Genesis of underground brine along south coast of Laizhou Bay： hydrochemical characteristics

1 INTRODUCTION Two large-scale concentration mechanisms, evaporation and freezing, have been proposed for marine origin brine production (Bein and Arad, 1992; Bottomley et al., 1999). There are three basic requirements for brine formation by seawater evap…     

VARIATIONS IN ISOTOPIC COMPOSITIONS OF CHLORINE IN EVAPORATION-CONTROLLED SALT LAKE BRINES OF QAIDAM BASIN，CHINA

ＩＮＴＲＯＤＵＣＴＩＯＮＣｈｌｏｒｉｎｅｈａｓｔｗｏｎａｔｕｒａｌｌｙｏｃｃｕｒｉｎｇｓｔａｂｌｅｉｓｏｔｏｐｅｓ,　35Ｃｌａｎｄ　37Ｃｌ.Ｓｅｖｅｒａｌｓｔｕｄｉｅｓｒｅｐｏｒｔｅｄｔｈｅｖａｒｉａｔｉｏｎｓｉｎｔｈｅｉｓｏｔｏｐｉｃｃｏｍｐｏｓｉｔｉｏｎｏｆｃｈｌｏｒｉｎｅｉｎｎａｔｕｒｅ.Ｈｏｗｅｖｅｒ,ｉｎｔｈｅｅａｒｌｙｙｅａｒｓＯｗｅｎａｎｄＳｃｈａｅｆｆｅｒ(1955)ｒｅｐｏｒｔｅｄｎｏｏｂｓｅｒｖａｂｌｅｄｉｆｆｅｒｅｎｃｅｉｎｔｈｅ　37Ｃｌ35Ｃｌｒａｔｉｏｓｉｎｔｅｎｓａｍｐｌｅｓｅｘ…     

The hydrochemical features of salt lakes in Qaidam Basin

There are 37 lakes in the Qaidam Basin: 1 freshwater lake, 6 brackish-water lakes, 2 saline-water lakes and 28 salt lakes. The pH value of salt lake brines is 7.014 on the average, and the average total mineralization is 340.75 g/1. Their water bodies belong mainly to the five-component equilibrium system,: Na, K, Mg//SO₄, Cl-H₂O, which can be further grouped into sodium-magnesium sulfate subtype, magnesium sulfate subtype, chloride transition subtype and chloride type water by their hydrochemical property. The salt lake brines of the first salt forming epoch (N₂−Q₃) were of the sulfate type. In the second salt forming epoch (Q₃−Q₄), some of them were of the chloride type. The pH value of brines decreases with the increase of total mineralization. The pH value is lower when the total mineralization is from 50–310 g/l and higher when the total mineralization is from 310–355 g/l, however, when the total mineralization is higher than 355 g/l, the pH value decreases slowly again. The total mineralization of the chloride type and the chloride transition subtype brine is higher than the sulfate type, being 310–530 g/l, 310–470 g/l, and less than 355 g/l in that order. Of the 40 chemical compositions in the saline lake brines in Qaidam Basin, potassium is mainly concentrated in the chloride type and chloride transition subtype brine, boron and lithium mainly in the sulfate type. Evaporation experiments show that boron and lithium are accumulated in concentrated brine until crystallization of bischofite takes place. Potassium is also accumulated in concentrated brine during the salt forming stage, but its concentration decreases with the increase of total mineralization during the potassium forming stage. This paper was published in Chinese inOcean. et Limn. Sinica;15 (4):341–359, 1984.     

微生物介导下高砷地下水系统的氧化还原分带性概念模型

微生物活动对地下水水化学组分、氧化还原环境及砷的迁移转化有重要影响。研究高砷地下水系统的氧化还原分带性,有助于进一步理解微生物作用下地下水中砷的迁移转化规律,并为高砷地下水原位修复技术提供理论依据。在综述前人的研究成果的基础上,阐明了不同生物地球化学阶段砷的吸附、释放及固定过程,并刻画出高砷地下水系统的氧化还原分带性概念模型。在地下水环境中,微生物依次消耗(还原)溶解氧、NO-₃、Fe(Ⅲ)、SO2-₄和CO₂等组分,氧化有机物获取能量。在溶解氧和NO-3还原阶段,地下水处于偏氧化环境,此时Fe(Ⅲ)还原受到抑制,其负载的砷不会释放到地下水中;当Fe(Ⅲ)还原时,地下水处于还原环境,会导致与之共存的砷释放,形成高砷地下水;而当SO2-₄还原时,地下水处于强还原环境,产生的HS-与Fe2+形成的铁硫化物吸附或共沉淀砷,会降低地下水中的砷浓度。      

察尔汗盐湖卤水结盐条件分析与防治结盐的措施

本文通过对近年来在盐湖开采和试验过程中采卤设备以及输卤管、渠结盐实例的分析,得出如下结论:控制卤水结盐的主要因素是卤水的水化学类型以及矿化度、Na~+/Mg~(++)、Na~+/SO_4~=系数和CaCl_2的含量,其中Na~+/Mg~(++)系数是控制各类型卤水结盐的关键。并提出用回灌老卤的措施来解决卤水结盐问题。     

深层卤水自喷钻井若干特征的分析

本文以四川盆地中部的L_1井为例,讨论深层卤水自喷钻井卤水产出特征、水文地球化学特征和开采动态特征,并对钻井的测试资料进行分析,预测该钻井的卤水可采资源量。     

山东省黄河下游地区浅层地下水地球化学特征与环境质量评价

浅层地下水调查是山东省黄河下游流域生态地球化学调查项目中的一项工作内容。调查是按每16 km2采集1件浅层地下水样品的密度,分析测试As,Ba,Be,Ca,Cd,Co,Cu,Fe,Hg,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等33项指标;通过对这些指标在浅层地下水中的背景变化规律研究认为:调查区内浅层地下水中各指标含量起伏变化大,局部富集程度高,特别是As,Fe,K,La,Sb,Sn,Zn,Cl-,NO2-等指标的变异系数均>3.0,说明这些指标在浅层地下水中分布极不均匀,虽然背景含量较低,但在局部地段会形成高含量区,影响浅层地下水质量。选择As,Ba,Be,Cd,Co,Cu,Fe,Hg,Mn,Mo,Ni,Pb,Se,Zn,F-,Cl-,Cr6 ,NO2-,COD,pH等20项指标,按《地下水环境质量标准》中的要求,对浅层地下水环境质量进行的单项组分和综合评价结果显示,达到较好级以上者不足9%,而较差和极差级者达90%以上,表明调查区内浅层地下水环境污染状况较为严重。     

A preliminary study on the distribution and genesis of underground brine in the littoral plain of Laizhou Bay in the Bohai Sea

Quaternary underground brine in the littoral plain region of the Bohai coast is new type littoral facies evaporation ore deposit in liquid state . This model of " littorally- forming brine " is based on study of the distribution, depositional environment, forming / storing process, and genesis of underground brine in the coast of Laizhou Bay . Essential conditions for genesis of brine are arid and semiarid climate , abundant sources of ancient seawater, and geological and geomorphological environment of wide tidal beach along a coast. The process of underground brine genesis may be : seawater/tidal beach-evaporation and concentration-seeping and accumulation- brine/tidal beach - burial (evolution of the sea- land )- underground brine .Underground brine is characterized by high content of chemical elements, shallow burial depth and easy exploitation . The process of extracting salt from underground brine present in the tidal flat is incomparably superior to that of producing salt from seawater, and has b     

Humic Acid and Iron Chelation Modified Anode Improves the Electrochemical Performance of Marine Sediment Microbial Fuel Cell

Marine sediment microbial fuel cell(MSMFCs)can be utilized as a long lasting power source to drive small instruments to work for long time on ocean floor and its higher power has a significant meaning for practical application.Anode modification can greatly improve the performance of MSMFCs.Herein,humic acid(HA)and humic acid-iron ion complex(HA-Fe)were used to modify the anode for constructing a better MSMFCs.The results indicated that HA-Fe modified anode,better than HA modification,significantly improved the MSMFCs cell power output.The maximum power density of HA-Fe modified MSMFCs is 165.3 mW m?2,which are 6.5-folds of blank MSMFCs.The number of microorganisms on anode,redox activity,and relative kinetic activity were 1.8-,6.1-,and 13.1-folds of blank MSMFCs,respectively.The MSMFCs improvement would be attributed to the electron transfer media of HA and the valence conversion of Fe ions.A synergistic interaction between the naturally occurring HA and Fe ions on the anodic surface in marine sediments would make the modified anodes have‘renewable’characteristics,which is beneficial for the MSMFCs to maintain its long-term higher power.     

The forming-storing environment and abundance conditions of quaternary underground brine in the embayed coast of Qingdao

ImODUcrIONGroundwaterwthAnneralimtionofmorethan5OgA(about5"Be')"iscalledunder-groundbrine.ltbelongstoevaporationoredepositinliquidstateandisantwortantrnaterialsourceforsaltonkingandthechewhcalindustry.QuatemarylittoralfadesundergroundbrinewasstoredinthelittoralsoneandhadtwobasictypesofgenesisenvironmentflittoralplaincoastenvironmentcharacterindbythecoastalongLaichouBay,andembayedcoastenvironmentcharaCterindbythecoastalzoneofQingdao.TheauthorresearchedthebrineintheLaizhoubaycoastareainthe…     

BIOGEOCHEMICAL MECHANISM OF POSTDEPOSITIONAL MIGRATION OF Fe AND Mn IN LAKE AHA, CHINA

I.INTRODUCTIONLakeAhaisamedium--sizedartificialreservoirwithseasonallyanoxichypolirnnion,andawaterresourceofGuizhouProvince,China,builtin1958,workedin1960andexpandedin1982.Ithasadrainagebasinof190kmZwithaverageannualtemperatureof15.3tandprecipitationof1109rum.Openplantcover,containiflgshrubandgrass,surroundsthelake,andsialliticandstfeteyellowsoilisdevelopedonPe~ianlimestoneandcoallayer,meanwhile,OThisprojectwassupportedbytheNationalNaturalaudienceFOundationofChinaandtheaudienceFOund…     

Porosity Distribution Characteristics and Geological Analysis of Brine Storage Medium in the Qaidam Basin,Western China

Underground brine is an unusual water resource that contains abundant mineral resources. It is distributed widely in the Qaidam Basin, western China, a hyperarid inland basin located in the northern Tibetan Plateau. Pores in the brine storage medium act as storage space and transmission channels of underground brine. Therefore, the porosity of brine storage medium determines its ability to store brine. In this study, Mahai Salt Lake was used as the research area as a modern saline lake located in the north area of the Qaidam Basin. A total of 100 porosity samples were collected from eight sampling points in two profiles of the research area at sampling depths of 1.30–314.78 m. The porosity distribution characteristics and influencing factors in brine storage medium were analysed according to the measured porosity data. Based on analysis of the pore structure characteristics, the brine storage medium contains intercrystalline pores, unlike conventional freshwater storage mediums. Moreover, the primary salt rock is susceptible to dissolution by lighter brine, facilitating the formation of secondary porosity. Due to the formation of secondary pores, a porosity greater than 20% remains even at buried depths greater than 100 m. Based on the geological statistical analysis, due to the geographic location, salt formation time, and depositional environment, the porosity values of Mahai Salt Lake do not exhibit a wider distribution, but also show more extreme values than a nearby salt lake. Based on the porosity characteristics by depth, due to the presence of secondary pores, flooding, stratigraphic static pressure, and other factors, porosity shows fluctuations with increasing depth.     

早期成岩作用过程中硫酸盐还原反应研究进展

文章概述近年来早期成岩作用中硫酸盐还原反应研究的某些新资料和新成果 ,综合分析了各种沉积环境下的早期成岩作用中的硫酸盐还原反应。重点论述贫氧缺氧条件下的反应机制。并讨论了判别沉积环境的Fe -C -S的关系及黄铁矿的形成和碳酸盐的溶解、沉淀与氧化还原带的对应关系。简要讨论了早期成岩作用中硫酸盐还原反应的研究意义。     

陕西谭家沟热水沉积型金矿床地质特征与成因分析

谭家沟金矿产于中泥盆统热水沉积岩中。矿体位于铁白云石硅质岩构造角砾带 ,是以浸染状矿化为主 ,由热水沉积铁白云石硅质岩提供矿质并基本在层内富集成矿的热水沉积改造型金矿床。铅同位素特征表明成矿金属来源于地壳 ;硫同位素组成特征表明硫主要来自海水硫酸盐的还原硫 ;氢氧同位素测试数据表明 ,成矿流体主要为原生建造水。成矿流体为SO4 2 F/Na Ca2 型 ,成矿物理化学条件为弱中等还原环境 ,成矿温度 15 0～ 170℃ ,盐度w(NaCl)为 6 .86 %。     

山东渤海沿岸第四纪地下卤水研究进展

山东渤海沿海岸广泛分布着丰富的第四纪地下卤水资源。近年来,相关部门大力开发地下卤水资源,其勘察研究程度逐渐提高。但是各勘察区域零散,山东省整个渤海沿岸地区第四纪地下卤水资源整体研究程度不够系统全面。该文在前人资料和研究成果的基础上,从3个方面对该区卤水资源的研究进展进行了综述,结合当前的研究工作分析,指出今后该区卤水资源研究的主要工作是卤水资源的可持续性利用及资源环境的可持续发展。     

黄河三角洲高效生态经济区卤水资源开采潜力评价

黄河三角洲高效生态经济区卤水资源较为丰富,历经几十年的集中开采后,已出现卤水开采水位下降、卤度及有益离子含量下降等问题,该文在核算研究区卤水资源量的基础上,结合开发利用现状进行了开采潜力评价,以期为当地卤水资源开采规划提供科学依据。     

Phylogenetic analysis of bacteria in sea ice brine sampled from the Canada Basin, Arctic Ocean

Bacterial diversity in sea ice brine samples which collected from four stations located at the Canada Basin, Arctic Ocean was analyzed by PCR-DGGE. Twenty-three 16S rDNA sequences of bacteria obtained from DGGE bands were cloned and sequenced. Phylogenetic analysis clustered these sequences within γ-proteobacteria, Cytophaga-Flexlbacter-Bacteroides （CFB） group, Firmicutes and Actinobacteria. The phylotype of Pseudoalteromonas in the γ-proteobacteria was predominant and members of the CFB group and γ-proteobacteria were highly abundant in studied sea ice brine samples.     

鄂尔多斯盆地南缘双龙地区直罗组下段后生蚀变地球化学特征及其对铀成矿的制约

勘探实践发现,双龙地区砂岩型铀矿受绿色蚀变控制,与东胜地区相似。为明确区内层间氧化带的地球化学识别标志,通过对研究区直罗组下段砂岩后生蚀变的宏观表征观察和酸解烃、Th/U、Fe3+/Fe2+及有机碳等的地球化学研究,并与东胜铀矿床对比,探讨了双龙矿床绿色砂岩的成因,并讨论后生蚀变作用对铀成矿的影响机制。分析结果表明:原生灰色砂岩各类烃含量高于绿色蚀变砂岩和氧化蚀变砂岩,绿色蚀变砂岩介于两者之间;Th/U、Fe3+/Fe2+和有机碳质量分数分别在0.37~1.82,0.06~5.09,0.01%~1.24%之间,氧化蚀变砂岩与绿色蚀变砂岩皆具有高Th/U值、低有机碳的特征,而绿色蚀变砂岩的各地球化学指标介于氧化蚀变砂岩和原生灰色砂岩之间。总之,双龙地区直罗组下段的蚀变砂岩地球化学特征显示,绿色蚀变是砂岩处于一种相对较强的还原状态下形成的产物,即还原性流体的二次还原作用,早期的层间氧化作用为铀成矿提供了物质基础,后期的二次还原作用则保存了矿体的完整性。这一研究对该区层间氧化带的判别及划分具有重要的指示作用,并为砂岩型铀矿成矿规律的研究提供重要依据。      

八方山层控多金属矿床地质特征及成因探讨

依据矿床地质特征沿及铅、硫、氢、氧同位素以及包裹体和微量元素等测试资料分析表明,该矿床为中泥盆世沿海底同生断层喷溢的含矿热卤水与生物还原海水硫酸盐中的硫相互作用,形成同生含矿硅质岩,再经后期改造而成层控多金属矿床。所以矿床既有同生沉积标志,又有后生改造迹象。属海底喷气沉积—受改造的层控矿床。     

潍坊北部地下卤水资源化学组分的关系

通过对潍坊北部沿海地区地下卤水矿床特征、有用成分含量、卤水浓度与化学组分相关关系等方面的研究，认为该区地下卤水中达到工业指标的有Br^-，NaCl，MgCl2，MgSO4，CaSO4 5种矿产，卤水浓度与矿化度、NaCl和Br^-呈正相关关系。该区地下卤水资源储量大、埋藏浅，具较好的开发利用前景。