Redox state of amphibole-bearing mantle peridotite from Nüshan, Anhui Province in eastern China and its implications

Using secondary spinel standard method, we have measured precisely the compositions of spinels of amphibole-bearing mantle peridotite xenoliths from Nüshan in eastern China, and calculated the mantle oxygen fugacities recorded by the xenoliths. Results indicate that the mantle metasomatism for forming amphiboles in Nüshan region of Anhui has resulted in the decrease of mantle redox, which is in contrast with theoretical estimation and previous research results from other areas around the world. Combining with related studies on the mantle of eastern China, we give a reasonable explanation to the 'new finding' and further elucidate the compositions and nature of mantle fluids in eastern China.     

Redox state of amphibole-bearing mantle peridotite from Nüshan, Anhui Province in eastern China and its implications

Using secondary spinel standard method, we have measured precisely the compositions of spinels of amphibole-bearing mantle peridotite xenoliths from Nüshan in eastern China, and calculated the mantle oxygen fugacities recorded by the xenoliths. Results indicate that the mantle metasomatism for forming amphiboles in Nüshan region of Anhui has resulted in the decrease of mantle redox, which is in contrast with theoretical estimation and previous research results from other areas around the world. Combining with related studies on the mantle of eastern China, we give a reasonable explanation to the ‘new finding’ and further elucidate the compositions and nature of mantle fluids in eastern China.     

Petrological feature of spinel lherzolite xenolith from Oki-Dogo Island: An implication for variety of the upper mantle peridotite beneath southwestern Japan

Abstract   Spinel lherzolite is a minor component of the deep-seated xenolith suite in the Oki-Dogo alkaline basalts, whereas other types of ultramafic (e.g. pyroxenite and dunite) and mafic (e.g. granulite and gabbro) xenoliths are abundant. All spinel lherzolite xenoliths have spinel with a low Cr number (Cr#; < 0.26). They are anhydrous and are free of modal metasomatism. Their mineral assemblages and microtextures, combined with the high NiO content in olivine, suggest that they are of residual origin. But the Mg numbers of silicate minerals are lower (e.g. down to Fo₈₆) in some spinel lherzolites than in typical upper mantle residual peridotites. The clinopyroxene in the spinel lherzolite shows U-shaped chondrite-normalized rare-earth element (REE) patterns. The abundance of Fe-rich ultramafic and mafic cumulate xenoliths in Oki-Dogo alkali basalts suggests that the later formation of those Fe-rich cumulates from alkaline magma was the cause of Fe- and light REE (LREE)-enrichment in residual peridotite. The similar REE patterns are observed in spinel peridotite xenoliths from Kurose and also in those from the South-west Japan arc, which are non-metasomatized in terms of major-element chemistry (e.g. Fo > 89), and are rarely associated with Fe-rich cumulus mafic and ultramafic xenoliths. This indicates that the LREE-enrichment in mantle rocks has been more prominent and prevalent than Fe and other major-element enrichment during the metasomatism.     

The water content and hydrogen isotope composition of continental lithospheric mantle and mantle-derived mafic igneous rocks in eastern China

The water contents of minerals and whole-rock in mantle-derived xenoliths from eastern China exhibit large variations and are generally lower than those from other on- and off-craton lithotectonic units. Nevertheless, the water contents of mineral and whole-rock in Junan peridotite xenoliths, which sourced from the juvenile lithospheric mantle, are generally higher than those elsewhere in eastern China. This suggests that the initial water content of juvenile lithospheric mantle is not low. There is no obvious correlation between the water contents and Mg^# values of minerals in the mantle xenoliths and no occurrence of diffusion profile in pyroxene, suggesting no relationship between the low water content of mantle xenolith and the diffusion loss of water during xenolith ascent with host basaltic magmas. If the subcontinental lithospheric mantle (SCLM) base is heated by the asthenospheric mantle, the diffusion loss of water is expected to occur. On the other hand, extraction of basaltic melts from the SCLM is a more efficient mechanism to reduce the water content of xenoliths. The primary melts of Mesozoic and Cenozoic basalts in eastern China have water contents, as calculated from the water contents of phenocrysts, higher than those of normal mid-ocean ridge basalts (MORB). The Mesozoic basalts exhibit similar water contents to those of island arc basalts, whereas the Cenozoic basalts exhibit comparable water contents to oceanic island basalts and backarc basin basalts with some of them resembling island arc basalts. These observations suggest the water enrichment in the mantle source of continental basalts due to metasomatism by aqueous fluids and hydrous melts derived from dehydration and melting of deeply subducted crust. Mantle-derived megacrysts, minerals in xenoliths and phenocrysts in basalts from eastern China also exhibit largely variable hydrogen isotope compositions, indicating a large isotopic heterogeneity for the Cenozoic SCLM in eastern China. The water content that is higher than that of depleted MORB mantle and the hydrogen isotope composition that is deviated from that of depleted MORB mantle suggest that the Cenozoic continental lithospheric mantle suffered the metasomatism by hydrous melts derived from partial melting of the subducted Pacific slab below eastern China continent. The metasomatism would lead to the increase of water content in the SCLM base and then to the decrease of its viscosity. As a consequence, the SCLM base would be weakened and thus susceptible to tectonic erosion and delamination. As such, the crust-mantle interaction in oceanic subduction channel is the major cause for thinning of the craton lithosphere in North China.     

Alkali-rich porphyry and its relation with intraplate deformation of north part of Jinsha River belt in western Yunnan, China

A suite of alkali-rich porphyry with 26. 5–37. 6Ma occur along the Jinsha River suture zone in west Yunnan. They are characterized by LREE-rich distribution patterns and no Eu anomaly. These porphyries have formed in post-collisional environment; (⁸⁷Sr/^8bSr) of porphyries, amphibolite xenolithes and associated basalts are 0.707 3, 0.706 5-0.707 l and0.705 8-0.706 5, E_Nd(T) are -3.4-6.3, -2.1-7.4 and -3.3 respectively. Pb isotope compositions of these rocks also show a little difference. The evidence shows that the porphyry could be derived from partial melting of the “crust-mantle mixed layer”. The relation between Cenozoic magmatism and intraplate deformation since Paleogene has been discussed. Project supported by the Nat~onal Natural Science Foundation of China (Grant Nos. 49472102 and 49232030).     

Characteristics of subcontinental lithospheric mantle beneath Baegryeong Island, Korea: Spinel peridotite xenoliths

Abstract   Geochemical data on Baegryeong Island spinel peridotites found in Miocene alkali basalt provide the information for lithosphere composition, chemical processes, equilibrium pressure and temperature conditions. Spinel peridotite xenoliths, showing transitional textures between protogranular and porpyroclastic textures, were accidentally trapped by the ascending alkali basalt magma. The xenoliths originate at depths from 50 to 70 km with a temperature range from 800 to 1100°C. The variations of modal and mineral compositions of the spinel peridotite xenoliths indicate that the xenoliths have undergone 1–10% fractional melting. The spinel peridotites from Baegryeong Island have undergone cryptic mantle metasomatism subsequent to melt extraction. Metasomatic agent of enriched spinel peridotite xenoliths was carbonatite melt.     

郯庐断裂带晚第三纪以来的浅部挤压活动与深部过程

郯庐断裂带晚第三纪以来持续遭受着挤压 ,使前期大规模的断陷盆地抬升、消亡 ,近代还是中国东部最大的地震活动带。断裂带所遭受的近WE向的挤压 ,是西太平洋弧后扩张和印度板块向北碰撞中的构造挤出作用产生的区域动力。断裂带在新生代挤压活动中切入上地幔 ,出现了地幔剪切、地幔交代、部分熔融等深部过程 ,最终形成了挤压背景下的陆内断裂带大规模的玄武岩喷发     

Major and trace element studies on garnets from Palaeozoic kimberlite-borne mantle xenoliths and megacrysts from the North China craton

Palaeozoic kimberlites from Mengyin, Shandong and Fuxian, Liaoning, eastern China, contain plenty of mantle xenoliths (peridotites, eclogites) and megacrystic minerals. In-situ electron and ion microprobe analyses on garnets from these xenoliths and megacrysts as well as relevant theoretical modeling reveal that these garnets were more or less affected by kimberlitic silicate melts prior to the encapsulation, in which eclogitic garnet from Fuxian, Liaoning Province, was little affected by mantle metasomatism, representing the primitive depleted mantle composition. In contrast, garnet from Mengyin, Shandong Province, and all megacrystic garnets were completely modified by metasomatic melts/fluids and reached perfectly chemical equilibrium, thus reflecting the characteristics of the enriched mantle. It is inferred that old lithospheric mantle beneath the North China craton was fairly strongly modified by metasomatism before Palaeozoic kimberlite emplacement.     

New insights into the Re-Os systematics of sub-continental lithospheric mantle from in situ analysis of sulphides

The Os isotopic compositions of mantle rocks generally are considered to be established during melt-depletion events and to be robust to subsequent disturbances (e.g. metasomatism). Consequently, Os isotopes are used to date the main melting event that a mantle section has undergone, i.e. transformation of fertile asthenospheric material into a depleted, buoyant lithosphere. However, Os resides almost entirely in Fe-Ni-Cu sulphides, which can be very mobile under mantle conditions. In situ laser ablation multi-collector ICP-MS measurement of Re/Os isotopic ratios in sulphides from spinel peridotite xenoliths demonstrates that whole-rock Os-isotope signatures record the mixing of multiple sulphide populations. Sulphides residual after melting events have unradiogenic Os isotopic compositions reflecting ancient melt depletion; those introduced by later metasomatism events contain more radiogenic Os. Therefore, the whole-rock Os isotopic signature can be strongly altered by metasomatic processes, and studies of mantle-derived xenoliths show that such disturbance is quite common in the lithospheric mantle. Because melt-depletion ages estimated from individual sulphide inclusions are systematically older than those obtained from whole-rock analysis, caution is essential in the interpretation of the Os model ages derived from whole-rock analysis, and their use and abuse in geodynamic models. This work suggests that sulphide could become a key phase in unravelling the formation and evolution of the lithosphere.     

Geodynamic significance of ultramafic xenoliths from Eastern Serbia: Relics of sub-arc oceanic mantle?

A suite of highly depleted peridotite xenoliths in East Serbian Palaeogene basanites represents the lithospheric mantle beneath the Balkan Peninsula. The xenoliths are harzburgites, clinopyroxene-poor lherzolites and rare dunites. They contain mostly <5 vol.% of modal clinopyroxene and are characterized by high Mg# in silicates (>91), high Cr# in spinel (mostly 0.5–0.7), and by distinctively low Al₂O₃ contents in orthopyroxene (mostly 1–2 wt.%). They have experienced some mantle metasomatism which has slightly obscured their original composition. Nevertheless, the general characteristics of the xenoliths imply a composition which is significantly more depleted than most non-cratonic sub-continental mantle xenolith suites, as well as orogenic peridotites and abyssal peridotites. Geological and compositional evidence suggests that the xenoliths do not represent Archean mantle. The existence of Proterozoic mantle cannot be entirely excluded, although it is in disagreement with geological evidence. On the other hand, the studied xenoliths are compositionally very similar to peridotites of modern oceanic sub-arc settings. The existence of such a depleted lithospheric mantle segment is also inferred from the presence of rare orthopyroxene-rich xenoliths in the same suite. These are interpreted to have originated as lithospheric precipitates of high-Mg, SiO₂-saturated magmas that require a highly depleted mantle source. Such source is typically required by boninitic-like magmas of intraoceanic suprasubduction settings. A proposed geodynamic model to explain these observations involves accretion or underplating of the lower parts of the Tethyan oceanic lithosphere during the Upper Jurassic closure of the eastern branch of the Vardar ocean.     

Intracratonic asthenosphere upwelling and lithosphere rejuvenation beneath the Hoggar swell (Algeria): Evidence from HIMU metasomatised lherzolite mantle xenoliths

The mantle xenoliths included in Quaternary alkaline volcanics from the Manzaz-district (Central Hoggar) are proto-granular, anhydrous spinel lherzolites. Major and trace element analyses on bulk rocks and constituent mineral phases show that the primary compositions are widely overprinted by metasomatic processes. Trace element modelling of the metasomatised clinopyroxenes allows the inference that the metasomatic agents that enriched the lithospheric mantle were highly alkaline carbonate-rich melts such as nephelinites/melilitites (or as extreme silico-carbonatites). These metasomatic agents were characterized by a clear HIMU Sr–Nd–Pb isotopic signature, whereas there is no evidence of EM1 components recorded by the Hoggar Oligocene tholeiitic basalts. This can be interpreted as being due to replacement of the older cratonic lithospheric mantle, from which tholeiites generated, by asthenospheric upwelling dominated by the presence of an HIMU signature. Accordingly, this rejuvenated lithosphere (accreted asthenosphere without any EM influence), may represent an appropriate mantle section from which deep alkaline basic melts could have been generated and shallower mantle xenoliths sampled, respectively. The available data on lherzolite xenoliths and alkaline lavas (including He isotopes, Ra < 9) indicate that there is no requirement for a deep plume anchored in the lower mantle, and that sources in the upper mantle may satisfactorily account for all the geochemical/petrological/geophysical evidence that characterizes the Hoggar swell. Therefore the Hoggar volcanism, as well as other volcanic occurrences in the Saharan belt, are likely to be related to passive asthenospheric mantle uprising and decompression melting linked to tensional stresses in the lithosphere during Cenozoic reactivation and rifting of the Pan–African basement. This can be considered a far-field foreland reaction of the Africa–Europe collisional system since the Eocene.     

Geochemistry of peridotite xenoliths in alkali basalts from Jeju Island, Korea

Abstract   Ultramafic xenoliths in alkali basalts from Jeju Island, Korea, are mostly spinel lherzolites with subordinate amounts of spinel harzburgites and pyroxenites. The compositions of major oxides and compatible to moderately incompatible elements of the Jeju peridotite xenoliths suggest that they are residues after various extents of melting. The estimated degrees of partial melting from compositionally homogeneous and unfractionated mantle to form the residual xenoliths reach 30%. However, their complex patterns of chondrite-normalized rare earth element, from light rare earth element (LREE)-depleted through spoon-shaped to LREE-enriched, reflect an additional process. Metasomatism by a small amount of melt/fluid enriched in LREE followed the former melt removal, which resulted in the enrichment of the incompatible trace elements. Sr and Nd isotopic ratios of the Jeju xenoliths display a wide scatter from depleted mid-oceanic ridge basalt (MORB)-like to near bulk-earth estimates along the MORB–oceanic island basalt (OIB) mantle array. The varieties in modal proportions of minerals, (La/Yb)_N ratio and Sr-Nd isotopes for the xenoliths demonstrate that the lithospheric mantle beneath Jeju Island is heterogeneous. The heterogeneity is a probable result of its long-term growth and enrichment history.     

Element diffusion ability in metasomatic agents and its effect on chemical characteristics of metasomatized peridotites

The partial melting and metasomatism are two most important geological processes of changing chemical compositions of mantle. Extracting partial melt from primitive mantle leads residual mantle to deplete in- compatible elements, whereas the metasomatism …     

Ultramafic xenoliths in mesozoic diorite in west shandong province

Deep-seated xenoliths are common in alkali ba-salts, kimberlites and lamprophyres[1]. These host rocks are all basic or ultrabasic volcanic and subvol-canic rocks originating from mantle. Reports of ul-tramafic xenoliths found in plutons are uncommon except those of Mesozoic diorites in North China[2—6]. This paper provides detailed mineralogy, petrology and geochemistry of ultramafic xenoliths in Tietong-gou pluton, Laiwu, Shandong Province, and discusses the possibility of their deep-sea…     

Tectonic setting of porphyry Cu–Au, Mo and related mineralization associated with contrasted Neogene magmatism in the Western Sulawesi Arc

The Neogene Western Sulawesi Arc, from the south going northwards, can be divided into three magmatic provinces of K alkaline–shoshonitic (AK-SH), high-K calc-alkaline (KCA), and low-K–normal calc-alkaline (TH-CA) affinity, referred to, respectively, as South, Central and North Sulawesi. The origin of this magmatism in terms of subduction and collision processes is contentious. Four widely spaced Cu–Au porphyry, and one Mo porphyry district(s) occur along the Western Sulawesi Arc, with the North Sulawesi province being the most mineralized. This porphyry mineralization is part of a regional belt that extends north into the Philippines and possibly south to the Sunda Arc. In western Sulawesi, common features that define the porphyry belt are obscure because the porphyry districts cannot be simply related, either in terms of their magmatic affinity, nature of basement, or tectonic setting. Nevertheless, it can be suggested that the generation of porphyry Mo systems requires involvement of continental crust in terms of magma source, while Au-rich porphyry systems are independent of the nature of the crust, and are derived from a mantle source.     

Mineral chemistry of spinel peridotite xenoliths from Baengnyeong Island, South Korea, and its implications for the paleogeotherm of the uppermost mantle

Abstract   The mantle-derived xenoliths entrained in the Pliocene basanite from Baengnyeong Island, South Korea, are spinel lherzolites and spinel harzburgites. The overall compositional range of the Baengnyeong xenoliths matches that of the post-Archean xenoliths of lithospheric mantle origin from eastern China, but without any compositional evidence for a refractory Archean mantle root. Mineral compositions of the xenoliths have been used to estimate the equilibrium temperatures and pressures, and to construct a paleogeothermal gradient of the source region. The xenolith-derived paleogeotherm is constrained from about 820°C at 7.3 kbar to 1000°C at 20.6 kbar. Like those from the post-Archean Chinese xenoliths of lithospheric mantle origin, the Baengnyeong geotherm is considerably elevated relative to the conductive models at the depth of the crust–mantle boundary, reflecting a thermal perturbation probably related to lithospheric thinning. There is no significant P / T difference between harzburgite and lherzolite, which suggests that the harzburgites are interlayered with lherzolites within the depth interval beneath Baengnyeong Island.     

华北地区新生代碱性玄武岩中超镁铁质捕掳体的初步研究(续)

(二)由新变晶大小估计地幔应力近些年来,据天然橄榄石的变形结构、显微亚构造及实验研究的结果,提出了多种估计上地幔应力的方法。Nicolas(1978)曾对此进行过综合评述。归纳起来有两类方法,一类是建立在位错显微构造基础上的方法,如根据橄榄石的位错密度和位错曲率与应力之间的经验关系或亚颗粒大小与应力之间的关系来估算应力值;另一类方法是由动力重结晶的橄榄石晶粒(新变晶)的大小来估计上地幔应力的方法。对同一样品采用上述诸方法常不能得到相     

Trace element and Sr and Nd isotope geochemistry of peridotite xenoliths from the Eifel (West Germany) and their bearing on the evolution of the subcontinental lithosphere

Peridotite xenoliths from the Eifel can be divided into incompatible element-depleted and -enriched members. The depleted group is restricted to dry lherzolites whereas the enriched group encompasses dry harzburgites, dry websterite and amphibole and/or phlogopite-bearing peridotites. Isotopically the depleted group is very diverse with¹⁴³Nd/¹⁴⁴Nd ranging from 0.51302 to 0.51355 and⁸⁷Sr/⁸⁶Sr from 0.7041 to 0.7019, thus occupying a field larger than expected for oceanic-type subcontinental mantle. These xenoliths are derived from a mantle which appears to have diverged from a bulk-earth Nd and Sr isotopic evolution path 2 Ga ago as a consequence of partial melting. The combination of high¹⁴³Nd/¹⁴⁴Nd with high⁸⁷Sr/⁸⁶Sr in some members of the depleted-xenoliths suite is likely to be the result of incipient reaction with incompatible element-enriched fluids in the mantle. In the enriched group such reactions have proceeded further and erased any pre-enrichment isotope memory resulting in a smaller isotopic diversity (¹⁴³Nd/¹⁴⁴Nd 0.51256–0.51273,⁸⁷Sr/⁸⁶Sr 0.7044–0.7032). An evaluation of SmHf and YbHf relationships suggests that the amphibole-bearing lherzolites and harzburgites acquired their high enrichment of light rare earth elements by fluid infiltration into previously depleted peridotite rather than by silicate melt-induced metasomatism. Upper mantle composed of such metasomatized peridotites does not represent a potential source for the basanites and nephelinites from the Eifel. The isotopic and chemical diversity of the subcontinental lithospheric part of the mantle may result from it having remained isolated from the convecting mantle for times > 1 Ga.     

Mineralization episode of porphyry copper deposits in the Jinshajiang-Red River mineralization belt: Re-Os dating

Re-Os isotopic dating for the molybdenites from the porphyry copper deposits of the Jinshajiang-Red River mineralization belt in Yunnan Province yields isochron ages of 33.9±1.1 Ma for the Machangqing deposit and 34.4±0.5 Ma for the Tongchang deposit. This result shows that both the Machangqing and the Tongchang porphyry Cu-Mo deposits from two different ore-fields formed simultaneously. This new data and the published Re-Os model ages of molybdenite (35.4 Ma, 35.9 Ma, 36.2 Ma) of the Yulong porphyry copper deposit in Tibet, which is located in the same Jinshajiang-Red River mineralization belt as the Machangqing deposit and the Tongchang deposit, suggest that these three Cenozoic porphyry copper deposits in the Jinshajiang-Red River mineralization belt were contemporary for their mineralization episode. That is to say, even their present locality is far away and nearly iso-distantly distributed, these three porphyry Cu(Mo) deposits belong to the same mineralization episode at the end of Eocene.     

由甘肃宕昌好梯幔源包体推导的上地幔物质组成、热结构和流变学特征

新生代火山岩中的幔源包体可以提供有关上地幔的直接信息。通过对采自甘肃宕昌县好梯乡的幔源橄榄岩包体的详细研究 ,探讨该地区上地幔的热结构和流变学特征 ,并与华北地区进行对比。研究结果表明 ,该区自壳幔边界以下至 75km深处的上地幔主要由尖晶石二辉橄榄岩组成 ,75km以下则主要由石榴石二辉橄榄岩组成 ,方辉橄榄岩只占少数 ;与华北地区没有明显的差异。由包体平衡温度、压力建立的上地幔地温线低于华北地区地温线 ;确定的壳幔边界在 5 2km左右 ,莫霍界面附近为下地壳物质与尖晶石二辉橄榄岩的过渡带 ;岩石圈底界深度约为 12 0km左右。根据包体的研究结果建立了研究区上地幔的差异应力、应变速率和等效黏滞度剖面。结果表明 ,该区新生代时期存在软流层的底辟 ,以及相应的岩石圈的减薄 ,但其规模明显小于华北地区。这些结果表明该区处在中国东部大陆裂谷带和中国中部克拉通块体群的过渡带