitatively greater than that from the valley‐head due to the proportionally larger area occupied by the side slope in the small catchment. The storm runoff responses of the small catchments reflected the change in the runoff components of each hillslope unit as the amount of rainfall increased and rainfall patterns changed. However, similar runoff responses were found for the small catchments with different areas. The similarity of the runoff responses is attributable to overlay effects of different hillslope units and the similar composition ratios of the valley‐head and side slope in the catchments. This study suggests that the relative roles of the valley‐head and side slope are important in runoff generation and solute transport as the catchment size increases from a hillslope/headwater to a small catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Hillslope‐swamp interactions and flow pathways in a hypermaritime rainforest,British Columbia

The process of water delivery to a headwater stream in a hypermaritime rainforest was examined using a variety of physical techniques and tracing with dissolved organic carbon (DOC) and the stable isotopes of water. Headwater swamps, often the major discharge zones for water draining off steep forest slopes, strongly affect the physical and chemical character of streamflow in the region. The headwater swamp selected for detailed investigation was sustained by relatively constant groundwater input from the steep colluvial slopes that maintained the water table above the ground surface. During significant storm events the water table rose quickly and the swamp expanded to engulf marginal pools that developed rapidly on the adjacent ground surfaces. The corresponding release of surface water directly to the stream typically comprised up to 95% of total stream discharge. The proportion of groundwater seepage to the stream by matrix flow (<1%) and via macropore‐fed springs (up to 73%) increased during the recession period, but could not be sustained over the longer term. In more protracted drying periods, deep groundwater contributions to the stream were routed first to the headwater swamp. Dissolved organic carbon (DOC) in the stream, measured daily or more frequently during storm events, was found to be directly proportional to discharge, owing to the domination of DOC‐rich headwater‐swamp water sources. Although δ¹⁸O and δ²H composition of rainwater, groundwater and stream flow were found to be similar, deuterium excess (d ? δ²H ? 8δ¹⁸O) of water components was often found to be distinct, and suggested short water residence times of roughly 12 days for one event. Overall, observations of a typical headwater swamp reveal that the groundwater regime is dominated by rapid infiltration and short, emergent flow paths. With a relatively short turnover time, potential disturbances to the system by harvesting of upslope areas can be expected to occur rapidly. Forest managers can mitigate some of the harmful effects of logging operations by respecting the integrity of headwater wetland systems. The nature and magnitude of such perturbations will require further study. Copyright © 2003 John Wiley & Sons, Ltd.     

Characterization of surface and ground water δ18O seasonal variation and its use for estimating groundwater residence times

¹⁸O is an ideal tracer for characterizing hydrological processes because it can be reliably measured in several watershed hydrological compartments. Here, we present multiyear isotopic data, i.e. ¹⁸O variations (δ¹⁸O), for precipitation inputs, surface water and groundwater in the Shingobee River Headwaters Area (SRHA), a well‐instrumented research catchment in north‐central Minnesota. SRHA surface waters exhibit δ¹⁸O seasonal variations similar to those of groundwaters, and seasonal δ¹⁸O variations plotted versus time fit seasonal sine functions. These seasonal δ¹⁸O variations were interpreted to estimate surface water and groundwater mean residence times (MRTs) at sampling locations near topographically closed‐basin lakes. MRT variations of about 1 to 16 years have been estimated over an area covering about 9 km² from the basin boundary to the most downgradient well. Estimated MRT error (±0·3 to ±0·7 years) is small for short MRTs and is much larger (±10 years) for a well with an MRT (16 years) near the limit of the method. Groundwater transit time estimates based on Darcy's law, tritium content, and the seasonal δ¹⁸O amplitude approach appear to be consistent within the limits of each method. The results from this study suggest that use of the δ¹⁸O seasonal variation method to determine MRTs can help assess groundwater recharge areas in small headwaters catchments. Copyright © 2005 John Wiley & Sons, Ltd.     

Suspended sediment discharge in subsurface flow from the head hollow of a small forested watershed,northern Japan

Surface flow and suspended sediment discharge from the head hollow of the Jozankei Experimental Watershed in Hokkaido, northern Japan, were measured to clarify the implications of subsurface hydrology for soil movement. Subsurface discharges during the extremely large storms of 1993 to 1994 were measured in a V-notch weir installed at a natural spring near the bottom of the head hollow, and shallow groundwater levels were observed in the wells excavated in the hollow. Sediment samples whose particle size range from 0·001 to 0·1 mm were manually and automatically collected at 15 to 60 min intervals, by use of 1 or 21 polyethylene bottles. Maximum concentration and flux of suspended sediment during the storms preceded the peak discharge of subsurface flow by several hours. Neither the changes in concentration (mg l⁻¹) nor flux (mg s⁻¹) of suspended sediment coincided with those in subsurface discharge (l s⁻¹). Furthermore, sediment concentration was poorly correlated with the rate of change in subsurface discharge (l s⁻²) during the rising limb of the hydrograph. Suspended sediment flux during the acceleratory limb, however, was closely correlated with the rate of change in subsurface discharge. The relationship between suspended sediment flux and rate of change in subsurface discharge were in inverse proportion to initial subsurface discharge before the storm runoff and they represented rare seasonal variation. Subsurface hydraulic erosion and transport of suspended sediment resulting from changes in rate of change in subsurface discharge actively occur during the acceleratory rising limb of the hydrograph. Accordingly, subsurface hydraulic erosion during the acceleratory rising limb of the hydrograph can be physically understood by analysing suspended sediment flux associated with rate of change in subsurface discharge and initial subsurface discharge. © 1997 John Wiley & Sons, Ltd.     

Hydrological control of dissolved organic carbon dynamics in a forested headwater catchment,Kiryu Experimental Watershed,Japan

To evaluate the influence of hydrological processes on dissolved organic carbon (DOC) dynamics in a forested headwater catchment, DOC concentration was observed along the flow path from rainfall to stream water via throughfall, soil water, groundwater, and spring water for 4 years, and DOC flux through the catchment was calculated. The spatial and temporal variations in DOC concentration and flux were compared with physical hydrological observations and the mean residence time of water. In the upslope soil layer, DOC concentrations were not significantly correlated with water fluxes, suggesting that DOC concentrations were not strictly controlled by water fluxes. In the upslope perennial groundwater, DOC concentration was affected by the change in the amount of microbial degradation of DOC produced by changes in the mean residence time of water. In stream water, the temporal variation in DOC concentration was usually affected by changes in DOC concentration of the inflow component via vertical infiltration from above the perennial groundwater. During dry periods, however, the component from inflow via vertical infiltration was negligible and DOC in the upslope perennial groundwater became the major component of stream water DOC. The temporal variation in stream water DOC concentration during baseflow was affected by rainfall patterns over several preceding months. Therefore, records of rainfall over several preceding months are one of the most important factors for predicting changes in DOC concentration on a catchment scale. Copyright © 2007 John Wiley & Sons, Ltd.     

A seasonal effect in diurnal variation of the atmospheric electric field on the Pacific coast of Japan

The measurement of the atmospheric electric field was carried out with a field mill at a small island in a bay on the Pacific coast of Japan. The data obtained during 80 months from 1971 to 1977 were analysed. It was found that characteristically the diurnal variation regularly alters with the seasons. Whereas the electric field in winter has the same diurnal pattern as that observed at globally representative stations, it exhibits in summer a pattern depending on the variation of the local electric conductivity. The alteration is inferred to be associated with regional atmospheric conditions surrounding the observation site.     

Determination of groundwater discharge rates and water residence time of groundwater‐fed lakes by stable isotopes of water (18O, 2H) and radon (222Rn) mass balances

Lacustrine groundwater discharge (LGD) and the related water residence time are crucial parameters for quantifying lake matter budgets and assessing its vulnerability to contaminant input. Our approach utilizes the stable isotopes of water (δ¹⁸O, δ²H) and the radioisotope radon (²²²Rn) for determining long‐term average and short‐term snapshots in LGD. We conducted isotope balances for the 0.5‐km² Lake Ammelshainer See (Germany) based on measurements of lake isotope inventories and groundwater composition accompanied by good quality and comprehensive long‐term meteorological and isotopic data (precipitation) from nearby monitoring stations. The results from the steady‐state annual isotope balances that rely on only two sampling campaigns are consistent for both δ¹⁸O and δ²H and suggested an overall long‐term average LGD rate that was used to infer the water residence time of the lake. These findings were supported by the good agreement of the simulated LGD‐driven annual cycles of δ¹⁸O and δ²H lake inventories with the observed lake isotope inventories. However, radon mass balances revealed lower values that might be the result of seasonal LGD variability. For obtaining further insights into possible seasonal variability of groundwater–lake interaction, stable water isotope and radon mass balances could be conducted more frequently (e.g., monthly) in order to use the derived groundwater discharge rates as input for time‐variant isotope balances.     

新疆艾比湖主要入湖河流同位素及水化学特征的季节变化

通过野外调查取样和室内测试分析,利用水文化学以及氢氧稳定同位素技术,分析艾比湖主要入湖河流氢氧同位素及水化学的组成特征,并探讨其季节性变化.结果表明：地表水水质指标高值多出现于博乐市、温泉市和精河县及艾比湖湿地附近,主要污染为水体富营养化、工矿业污染以及有机质污染,其污染程度夏、秋季高于春、冬季.河水的δ¹⁸O与δ²H存在明显的线性关系,其相关指数为夏季（R²=0.99） > 春季（R²=0.98） > 秋季（R²=0.96） > 冬季（R²=0.90）,均沿当地大气降水线分布,受西北干旱区强烈的蒸发作用影响,各季节河流斜率均小于8,氘过量参数值多为正值.博尔塔拉河与精河地表水体δ¹⁸O值整体上表现为沿流程逐渐偏正的趋势,博尔塔拉河水体氢氧同位素与高程相关指数表现为春季（R²=0.70） > 冬季（R²=0.57） > 夏季（R²=0.45） > 秋季（R²=0.30）,精河因其海拔差异不大,流程简短,与高程相关性低.博尔塔拉河和精河氢氧同位素与氯化物、硫酸盐、五日生物需氧量等指标间存在相关性,且在夏、秋季最大,相关系数R>0.75,与总磷、Cu²⁺、色度、浊度等指标基本都不显著相关,相关系数R<0.25.     

Trends in the chemistry of precipitation and surface water in a national network of small watersheds

Trends in precipitation and surface water chemistry at a network of 15 small watersheds (< 10 km²) in the USA were evaluated using a statistical test for monotonic trends (the seasonal Kendall test) and a graphical smoothing technique for the visual identification of trends. Composite precipitation samples were collected weekly and surface water samples were collected at least monthly. Concentrations were adjusted before trend analysis, by volume for precipitation samples and by flow for surface water samples. A relation between precipitation and surface water trends was not evident either for individual inorganic solutes or for solute combinations, such as ionic strength, at most sites. The only exception was chloride, for which there was a similar trend at 60% of the sites. The smoothing technique indicated that short-term patterns in precipitation chemistry were not reflected in surface waters. The magnitude of the short-term variations in surface water concentration was generally larger than the overall long-term trend, possibly because flow adjustment did not adequately correct for climatic variability. Detecting the relation between precipitation and surface water chemistry trends may be improved by using a more powerful sampling strategy and by developing better methods of concentration adjustment to remove the effects of natural variation in surface waters.     

The Weierbach experimental catchment in Luxembourg: A decade of critical zone monitoring in a temperate forest - from hydrological investigations to ecohydrological perspectives

The Weierbach experimental catchment (0.45 km²) is the most instrumented and studied sub-catchment in the Alzette River basin in Luxembourg. Within the last decade, it has matured towards an interdisciplinary critical zone observatory focusing on a better understanding of hydrological and hydro-geochemical processes. The Weierbach catchment is embedded in an elevated sub-horizontal plateau, characterized by slate bedrock and representative of the Ardennes Massif. Its climate is semi-marine, with precipitation being rather evenly distributed throughout the year. Base flow is lowest from July to September, essentially due to higher losses through evapotranspiration in summer. The regolith is composed of Devonian slates, overlaid by Pleistocene slope deposits and entirely covered by forest with 70% deciduous and 30% coniferous trees. Since 2009, the Weierbach has been extensively equipped for continuously monitoring water fluxes and physico-chemical parameters within different compartments of the critical zone. Additionally, these compartments are sampled fortnightly at several locations to analyze δ¹⁸O and δ²H isotopic composition of water including rainfall, throughfall, soil water, groundwater and streamwater. This ongoing monitoring and sampling programme is used for answering pressing questions related to fundamental catchment functions of water infiltration, storage, mixing and release in forest ecosystems. A recently started research line aims at investigating interactions between forest eco-hydrosystems with the atmosphere and understanding how catchments will respond to a non-stationary climate.