共查询到20条相似文献,搜索用时 62 毫秒
2.
海水中溶解有机磷的测定方法 总被引:9,自引:2,他引:9
磷和氮一样,都是海洋环境中的重要生源要素,其在水环境中的时空分布控制着海洋生态系统中的初级生产过程.在大洋或深海区,氮的供应相对不足常是初级生产的制约因素,但在浅海区,特别是河口和海湾,由于农业施肥、城市污水及大气干湿沉降等的作用,氮/磷比值常远高于Redfield比值,从而使磷成为初级生产的制约因素[1-6]. 相似文献
3.
海水中硼的快速测定方法 总被引:2,自引:2,他引:2
海水、卤水及废水等样品中微量硼的测定方法很多,其中姜黄素法是测硼灵敏度最高的一种,现已被列入美国《水和废水标准检验法》第13版中。我们以姜黄素-分光光度法测定海水中微量硼时,在标准曲线中加入了与海水样相当的无硼人工海水,消除了阴阳离子的干扰,在半年多的海水中硼的间断性测定试验方面,获得了较满意的结果,其相对标准偏差为3.1%,测一批样品仅需4小时,因此,该法是测定海水中硼的快速准确的较好方法。 相似文献
4.
5.
黄色物质是海洋中的有色可溶性有机物,是重要的水质参数之一。目前实验室黄色物质样品测量技术虽已有标准参考,但测量过程的一些重要变量对测量结果的定量影响仍未明确。基于2016年东印度洋南部水体综合调查所得的实测样品,分析了参比纯水是否过滤和过滤压力等因素对测量结果准确性的具体影响,发现:(1)参比纯水未过滤会使测量结果明显高估,ag(350)和ag(440)的高估程度分别为0.137 m~(-1)和0.114 m~(-1);(2)过滤压力的不同对测量结果影响较为明显,过滤压力越大,测得的吸收系数越大,对于a_g(350),150 mm Hg相对100 mm Hg的平均偏差为0.195 m~(-1),200 mm Hg相对150 mm Hg的平均偏差为0.058 m~(-1);对于ag(440),150 mm Hg相对100mm Hg的平均偏差为0.168 m~(-1),200 mm Hg相对150 mm Hg的平均偏差为0.064 m~(-1)。本文的实验研究可促进实验者对规范中黄色物质样品处理过程以及相关参数设置原因和意义的理解。 相似文献
6.
本文介绍了海水中砷标准物质的研制过程,其中包括溶液的配制、均匀性和稳定性检验,标样的分析方法。并对标准物质的定值数据进行统计处理,两种浓度的定值结果分别为:1.00μg/cm3±0.04μg/cm3和51.0μg/dm3±2.6μg/dm3。两种浓度砷标准物质的稳定期均为一年 相似文献
7.
8.
9.
10.
11.
The concentration level of cadmium (Cd) and the regeneration related to phosphate (PO4) were examined at two stations (CM10, CM12) in the eastern Japan Basin in July 1998. The observed Cd concentrations were around 0.2–0.3 nM and 0.5–0.6 nM in the surface and deep layers (Japan Sea Proper Water; JSPW), respectively; the concentration of Cd in the JSPW was much lower than that in the Pacific deep water, which is attributed to its specific formation system (which driven by the winter convection of the surface layer within the Japan Sea, thereafter descending to the deep layer) connected with the relatively active vertical mixing in the Japan Sea. A plot of Cd against PO4 showed good linearity with positive y-intercept values, suggesting that the excess Cd was apparently not available in the biogeochemical cycle. The molecular ratios of consumed O2 to regenerated Cd and PO4 in the JSPW were 688,000, 140 and 881,000, 146 for CM10 and CM12, respectively, and a lower preformed Cd concentration (around 0.37 nM) was also estimated in the JSPW, different from that of the North Pacific deep water (613,000 for Cd, 170 for PO4, and 0.64 nM of preformed Cd). 相似文献
12.
黄东海非色素颗粒与黄色物质的吸收系数光谱模型研究 总被引:26,自引:3,他引:26
黄色物质和非色素颗粒物是我国近岸水体重要的水色成分,对其光谱特性的了解,直接关系到水色遥感色素算法的精度。文章对2003春季黄东海航次获取的数据分析处理,得到黄色物质吸收系数斜率经验值Sg=0.0175和非色素颗粒物吸收系数斜率经验值Sd=0.0103。经采用2002春季和2003秋季同海区试验数据进行检验,结果表明得到的光谱模型具有较强的区域适用性。 相似文献
13.
于2009年6~10月采集草鱼(Ctenopharyngodon idellus)不同养殖模式围隔底泥的样品,对上覆水和间隙水中营养盐形态与含量进行分析,探讨间隙水和上覆水中营养盐浓度间的相关关系。结果表明:草鱼不同养殖模式围隔大部分间隙水中营养盐浓度要高于上覆水,上覆水与间隙水中PO43--P浓度呈极显著的正相关性(P<0.01)。上覆水和间隙水中的NO2--N和NO3--N浓度垂直分布特征随月变化规律较一致。养殖期间,间隙水溶解态无机氮(DIN)中NH4+-N比例最高,占95%以上。间隙水中NH4+-N浓度随深度增加而逐渐升高(0~10cm),而NO2--N和NO3--N浓度则随深度增加而减小(0~4cm)。表层底泥在0→1cm方向PO43--P浓度明显增加,从2~3cm层后多数养殖模式下浓度缓慢下降,而4→10cm方向上浓度会随深度增加而明显下降。总体而言,三元混养组中(GSL2)上覆水中营养盐的浓度一般要低于GSL1组和GSL3组,且养殖期间该组底层水DO浓度要高于GSL1组和GSL3组,初步认为是一种较为优化的草鱼混养模式。 相似文献
14.
Marmara Sea (MS) lies in the strategic crossroad, accommodating one of the busiest shipping routes in the world. In general, there is a two-layer current system in the MS and Turkish Straits system; the brackish waters originating in the Black Sea (BS) (18 PSU) moving southward to the Aegean Sea (AS), and a lower layer return flow of saltier Aegean waters (38.5 PSU) back to the BS. This variability poses a challenging task within the modeling perspective. In this research, 3D hydrodynamic modeling of MS is performed in order to investigate the spatial and temporal behavior of elevations between years 2000 and 2015. During the calibration process, the grid configuration, time step, and model coefficients (Manning bed roughness coefficient, a wind drag coefficient and horizontal viscosity are coefficients) are adjusted until the computed solution produced the best match to the observed data such as water surface elevations, velocities, and net discharges. To this end, a series of simulations are made. As a result, the observed and the predicted water surface elevations follow each other very closely. The developed model could accurately estimate the net discharge as well. In order to understand the behavior of MS, elevation pattern is calculated and depicted both on annual and seasonal scales. It is demonstrated that the influence of seasonally varying strong fresh water river discharges of Danube in BS have strong influence on the water mass characteristics of the MS. 相似文献
15.
黄东海灾害地质类型及声学反射特征 总被引:2,自引:0,他引:2
高分辨率声学剖面资料是识别海洋灾害地质现象的有效手段。该文利用国家“12 6”专项调查在黄东海海域获得的各种声学剖面及历史资料 ,在黄东海海底及浅层识别出多种灾害地质类型 ,如潮成沙脊、沙波、古河道、断层、浅层气等。根据对它们的声学特征及成因机制的分析 ,作者认为 :潮流是黄东海海底表层灾害地质形成的主要动力因素 ;而浅层灾害地质因素以古河道、断层、浅层气等为主。 相似文献
16.
叙述了目前海水现场水色测量的弊端 ,指出数字化海洋水色的潜在应用价值 ;根据色度学及色度学的三原色基本理论 ,确定海洋现场水色的色度要素 ,使海洋现场水色标号统一为物理学中严格的颜色物理量。结合 1 996年渤海水域光谱反射测量 ,对渤海水域 4个典型站位的反射光谱做了水色色度分析 ,并进行了 2种测量方法的比较 相似文献
17.
18.
19.
针对渤海及附近海区的曲折岸线变化以及水文资料时空分布不均匀性的特点,使用四维客观分析LOESS方法得到逐月气候态盐度场。结果表明:渤海南部沿岸水扩展和运移受季风影响显著。冬季沿岸水向渤海湾和莱州湾堆积,形成沿山东半岛龙口海岸东向爬行的水舌,该水舌在蓬莱水域向东扩展;夏季沿岸水向渤海中部冲溢,特别是在黄河口附近,其核心区厚度可达8 m,可扩展到119°30′E处,同时莱州湾内的沿岸水向湾内西部收缩。冬季渤海海峡呈现显著北进南出水交换态势;夏季渤海海峡定常流方式的水交换特征不明显。 相似文献
20.
Naoto Takahata Yuji Sano Keika Horiguchi Kotaro Shirai Toshitaka Gamo 《Journal of Oceanography》2008,64(2):293-301
We have collected fifty-five seawater samples at seven stations at various depths in the Yamato and Japan Basins of the Japan
Sea and measured their helium isotopic ratios. The 3He/4He ratios vary from 0.997 Ratm to 1.085 Ratm where Ratm is the atmospheric ratio. The maximum 3He excesses about 8%, are observed at mid-depth (1000 m), and these values are significantly lower than those observed in
deep Pacific waters. This implies that mantle-derived helium in deep Pacific water cannot enter the Japan Sea since it is
an almost landlocked marginal sea. The observed 8% excess 3He may be attributable to the decay product of tritium. Slightly higher 3He/4He ratios in the Bottom Water were observed in the Yamato Basin than in the Japan Basin. The ventilation ages of seawater
shallower than 1000 m are calculated as about 5 to 20 years, which is consistent with the CFC ages reported in the literature.
There is a positive correlation between the apparent oxygen utilization and 3H-3He ages. The estimated oxygen utilization rate from the correlation in a layer between 500 m and 1000 m is about 3 μmol/kg/yr, which is similar to that in the eastern subtropical North Atlantic. 相似文献