A Review and Evaluation of Specific Heat Capacities of Rocks,Minerals, and Subsurface Fluids. Part 1: Minerals and Nonporous Rocks

Heat capacities of the rocks within a sedimentary basin can significantly influence geothermal gradients if sedimentation or erosion is rapid. This paper provides data on specific heat capacities of minerals and nonporous rocks at 20°C, derives equations for calculating specific heat capacities of minerals and nonporous rocks at temperatures between 0°C and 1200°C, and shows that pressure effects on heat capacities of solids can be neglected. It derives an equation for estimating specific heat capacity of any mineral or nonporous rock as a function of density. Finally, it shows how to calculate the specific heat capacity of any mixture of solid materials. A companion paper discusses specific heat capacities of the fluids in pore spaces of rocks and of fluid-filled porous rocks. The data for minerals and rocks provided herein can be incorporated directly into existing modeling software by users. However, the temperature-dependent equations would have to be incorporated by software developers.     

Seal capacity estimation from subsurface pore pressures

A cap rock's capacity to seal hydrocarbons depends on its wettability and the sizes of the pore throats within the interconnected pore system that the leaking hydrocarbons must penetrate. These critical pore throat sizes are often poorly constrained in hydrocarbon exploration, partly because measurements of pore throat sizes have not been performed, and partly because pore throat measurements on a few individual samples in the cap rock may not be representative for the seal capacity of the top seal as a whole. To the contrary, the presence of formation overpressure can normally be estimated in drilled exploration targets. The presence of overpressure in reservoirs testifies to small pore throats in the cap rocks, as large pore throats will result in sufficiently high cap rock permeability to bleed off the overpressure. We suggest a stepwise procedure that enables quantification of top seal capacities of overpressured traps, based on subsurface pressure information. This procedure starts with the estimation of cap rock permeabilities, which are consistent with observed overpressure gradients across the top seals. Knowledge of burial histories is essential for these estimations. Relationships between pore throat size and permeability from laboratory experiments are then applied to estimate critical pore throat diameters in cap rocks. These critical pore throat diameters, combined with information of the physical properties of the pore fluids, are then used to calculate membrane seal capacity of cap rocks. Estimates of top seal capacity based on this procedure are rather sensitive to the vertical fluid velocity, but they are also to some extent sensitive to inaccuracies of the pore throat/permeability relationship, overpressure gradient, interfacial tensions between pore fluids, hydrocarbon density and water viscosity values. Despite these uncertainties, applications of the above‐mentioned procedure demonstrated that the mere presence of reservoir overpressures testifies to sufficient membrane seal capacity of cap rocks for most geological histories. Exempt from this statement are basins with rapid and substantial sediment compaction in the recent past.     

美国溴产品近况和前景

对美国近年来有关溴及其产品的生产研发情况进行了评述。包括原料资源,生产厂家,装置能力,近期统计资料,消耗构成,Albemarle’s真空提溴技术,国际合作项目,溴系阻燃剂,溴系杀生剂,完井液和重点含溴农药等,并展望了发展前景。     

Summertime temperature variations in the middle and lower reaches of Yangtze River and their related circulation anomalies in the past five decades

Using the daily data of temperature from China Meteorological Administration and the NCEP/NCAR reanalysis from 1960 to 2005, we have analyzed the relationships between the summertime high/low temperature events in the middle and lower reaches of the Yangtze River (MLRYR) and the related circulation anomalies in the Eastern Hemisphere. Our results have demonstrated that a significantly increasing trend is observed in daily minimum temperature in the past 50 years. And in some regions in the Northern Hemisphere, the opposite scenarios are observed in circulation anomalies in lower and upper parts of the troposphere in the years when the temperatures are higher than normal, as compared to those in the years when the temperatures are lower than normal in the middle and lower reaches of the Yangtze River (MLRYR). Additionally, the anomalous circulation structure in vertical direction in both the high and lower temperature years are barotropic. It is found that the emergence and maintenance of the aforementioned anomalous circulations are related to three kinds of wave train teleconnection patterns. Further more, influences of the long wave surface radiation on the air temperature are stronger in the nighttime than that in the daytime. While both the maximum and minimum temperatures have negative relationships with the sensible heat flux but positive relationships with the latent heat flux. To some extent, the anomalous dynamic heating (cooling) caused by the vertical thermal advection as well as the diabatic heating (cooling) caused by diabatic processes can explain the formation of the high (low) temperature events in the middle and lower reaches of the Yangtze River (MLRYR) in boreal summer.     

近50年长江中下游地区夏季气温变化与环流异常

Using the daily data of temperature from China Meteorological Administration and the NCEP/NCAR reanalysis from 1960 to 2005, we have analyzed the relationships between the summertime high/low temperature events in the middle and lower reaches of the Yangtze River (MLRYR) and the related circulation anomalies in the Eastern Hemisphere. Our results have demonstrated that a significantly increasing trend is observed in daily minimum temperature in the past 50 years. And in some regions in the Northern Hemisphere, the opposite scenarios are observed in circulation anomalies in lower and upper parts of the troposphere in the years when the temperatures are higher than normal, as compared to those in the years when the temperatures are lower than normal in the middle and lower reaches of the Yangtze River (MLRYR). Additionally, the anomalous circulation structure in vertical direction in both the high and lower temperature years are barotropic. It is found that the emergence and maintenance of the aforementioned anomalous circulations are related to three kinds of wave train teleconnection patterns. Further more, influences of the long wave surface radiation on the air temperature are stronger in the nighttime than that in the daytime. While both the maximum and minimum temperatures have negative relationships with the sensible heat flux but positive relationships with the latent heat flux. To some extent, the anomalous dynamic heating (cooling) caused by the vertical thermal advection as well as the diabatic heating (cooling) caused by diabatic processes can explain the formation of the high (low) temperature events in the middle and lower reaches of the Yangtze River (MLRYR) in boreal summer.     

Simultaneous determination of thermal conductivity, thermal diffusivity and specific heat in sI methane hydrate

Thermal conductivity, thermal diffusivity and specific heat of sI methane hydrate were measured as functions of temperature and pressure using a needle probe technique. The temperature dependence was measured between −20°C and 17°C at 31.5 MPa. The pressure dependence was measured between 31.5 and 102 MPa at 14.4°C. Only weak temperature and pressure dependencies were observed. Methane hydrate thermal conductivity differs from that of water by less than 10 per cent, too little to provide a sensitive measure of hydrate content in water-saturated systems. Thermal diffusivity of methane hydrate is more than twice that of water, however, and its specific heat is about half that of water. Thus, when drilling into or through hydrate-rich sediment, heat from the borehole can raise the formation temperature more than 20 per cent faster than if the formation's pore space contains only water. Thermal properties of methane hydrate should be considered in safety and economic assessments of hydrate-bearing sediment.     

Adsorption kinetics, isotherm, and thermodynamic studies of adsorption of pollutant from aqueous solutions onto humic acid

In the present study,humic acid was used as an adsorbent for the investigation of the adsorption kinetics,isotherms,and thermo-dynamic parameters of hexavalent chromium from aqueous solution at varying pH,temperatures,and concentrations.Adsorption isotherms and equilibrium adsorption capacities were determined by the fittings of the experimental data to three well-known iso-therm models:Langmuir,Freundlich,and Redlich-Peterson.The results showed that the Langmuir and Redlich-Peterson models appear to fit the adsorption better than did the Freundlich adsorption model for the adsorption of chromium onto humic acid.The equilibrium constants were used to calculate thermodynamic parameters such as the change of free energy,enthalpy,and entropy.The derived adsorption constants (logaL) and their temperature dependencies from Langmuir isotherm have been used to calculate the corresponding thermodynamic quantities such as the free energy of adsorption,heat,and entropy of adsorption.The thermo-dynamic data indicate that Cr (VI) adsorption onto humic acid is entropically driven and characterized by physical adsorption.     

Simulation of Power Production from Dry Geothermal Well Using Down-hole Heat Exchanger in Sabalan Field,Northwest Iran

In this research, a simulation was performed for evaluating power production from an abandoned geothermal well as an enhanced geothermal system by injecting a secondary fluid. Abandoned wells, due to lack of fluid or very low transmissivity, are regarded among the low-to moderate-temperature resources that have the potential for heat production without any cost for deep drilling. Accordingly, they are taken as suitable sources of energy. In the present paper, an abandoned geothermal well at Meshkinshahr geothermal field in Sabalan district, northwestern Iran, with 3176 m depth was simulated. The bottom-hole temperature of 148 °C, as well as well casing size, and real thermal gradient for well were applied in the model. A 3D heat transfer simulation model was designed by considering a coaxial pipe as a down-hole heat exchanger between surrounding rocks of the well and injected fluid. Injected fluid to the well with specified pressure and temperature receives heat from rocks surrounding the well, until it reaches the bottom of the well and converts to vapor. The vapor returns to the surface from inner pipe with very low heat loss during its return. The inner pipe is isolated by a thin layer having a low heat conductivity to prevent heat loss from the returned fluid. It was observed that obtained heat in the well depends on temperature profile of the well, injection velocity, and fluid mass flow rate. The model results were optimized by selecting suitable parameters such as inlet injection speed and fluid flow rate to achieve the highest temperature of the fluid returned from the well. A binary power plant was also modeled to determine the extractable power using returned fluid as input using ammonia and isobutene, as working fluids in binary cycle. Finally, electric power of 270 kW was generated from well NWS3 using designed down-hole heat exchanger.     

Monitoring and simulation of water, heat,and CO2 fluxes in terrestrial ecosystems based on the APEIS-FLUX system

1IntroductionInJune1992,theworldsummitorganizedbytheUnitedNations,withparticipantsincludingnationalleadersfromaroundtheworld,concludedwithAgenda21(UnitedNations,1992),theRioDeclarationonEnvironmentandDevelopment,inRiodeJaneiro.Thedeclarationpromptedcountr…     

Monitoring and simulation of water, heat, and CO2 fluxes in terrestrial ecosystems based on the APEIS-FLUX system

The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, monitor, and assess environmental disasters, degradation, and their impacts in the Asia-Pacific region. The system primarily employs data from the moderate resolution imaging spectrometer (MODIS) sensor on the Earth Observation System- (EOS-) Terra/Aqua satellite, as well as those from ground observations at five sites in different ecological systems in China. From the preliminary data analysis on both annual and daily variations of water, heat and CO2 fluxes, we can confirm that this system basically has been working well. The results show that both latent flux and CO2 flux are much greater in the crop field than those in the grassland and the saline desert, whereas the sensible heat flux shows the opposite trend. Different data products from MODIS have very different correspondence, e.g. MODIS-derived land surface temperature has a close correlation with measured ones, but LAI and NPP are quite different from ground measurements, which suggests that the algorithms used to process MODIS data need to be revised by using the local dataset. We are now using the APEIS-FLUX data to develop an integrated model, which can simulate the regional water, heat, and carbon fluxes. Finally, we are expected to use this model to develop more precise high-order MODIS products in Asia-Pacific region.     

基于亚太地区环境综合监测的陆地生态系统中水、热和二氧化碳的监测与模拟

The Integrated Environmental Monitoring (IEM) project, part of the Asia-Pacific Environmental Innovation Strategy (APEIS) project, developed an integrated environmental monitoring system that can be used to detect, monitor, and assess environmental disasters, degradation, and their impacts in the Asia-Pacific region. The system primarily employs data from the moderate resolution imaging spectrometer (MODIS) sensor on the Earth Observation System- (EOS-) Terra/Aqua satellite,as well as those from ground observations at five sites in different ecological systems in China. From the preliminary data analysis on both annual and daily variations of water, heat and CO2 fluxes, we can confirm that this system basically has been working well. The results show that both latent flux and CO2 flux are much greater in the crop field than those in the grassland and the saline desert, whereas the sensible heat flux shows the opposite trend. Different data products from MODIS have very different correspondence, e.g. MODIS-derived land surface temperature has a close correlation with measured ones, but LAI and NPP are quite different from ground measurements, which suggests that the algorithms used to process MODIS data need to be revised by using the local dataset. We are now using the APEIS-FLUX data to develop an integrated model, which can simulate the regional water,heat, and carbon fluxes. Finally, we are expected to use this model to develop more precise high-order MODIS products in Asia-Pacific region.     

资源与环境模型标准文档库及其与GIS集成

论述了中国资源与环境模型标准文档库的结构和内容。通过研究总结数学模型及其研究现状发现，中国资源与环境模型标准文档库建设需要完善尚有缺陷的数学模型、创建尚缺少的数学模型；通过归纳现有数学模型与地理信息系统的现有集成方法发现，目前的集成方法不能满足区域可持续发展集成模型的需要，据此讨论了数学模型与地理信息系统有效集成需要深入研究的内容。最后，提出了通过大量案例研究，形成区域可持续发展集成模型和中国资源与环境模型标准文档库2个软件包的可行研究思路。     

Thermal properties of sediments in southern Israel: a comprehensive data set for heat flow and geothermal energy studies

To decipher the thermal structure of the sedimentary veneer in southern Israel, new values of thermal conductivity and porosity as well as of the radiogenic heat budget are provided. Thermal conductivity is measured for lithotypes and scaled up for geological formations. The new data are higher than most of the previously measured values, in particular for sandstones and siltstones, whose mean values are 5.0 and 2.9 W m^?1 K^?1. Mean values of the most abundant lithotypes, which are dolomites and limestones, are on the order of 4.1 and 2.7 W m^?1 K^?1, respectively. The total radiogenic heat production of the sedimentary cover varies slightly over southern Israel, due to variable lithology and total sediment thickness, yielding a maximum heat flow on the order of 4 mW m^?2 where the sedimentary section is thickest (ca. 7 km). A temperature prognosis was made by calculating temperature profiles to the top of the crystalline basement at five well locations applying the new thermal‐conductivity data set and three scenarios of surface heat flow (50, 55 and 60 mW m^?2). The calculated temperatures best match with measured drillstem‐test temperatures by using heat‐flow values close to the upper bound of range. Surface heat flow on the order of 55–60 mW m^?2 is supported by a reevaluation of an existing temperature log and the application of thermal conductivity from this study. The temperature prediction for southern Israel shows values of 100–120°C at 3500–4500 m depth, indicating a geothermal potential that can be used for heating as well as electricity production.     

Neumann stochastic finite element method for calculating temperature field of frozen soil based on random field theory

To study the effect of uncertain factors on the temperature field of frozen soil, we propose a method to calculate the spatial average variance from just the point variance based on the local average theory of random fields. We model the heat transfer coefficient and specific heat capacity as spatially random fields instead of traditional random variables. An analysis for calculating the random temperature field of seasonal frozen soil is suggested by the Neumann stochastic finite element method, and here we provide the computational formulae of mathematical expectation, variance and variable coefficient. As shown in the calculation flow chart, the stochastic finite element calculation program for solving the random temperature field, as compiled by Matrix Laboratory (MATLAB) software, can directly output the statistical results of the temperature field of frozen soil. An example is presented to demonstrate the random effects from random field parameters, and the feasibility of the proposed approach is proven by comparing these results with the results derived when the random parameters are only modeled as random variables. The results show that the Neumann stochastic finite element method can efficiently solve the problem of random temperature fields of frozen soil based on random field theory, and it can reduce the variability of calculation results when the random parameters are modeled as spatially random fields.     

Thermal state of the Roer Valley Graben,part of the European Cenozoic Rift System

We performed a detailed analysis of the thermal state of the Cenozoic Roer Valley Graben, the north–western branch of the European Cenozoic Rift System, based on a new set of temperature data. We developed a numerical technique for correcting bottom hole temperatures, including an evaluation of the uncertainty of thermal parameters. Comparison with drill stem test temperatures indicated that the uncertainty in corrected bottom hole temperatures using a two‐component numerical model is approximately ± 4 °C, which is much more accurate than the up to 15 °C errors encountered in often‐used line‐source or Horner correction methods. The subsurface temperatures and the derived regional heat flow estimates of 53 ± 6 to 63 ± 6 mW m^?2 show no significant difference between the central rift and the adjacent structural highs. The absence of an elevated heat flow is attributed to the low amount of lithospheric thinning during the Cenozoic rifting phase (β=1.06–1.15). A local thermal anomaly exceeding +10 °C was found in five wells in the north–western part of the rift basin at depths of 1000–1500 m, and is most likely caused by the upward flow of fluids along faults, whereas lower temperatures in the upper 1500 m in the southern part of the rift basin could indicate cooling by topography‐driven groundwater flow. Conflicting ideas exist on the active or passive rifting mechanisms responsible for the formation of the different rift basins of European Cenozoic Rift System. The low spatial variation in heat flow found in this study suggests that the mechanism responsible for forming the Roer Valley Graben is passive rifting.     

The analysis of heat and water fluxes in frozen silty soil

In this paper, based on the basic equations of water flow and heat transfer, the hydrothermal coupling model is established.The numerical model was realized in COMSOL Multiphysics software, and simulation results are compared with the experimental results of Watanabe and Wake(2008) to verify the effectiveness of the model. Through the calculation, we can obtain the dynamic changes of heat and water fluxes, thermal and hydrological properties, matric potential and temperature gradient in unsaturated freezing soil; and these variables are unmeasurable in practice.     

The pulse-probe method of conductivity measurement

Summary. An alternative to the steady heating of a cylindrical probe, in the 'needle-probe' method of conductivity measurement, is the observation of the thermal decay from a short, calibrated, heat pulse. The theoretical solution is the time-differential of that for the former method, and requires only the measurement of point temperatures rather than the determination of a gradient. A careful analysis of the theoretical decay function shows that it should be possible to make accurate conductivity measurements in as little as three probe 'time constants' if external information is available on the heat capacity of the medium. A self-contained method, using two temperature determinations from a record about six time-constants long, can be used where such information is not available. The theory was tested by measurements on the ocean-floor, and the data correspond to the theory when a correction was applied for some internal probe conduction problems.     

不同类型生态系统水热碳通量的监测与研究

亚太地区环境革新战略项目(APEIS) 在中国5种主要生态系统类型区(草地: 海北、耕地: 禹城、稻田: 桃源、林地: 千烟洲、荒漠: 阜康) 建立了一个以连续观测能量、水分和碳素通量为中心,包括气象、水文、土壤、植被等各项生态要素的监测网络系统,被称之为APEIS-FLUX系统。作者首先对APEIS-FLUX系统的观测数据进行了初步分析,表明该系统稳定可靠,它可以实时地提供高质量、高精度、长期而连续的通量及生态要素的观测数据。对数据的比较清楚地反映出了不同生态系统类型区的水热碳通量的差异性。其次,利用APEIS-FLUX数据对美国航空航天局(NASA) 的MODIS数据产品进行比较验证后发现,除部分产品如地表面温度(MOD11) 等与观测数据较吻合以外,大部分数据产品如土地覆盖(MOD12),叶面积指数(MOD15) 和光合速率与净第一性生产力(MOD17) 等都与观测数据相差深远,有必要对其处理程序和模式进行修正。为此,我们利用APEIS-FLUX的数据作为MOD15和MOD17的生成模型(BIOME-BGC) 的输入数据,并对该模型的有关参数进行了修订。结果表明,该模式在通过修正后,可以很好地模拟植被的生长过程及其相应的水热碳循环过程。     

硼砂热力学性质的研究

通过精密自动绝热量热仪测定了硼砂(Na2B4O7.10H2O)在78~345 K的热容。实验结果表明,硼砂在330~336 K温度区间有一个脱水-溶解峰,密闭加热条件下其熔点为334.38 K。用最小二乘法将脱水前的实验摩尔热容对折合温度进行拟合,得到了此温区的热容随温度变化的多项式方程,Cp,m=447.782 77+229.452 55X-49.129 89X2+21.504 25X3十24.551 12X4。用热容多项式方程进行数值积分获得了该物质在80~325 K温区每隔5 K的热力学函数值。     

宁夏盐池县相对资源承载力

采用相对资源承载力的理论与研究方法,定量分析了盐池县8个乡镇相对资源承载力时空变化及差异特征,并对承载力匹配特征进行空间表达。结果表明：盐池县辖各乡镇相对于盐池县的综合人口承载力表现出严重超载、超载和富余3种不同的状态;相对自然资源经济承载力时空变化稳定,自然资源的经济潜力不断增大;相对草地资源牲畜承载力随时间推移不断递增且空间差异明显;依据3种承载力状态组合划分了不同的承载力匹配类型,并提出不同类型的可持续发展策略。本研究可为盐池县禁牧10年后各乡镇发展提供建议,并为“退牧还草”政策的继续实施提供理论支持。