Distribution of iron in the surface and groundwaters of East Godavari district,Andhra Pradesh,India

With the progradation of Godavari delta in the east coast of India, increase in iron (Fe) concentrations in the groundwater was observed. High concentrations of Fe (>10 mg/l) were observed in khondalite and charnockite formations. A lower portion of the Godavari river basin, viz. East Godavari district was chosen for the study of the distribution of iron with special reference to the existing geological formations and the geomorphology of the area. The concentration of iron was observed to vary from below detection limit to 69 mg/l in the groundwater while it was less than 1 mg Fe/l in river and spring waters. The Fe of river water was reduced due to seawater mixing and the electrical conductivity (EC) was increased approximately to half of the seawater conductivity. Unlike the mixing of seawater at the surface, the same seawater mixing with groundwater yielded a water having similar order of EC with relatively high Fe. Fe was inversely related with nitrate in the groundwater. Fe was found to correlate considerably better with manganese in fluvial and coastal alluvium zones. The locations having higher Fe in delta are suspected to be related to palaeo channels. The association between Fe and Mn and their negative association with NO₃ may be due to the possible autotrophic denitrification that might have taken place in the subsurface.     

Groundwater quality in a coastal area: a case study from Andhra Pradesh, India

Over-exploitation of groundwater results in decline of water levels, leading to intrusion of salt water along the coastal region, which is a natural phenomenon. A groundwater quality survey has been carried out to assess such phenomena along the coast of Visakhapatnam, Andhra Pradesh, India. Brackish groundwaters are observed in most of the wells. The rest of the wells show a fresh water environment. The factors responsible for the brackish groundwater quality with respect to the influence of seawater are assessed, using the standard ionic ratios, such as Ca²⁺:Mg²⁺, TA:TH and Cl⁻:HCO⁻ ₃. Results suggest that the brackish nature in most of the groundwaters is not due to the seawater influence, but is caused by the hydrogeochemical process. Some influence of seawater on the groundwater quality is observed along the rock fractures. The combined effect of seawater and urban wastewaters is due to the inferior quality of groundwater in a few wells, where they are at topographic lows close to the coast.     

Geoenvironmental effects of groundwater regime in Andhra Pradesh, India

 The Indian subcontinent has the largest semi-arid tropical (SAT) area among developing nations. The State of Andhra Pradesh falls under the SAT region in India and is mostly covered by compact and hard rocks, characterized by seasonal rainfall of a highly fluctuating nature, in both space and time. As a consequence of the green revolution and an increase in industrial activity, there has been an increase in the utilization of groundwater resources during the last two decades in Andhra Pradesh. The development has also caused a number of problems, such as water table decline, decrease in well yields and seawater intrusion. Although major irrigation projects have contributed to improved agricultural production, the associated problems of waterlogging, salinization and loss of valuable bioresources have led to the gradual degradation of the land, affecting agricultural productivity. Surface water and groundwater have also been polluted in several parts of the State because of untreated discharge of effluents from the industries into nearby streams or open lands. A brief account of the overall scenario of the hydrogeological framework and geo-environmental effects on the groundwater regime in Andhra Pradesh is presented. Possible management practices and conservation methods are suggested. Received: 9 August 1999 · Accepted: 10 July 2000     

Sphene coronites from Hyderabad granites,Andhra Pradesh,India

Sphene coronites around magnetite are recorded in the granodiorite of Hyderabad. The metamorphic origin of the corona is discussed.     

An integrated approach to assess the quality of groundwater in a coastal aquifer of Andhra Pradesh, India

The Narava basin in Visakhapatnam district situated on the east coast is a productive agricultural area, and is also one of the fastest growing urban areas in India. The agricultural and urban-industrialization activities have a lot of impact on this coastal aquifer water quality. The hydrochemistry of the groundwater was analyzed in the basin area with reference to drinking and agricultural purposes. The area is underlain by Precambrian rocks like khondalites, charnockites and migmatites. The water samples were collected from shallow wells for the year 2008. Physical and chemical parameters of groundwater such as pH, total alkalinity (TA), electrical conductivity (EC), total dissolved solids (TDS), total hardness (TH), Ca²⁺, Mg²⁺, Na⁺, K⁺, HCO₃ ^?, Cl^?, SO₄ ^2?, NO₃ ^?, F^? were determined. The analytical results revealed that the most of the groundwater found to be in polluted category. Geographical information system (GIS) was utilized to generate different spatial distribution maps of various chemical constituents in the study area. The analytical data were used to compute certain parameters such as salinity hazard, percent sodium (Na%), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), permeability index (PI), Kelley??s ratio (KR) and corrosivity ratio (CR) to determine the quality of water for agricultural purposes. The abundance of the major ions in the basin area was found to be in the following sequence: Na⁺?>?Ca²⁺?>?Mg²⁺?>?K⁺:Cl^??>?HCO₃ ^??>?SO₄ ^2??>?NO₃ ^??>?F^?. According to Gibbs?? diagram most of the samples fall under rock dominance. As per Wilcox and USSL classification most of the groundwater samples are suitable for irrigation except few samples which are unsuitable due to the presence of high salinity and high sodium hazard. From the obtained data, it can be concluded that the water quality profile was good and useful for normal irrigation agriculture.     

The Purimetla gabbros,Prakasam District,Andhra Pradesh,India

Gabbros at Purimetla occur in close association with the alkaline pluton. Petrography and petrochemistry of these gabbros indicate their tholeiitic nature. Chemical variation of these tholeiites suggests that an initial undersaturated tholeiitic magma yielded oversaturated fractions in the final stages of differentiation. Their regional distribution suggests that basic magmatism preceded the emplacement of the alkaline rocks in the Prakasam alkaline province.     

Petrology of calc-silicate rocks from Koduru,Andhra Pradesh,India

Mineral assemblages, rock and mineral chemistry, and mineral reactions, in calc-silicate rocks from Koduru area, Andhra Pradesh, India are discussed. Mineralogical and bulk chemical differences indicate 3 calc-silicate rock types — type I with K feldspar+calcite+wollastonite+quartz+scapolite+diopside_ss +andradite_ss+sphene, has relatively high rock oxidation ratios. Type II is a highly calcic variety with high rock MgFe ratios, and has K feldspar+calcite+wollastonite+quartz+scapolite + diopside_ss±grossularite_ss+sphene+zoisite. Type III has K feldspar +calcite+wollastonite+quartz+scapolite+diopside_ss +sphene+hornblende+magnetite, and has relatively low oxidation ratio and low MgFe ratio. The 3 calc-silicate rock types have originated as mixtures of limestone/dolomite/marl.Diopside was produced by a reaction involving Ca-amphibole +calcite+quartz, and reversed during retrogression. Andradite_ss in type I rocks was produced at the expense of hedenbergitic component of pyroxene in a continuous reaction as a consequence of increase in the oxygen content of the original sediment relative to type III. Calcite+quartz reacted to give wollastonite. During cooling an influx of water caused scapolite to alter to zoisite.     

Fluorine distribution in waters of Nalgonda District, Andhra Pradesh, India

Geochemical and hydrochemical studies were conducted in Nalgonda District (A.P.), to explore the causes of high fluorine in waters, causing a widespread incidence of fluorosis in the local population. Samples of granitic rocks, soils, stream sediments, and waters were analyzed for F and other salient chemical parameters. Samples from the area of Hyderabad city were analyzed for comparison. The F content of waters in areas with endemic fluorosis ranges from 0.4 to 20 mg/l. The low calcium content of rocks and soils, and the presence of high levels of sodium bicarbonate in soils and waters are important factors favoring high levels of F in waters.     

Heavy mineral studies on late quaternary red sediments of Bhimunipatnam,Andhra Pradesh,East coast of India

Thirty one sediment samples from different varieties viz. yellow, reddish brown, brick red and light yellow sands from red sediments of Bhimunipatnam, Andhra Pradesh were studied to understand the heavy mineral assemblage, their fractionwise distribution and concentration. The heavy mineral assemblage in red sediments is ilmenite, magnetite, sillimanite, garnet, zircon, rutile, kyanite, monazite etc. Total heavy minerals (THM) wt. % varies from 16.67 to 23.99% and their concentration is not uniform in all the sedimentary samples. The higher THM wt% in brick red sands (23.99%) followed by reddish brown sands (20.24%), light yellow sands (17.10%) and yellow sands (16.67%). The finer fractions have more concentration of THM wt% than coarse fraction. The vertical distribution of heavy minerals in each sedimentary unit indicates that these units are not formed in single phase of deposition. Less concentration of garnets in yellow and light yellow sedimentary units indicates that the garnets might be chemically altered into iron hydroxide–limonite which gives yellow colour to the sediments under slightly oxidizing environment. Low concentration of garnets in brick red and reddish brown sediments indicates that garnets might have been undergone chemical decomposition under acidic conditions leads to produce iron oxides (Hematite) causes for red colorization of these units. The heavy mineral assemblage in different sand units indicates that they are derived from Eastern Ghat Group of rocks (khondalites and charnockites).     

Heavy minerals and the characters of ilmenite in the beach placer sands of Chavakkad-Ponnani,Kerala Coast,India

Indian beach placer sand deposits are, in general, ilmenite-rich. However, some concentrations are dominated by pyriboles. The Chavakkad-Ponnani (CP) area along the northern Kerala coast is one such deposit. This paper deals with the general character of the heavy minerals of CP with special emphasis on the characters of ilmenite. Most Indian beach sand ilmenites are of good quality. However, our observations on the ilmenites of CP using Optical Microscope, SEM and EPMA reveals that these are mineralogically very complex. The CP ilmenite varies from pure ilmenite to highly impure variety having intergrowths and inclusions of other oxide and silicate minerals. Ilmenite occurs as mixcrystals and forms intergrowth structure with hematite and Ti-hematite/ulvöspinel; contains inclusions of hematite, quartz, and monazite. On the other hand ilmenite also occurs as inclusions within hematite and garnet. The pyriboles are dominantly amphiboles with hornblende-composition. Interestingly an inclusion of gold has been recorded within amphibole of hornblende composition. Garnets are mostly of almandine and pyrope type. Subordinate heavy minerals are sillimanite, zircon and rutile. Characteristic morphology, mineralogy and chemistry of amphibole, garnet and ilmenite together indicate that the placer sands of CP area are derived from the amphibolites, granite gneisses and basic igneous rocks lying in the hinterland towards the eastern border of Kerala. Though the overall quality of ilmenite is poor, highgrade ilmenite concentrate can be generated (of course with lower yield), by adopting precise mineral processing techniques. The CP deposit can be considered as a second-grade deposit but it has potential for future exploitation.     

Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India

Hydrogeochemical investigations, which are significant for the assessment of water quality, have been carried out to study the sources of dissolved ions in groundwaters of some rural areas of Guntur district, Andhra Pradesh, India. Groundwaters in the area are mostly brackish. High contents of SiO₂, and Na⁺ and Cl^- ions in groundwater, in comparison with those of seawater, suggests a meteoric origin of groundwater. The high concentration of SiO₂ and various geochemical signatures reflect the weathering of minerals. However, the Na⁺+K⁺ vs Cl^- ratio suggests weathering, has occurred only to some extent. The chemistry of groundwater favours the formation of clay minerals (montmorillonite, illite and chlorite), because of evapotranspiration. The positive saturation index of CaCO₃ and the high signatures of Ma²⁺:Ca²⁺ and Na⁺:Ca²⁺ reveals the occurrence of evaporation. The evaporation enhances the concentration of ions (which occurred originally in the water) in the soils during summer. The very high % MathType!MTEF!2!1!+- % feaaeaart1ev0aaatCvAUfKttLearuavTnhis1MBaeXatLxBI9gBae % bbnrfifHhDYfgasaacH8srps0lbbf9q8WrFfeuY-Hhbbf9v8qqaqFr % 0xc9pk0xbba9q8WqFfea0-yr0RYxir-Jbba9q8aq0-yq-He9q8qqQ8 % frFve9Fve9Ff0dmeaabaqaciGacaGaaeqabaqabeaadaaakeaacqqG % tbWucqqGpbWtdaqhaaWcbaGaeeinaqdabaGaeeOmaiJaeeyla0caaa % aa!2EC5! SO₄^{2 -} {\rm SO}_{\rm 4}^{{\rm 2 - }} and Cl^- contents in some groundwaters and the occurrence of kankar (CaCO₃) in the area suggest a long history of evaporation. Greater ionic concentration in the groundwaters of post-monsoon compared with pre-monsoon indicates the increasing addition of leachates into the groundwater from the soils in the monsoon and anthropogenic activities, which leads to a deteriorating quality of groundwater. According to the Gibbs' diagrams, rock weathering, to some extent, and evaporation are the dominant phenomena responsible for the higher ionic concentrations found in groundwater. Measures that benefit sustainable management of groundwater quality are suggested in this study.     

Revisit to graphite-tungsten deposits of East Godavari district,Andhra Pradesh

The graphite-tungsten deposits under consideration in this study are located in the Burugubanda, Pydiputta, Tapasikonda, Marripalem and Madyaratigudem areas of the East Godavari district of Andhra Pradesh, India. These deposits were formed due to wide spread tectonothermal events associated with the evolution of Eastern Ghats Mobile Belt (EGMB). The graphite deposits of East Godavari district are epigenetic, rhombohedral fluid deposited type and are one of the four deposits of such type reported so far from Srilanka, Spain and England. The graphite deposits were formed due to granodioritic intrusion into the Narsipatnam shear zone, which caused migmatisation of khondalites along with mobilisation and concentration of graphite, as veins and lenses, into the graphite gneisses. The graphite gneisses were subsequently intruded by quartz rich pegmatites that were laden with tungsten mineralisation. The tungsten mineralisation occurs as thin bands, lenses, stringers and vein lets within the quartz matrix and also dispersed in the graphite gneisses. Inclusions of tungsten in graphite indicate that tungsten mineralisation succeeded graphite mineralisation. However, the low P-T phenomenon of tungsten (wolframite-ferberite) mineralisation resulted in low tenor of tungsten ore deposits (WO₃: 0.10%). Rare earth elements (REE) are associated with tungsten mineralisation in these areas. During the present study, these graphite-tungsten deposits have been re-examined, in the backdrop of shelving graphite-tungsten projects in these areas. The feed for mineral beneficiation tests was decided on the basis of dispersion of tungsten in quartz and graphite rich fractions of the ore zone. The feed (ROM material) on beneficiation gave recovery of +75% graphite concentrate, tungsten concentrate of consistent chemical grade, besides recovery of sizeable REE concentrate. It also rendered use of unutilised graphite tailing dumps at beneficiation plants, thereby effecting conservation. Thus, the association of tungsten and REE with the entire graphite deposits along with their value addition during beneficiation, as by-product, revived opportunities to restart graphite mining in the Burugubanda, Pydiputta and Tapasikonda areas in particular and East Godavari district, in general, as an economically viable venture. This will initiate opening of graphite mines in other districts of Andhra Pradesh and energise economics of working graphite mines within EGMB, in the states of Jharkhand, Odisha and Tamil Nadu.     

Fluoride-bearing groundwater in Gummanampadu Sub-basin, Guntur District, Andhra Pradesh, India

The functional factors responsible for fluoride (F^?)-bearing groundwater used for drinking as well as for cooking in the area of Gummanampadu Sub-basin, Guntur District, Andhra Pradesh, India are discussed. The study area is a part of an Archean Gneissic Complex, consisting of banded-biotite-hornblende-gneisses, over which the Proterozoic Cumbhum quartzites, shales, phyllites, and dolomitic limestones occur. The chemistry of groundwater is dominated by carbonates (HCO₃ ^? and CO₃ ^2?) at a higher pH. This results in a higher total alkalinity over total hardness, causing an excess alkalinity. Sodium ion is dominated among the cations (Ca²⁺, Mg²⁺, and K⁺). The concentration of F^? (2.1–3.7 mg/L) is higher than that of desirable national limit (1.2 mg/L) prescribed for drinking purpose. A significant positive correlation exists between F^? and pH as well as that between F^? and HCO₃ ^? + CO₃ ^2?. This indicates that the alkaline condition is the prime conducive factor for dissolving F^?-bearing minerals more effectively leading to a higher concentration of F^? in the groundwater. Furthermore, a positive chloro-alkaline index reflects the ion exchange, and an oversaturation with respect to CaCO₃ indicates the evaporation. In addition, a negative relation between the well depth and F^? shows the effect of solubility and/or leaching of salts in different depth levels. These factors regulate the concentration of F^? in the groundwater. On the other hand, a positive correlation of F^? with SO₄ ^2? as well as with K⁺ shows the human land use activities (namely, use of chemical fertilizers, disposal of domestic wastes, etc.), which add F^? to the groundwater. A significant number of the residents of the study area suffer from the health disorders related to fluorosis, which is a consequence of higher concentration of F^? in the drinking water. Thus, this study emphasizes the need for supply of safe drinking water, nutritional diet, rainwater-harvesting structures, and public education to realize “health for all” motto of World Health Organization.     

The impact of paleo-channel on groundwater contamination,Andhra Pradesh,India

 Nakka vagu, a tributary of the River Manjira in the Medak district of Andhra Pradesh, has a catchment area of ∼500 km². Patancheru is an industrial development area (IDA) near the vagu. There are about 350 industries of varied nature (pulp, plastic, bulk drugs, pharmaceuticals, paints and steel rolling mills) that are engaged in the manufacture/processing of their respective products and that use water extensively. The hydrogeological setup has a bearing on the widespread contamination in the area because of discharge of industrial effluents into open land and streams. Several dug wells and boreholes situated in the study area have been monitored for water level fluctuations and quality variations. Pumping tests have been conducted to evaluate aquifer parameters. The geology, drainage, chemistry and other related anthropogenic factors play a major role in the spread of pollution in the area. Hence, it is very important to determine the degree of vulnerability to pollution based on hydrogeological factors. Amidst the granite terrain, the Nakka vagu has been identified as a paleo-channel (composed of clay–silt–sand facies); its presence in the area has immensely increased the spread of groundwater contamination. The transmissivity of the alluvial aquifer varies from 750 to 1315 m²/day. The adjoining granite has a transmissivity that varies from 30–430 m²/day. The thickness of the valley fill in the discharge region is about 10–12 m, with a lateral spread of 500–700 m, east of Nakka vagu. Received: 17 November 1999 · Accepted: 14 March 2000     

Tectonic Setting of the Kadiri Schist Belt, Andhra Pradesh, India

Plate tectonic activity has played a critical role in the development of petrotectonic associations in the Kadiri schist belt. The calc alkaline association of basalt, andesite, dacite and rhyolite(BADR) is the signature volcanic rock suite of the convergent margin. The N-S belt has gone below the unconformity plane of Cuddapah sediments. In the northern part geochemical and structural attributes of the Kadiri greenstone belt is studied along with microscopic observations of selected samples. Harker diagram plots of major elements generally indicate a liquid line of descent from a common source, such that BADR rocks are derived from a common parent magma of basaltic to andesitic composition. These calc-alkaline volcanic rocks are formed at convergent margins where more silicic rocks represent more highly fractionated melt. All the litho-units of this greenstone belt indicate crush and strain effects. The stretched pebbles in the deformed volcanic matrix with tectonite development along with associated greenschist facies metamorphism, alteration and hydration is remarkable. Flow foliation plane with N-S strike and very low angle(5° to 10°) easterly dip and N-S axial planar schistosity formed due to later phase isoclinal folding can be clearly identified in the field. Basic intrusives are quite common in the surrounding area. All the observations including the field setting and geochemistry clearly demonstrate ocean-continent subduction as the tectonic environment of the study area.     

Alkaline basic intrusives of Elchuru,Prakasam District,Andhra Pradesh,India

The igneous alkaline rocks at Elchuru start from a parent ijolite-melteigite association to basic malignite, melalusitanite and shonkinite followed by nepheline syenites and then biotite lamprophyres (as dykes) at the waning phase of the evolutionary course of the complex. The distinct alkalinity of the rocks is manifested by the development of modal nepheline and calcic amphibole (kaersutite). For both the basic rocks,i.e. alkali gabbro and biotite lamprophyre, the percentages of normative nepheline are always higher than modal nepheline, indicating silica deficiency and alkali enrichment of the mafics. It is evident from detailed petrological and geochemical studies that the two basic members are very much akin to each other and there is no major deviation in their bulk chemistry.     

Hydrogeochemistry of the Sarada river basin,Visakhapatnam district,Andhra Pradesh,India

Systematic hydrogeochemical survey has been carried out for understanding the sources of dissolved ions in the groundwaters of the area occupied by Sarada river basin, Visakhapatnam district, Andhra Pradesh, India. Khondalites, charnockites and granite gneisses and calc-granulites of Precambrians and alluvial deposits of Quaternaries underlie the study area. Groundwaters are both fresh and brackish; the latter waters being a dominant. Most groundwaters are characterized by Na⁺:HCO₃⁻ facies due to chemical weathering of the rocks. Enrichment of Na⁺, K⁺, Cl⁻, SO₄²⁻, NO₃⁻ and F⁻ in some groundwater samples is caused by seawater intrusion, locally accompanied by ion-exchange, and anthropogenic activities, resulting in an increase of brackish in the groundwaters. Based on the results of this hydrogeochemical study, suitable management measures are recommended to solve the water quality problems.