Environmental evolution recorded by lipid biomarkers from the Tawan loess–paleosol sequences on the west Chinese Loess Plateau during the late Pleistocene

This study provides a reconstruction of the environmental evolution since 128 ka recorded by the lipid biomarkers of the C₁₅–C₃₅ n-alkanes, the C₁₃–C₃₃ n-alkan-2-ones and the C₁₂–C₃₀ n-alkanols isolated from the Tawan loess section, Northwest China. Variations in paleoenvironment are reconstructed from the values of the carbon preference index (CPI), the average chain length (ACL), the L/H (ratio of lower-molecular-weight to higher-molecular-weight homologues), the n-alkane C₂₇/C₃₁ ratios, and the n-alkan-2-one C₂₇/C₃₁ ratio. These parameters indicate the dominance of grasses over the west Chinese Loess Plateau (CLP) during the late Pleistocene. Lower values of the CPI and the ACL values, respectively, indicate stronger microbial reworking of organic matter and changes in plant species, which are both indicative of a warmer-wetter environment. Furthermore, the fluctuations of environment recorded in the Tawan section exhibit ten phases that show obvious cycles between warm periods and cold intervals. This study reveals that changes in the biomarker proxies agree well with changes in the magnetic susceptibility and grain size, and it indicates a huge potential for paleoenvironmental reconstructions by using the n-alkan-2-one and n-alkanol proxies.     

Impact of tunneling on regional groundwater flow and implications for swelling of clay–sulfate rocks

Tunnels play a key role in many transportation concepts. The swelling of clay–sulfate rocks leads to serious damage to many tunnels crossing such rock, producing great difficulties and high extra costs in tunnel engineering. The swelling is caused by the transformation of the sulfate mineral anhydrite into gypsum, entailing a 60% volume increase. The transformation involves anhydrite dissolution in water, transport of the solution with groundwater flow, and gypsum precipitation at a different location. Therefore, the knowledge of groundwater flow systems at the tunnel and adjacent areas is essential to better understand the swelling processes. The present study investigates the groundwater flow systems at the Chienberg tunnel in Switzerland before and after the tunnel excavation, based on numerical flow modeling. The models include faults and the hydrostratigraphic layering in the subsurface to assess the role of the hydrogeological setting. The results of this study indicate effects on groundwater flow caused by the tunneling, which may trigger rock swelling by favoring anhydrite dissolution and gypsum precipitation, including (1) increase of flow rates around the tunnel, (2) broadened, shifted and more distributed capture zones leading to a change in origin and age of groundwater, (3) access of groundwater from preferential flow paths (e.g. faults) due to the drainage effect of the tunnel, and (4) change in geochemical equilibrium conditions because of decreased pore water pressures in the tunnel area.     

Provenance of the Permo–Carboniferous sediments in the northern Alxa and its tectonic implications for the southernmost Central Asian Orogenic Belt

As the southernmost segment of the Central Asian Orogenic Belt (CAOB), the northern Alxa orogenic belt (NAOB) connects the southeastern and southwestern segments of the CAOB. The NAOB amalgamated with the closure of the Paleo-Asian Ocean; however, the closure time of the Paleo-Asian Ocean is still on great debate. In this study, we reported new detrital zircon U–Pb geochronology and Hf–O isotopes for the Permo–Carboniferous sediments in the northern Alxa to constrain the provenance and its tectonic implications. The Permo–Carbonifereous Amushan Formation is composed of volcanic-carbonite-clastic rocks and was deposited in a shallow marine environment. Based on the zircon U–Pb geochronology, the Amushan Formation was deposited in the late Carboniferous to early Permian, but some outcrops of volcanic and clastic rocks in the Quaganqulu area were likely formed in the middle to late Permian. The integrated zircon age spectrum for the clastic rocks shows a wide range from late Archean to Paleoproterozoic, Mesoproterozoic (with a peak age at 1458 ​Ma), early Neoproterozoic (with peak ages of 988 ​Ma and 929 ​Ma), early Paleozoic (with a peak age at 447 ​Ma) and late Paleozoic (with a peak age at 294 ​Ma). Combined with the zircon Hf–O isotopes, the provenance was considered to be the Alxa Block, the Shalazhashan terrane and the Zhusileng–Hangwula block (and the southern Beishan orogenic belt). The multiple source regions to the south and north of the Paleo-Asian Ocean indicate the closure of this ocean before the late Carboniferous. The absence or small proportion of depositional age-approximated zircons in most samples makes their age spectra similar to extensional basins. Combined with the intra-plate volcanism, the deposits were considered to be formed in extensional settings. Accordingly, after the closure of the Paleo-Asian Ocean, the NAOB stepped into an extensional stage.     

Geochemical constraints on the provenance of Oligocene–Miocene siliciclastic deposits (Zivah Formation) of NW Iran: implications for the tectonic evolution of the Caucasus

In this study, the whole-rock geochemistry of 35 Oligocene–Miocene sandstone and shale samples from the Zivah Formation, Moghan area (NW Iran) were collected and analyzed for evaluation of their provenance, tectonic setting and the intensity of paleo-weathering. Low to moderate values of the chemical index of alteration (mean CIA?=?53/68 for sandstones/shales) and relatively high values of index of compositional variability (mean ICV?=?1.23/1.08 for sandstones/shales) suggest weak chemical weathering and an immature source. These results support for the semi-arid and semi-humid paleoclimate conditions in the source area. The geochemistry results reveal that the sediments were deposited in a basin related to the island arc and active continental margin tectonic settings, probably indicating the time of initial collision between Arabia and Eurasia. The enrichment of Cr, Ni and V in the sandstone and shales are consistent with mafic input from the source area. However, La/Th vs. Hf and La/Sc vs. Co/Th plots reveal mixed source of felsic and intermediate volcanic rocks. The data indicate that the sediments most likely originated from a mixture of mafic, intermediate and felsic igneous source areas, possibly as the erosional products of localized topography of the Talysh and the Lesser Caucasus mountains (south to southwest), created by compression in the Moghan region during the syn-collisional development of the Caucasus.     

Temporal stability of soil water storage and its influencing factors on a forestland hillslope during the rainy season in China’s Loess Plateau

Large-scale vegetation restoration in China’s Loess Plateau has been initiated by the central government to control soil and water losses since 1999. Knowledge of the spatio-temporal distribution of soil water storage (SWS) is critical to fully understand hydrological and ecological processes. This study analysed the temporal stability of the SWS pattern during the rainy season on a hillslope covered with Chinese pine (Pinus tabulaeformis Carr.). The soil water content in eight soil layers was obtained at 21 locations during the rainy season in 2014 and 2015. The results showed that the SWS at the 21 locations followed a normal distribution, which indicated moderate variability with the coefficients of variation ranging from 14 to 33%. The mean SWS was lowest in the middle slope. The spatial pattern of SWS displayed strong temporal stability, and the Spearman correlation coefficient ranged from 0.42 to 0.99 (p < 0.05). There were significant differences in the temporal stability of SWS among different soil layers (p < 0.01). The spatial patterns of SWS distribution showed small differences in different periods. The best representative locations of SWS were found at different soil depths. The maximum RMSE and MAE at 0–1.6 m soil depth for the rainy season were 4.27 and 3.54 mm, respectively. The best representative locations determined during a short period (13 days) can be used to estimate the mean SWS well for the same rainy season, but not for the next rainy season. Samples of SWS collected over a fortnight during the rainy season were able to capture the spatial patterns of soil moisture. Roots were the main factor affecting the temporal stability of SWS. Rainfall increased the temporal stability of the soil water distribution pattern. In conclusion, the SWS during the rainy season had a strong temporal stability on the forestland hillslope.     

Petrology,geochemistry and metamorphic evolution of Lancang Group in the Changning-Menglian complex belt and its implications on the tectonic evolution of the Paleo-TethysEI北大核心CSCD

Lancang Group within the Changning-Menglian complex belt in the Sanjiang area, Yunnan Province involves many kinds of meta-sediments, including staurolite-kyanite-bearing garnet-mica schist, garnet-mica schist, chloritoid-white mica schist and chlorite-glaucophane-albite schist. Detailed petrographic observation, mineral chemistry analysis and phase equilibrium modelling have shown that these meta-sediments preserve distinctly metamorphic evolutions. The staurolite-kyanite-bearing garnet-mica schist records the decompression and cooling histories related to retrograded metamorphic processes from middle-temperature eclogite facies to amphibolite facies with a peak mineral assemblage of garnet + kyanite + phengite + jadeite formed at the P-T condition of about 19 similar to 30kbar and 600 similar to 750 degrees C. For the garnet-mica schist, the peak metamorphic mineral association constrained by X-Prp and X-Grs in garnet, and Si content in phengite includes garnet + phengite + omphacite + lawsonite + paragonite and the related P-T condition is around 17 similar to 19. 5kbar and 430 similar to 475 degrees C . The chloritoid-white mica schist is characterized by the mineral assemblage of chloritoid + phengite + paragonite + chlorite whereas the peak mineral assemblage includes phengite + paragonite + carpholite. The peak P-T condition defined by Si content in phengite is limited in the range of 17 similar to 19kbar and 300 similar to 330 degrees C. Both garnet-mica schist and chloritoid-white mica schist consistently record heating and decompression processes from lawsonite-blueschist facies to epidote-blueschist facies. Metamorphic reactions and mineralogy of chlorite-glaucophane-albite schist roughly give the P-T condition of 9 similar to 11kbar and 430 similar to 520 degrees C. Studies on the geochemistry of Lancang Group reveal that these meta-sediments show the geochemistry affinity to the continental arc, active continental margin and upper crust sediments. The protoliths are mainly mud rock and sandstone with low maturity and a little of mafic-intermediate volcanic rock. The sediment sources are predominantly intermediate-acid magmatic rocks with old sedimentary contamination to different degree. Tectonic discrimination diagrams show that meta-sediments in the Lancang Group are mainly derived from the continental island arc or active continental margin tectonic setting. Combined with the metamorphism and geochemistry characteristics of these rocks in the Changning-Menglian complex belt, it is therefore inferred that the meta-sediments of Lancang Group display various metamorphic evolutions. Lancang Group are considered to have experienced multi-phase/stage and complex tectonic evolution histories.     

Runoff and water budget of the Liudaogou Catchment at the wind–water erosion crisscross region on the Loess Plateau of China

The objectives of this study were to examine the runoff characteristics and to estimate water budget at the wind–water erosion crisscross region on the Loess Plateau of China. A small catchment known as Liudaogou that has representative meteorological and hydrological conditions of the wind–water erosion crisscross region was chosen as the study location. A numerical model for rainfall-runoff was developed and verified; rainfall-runoff calculation for 5 years (2005–2009) was performed. The observed data and numerical result of the surface runoff were used for evaluating runoff characteristics and estimating the annual water budget. Runoff rate was proportional to average intensity of rain. Even though rainfall duration was for few minutes, surface runoff was generated by intensity of more than 2.6 mm × 5 min^?1, when rainfall duration exceeded 10 h; surface runoff was generated by an intensity of 0.6 mm × 5 min^?1, while annual runoff rate was 10–15 %. The unit area of 1 km² was adopted as the index area for estimating annual water budget. Runoff, evapotranspiration, variation of water storage, and habitant water consumption accounted for 20.4, 75.6, 0, and 4 % of the total annual precipitation, respectively. Results of this study provide the basis for further research on hydrology, water resources, and sustainable water development and utilization at the wind–water erosion crisscross region on the northern Loess Plateau where annual water resources are relatively deficient.     

The ~1.85 Ga carbonatite in north China and its implications on the evolution of the Columbia supercontinent

Mantle-derived carbonatites provide a unique window in the understanding of mantle characteristics and dynamics, as well as insight into the assembly and breakup of supercontinents. As a petrological indicator of extensional tectonic regimes, Archean/Proterozoic carbonatites provide important constraints on the timing of the breakup of ancient supercontinents. The majority of the carbonatites reported worldwide are Phanerozoic, in part because of the difficulty in recognizing Archean/Proterozoic carbonatites, which are characterized by strong foliation and recrystallization, and share broad petrologic similarities with metamorphosed sedimentary lithologies. Here, we report the recognition of a ~1.85 Ga carbonatite in Chaihulanzi area of Chifeng in north China based on systematic geological, petrological, geochemical, and baddeleyite U-Pb geochronological results. The carbonatite occurs as dikes or sills emplaced in Archean metasedimentary rocks and underwent intense deformation. Petrological and SEM/EDS results show that calcite and dolomite are the dominant carbonate minerals along with minor and varied amounts of Mg-rich mafic minerals, including forsterite (with Fo > 98), phlogopite, diopside, and an accessory amount of apatite, baddeleyite, spinel, monazite, and ilmenite. The relatively high silica content together with the non-arc and OIB-like trace element signatures of the carbonatite indicates a hot mantle plume as the likely magma source. The depleted Nd isotopic signatures suggest that plume upwelling might be triggered by the accumulation of recycled crust in the deep mantle. As a part of the global-scale Columbia supercontinent, the Proterozoic tectonic evolution of the North China Craton (NCC) provides important insights into the geodynamics governing amalgamation and fragmentation of the supercontinent. The Paleo-Mesoproterozoic boundary is the key point of tectonic transition from compressional to extensional settings in the NCC. The newly identified ~1.85 Ga carbonatite provides a direct link between the long-lasting supercontinental breakup and plume activity, which might be sourced from the “slab graveyard,” continental crustal slabs subducted into asthenosphere, beneath the supercontinent. The carbonatite provides a precise constraint of the initiation of the continental breakup at ~1.85 Ga.     

A comment on “Tectonic evolution of the Hengshan–Wutai–Fuping complexes and its implication for the Trans-North China Orogen”

In a recent issue of Precambrian Research (vol. 170, pp. 73–87), Wang (2009) published a paper entitled ‘Tectonic evolution of the Hengshan–Wutai–Fuping complexes and its implication for the Trans-North China Orogen, in which he proposes that (1) the formation of arc-related igneous rocks in the Hengshan and Wutai Complexes formed by northwest-directed subduction, not by (south)east-directed subduction; and (2) the Wutai granitoids were the products of an intra-oceanic island arc, not formed in a continent-derived arc. However, we consider both the structural and geochemical approaches Wang (2009) adopted to determine the polarity of the subduction and the tectonic setting of the Wutai granitoids are inappropriate or invalid. Firstly, all his structural observations used to determine the polarity of subduction are restricted to the Zhujiafang and Longquanguan ductitle shear zones, both of which developed at the late stage. It is unreliable to use kinematic indicators from these later structures to infer the polarity of the pre-collisional subduction. Secondly, Wang (2009) assumed that the initial positive ?(Nd) values (+0.5 to +4.5) of the Wutai granitoids indicate their generation directly from a mantle source, forming in an intra-oceanic arc. Such an interpretation is incorrect because the positive ?(Nd) values of the Wutai granitoids merely indicate that the igneous protoliths of these granitoids originated from a depleted mantle source, not the Wutai granitoids themselves. As the products of the earliest arc magmatism in the Wutai arc, the Wutai granitoids could not be generated directly from a mantle source but must have been derived by partial melting of juvenile crust.     

Sr–Nd isotope data of basement rocks from the northernmost argentine Precordillera and its implications for the early Paleozoic evolution of SW Gondwana margin

The Precordillera terrane (Cuyania) in western Argentina is commonly accepted as an exotic fragment derived from Laurentia in the Early Paleozoic. Evidence supporting such an interpretation is manly based on similarities in the sedimentary cover successions and their paleontological content. Little is known about the basement of the Precordillera terrane. Its isotopic characterization is essential to better constrain the present areal distribution of the terrane and it may provide more insight into the pre-rifting evolution of the Precordillera terrane along the Iapetan margin of Laurentia. We present new Sr and Nd isotope data of pre-Late Ordovician meta-igneous rocks from the Río Bonete region in NW Argentina, interpreted as the northernmost extent of the Precordillera. The Nd systematics of the Río Bonete basement rocks including greenschists and metagabbros (εNd₍₄₇₀₎ = +2.14–−0.19; T_DM = 0.99–1.2 Ga), a garnet-amphibolite (εNd₍₄₇₀₎ = −0.53; T_DM = 1.32 Ga) and a quartz-phyllite (εNd₍₄₇₀₎ = −3.83; T_DM = 1.55 Ga), are similar to other pre-Ordovician meta-igneous rocks from Sierra de Umango, Pie de Palo and the Ullum xenoliths, usually interpreted as the basement of the Precordillera terrane. Nd model ages around 1.2 Ga are also typical from the Mesoproterozoic Grenvillian basement of southern North America, currently exposed in the Llano region. In addition, the greenschists and metagabbros show a robust correlation with the Late Neoproterozoic Catoctin volcanics in the central Appalachians. The Sr isotope data (when not disturbed) also supports this novel interpretation and suggests the presence of the Blue Ridge rifting event in Precordillera. According to our interpretation, some lithotypes included within the basement complex of the Río Bonete area belonged to the basement of the Precordillera terrane supporting previous correlation between both regions.     

Jurassic formation and Eocene subduction of the Zermatt–Saas-Fee ophiolites: implications for the geodynamic evolution of the Central and Western Alps

The Zermatt–Saas-Fee ophiolites (ZSFO) are one of the best preserved slices of eclogitic oceanic crust in the Alpine chain. They formed during the opening of the Mesozoic Tethys and underwent subduction to HP/UHP conditions during Alpine compression. A cathodoluminescence-based ion microprobe (SHRIMP) dating of different zircon domains from metagabbros and oceanic metasediments was carried out to constrain the timing of formation and subduction of this ophiolite, two fundamental questions in Alpine geodynamics. The formation of the ophiolitic sequence is constrained by the intrusion ages of the Mellichen and the Allalin metagabbros (164.0 ± 2.7 Ma and 163.5 ± 1.8 Ma) obtained on magmatic zircon domains. These data are in line with the maximum deposition age for Mn-rich metasediments which overlie the mafic rocks at Lago di Cignana (161 ± 11 Ma) and at Sparrenflue (ca. 153–154 Ma). An Eocene age of 44.1 ± 0.7 Ma was obtained for whole zircons and zircon rims from an UHP eclogite and two metasediments at Lago di Cignana. One of the Eocene zircons contains a rutile inclusion indicating formation at HP conditions. As the temperature and pressure peak of these rocks nearly coincide, the Eocene zircons probably constrain the age for the deepest subduction of the ZSFO. This Eocene age for the UHP metamorphism implies that the ZSFO were subducted later than the Adriatic margin (Sesia-Lanzo Zone) and before the Late Eocene subduction of the European continental crust below Apulia. A scenario with three subduction episodes propagating in time from SE to NW is proposed for the geological evolution of the Central and Western Alps. Received: 1 December 1997 / Accepted: 8 April 1998     

Long‐term landscape evolution in the Darwin region and its implications for the origin of landsurfaces in the north of the Northern Territory

The development of landsurfaces in the north of the Northern Territory has traditionally been attributed to successive episodes of uplift, erosion and weathering. The lower and younger two of the four landsurfaces attributed to such development, the Wave Hill and Koolpinyah surfaces, dominate the landscape in the Darwin region. Investigations of the relationship between the Cretaceous stratigraphy and the nature of deep weathering in the Darwin region show that these surfaces are structurally controlled. A bioturbated bed in the Darwin Member of the Cretaceous Bathurst Island Formation has limited the depth of weathering in this region mainly to the level of the Koolpinyah surface. A silicified horizon in the deeply weathered Cretaceous strata has controlled the level of the Koolpinyah and Wave Hill surfaces elsewhere. Furthermore, the presence of detrital laterite profiles, being the main form of evidence used for the identification of both of these surfaces, is challenged; in many localities these detrital profiles are in fact in situ, discounting the idea that these surfaces developed as a result of successive episodes of pediplanation. Similarities are drawn between the origin of these surfaces and the development of equivalent surfaces in the Daly River Basin to the south of Darwin. The practice of extrapolation between surfaces across widely separated regions of northern Australia has been previously shown to be based on tenuous grounds. The same degree of tenuity must now be placed upon such extrapolations in the north of the Northern Territory.     

Thermal properties of harzburgite and dunite at 0.8–3 GPa and 300–823 K and implications for the thermal evolution of Tibet

Thermal diffusivity(D)and thermal conductivity(κ)of harzburgite and dunite from Luobusha ophiolite were simultaneously measured up to 3 GPa and 823 K using the transient plane-source method in a multi anvil apparatus.The results show that the values of D andκof both samples systematically decrease with increasing temperature and increase with increasing pressure.By combination of the thermal physical data of rocks and minerals and geophysical constraints,we performed numerical simulation on the thermal evolution of Tibet vary over depth,distance and geologic ages.The present results provide new constraints on occurrence of partial melting and its geophysical significance beneath Tibetan crust.     

The Ridgeway Conglomerate Formation of SW Wales,and its implications. The end of the Lower Old Red Sandstone?

The Devonian Old Red Sandstone Ridgeway Conglomerate Formation crops out in Pembrokeshire, SW Wales. It was deposited as part of a dryland alluvial fan, axial fluvial valley deposystem. It conformably overlies the mid Lochkovian Freshwater West Formation and probably predates deposition of the Lower Cosheston Group Mill Bay Formation indicating an Early Devonian (latest Lochkovian to earliest Pragian) age, rather than a Middle Devonian age as suggested by previous workers. It therefore represents the youngest preserved formation of the Milford Haven Group south of the Ritec Fault. The Formation thickens drastically into the Ritec Fault, indicating its control on sedimentation. The half‐graben topography initiated deposition of a hangingwall alluvial fan that was sourced from a southerly Lower Palaeozoic/Precambrian provenance within the present‐day Bristol Channel. The Formation is heterolithic in nature, with deposits on the fan reflecting a mixture of processes. Conglomerates were deposited primarily by laterally extensive sheetfloods, and as bars in low‐relief, laterally accreted channels. Sandstones were also predominantly deposited by sheetfloods. Gritty mudrocks in comparison demonstrate deposition by cohesive debris flows. The fan prograded northward and interfingered with a low‐gradient, high‐sinuosity fluvial channel system dominated by inclined and non‐inclined heterolithic stratification. Thinly laminated mudstone and sandstone interbeds were deposited in ephemeral fan‐toe and axial valley lakes that may have developed during sub‐humid climatic episodes. The lacustrine heterolithic association has associated matgrounds and possible ‘algal roll‐up’ structures. Calcretized peetee structures and root traces comprise a lake margin calcrete association. Fan gravels prograded into the axial fluvial valley during periods of increased sediment flux that may represent semi‐arid conditions and/or episodes of tectonic activity. Calcretes of varying development were established in both the fan and axial valley zones. Calcretes with lower stages of development are more proximal to the Ritec Fault reflecting decreased soil residence times and high deposition rates within the axial valley. More strongly developed soil profiles on the fan may indicate sequence boundaries associated with low sediment flux, or increased soil residence time due to active fan‐channel migration (the pedofacies concept). Groundwater calcretes have sharp‐based and layer‐bound calcrete profiles. Gully‐bed cements are locally developed within the fan gravels. Copyright © 2007 John Wiley & Sons, Ltd.     

Petrology and P–T history of the Wutai amphibolites: implications for tectonic evolution of the Wutai Complex,China

The Wutai Complex represents the best preserved granite-greenstone terrane in the North China Craton. The complex comprises a sequence of metamorphosed ultramafic to felsic volcanic rocks, variably deformed granitoid rocks, along with lesser amounts of siliciclastic and carbonate rocks and banded iron formations. Petrological evidence from the Wutai amphibolites indicates four metamorphic evolutionary stages. The M₁ assemblage is composed of plagioclase+quartz+actinolite+chlorite+epidote+biotite+rutile, preserved as mineral inclusions in garnet porphyroblasts. The metamorphic conditions for this assemblage cannot be quantitatively estimated. The M₂ stage is represented by garnet porphyroblasts in a matrix of quartz, plagioclase, amphibole, biotite, rutile and ilmenite. P–T conditions for this assemblage have been estimated using the program Tweequ at 10–12 kbar and 600–650°C. The M₃ assemblage is shown by amphibole+plagioclase±ilmenite symplectic coronas around embayed garnets and yields P–T conditions of 6.0–7.0 kbar and 600–650°C. M₄ is represented by chlorite and epidote rimming garnet, chlorite rimming amphibole and epidote replacing plagioclase under greenschist-facies conditions of 400–500°C and relatively lower pressures. Taken together, the qualitative P–T estimates from M₁ and M₄ and the quantitative P–T estimates from M₂ and M₃ define a clockwise P–T path for the Wutai amphibolites.The estimated P–T path from the four stages suggests that the Wutai Complex underwent initial burial and crustal thickening (M₁+M₂), subsequent isothermal exhumation (M₃), and finally cooling and retrogression (M₄). This tectonothermal path, along with those of the Fuping and Hengshan complexes, which bound the southeast and northwest margins, respectively, of the Wutai Complex, is considered to record the early Paleoproterozoic collision between the eastern and western segments of the North China craton.     

Garnet amphibolites from the Ganzi–Litang fault zone,eastern Tibetan Plateau: mineralogy,geochemistry, and implications for evolution of the eastern Palaeo-Tethys Realm

The Ganzi–Litang fault zone, an outstanding tectonic element in the eastern Tibetan Plateau has been intensively debated as an in-situ suture zone marking relict of a subducted Palaeo-Tethyan oceanic crust or a failed intracontinental rift. This paper reports the garnet amphibolites discovered along the Ganzi–Litang fault zone, eastern Tibetan Plateau. These garnet amphibolites are characterized by the garnet–hornblende–rutile–sphene–plagioclase–quartz assemblage. Conventional geothermobarometry figures out the metamorphic temperature and pressure conditions at 582–626°C and 1.61–1.82 GPa, respectively. Geochemical analysis (no Nb–Ta deletions and left-inclined to flat patterns of rare-earth elements) indicates that the garnet amphibolites could represent metamorphic product of the mid-ocean-ridge (MORB)-type mafic rocks that were contaminated by a mantle plume. The protolith of the garnet amphibolites was dated at 236 Ma using in-situ U–Pb zircon method, and the retrograde metamorphism was dated at 218 Ma using in-situ U–Pb sphene method. A comprehensive analysis combined with the development of the Palaeo-Tethys Ocean and the Yidun arc through geologic time indicates a Triassic to Early Jurassic age (236–195 Ma) for the metamorphism of the garnet amphibolites. The low geothermal gradient of 9.8ºC/km and the N-MORB nature of the garnet amphibolites suggest a subduction-zone environment for the high-pressure metamorphism. Therefore, the Ganzi–Litang fault zone is a Palaeo-Tethyan suture separating the Yidun arc and the Songpan–Ganzi terrane, representing the relics of a branch of the Palaeo-Tethys Ocean that was contaminated by a mantle plume.     

Electrical conductivity of the plagioclase–NaCl–water system and its implication for the high conductivity anomalies in the mid-lower crust of Tibet Plateau

In order to investigate the origin of the high conductivity anomalies geophysically observed in the mid-lower crust of Tibet Plateau, the electrical conductivity of plagioclase–NaCl–water system was measured at 1.2 GPa and 400–900 K. The relationship between electrical conductivity and temperature follows the Arrhenius law. The bulk conductivity increases with the fluid fraction and salinity, but is almost independent of temperature (activation enthalpy less than 0.1 eV). The conductivity of plagioclase–NaCl–water system is much lower than that of albite–NaCl–water system with similar fluid fraction and salinity, indicating a strong effect of the major mineral phase on the bulk conductivity of the brine-bearing system. The high conductivity anomalies of 10^?1 and 10⁰ S/m observed in the mid-lower crust of Tibet Plateau can be explained by the aqueous fluid with a volume fraction of 1 and 9%, respectively, if the fluid salinity is 25%. The anomaly value of 10^?1 S/m can be explained by the aqueous fluid with a volume fraction of 6% if the salinity is 10%. In case of Southern Tibet where the heat flow is high, the model of a thin layer of brine-bearing aqueous fluid with a high salinity overlying a thick layer of partial melt is most likely to prevail.