Geodynamic evolution of the Eastern Sierras Pampeanas (Central Argentina) based on geochemical, Sm–Nd, Pb–Pb and SHRIMP data

Whole-rock geochemical analyses using major and trace elements in combination with the Sm–Nd and Pb–Pb isotope systems, together with SHRIMP age dating on metasedimentary rocks from the Sierras de Chepes, the Sierras de Córdoba, the Sierra Norte and the San Luis Formation in the Sierra de San Luis, have been carried out to unravel the provenance and the geodynamic history of the Eastern Sierras Pampeanas, Central Argentina. The geochemical and the Sm–Nd data point to a slightly stronger mafic and less-fractionated material in the provenance area of the Sierras de Córdoba when compared to the other units. The T_DM model ages from the Sierras de Chepes (~1.82 Ga) and the Sierra Norte (~1.79 Ga) are significantly older than the data from the Sierras de Córdoba (1.67 Ga). The Pb data are homogeneous for the different units. Only the ²⁰⁸Pb/²⁰⁴Pb ratios of some samples from the Sierras de Córdoba are higher. A late Pampean detrital zircon peak around 520 Ma from the Sierras de Chepes is in accordance with the new data from the San Luis Formation. This is similar to the literature data from the Famatina Belt located to the northwest of the Sierras de Chepes and also fits the detrital zircon peaks in the Mesón group. These maximum depositional ages were also reported from some locations in the Puncoviscana Formation but are absent in the Sierras de Córdoba. An improved model for the development of the Eastern Sierras Pampeanas in the area between the Sierras de Córdoba and the Puncoviscana Formation is provided. This gives new insights into the late Pampean development of the Sierra de San Luis and the complex development of the Eastern Sierras Pampeanas. This new model explains the younger detrital ages in the Puncoviscana Formation compared with the older ages of the Sierras de Córdoba. Another model of the Sierra de San Luis explains the younger depositional ages of the Pringles Metamorphic Complex and the San Luis Formation when compared to the Nogolí Metamorphic Complex and the Conlara Metamorphic Complex. Additionally, the rather fast change of the high-grade metamorphic conditions in the Pringles Metamorphic Complex and the low-grade metamorphic conditions in the San Luis Formation is explained by extension, the ascent of (ultra) mafic material and later folding and erosion.     

Early Paleozoic orogeny in southern South America

In northwest Argentina, weakly metamorphic clastic and calcareous sedimentary rocks of latest Precambrian to Lower Cambrian age (Puncoviscana Formation and related units) contain an abundant ichnofauna of both chronostratigraphic and paleoenvironmental value. In the western and central Sierras Pampeanas, metasedimentary and metavolcanic rocks are considered to form part of the same geotectonic unit. This “Pampean orogenic cycle” includes geosynclinal sedimentation of latest Precambrian to Lower Cambrian age, as well as magmatism, metamorphism and deformation of Middle to Upper Cambrian age, documented by an angular unconformity below the Upper Cambrian to Devonian rocks of the “Famatinian orogenic cycle”. In some of the metamorphic rocks of the Pampean Cycle a pre-Ordovician folding is also distinguished from a later tectonic overprinting. Hence, the concept of a Pampean cycle differs from other concepts of late Precambrian orogenic cycles of South America which are only defined by radiometric ages. The Pampean orogenesis may be compared with the Ross orogenesis of the Transantarctic Mts., the Tyennan orogenesis of Australia and some of the deformation phases of the Damara orogen in Namibia.     

Proterozoic–Paleozoic development of the basement of the Central Andes (18–26°S) — a mobile belt of the South American craton

The Late Precambrian–Early Paleozoic metamorphic basement forms a volumetrically important part of the Andean crust. We investigated its evolution in order to subdivide the area between 18 and 26°S into crustal domains by means of petrological and age data (Sm–Nd isochrons, K–Ar). The metamorphic crystallization ages and t_DM ages are not consistent with growth of the Pacific margin north of the Argentine Precordillera by accretion of exotic terranes, but favor a model of a mobile belt of the Pampean Cycle. Peak metamorphic conditions in all scattered outcrop areas between 18 and 26°S are similar and reached the upper amphibolite facies conditions indicated by mineral paragensis and the occurrence of migmatite. Sm–Nd mineral isochrons yielded 525±10, 505±6 and 509±1 Ma for the Chilean Coast Range, the Chilean Precordillera and the Argentine Puna, and 442±9 and 412±18 Ma for the Sierras Pampeanas. Conventional K–Ar cooling age data of amphibole and mica cluster around 400 Ma, but are frequently reset by Late Paleozoic and Jurassic magmatism. Final exhumation of the Early Paleozoic orogen is confirmed by Devonian erosional unconformities. Sm–Nd depleted mantle model ages of felsic rocks from the metamorphic basement range from 1.4 to 2.2 Ga, in northern Chile the average is 1.65±0.16 Ga (1σ; n=12), average t_DM of both gneiss and metabasite in NW Argentina is 1.76±0.4 Ga (1σ; n=22), and the isotopic composition excludes major addition of juvenile mantle derived material during the Early Paleozoic metamorphic and magmatic cycle. These new data indicate a largely similar development of the metamorphic basement south of the Arequipa Massif at 18°S and north of the Argentine Precordillera at 28°S. Variations of metamorphic grade and of ages of peak metamorphism are of local importance. The protolith was derived from Early to Middle Proterozoic cratonic areas, similar to the Proterozoic rocks from the Arequipa Massif, which had undergone Grenvillian metamorphism at ca. 1.0 Ga.     

Identifying Laurentian and SW Gondwana sources in the Neoproterozoic to Early Paleozoic metasedimentary rocks of the Sierras Pampeanas: Paleogeographic and tectonic implications

The provenance of Neoproterozoic to Early Paleozoic sedimentary rocks in the Sierras Pampeanas has been established using U–Pb SHRIMP age determination of detrital zircons in twelve metasedimentary samples, with supplementary Hf and O isotope analyses of selected samples. The detrital zircon age patterns show that the western and eastern sectors of the Sierras Pampeanas are derived from different sources, and were juxtaposed during the Early Cambrian ‘Pampean’ collision orogeny, thus defining initiation of the supercontinent stage of southwestern Gondwana. The Western Sierras Pampeanas (WSP), which extend northwards to the southern Puna (Antofalla) and the Arequipa Massif (Peru), constitute a single large continental basement of Paleoproterozoic age — the MARA block — that was reworked during the Grenvillian orogeny. The MARA block probably extends eastwards to include the Río Apa block (southern Brazil), but in this case without a Mesoproterozoic overprint. Detrital zircons from the WSP and Antofalla yield age peaks between 1330 and 1030 Ma, remarkably similar to the range of ages in the Grenville province of eastern Laurentia. The WSP Neoproterozoic sedimentary cover to this basement shows the same 1330–1030 component, but also includes important 1430–1380 Ma zircons whose juvenile Hf and O isotopic signatures strongly suggest derivation from the Grenville and the Southern Granite–Rhyolite provinces of eastern Laurentia. In contrast the Eastern Sierras Pampeanas metasedimentary rocks have a typically bimodal detrital zircon pattern with peaks at ca. 1000 and 600 Ma, which respectively indicate sources in the Natal–Namaqua belt and the East African orogen and/or the Dom Feliciano belt of SE Brazil and Uruguay. Sedimentary rocks in the Eastern Sierras Pampeanas and Patagonia deposited during the Late Early Cambrian–Early Ordovician interval, after the Pampean orogeny, have detrital patterns common to many sectors along the Terra Australis orogen, reflecting increasingly dominant input to the Paleozoic basins from the Neoproterozoic to Early Cambrian orogenic belts of the Gondwana margin.     

High T/P evolution and metamorphic ages of the migmatitic basement of northern Sierras Pampeanas,Argentina: Characterization of a mid-crustal segment of the Famatinian belt

New petrologic, thermobarometric and U-Pb monazite geochronologic information allowed to resolve the metamorphic evolution of a high temperature mid-crustal segment of an ancient subduction-related orogen. The El Portezuelo Metamorphic-Igneous Complex, in the northern Sierras Pampeanas, is mainly composed of migmatites that evolved from amphibolite to granulite metamorphic facies, reaching thermal peak conditions of 670–820 °C and 4.5–5.3 kbar. The petrographic study combined with conventional and pseudosection thermobarometry led to deducing a short prograde metamorphic evolution within migmatite blocks. The garnet-absent migmatites represent amphibolite-facies rocks, whereas the cordierite-garnet-K-feldspar-sillimanite migmatites represent higher metamorphic grade rocks. U-Pb geochronology on monazite grains within leucosome record the time of migmatization between ≈477 and 470 Ma. Thus, the El Portezuelo Metamorphic-Igneous Complex is an example of exhumed Early Ordovician anatectic middle crust of the Famatinian mobile belt. Homogeneous exposure of similar paleo-depths throughout the Famatinian back-arc and isobaric cooling paths suggest slow exhumation and consequent longstanding crustal residence at high temperatures. High thermal gradients uniformly distributed in the Famatinian back-arc can be explained by shallow convection of a low-viscosity asthenosphere promoted by subducting-slab dehydration.     

The Neoproterozoic-early Paleozoic metamorphic and magmatic evolution of the Eastern Sierras Pampeanas: an overview

The Eastern Sierras Pampeanas were structured by three main events: the Ediacaran to early Cambrian (580?C510?Ma) Pampean, the late Cambrian?COrdovician (500?C440?Ma) Famatinian and the Devonian-Carboniferous (400?C350?Ma) Achalian orogenies. Geochronological and Sm?CNd isotopic evidence combined with petrological and structural features allow to speculate for a major rift event (Ediacaran) dividing into two Mesoproterozoic major crustal blocks (source of the Grenvillian age peaks in the metaclastic rocks).This event would be coeval with the development of arc magmatism along the eastern margin of the eastern block. Closure of this eastern margin led to a Cambrian active margin (Sierra Norte arc) along the western margin of the eastern block in which magmatism reworked the same crustal block. Consumption of a ridge segment (input of OIB signature mafic magmas) which controlled granulite-facies metamorphism led to a final collision (Pampean orogeny) with the western Mesoprotrozoic block. Sm?CNd results for the metamorphic basement suggest that the T _DM age interval of 1.8?C1.7?Ga, which is associated with the less radiogenic values of ??Nd₍₅₄₀₎ (?6 to ?8), can be considered as the mean average crustal composition for the Eastern Sierras Pampeanas. Increasing metamorphic grade in rocks with similar detrital sources and metamorphic ages like in the Sierras de Córdoba is associated with a younger T _DM age and a more positive ??Nd₍₅₄₀₎ value. Pampean pre-540?Ma granitoids form two clusters, one with T _DM ages between 2.0 and 1.75?Ga and another between 1.6 and 1.5?Ga. Pampean post-540?Ma granitoids exhibit more homogenous T _DM ages ranging from 2.0 to 1.75?Ga. Ordovician re-activation of active margin along the western part of the block that collided in the Cambrian led to arc magmatism (Famatinian orogeny) and related ensialic back-arc basin in which high-grade metamorphism is related to mid-crustal felsic plutonism and mafic magmatism with significant contamination of continental crust. T _DM values for the Ordovician Famatinian granitoids define a main interval of 1.8?C1.6, except for the Ordovician TTG suites of the Sierras de Córdoba, which show younger T _DM ages ranging from 1.3 to 1.0?Ga. In Devonian times (Achalian orogeny), a new subduction regime installed west of the Eastern Sierras Pampeanas. Devonian magmatism in the Sierras exhibit process of mixing/assimilation of depleted mantle signature melts and continental crust. Achalian magmatism exhibits more radiogenic ??Nd₍₅₄₀₎ values that range between 0.5 and ?4 and T _DM ages younger than 1.3?Ga. In pre-Devonian times, crustal reworking is dominant, whereas processes during Devonian times involved different geochemical and isotopic signatures that reflect a major input of juvenile magmatism.     

Provenance of the late Proterozoic to early Cambrian metaclastic sediments of the Sierra de San Luis (Eastern Sierras Pampeanas) and Cordillera Oriental, Argentina

Provenance studies have been performed utilising major and trace elements, Nd systematics, whole rock Pb–Pb isotopes and zircon U/Pb SHRIMP data on metasedimentary rocks of the Sierra de San Luis (Nogolí Metamorphic Complex, Pringles Metamorphic Complex, Conlara Metamorphic Complex and San Luis Formation) and the Puncoviscana Formation of the Cordillera Oriental. The goal was the characterisation of the different domains in the study area and to give insights to the location of the source rocks. An active continental margin setting with typical composition of the upper continental crust is depicted for all the complexes using major and trace elements. The Pringles Metamorphic Complex shows indications for crustal recycling, pointing to a bimodal provenance. Major volcanic input has to be rejected due to Th/Sc, Y/Ni and Cr/V ratios for all units. The εNd_{(540 Ma)} data is lower for the San Luis Formation and higher for the Conlara Metamorphic Complex, as compared to the other units, in which a good consistency is given. This is similar to the T_DM ages, where the metapsammitic samples of the San Luis Formation are slightly older. The spread of data is largest for the Pringles Metamorphic Complex, again implying two different sources. The whole rock ²⁰⁷Pb/²⁰⁶Pb isotopic data lies in between the South American and African sources, excluding Laurentian provenances. The whole rock Pb–Pb data is almost indistinguishable in the different investigated domains. Only the PMC shows slightly elevated ²⁰⁸Pb/²⁰⁴Pb values. Possible source rocks for the different domains could be the Quebrada Choja in the Central Arequipa–Antofalla domain, the Southern domain of the Arequipa–Antofalla basement, the Brazilian shield or southern Africa. Zircon SHRIMP data point to a connection between the Puncoviscana Formation and the Conlara Metamorphic Complex. Two maxima around 600 Ma and around 1000 Ma have been determined. The Nogolí Metamorphic Complex and the Pringles Metamorphic Complex show one peak of detrital zircons around 550 Ma, and only a few grains are older than 700 Ma. The detrital zircon ages for the San Luis Formation show age ranges between 590 and 550 Ma. A common basin can be assumed for the Conlara Metamorphic Complex and the Puncoviscana Formation, but the available data support different sources for the rest of the Complexes of the Sierra de San Luis. These share the diminished importance or the lack of the Grenvillian detrital peak, a common feature for the late Cambrian–early Ordovician basins of the Eastern Sierras Pampeanas, in contrast to the Sierras de Córdoba, the PVF and the Conlara Metamorphic Complex.     

Evolution of exhumation and erosion in western West Gondwanaland as recorded by detrital zircons of late Neoproterozoic and Cambrian sedimentary rocks of NW and Central Argentina

The evolution of the provenance areas for Late Neoproterozoic, Cambrian and Early Ordovician sedimentary and meta-sedimentary rocks of north central and northwest Argentina is discussed using 123 maximum ages of detrital zircons from 42 samples from this and previously published studies. Most detrital zircon ages fall into two groups: 1,200–900 Ma and 670–545 Ma. These ages are essentially identical for the non- to very low grade metamorphic late Neoproterozoic to Early Cambrian Puncoviscana Formation and the low to high grade metamorphic rocks of Eastern Sierras Pampeanas. Hence, both units are related to similar provenance areas at the same time of sedimentation. The time span from zircon crystallization in the Earth’s crust to exhumation and erosion may be very long. This is important when determining maximum ages of sedimentary rocks. Variation of zircon maxima may also be influenced by concurrent sedimentary cover of proposed provenance areas. For the late Mesoproterozoic to early Neoproterozoic zircon age group, an active mountain range of the southwest Brazilian Sunsás orogen is the most probable provenance area. The younger, late Neoproterozoic zircons are related to the continuously developing mountains of the Brasiliano orogen of southwest and south central Brazil. Young zircons, up to 514 Ma, from fossil-bearing Puncoviscana and Suncho Formation outcrops are related to late Early Cambrian volcanism contemporaneous with sedimentation. This situation continues through the Late Cambrian to the Early Ordovician, but the Sunsás orogen provenance diminishes as possible Río de la Plata craton origins become important.     

Cambrian to Devonian Geologic Evolution of the Sierra de Comechingones, Eastern Sierras Pampeanas, Argentina: Evidence for the Development and Exhumation of Continental Crust on the Proto-Pacific Margin of Gondwana

Crystalline rocks from the Sierra de Comechingones, eastern Sierras Pampeanas, evolved through three distinct orogenic cycles during the Eopalaeozoic: (1) the first tectono-thermal event named Pampean orogeny (550 to 505 Ma), which peaked in the Early Cambrian, was responsible for extensive metamorphism, partial melting, juvenile magmatism, rapid decompression, and persistent tectonic activity. Large part of the crustal section that was residing at middle levels (c. 27 km) was heated above 800 °C during the thermal peak stage of the Pampean orogeny; decompression of the Pampean orogen's core took place at this high temperature. The exhumation mechanism that assisted rapid uplifting combined the effects of ongoing tectonic forces with a buoyant instability created by a large amount of anatectic magmas in the middle to lower crust. (2) Beginning at the Early Ordovician, the Famatinian orogeny produced an overall shortening, causing pervasive textural reworking of the Cambrian metamorphic sequences under a high-strain regime. By being adjacent to the Famatinian magmatic arc, the western border of the Cambrian crystalline package absorbed imposed deformation along a crustal scale ductile shear zone. Within this zone, the high-grade metamorphic rocks were reworked and re-hydrated to lower temperature assemblages (<600°C and 3–6 kbar). Early Ordovician subduction-related igneous activity, even though manifested as small plutons, intruded Cambrian crystalline sequences, and experienced textural reworking during Late Famatinian tectonic exhumation. Late Famatinian convergence resulted in west-vergent ductile shear zones that placed Cambrian onto Ordovician crystalline sequences. (3) During post-Famatinian times (360–400 Ma) enduring crustal perturbation produced intra-crustal-derived granitic magmatism. West- to northwest-directed thrusting was concentrated in belts nucleated along crustal-scale tectonic boundaries formed between older tectono-stratigraphic units. As a result, Devonian anatectic granites were formed and tectonically extruded among Pampean and Famatinian crystalline sequences. The post-Famatinian event is also characterised by the intrusion of batholith-scale monzogranites into Pampean and Famatinian crystalline sequences residing in the upper crust.

Crystalline rocks currently exposed in the Sierra de Comechingones show that they crystallised and were exhumed in a setting where tectono-thermal activity lasted, even though it might have waned, until the Middle Palaeozoic. From the latest Neoproterozoic (c. 550 Ma) until the Late Devonian (c. 360 Ma) tectonic activity was intermittently acting, indicating continuous convergence along the proto-Pacific margin of Gondwana.     

Proterozoic metavolcanics from western Sierras Pampeanas terrane, Argentina

A series of medium grade metamorphic rocks of the western sector of the Sierras Pampeanas Terrane in central western Argentina are represented by amphibolites, gneisses and schists derived from sedimentary as well as from igneous rocks. The metavolcanics consist of amphibolites, quartz-K-feldspar-muscovite schists, and hornblende-biotite and biotite-epidote-plagioclase schists. Based on petrographic and geochemical data they are interpreted as originating as basaltic tholeiites, rhyolites and mesosilicic volcanics. The distribution and geochemical behavior are similar to present day western Pacific lavas, mainly those developed on island arcs or heavily attenuated continental crust. Based on these characteristics, an accretionary tectonic model involving a series of island-arc collisions is proposed for the Proterozoic. The complex Proterozoic tectonic history of the western Sierras Pampeanas has been partially obliterated by the emplacement of the Early Paleozoic magmatic arc rocks.     

Multiple data-type processing as applied to the selection of areas with high gold potential in French Guyana

As part of the Guyana Shield, the basement rocks of French Guyana, between latitudes 3° and 3°30′N, consist of greenstones belts of Proterozoic age (2.0–2.1 Ga) enclosed by anatectic granitoïds and migmatites, and of acid or basic intrusives.     

Cordieritite and Leucogranite Formation during Emplacement of Highly Peraluminous Magma: the El Pilon Granite Complex (Sierras Pampeanas, Argentina)

Cordieritites and highly peraluminous granites within the ElPilón granite complex, Sierras Pampeanas, Argentina,were emplaced during a medium-P, high-T metamorphic event duringthe initial decompression of a Cambrian orogen along the southwesternmargin of Gondwana. Very fresh orbicular and massive cordierititebodies with up to 90% cordieritite are genetically associatedwith a cordierite monzogranite pluton and a larger body of porphyriticgranodiorite. The petrogenesis of this association has beenstudied using petrographical, mineralogical, thermobarometric,geochemical, geochronological and isotope methods. The graniticmagmas were formed by anatexis of mid-crustal metamorphic rocksformed earlier in the Pampean orogeny. The cordieritites appearat the top of feeder conduits that connected the source regionlocated at     

P–T–t conditions of high-grade metamorphic rocks of the Garzon Massif, Andean basement, SE Colombia

The metamorphic evolution of the Garzón Massif, Colombia, is established on the basis of the textural, goethermobarometric, and geochronological relationships of the metamorphic minerals. The geothermobarometric data define a clockwise, nearly isothermal decompression path (ITD) for rocks from Las Margaritas migmatites, constrained by four P–T areas: 780–826 °C and 6.3–8.0 kbar, 760–820 °C and 8.0–8.8 kbar, 680–755 °C and 6.6–9.0 kbar, and 630 °C and 4 kbar. For the a garnet-bearing charnockitic gneiss from the Vergel granulites, the path is counterclockwise, constrained by geothermobarometric data of 5.3–6.2 kbar and 700–780 °C and 6.2–7.2 kbar and 685–740 °C. The clockwise ITD path represents a loop followed by the orogen during the transitional granulite–amphibolite metamorphic conditions, probably associated with a subduction process followed by a collisional tectonic event. This subduction framework produced continental crust thickening between 1148 and 1034 Ma and later collision with another continental block approximately 1000 Ma ago. The orogenic exhumation occurred with moderate uplift rate. The counterclockwise trajectory and two metamorphic events suggest a vertical displacement between the Vergel granulites and Las Margaritas migmatites units, because there is no isotopic difference that indicates the existence of different terranes. The data confirm that the metamorphic evolution for this domain was more dynamic than previously believed and includes: (1) metamorphic processes with the generation of new crust with a possible mixture of old material and (2) metamorphic recycling of continental crust. These geological processes characterize a complex Mesoproterozoic orogenic event that shares certain features with the Grenvillian basement rocks participating in the formation of Rodinia.     

A deformed alkaline igneous rock–carbonatite complex from the Western Sierras Pampeanas, Argentina: Evidence for late Neoproterozoic opening of the Clymene Ocean?

A deformed ca. 570 Ma syenite–carbonatite body is reported from a Grenville-age (1.0–1.2 Ga) terrane in the Sierra de Maz, one of the Western Sierras Pampeanas of Argentina. This is the first recognition of such a rock assemblage in the basement of the Central Andes. The two main lithologies are coarse-grained syenite (often nepheline-bearing) and enclave-rich fine-grained foliated biotite–calcite carbonatite. Samples of carbonatite and syenite yield an imprecise whole rock Rb–Sr isochron age of 582 ± 60 Ma (MSWD = 1.8; Sri = 0.7029); SHRIMP U–Pb spot analysis of syenite zircons shows a total range of ²⁰⁶Pb–²³⁸U ages between 433 and 612 Ma, with a prominent peak at 560–580 Ma defined by homogeneous zircon areas. Textural interpretation of the zircon data, combined with the constraint of the Rb–Sr data suggest that the carbonatite complex formed at ca. 570 Ma. Further disturbance of the U–Pb system took place at 525 ± 7 Ma (Pampean orogeny) and at ca. 430–440 Ma (Famatinian orogeny) and it is concluded that the Western Sierras Pampeanas basement was joined to Gondwana during both events. Highly unradiogenic ⁸⁷Sr/⁸⁶Sr values in calcites (0.70275–0.70305) provide a close estimate for the initial Sr isotope composition of the carbonatite magma. Sm–Nd data yield Nd₅₇₀ values of +3.3 to +4.8. The complex was probably formed during early opening of the Clymene Ocean from depleted mantle with a component from Meso/Neo-proterozoic lower continental crust.     

Time constraints on the tectonic evolution of the Eastern Sierras Pampeanas (Central Argentina)

The application of the SHRIMP U/Pb dating technique to zircon and monazite of different rock types of the Sierras de Córdoba provides an important insight into the metamorphic history of the basement domains. Additional constraints on the Pampean metamorphic episode were gained by Pb/Pb stepwise leaching (PbSL) experiments on two titanite and garnet separates. Results indicate that the metamorphic history recorded by Crd-free gneisses (M2) started in the latest Neoproterozoic/earliest Cambrian (553 and 543 Ma) followed by the M4 metamorphism at ~530 Ma that is documented in the diatexites. Zircon ages of 492 Ma in the San Carlos Massif correlate partly with rather low Th/U ratios (<0.1) suggesting their growth by metamorphic fluids. This age is even younger than the PbSL titanite ages of 506 Ma. It is suggested that the fluid alteration relates to the beginning of the Famatinien metamorphic cycle in the neighbouring Sierra de San Luis and has not affected the titanite ages. The PTt evolution can be correlated with the plate tectonic processes responsible for the formation of the Pampean orogene, i.e., the accretion of the Pampean basement to the Río de La Plata craton (M2) and the later collision of the Western Pampean basement with the Pampean basement.     

Crustal Provenance and Cooling of the Basement Complexes of the Sierra de San Luis: An Insight Into the Tectonic History of the Pro to-Andean Margin of Gondwana

The Sierra de San Luis constitutes the southernmost tip of the Eastern Sierras Pampeanas. Its Palaeozoic metamorphic basement units define a key location for the understanding of the accretional history along the proto-Andean margin of Gondwana. Although, it is largely accepted that the polyphase accretional history of the Sierras Pampeanas is preluded by the docking of the Pampean Terrane followed by the Famatinian Orogenic Cycle that involves subduction along the margin of Gondwana and the accretion of the Precordillera (Cuyania) Terrane and finally ceased with the collision of the Chilenia terrane, a vast amount of controversial information concerning the timing and mode of collisions as well as the origin of the different involved crustal fragments within the Eastern Sierras Pampeanas is published. In this paper, those different hypothesis are presented and evaluated under the light of new isotopic data of the Sierra de San Luis. Nd-systematics of the metasedimentary sequences of the Sierra de San Luis indicate that the studied sequences were developed on the Pampean Terrane. An Amazonian origin of the Pampean Terrane that was probably detached from the Arequipa Antofalla Craton is proposed. Furthermore, the correlation of two low-grade phyllitic belts (San Luis Formation) with the widespread Puncoviscana Formation is not supported by Sm-Nd data. It is suggested that the sedimentary precursors of the Pringles Metamorphic Complex and the topping phyllites were sourced on the Pampean Orogen and accommodated in a newly formed back arc basin during the early Famatinian.

The cooling history of the basement complex is recorded by an extensive amount of K-Ar muscovite and biotite ages. A high variability in muscovite ages is only partly related to different intrusion times of two pegmatoid generations. Post Famatinian to Achalian crustal scale mylonite formation (-359 Ma) and a rotational exhumation of the central basement unit are causal for the observed K-Ar muscovite age pattern in the range from 395 Ma to 447 Ma. Therefore, the decrease in metamorphic degree from west to east is the result of the erosion level of a crustal profile from the mid lower crust to the upper crust. An even higher variability in K-Ar biotite cooling ages covering the range from 315 Ma to 418 Ma is related to the slow cooling after the Famatinian Orogenic Cycle or reheating during the Achalian Orogenic Cycle and consequent variable reset of the isotopic system. However, ages recorded by biotite booklets substantiate the hypothesis of a differential exhumation of the basement of the Sierra de San Luis.     

Applying sandstone petrofacies to unravel the Upper Carboniferous evolution of the Paganzo Basin, northwest Argentina

A compositional study of sandstones belonging to the lower section of the Paganzo Group (Middle Carboniferous–Early Permian) in the Paganzo Basin (northwestern Argentina) helps unravel the stratigraphic and paleogeographic evolution of the basin. Three morphotectonic units constitute the complex basement of the basin: (1) to the east, the igneous–metamorphic basement of the Sierras Pampeanas and Famatina systems; (2) to the west, the Precordillera, made up of Early and Middle Paleozoic sedimentary rocks; and (3) the Upper Paleozoic volcanic arc along the western boundary with the Río Blanco Basin. On the basis of sandstone detrital modes of the Lagares, Malanzán, Loma Larga, Guandacol, Tupe, Punta del Agua, and Río del Peñón formations, seven petrofacies are distinguished: quartzofeldespathic (QF), quartzofeldespathic-metamorphic enriched (QF-Lm), quartzofeldespathic-sedimentary enriched (QF-Ls), mixed quartzolithic (QL), quartzolithic-volcanic (QLv), volcanolithic-quartzose (LvQ), and volcanolithic (Lv). The spatial and temporal distribution of these petrofacies suggest an evolutive model for the Upper Paleozoic sedimentary filling of the basin that includes three “petrosomes”: (1) the basement petrosome, a clastic wedge of arkosic composition that diachronically prograded and thinned from east to west; (2) the recycled orogen petrosome, revealing the Protoprecordillera as a positive element in the western Paganzo Basin during the Namurian; and (3) the volcanic arc petrosome, recording volcanic activity along the western margin of Gondwana during the Westphalian.     

Tourmalinites from the Eastern Sierras Pampeanas, Argentina

In the eastern Sierras Pampeanas, Central Argentina, tourmalinites and coticules are found in close association with stratabound scheelite deposits in metamorphic terranes. In Sierra Grande (Agua de Ramón and Ambul districts) and Sierra de Altautina, tourmalinites are associated with stratabound scheelite deposits related to orthoamphibolites. In the Pampa del Tamboreo area, tourmalinites are located in biotite schists stratigraphically related to acid to intermediate metavolcanic rocks and scheelite-bearing quartzites.The mineral chemistry and boron isotopic compositions of tourmalinite-hosted and vein-hosted tourmalines are investigated. Overall, the tourmalines belong to the dravite-schorl series and are generally aluminous; Fe/(Fe+Mg) ranges from 0.33 to 0.85, Al/(Al+Fe+Mg) from 0.66 to 0.76 and the amount of X-site vacancy (0.12–0.48) indicates significant foitite components. Their boron isotopic compositions (δ¹¹B) are from −24.0‰ to−15.0‰.Similar mineral chemistries and boron isotopic values for tourmaline in tourmalinites related to stratabound scheelite mineralisation and in tungsten-bearing quartz veins suggest a common source for the boron and probably the tungsten. The field, chemical and isotopic relationships are consistent with tungsten and boron in quartz-vein deposits being remobilised from stratabound scheelite and tourmalinite, dominantly by liquid-state transfer associated with regional shear zones. Tungsten and boron in the original sedimentary sequence (now meta-exhalites) are ascribed to volcanogenic exhalations.     

Large P–T gap between Ballantrae blueschist/garnet pyroxenite and surrounding ophiolite, southern Scotland, UK: Diapiric exhumation of a Caledonian serpentinite mélange

The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.     

Fluid–rock interaction at the roots of an Eopaleozoic epithermal system, Sierra Norte de Córdoba, Argentina: Paragenesis, thermometry and fluid sources

A deep epithermal vein system hosted in Late Proterozoic to Cambrian granodiorite has been identified in the Sierra Norte de Córdoba, the easternmost range of the Sierras Pampeanas Orientales of Argentina. The vein swarm extends over an area of 3 km² parallel to a mylonitic belt and formed in fractured granodiorite. Thicknesses of veins are less than 0.5 m and their visible strike length is less than 100 m. Veins are either barren or weakly mineralized in base-metal sulfides. Most veins have mineral associations dominated by calcite and quartz with lesser amounts of chlorite, sericite, pyrite, and minor illite. In other less exposed albite-rich, adularia-bearing veins, chalcopyrite, bornite, galena, sphalerite, chalcocite and covellite may occur. The widespread occurrence of bladed calcite without any petrographic or microthermometric evidence of boiling implies that this particular habit of calcite may also develop under sub-near boiling fluid conditions. Thermometric calculations based on fluid inclusion data, chlorite composition and oxygen isotopes in the quartz–calcite pair, constrain the formation of the system between 300 and 350 °C, at pressures between 42 and 64 MPa (1.5–2.3 km). Stable isotope data suggest that W/R interaction might have been the most probable mechanism of alteration, involving the participation of meteoric fluids; nevertheless, the metallic signature of some weakly mineralized veins as well as intermediate fluid inclusion salinities favor a magmatic input and a mixed origin for the fluids. Textures and mineral associations, as well as the absence of evidence of boiling in fluid inclusions, all suggest that the silica–carbonate vein system formed deeper than typically shallow Au and Ag-bearing boiling solutions. A 485 (±25) Ma lamprophyre dike crosscuts some of these veins locally producing metasomatic reactions and skarn formation, which constrains the age of the hydrothermal system to the Cambrian-Early Ordovician time span.