Fluid-assisted fracturing,cataclasis, and resulting plastic flow in mylonites from the Moresby Seamount detachment,Woodlark Basin

The Moresby Seamount detachment (MSD) in the Woodlark Basin (offshore Papua New Guinea) is a large active low-angle detachment excellently exposed at the seafloor, and cutting through mafic metamorphic rocks. Hydrothermal infiltration of quartz followed by that of calcite occurred during cataclastic deformation. Subsequent deformation of these a priori softer minerals leads to mylonite formation in the MSD. This study aims at a better understanding of the deformation mechanism switch from cataclastic to plastic flow. Deformation fabrics of the fault rocks were analyzed by light-optical microscopy. Rheologically critical phases were mapped to determine distributions and area proportions, and EBSD was used to measure crystallographic preferred orientation (CPO). Strong calcite CPOs indicate dominant dislocation creep. Quartz CPOs, however, are weak and more difficult to interpret, suggesting at least some strain accommodation by diffusion creep mechanisms. When quartz aggregates are intermixed with the polymineralic mylonite matrix diffusion creep grain boundary sliding may be dominant. The syntectonic conversion from mafic cataclasites to more siliceous and carbonaceous mylonites induced by hydrothermal processes is a critical weakening mechanism enabling the MSD to at least intermittently plastic flow at low shear stresses. This is probably a crucial process for the operation of low-angle detachments in hydrated and dominantly mafic crust.     

Dolomite microstructures between 390° and 700 °C: Indications for deformation mechanisms and grain size evolution

Dolomitic marble on the island of Naxos was deformed at variable temperatures ranging from 390 °C to >700 °C. Microstructural investigations indicate two end-member of deformation mechanisms: (1) Diffusion creep processes associated with small grain sizes and weak or no CPO (crystallographic preferred orientation), whereas (2) dislocation creep processes are related with larger grain sizes and strong CPO. The change between these mechanisms depends on grain size and temperature. Therefore, sample with dislocation and diffusion creep microstructures and CPO occur at intermediate temperatures in relative pure dolomite samples. The measured dolomite grain size ranges from 3 to 940 μm. Grain sizes at T_max >450 °C show an Arrhenius type evolution reflecting the stabilized grain size in deformed and relative pure dolomite. The stabilized grain size is five times smaller than that of calcite at the same temperature and shows the same Arrhenius-type evolution. In addition, the effect of second phase particle influences the grain size evolution, comparable with calcite. Calcite/dolomite mixtures are also characterized by the same difference in grain size, but recrystallization mechanism including chemical recrystallization induced by deformation may contribute to apparent non-temperature equilibrated Mg-content in calcite.     

Local modification of rock chemistry by deformation

Metabasalts subjected to progressive deformation in large-scale shear zones at Yellowknife display corresponding changes in major element abundances. Deformation, under conditions of greenschist facies metamorphism, has involved grain size reduction from 1200 m to <20 m, depletion of SiO₂ (5%) and Na₂O, together with hydration, and a decrease in specific gravity from 2.97 to 2.80. Chemical redistribution by deformation has been accomplished through a decrease in grain diameter of quartz and albite by intercrystalline diffusive mass transport (pressure solution), with concomitant transfer of material into extension veins. The degree of chemical modification is related to the finite strain. Deformation has involved a redistribution of 7.10¹⁵g of SiO₂ over a volume of about 50km³.The microstructure of an adamellite deformed in a shear zone at higher temperature, under conditions of amphibolite facies metamorphism is indicative of dominant dislocation creep. A low degree of tectonic grain refinement is present. Constant values of major element abundances and specific gravity determined across the shear zone at increasing states of strain imply isochemical and isovolumetric deformation. These results are taken to support the precept that crustal deformation is characterised by a low temperature deformation regime dominated by pressure solution, with local changes of rock chemistry and volume; and a high temperature regime in which strain is accommodated principally by dislocation creep, an isochemical and isovolumetric deformation mechanism.     

Microstructure and fabric development in ice: Lessons learned from in situ experiments and implications for understanding rock evolution

In this contribution we present a review of the evolution of microstructures and fabric in ice. Based on the review we show the potential use of ice as an analogue for rocks by considering selected examples that can be related to quartz-rich rocks. Advances in our understanding of the plasticity of ice have come from experimental investigations that clearly show that plastic deformation of polycrystalline ice is initially produced by basal slip. Interaction of dislocations play an essential role for dynamic recrystallization processes involving grain nucleation and grain-boundary migration during the steady-state flow of ice. To support this review we describe deformation in polycrystalline ‘standard’ water-ice and natural-ice samples, summarize other experiments involving bulk samples and use in situ plane-strain deformation experiments to illustrate the link between microstructure and fabric evolution, rheological response and dominant processes. Most terrestrial ice masses deform at low shear stresses by grain-size-insensitive creep with a stress exponent (n ≤ 3). However, from experimental observations it is shown that the distribution of plastic activity producing the microstructure and fabric is initially dominated by grain-boundary migration during hardening (primary creep), followed by dynamic recrystallization during transient creep (secondary creep) involving new grain nucleation, with further cycles of grain growth and nucleation resulting in near steady-state creep (tertiary creep). The microstructural transitions and inferred mechanism changes are a function of local and bulk variations in strain energy (i.e. dislocation densities) with surface grain-boundary energy being secondary, except in the case of static annealing. As there is a clear correspondence between the rheology of ice and the high-temperature deformation dislocation creep regime of polycrystalline quartz, we suggest that lessons learnt from ice deformation can be used to interpret polycrystalline quartz deformation. Different to quartz, ice allows experimental investigations at close to natural strain rate, and through in-situ experiments offers the opportunity to study the dynamic link between microstructural development, rheology and the identification of the dominant processes.     

Deformation mechanism maps for feldspar rocks

Deformation mechanism maps for feldspar rocks were constructed based on recently published constitutive laws for dislocation and grain boundary diffusion creep of wet and dry plagioclase aggregates. The maps display constant temperature contours in stress-grain size space for strain rates ranging from 10⁻¹⁶ to 10⁻¹² s⁻¹.Two fields of dominance of grain boundary diffusion-controlled creep and dislocation creep are separated by a strongly grain size-sensitive transition zone. For wet rocks, diffusion-controlled creep dominates below a grain size of about 0.1–1 mm, depending on temperature, stress, strain rate and feldspar composition. Plagioclase aggregates containing up to 0.3 wt.% water as often found in natural feldspars are more than 2 orders of magnitude weaker than dry rocks. The strength of water-bearing feldspar rocks is moderately dependent on composition and water fugacity.For a grain size range of about 10–50 μm commonly observed in natural ultramylonites, the deformation maps predict that diffusion-controlled creep is dominant at greenschist to granulite facies conditions. Low viscosity estimates of 10¹⁸–10¹⁹ Pa·s from modeling postseismic stress relaxation and channel flow of the continental lower crust can only be reconciled with laboratory experiments assuming dislocation creep at high temperatures >900 °C or, at lower temperatures, diffusion creep of fine-grained rocks possibly localized in abundant high strain shear zones. For similar thermodynamic conditions and grain size, lower crustal rocks are predicted to be less than order of magnitude weaker than upper mantle rocks.     

The effect of dissolved magnesium on creep of calcite II: transition from diffusion creep to dislocation creep

We extended a previous study on the influence of Mg solute impurity on diffusion creep in calcite to include deformation under a broader range of stress conditions and over a wider range of Mg contents. Synthetic marbles were produced by hot isostatic pressing (HIP) mixtures of calcite and dolomite powders for different intervals (2–30 h) at 850°C and 300 MPa confining pressure. The HIP treatment resulted in high-magnesian calcite aggregates with Mg content ranging from 0.5 to 17 mol%. Both back-scattered electron images and chemical analysis suggested that the dolomite phase was completely dissolved, and that Mg distribution was homogeneous throughout the samples at the scale of about two micrometers. The grain size after HIP varied from 8 to 31 μm, increased with time at temperature, and decreased with increasing Mg content (>3.0 mol%). Grain size and time were consistent with a normal grain growth equation, with exponents from 2.4 to 4.7, for samples containing 0.5–17.0 mol% Mg, respectively. We deformed samples after HIP at the same confining pressure with differential stresses between 20 and 200 MPa using either constant strain rate or stepping intervals of loading at constant stresses in a Paterson gas-medium deformation apparatus. The deformation tests took place at between 700 and 800°C and at strain rates between 10⁻⁶ and 10⁻³ s⁻¹. After deformation to strains of about 25%, a bimodal distribution of large protoblasts and small recrystallized neoblasts coexisted in some samples loaded at higher stresses. The deformation data indicated a transition in mechanism from diffusion creep to dislocation creep. At stresses below 40 MPa, the strength was directly proportional to grain size and decreased with increasing Mg content due to the reductions in grain size. At about 40 MPa, the sensitivity of log strain rate to log stress, (n), became greater than 1 and eventually exceeded 3 for stresses above 80 MPa. At a given strain rate and temperature, the stress at which that transition occurred was larger for samples with higher Mg content and smaller grain size. At given strain rates, constant temperature, and fixed grain size, the strength of calcite in the dislocation creep regime increased with solute content, while the strength in the diffusion creep regime was independent of Mg content. The results suggest that chemical composition will be an important element to consider when solid substitution can occur during natural deformation.     

Superplastic flow in finegrained limestone

Creep of Solnhofen limestone at temperatures between 600° and 900° C was found to fall into three different flow regimes: regime 1 with an exponential stress-dependence of strain rate, regime 2 with power-law creep and n ~ 4.7 and finally a superplastic regime 3 with n ~ 1.7. Within the superplastic regime the creep behaviour is strongly grain-size dependent, the strain rate increasing markedly with decrease in grain size at a given stress. Microstructural observations indicate that in regimes 1 and 2 intracrystalline plasticity is dominant whereas the superplastic regime is characterized by grain-boundary sliding. The crystallographic preferred orientation within the superplastic regime is weaker and of different geometry when compared with that in flow regimes 1 and 2. In a discussion on the deformation mechanisms it is suggested that flow regimes 1 and 2 are regimes of dis location creep in which the rate controlling step is diffusion assisted; for the superplastic regime existing models of grain-boundary sliding are compared with the observations Finally, the tectonophysical importance of superplasticity is discussed and by extra polating the observed creep behaviour to geological strain rates it is found that super plasticity in rocks is to be expected under a wide range of conditions, particularly at smal grain sizes.     

Macro‐and Microstructural,Textural Fabrics and Deformation Mechanism of Calcite Mylonites from Xar Moron‐Changchun Dextral Shear Zone,Northeast China

The calcite mylonites in the Xar Moron-Changchun shear zone show a significance dextral shearing characteristics. The asymmetric(σ-structure) calcite/quartz grains or aggregates, asymmetry of calcite c-axes fabric diagrams and the oblique foliation of recrystallized calcite grains correspond to a top-to-E shearing. Mineral deformation behaviors, twin morphology, C-axis EBSD fabrics, and quartz grain size-frequency diagrams demonstrate that the ductile shear zone was developed under conditions of greenschist facies, with the range of deformation temperatures from 200 to 300°C. These subgrains of host grains and surrounding recrystallized grains, strong undulose extinction, and slightly curved grain boundaries are probably results of intracrystalline deformation and dynamic recrystallization implying that the deformation took place within the dislocation-creep regime at shallow crustal levels. The calculated paleo-strain rates are between 10~(–7.87)s~(–1) and 10~(–11.49)s~(–1) with differential stresses of 32.63–63.94 MPa lying at the higher bound of typical strain rates in shear zones at crustal levels, and may indicate a relatively rapid deformation. The S-L-calcite tectonites have undergone a component of uplift which led to subhorizontal lifting in an already non-coaxial compressional deformation regime with a bulk pure shear-dominated general shear. This E-W large-scale dextral strike-slip movement is a consequence of the eastward extrusion of the Xing'an-Mongolian Orogenic Belt, and results from far-field forces associated with Late Triassic convergence domains after the final closure of the Paleo-Asian Ocean.     

Dynamic recrystallization of wet synthetic polycrystalline halite: dependence of grain size distribution on flow stress, temperature and strain

It is often observed that dynamic recrystallization results in a recrystallized grain size distribution with a mean grain size that is inversely related to the flow stress. However, it is still open to discussion if theoretical models that underpin recrystallized grain size–stress relations offer a satisfactorily microphysical basis. The temperature dependence of recrystallized grain size, predicted by most of these models, is rarely observed, possibly because it is usually not systematically investigated. In this study, samples of wet halite containing >10 ppm water (by weight) were deformed in axial compression at 50 MPa confining pressure. The evolution of the recrystallized grain size distribution with strain was investigated using experiments achieving natural strains of 0.07, 0.12 and 0.25 at a strain rate of 5×10⁻⁷ s⁻¹ and a temperature of 125 °C. The stress and temperature dependence of recrystallized grain size was systematically investigated using experiments achieving fixed strains of 0.29–0.46 (and one to a strain of 0.68) at constant strain rates of 5×10⁻⁷–1×10⁻⁴ s⁻¹ and temperatures of 75–240 °C, yielding stresses of 7–22 MPa. The microstructures and full grain size distributions of all samples were analyzed. The results showed that deformation occurred by a combination of dislocation creep and solution-precipitation creep. Dynamic recrystallization occurred in all samples and was dominated by fluid assisted grain boundary migration. During deformation, grain boundary migration results in a competition between grain growth due to the removal of grains with high internal strain energy and grain size reduction due to grain dissection (i.e. moving boundaries that crosscut or consume parts of neighbouring grains). At steady state, grain growth and grain size reduction processes balance, yielding constant flow stress and recrystallized grain size that is inversely related to stress and temperature. Evaluation of the recrystallized grain size data against the different models for the development of mean steady state recrystallized grain size revealed that the data are best described by a model based on the hypothesis that recrystallized grain size organizes itself in the boundary between the (grain size sensitive) solution-precipitation and (grain size insensitive) dislocation creep fields. Application of a piezometer, calibrated using the recrystallized grain size data, to natural halite rock revealed that paleostresses can vary significantly with temperature (up to a factor of 2.5 for T=50–200 °C) and that the existing temperature independent recrystallized grain size–stress piezometer may significantly underestimate flow stresses in natural halite rock.     

Unusual transition in quartzite dislocation creep regimes and crystal slip systems in the aureole of the Eureka Valley–Joshua Flat–Beer Creek pluton, California: a case for anhydrous conditions created by decarbonation reactions

Microstructures and quartz c-axis fabrics were analyzed in five quartzite samples collected across the eastern aureole of the Eureka Valley–Joshua Flat–Beer Creek composite pluton. Temperatures of deformation are estimated to be 740±50 °C based on a modified c-axis opening angle thermometer of Kruhl (J. Metamorph. Geol. 16 (1998) 142). In quartzite layers located closest (140 m) to the pluton-wall rock contact, flattened detrital grains are plastically deformed and partially recrystallized. The dominant recrystallization process is subgrain rotation (dislocation creep regime 2 of Hirth and Tullis (J. Struct. Geol. 14 (1992) 145)), although grain boundary migration (dislocation creep regime 3) is also evident. Complete recrystallization occurs in quartzite layers located at a distance of 240 m from the contact, and coincides with recrystallization taking place dominantly through grain boundary migration (regime 3). Within the quartzites, strain is calculated to be lowest in the layers closest to the pluton margin based on the aspect ratios of flattened detrital grains.The c-axis fabrics indicate that a slip operated within the quartzites closest to the pluton-wall rock contact and that with distance from the contact the operative slip systems gradually switch to prism [c] slip. The spatial inversion in microstructures and slip systems (apparent “high temperature” deformation and recrystallization further from the pluton-contact and apparent “low temperature” deformation and recrystallization closer to the pluton-contact) coincides with a change in minor phase mineral content of quartzite samples and also in composition of the surrounding rock units. Marble and calc-silicate assemblages dominate close to the pluton-wall rock contact, whereas mixed quartzite and pelite assemblages are dominant further from the contact.We suggest that a thick marble unit located between the pluton and the quartzite layers acted as a barrier to fluids emanating from the pluton. Decarbonation reactions in marble layers interbedded with the inner aureole quartzites and calc-silicate assemblages in the inner aureole quartzites may have produced high X_CO2 (water absent) fluids during deformation. The presence of high X_CO2 fluid is inferred from the prograde assemblage of quartz+calcite (and not wollastonite)+diopside±K-feldspar in the inner aureole quartzites. We suggest that it was these “dry” conditions that suppressed prism [c] slip and regime 3 recrystallization in the inner aureole and resulted in a slip and regime 2 recrystallization, which would normally be associated with lower deformation temperatures. In contrast, the prograde assemblage in the pelite-dominated outer part of the aureole is biotite+K-feldspar. These “wet” pelitic assemblages indicate fluids dominated by water in the outer part of the aureole and promoted prism [c] slip and regime 3 recrystallization. Because other variables could also have caused the spatial inversion of c-axis fabrics and recrystallization mechanisms, we briefly review those variables known to cause a transition in slip systems and dislocation creep regimes in quartz. Our conclusions are based on a small number of samples, and therefore, the unusual development of crystal fabrics and microstructures in the aureole to the EJB pluton suggests that further study is needed on the effect of fluid composition on crystal slip system activity and recrystallization mechanisms in naturally deformed rocks.     

The effect of ductile deformation on the kinetics and mechanisms of the aragonite-calcite transformation

Abstract The effect of ductile deformation (dislocation creep) on the kinetics of the aragonite-calcite transformation has been studied at 1 atm (330° C and 360° C) and 900-1500 MPa (500° C) using undeformed and either previously or simultaneously deformed samples (500° C and a strain rate of 10^-6 s). Deformation enhances the rate of the transformation of calcite to aragonite, but decreases the rate of transformation of aragonite to calcite. The difference results from a dependence of transformation rate on grain size, coupled with a difference in the accommodation mechanisms, climb versus recry-stallization, of these minerals during dislocation creep. Dislocation climb is relatively easy in calcite and thus plastic strain results in high dislocation densities without significant grain size reduction. The rate of transformation to aragonite is enhanced primarily because of the increase in nucleation sites at dislocations and subgrain boundaries. In aragonite, on the other hand, dislocation climb is difficult and thus plastic strain produces extensive dynamic recry-stallization resulting in a substantial grain size reduction. The transformation of aragonite is inhibited because the increase in calcite nucleation sites at dislocations and/or new grain boundaries is more than offset by the inability of calcite to grow across high angle grain boundaries. Thus the net effect of ductile deformation by dislocation creep on the kinetics of polymorphic phase transformations depends on the details of the accommodation mechanism.     

High-temperature creep in a Ni2GeO4: a contribution to creep systematics in spinel

 High-temperature creep behavior in Ni₂GeO₄ spinel was investigated using synthetic polycrystalline aggregates with average grain sizes ranging from submicron to 7.4 microns. Cylindrical samples were deformed at constant load in a gas-medium apparatus at temperatures ranging from 1223 to 1523 K and stresses ranging from 40 to 320 MPa. Two deformation mechanisms were identified, characterized by the following flow laws: where σ is in MPa, d is in μm and T is in Kelvin. These flow laws suggest that deformation was accommodated by dislocation creep and grain-boundary diffusion (Coble) creep, respectively. A comparison with other spinels shows that an isomechanical group can be defined for spinels although some differences between normal and inverse spinels can be identified. When creep data for olivine and spinel are normalized and extrapolated to Earth-like conditions, spinel (ringwoodite) has a strength similar to olivine in the dislocation creep regime and is considerably stronger than olivine in the diffusion creep regime at coarse grain size. However, when grain-size reduction occurs, spinel can become weaker than olivine due to its high grain-size sensitivity (Coble creep behavior). Analysis of normalized diffusion creep data for olivine and spinel indicate that spinel is weaker than olivine at grain sizes less than 2 μm. Received: 18 June 2000 / Accepted: 3 April 2001     

Dislocation microstructure and phase distribution in a lower crustal shear zone – an example from the Ivrea-Zone, Italy

The analysis of fabric and microstructure across an amphibolite facies shear zone of mafic composition reveals that the strain-dependent change from grain size insensitive to grain size sensitive creep is associated with a fundamental reorganization of the mylonitic fabric. At moderate strain a banded mylonite evolves from a metagabbro, which displays a mechanically-induced compositional layering. Strain is concentrated in monomineralic layers of dynamically recrystallized plagioclase. At higher strain and decreasing grain size (10-30 µm) the phase segregation is progressively destroyed and replaced by a phase mixture of amphibole and plagioclase. Phase mixing in these ultramylonites is developed and stabilized by heterogeneous nucleation processes of amphibole and plagioclase within unlike phases and at dilatant sites. Nucleation appears to be controlled by grain-scale gradients in stress. A dispersed phase distribution in fine-grained ultramylonites indicates (water-assisted) diffusion processes that accommodate grain boundary sliding. Although diffusion-controlled creep plays a dominant role in these ultramylonites, the dislocation densities remain high (2.0-4.0᎒⁹ cm^-2) and indicate that two competing mechanisms (dislocation and diffusion creep) accommodate grain boundary sliding. Commonly accepted criteria for superplastic or granular flow derived from monomineralic aggregates must be applied with caution to polymineralic rocks of mafic composition.     

Diffusion creep and partial melting in high temperature mylonitic gneisses, Hope Valley shear zone, New England Appalachians, USA

Field, petrographic, microstructural and isotopic studies of mylonitic gneisses and associated pegmatites along the Hope Valley shear zone in southern Rhode Island indicate that late Palaeozoic deformation (c. 275 Ma) in this zone occurred at very high temperatures (>650 °C). High‐energy cuspate/lobate phase boundary microstructures, a predominance of equant to sub‐equant grains with low internal lattice strain, and mixed phase distributions indicate that diffusion creep was an important and possibly predominant deformation mechanism. Field and petrographic evidence are consistent with the presence of an intergranular melt phase during deformation, some of which collected into syntectonic pegmatites. Rb/Sr isotopic analyses of tightly sampled pegmatites and wall rocks confirm that the pegmatites were derived as partial melts of the immediately adjacent, isotopically heterogeneous mylonitic gneisses. The presence of syntectonic interstitial melts is inferred to have permitted a switch from dislocation creep to melt‐enhanced diffusion creep as the dominant mechanism in these relatively coarse‐grained mylonitic gneisses (200–500 µm syn‐deformational grain size). A switch to diffusion creep would lead to significant weakening, and may explain why the Hope Valley shear zone evolved into a major regional tectonic boundary. This work identifies conditions under which diffusion creep operates in naturally deformed granitic rocks and illuminates the deformation processes involved in the development of a tectonic boundary between two distinct Late Proterozoic (Avalonian) basement terranes.     

Microfabric of folded quartz veins in metagreywackes: dislocation creep and subgrain rotation at high stress

The microfabrics of folded quartz veins in fine‐grained high pressure–low temperature metamorphic greywackes of the Franciscan Subduction Complex at Pacheco Pass, California, were investigated by optical microscopy, scanning electron microscopy including electron backscatter diffraction, and transmission electron microscopy. The foliated host metagreywacke is deformed by dissolution–precipitation creep, as indicated by the shape preferred orientation of mica and clastic quartz without any signs of crystal‐plastic deformation. The absence of crystal‐plastic deformation of clastic quartz suggests that the flow stress in the host metagreywacke remained below a few tens of MPa at temperatures of 250–300 °C. In contrast, the microfabric of the folded quartz veins indicates deformation by dislocation creep accompanied by subgrain rotation recrystallization. For the small recrystallized grain size of ～8 ± 6 μm, paleopiezometers indicate differential stresses of a few hundred MPa. The stress concentration in the single phase quartz vein is interpreted to be due to its higher effective viscosity compared to the fine‐grained host metagreywacke deforming by dissolution–precipitation creep. The fold shape suggests a viscosity contrast of one to two orders of magnitude. Deformation by dissolution–precipitation creep is expected to be a continuous process. The same must hold for folding of the vein and deformation of the vein quartz by dislocation creep. The microfabric suggests dynamic recrystallization predominantly by subgrain rotation and only minor strain‐induced grain boundary migration, which requires low contrasts in dislocation density across high‐angle grain boundaries to be maintained during climb‐controlled creep at high differential stress. The record of quartz in these continuously deformed veins is characteristic and different from the record in metamorphic rocks exhumed in seismically active regions, where high‐stress deformation at similar temperatures is episodic and related to the seismic cycle.     

Rheological evolution of a Mediterranean subduction complex

We use field and microstructural observations, coupled to previously published P-T-time histories, to track the rheological evolution of an intracontinental subduction complex exposed in the Betic Cordillera in the western Mediterranean region. The body of rock we focus on, known as the Nevado-Filabride Complex (NFC), was originally part of the upper crust of the Iberian margin. It was subducted into hot asthenospheric mantle, then exhumed back toward the surface in two stages: an early stage of fast exhumation along the top of the subducting slab in a subduction channel, and a late stage of slower exhumation resulting from capture by a low-angle detachment fault rooted at the brittle-ductile transition. Each stage of deformation in the NFC was punctuated by changes in the dominant deformation mechanism. Deformation during initial subduction of the complex was accommodated by pressure-solution creep in the presence of a fluid phase – the grain sizes, stress magnitudes, and estimated strain rates for this stage are most consistent with a thin-film model for pressure solution in which the diffusion length scale is controlled by the grain size. During the early stages of exhumation within the subduction channel, deformation transitioned from pressure solution to dislocation creep due to increases in temperature, which resulted in increases in both water fugacity and grain size, each of which favor the dislocation creep mechanism. Differential stress magnitudes for this stage were ∼10 MPa, and are consistent with simple models of buoyancy-driven channel flow. With continuing subduction-channel exhumation, deformation remained within the dislocation creep field because sequestration of free water into hydrous, retrogressive minerals suppressed the pressure-solution mechanism. Differential stresses progressively increased to ∼100 MPa near the mouth of the channel during cooling as the rocks moved into mid-crustal levels. During the final, core-complex stage of exhumation, deformation was progressively concentrated into a narrow zone of highly localized strain beneath a mid-crustal detachment fault. Localization was promoted by a transition from dislocation creep to dislocation-creep-accommodated grain boundary sliding at temperatures of ∼350–380 °C, grain sizes of ∼4 μm and differential stress magnitudes of ∼200 MPa. Peak differential stress magnitudes of ∼200 MPa recorded just below the brittle-ductile transition are consistent with Byerlee's law in the upper crust assuming a vertical maximum principal stress and near-hydrostatic pore fluid pressures. Overall, the distribution of stress with temperature, coupled to independent constraints on strain rate from field observations and geochronology, indicate that the naturally calibrated Hirth et al. (2001) flow law for wet quartzite accurately predicts the rheological behavior of mid-crustal rocks deforming by dislocation creep.     

Strain localisation in the subcontinental mantle — a ductile alternative to the brittle mantle

It is now admitted that the high strength of the subcontinental uppermost mantle controls the first order strength of the lithosphere. An incipient narrow continental rift therefore requires an important weakening in the subcontinental mantle to promote lithosphere-scale strain localisation and subsequent continental break-up. Based on the classical rheological layering of the continental lithosphere, the origin of a lithospheric mantle shear/fault zone has been attributed to the existence of a brittle uppermost mantle. However, the lack of mantle earthquakes and the absence of field occurrences in the mantle fault zone led to the idea of a ductile-related weakening mechanism, instead of brittle-related, for the incipient mantle strain localisation. In order to provide evidence for this mechanism, we investigated the microstructures and lattice preferred orientations of mantle rocks in a kilometre-scale ductile strain gradient in the Ronda Peridotites (Betics cordillera, Spain). Two main features were shown: 1) grain size reduction by dynamic recrystallisation is found to be the only relevant weakening mechanism responsible for strain localisation and 2), with increasing strain, grain size reduction is coeval with both the scattering of orthopyroxene neoblasts and the decrease of the olivine fabric strength (LPO). These features allow us to propose that grain boundary sliding (GBS) partly accommodates dynamic recrystallisation and subsequent grain size reduction.A new GBS-related experimental deformation mechanism, called dry-GBS creep, has been shown to accommodate grain size reduction during dynamic recrystallisation and to induce significant weakening at low temperatures (T < 800 °C). The present microstructural study demonstrates the occurrence of the grain size sensitive dry-GBS creep in natural continental peridotites and allows us to propose a new rheological model for the subcontinental mantle. During dynamic recrystallisation, the accommodation of grain size reduction by three competing deformation mechanisms, i.e., dislocation, diffusion and dry-GBS creeps, involves a grain size reduction controlled by the sole dislocation creep at high temperatures (> 800 °C), whereas dislocation creep and dry-GBS creep, are the accommodating mechanisms at low temperatures (< 800 °C). Consequently, weakening is very limited if the grain size reduction occurs at temperatures higher than 800 °C, whereas a large weakening is expected in lower temperatures. This large weakening related to GBS creep would occur at depths lower than 60 km and therefore provides an explanation for ductile strain localisation in the uppermost continental mantle, thus providing an alternative to the brittle mantle.     

Grain size reduction by dynamic recrystallization: can it result in major rheological weakening?

It is widely believed that grain size reduction by dynamic recrystallization can lead to major rheological weakening and associated strain localization by bringing about a switch from grain size insensitive dislocation creep to grain size sensitive diffusion creep. Recently, however, we advanced the hypothesis that, rather than a switch, dynamic recrystallization leads to a balance between grain size reduction and grain growth processes set up in the neighborhood of the boundary between the dislocation creep field and the diffusion creep field. In this paper, we compare the predictions implied by our hypothesis with those of other models for dynamic recrystallization. We also evaluate the full range of models against experimental data on a variety of materials. We conclude that a temperature dependence of the relationship between recrystallized grain size and flow stress cannot be neglected a priori. This should be taken into account when estimating natural flow stresses using experimentally calibrated recrystallized grain size piezometers. We also demonstrate experimental support for the field boundary hypothesis. This support implies that significant weakening by grain size reduction in localized shear zones is possible only if caused by a process other than dynamic recrystallization (such as syntectonic reaction or cataclasis) or if grain growth is inhibited.     

Post-deformational annealing of calcite rocks

The evolution of microstructure and crystallographic preferred orientation (CPO) during post-deformational annealing was studied on three calcite rock types differing in purity and grain size: Carrara marble (98% calcite, mean grain size of 115 μm), Solnhofen limestone (96%, 5 μm) and synthetic calcite aggregates (99%, 7 μm). Samples were first deformed in torsion at 727 °C at a shear strain rate of 3 × 10^{− 4} s^{− 1} to a shear strain of 5 and subsequently heat-treated at 727 °C for various durations between 0 and 24 h. Microstructures and CPOs were analysed by optical microscopy, image analysis and electron backscatter diffraction (EBSD).All rock types deformed in the dislocation creep field at the same applied conditions, but their microstructures and CPOs after deformation and after annealing differed depending on starting grain size and material composition. In Carrara marble and in the synthetic calcite aggregate, a strong CPO developed during deformation accompanied by dynamic recrystallisation with significant changes in grain size. During annealing, widespread grain growth and subtle changes of CPO occurred, and equilibrated foam microstructures were approached after long annealing times. The CPO is the only feature in annealed samples indicating an earlier deformation phase, although it is not always identical to the CPO formed during deformation. In the more impure Solnhofen limestone, secondary phases on grain boundaries suppressed grain boundary mobility and prevented both the formation of a recrystallisation CPO during deformation and grain size modification during deformation and annealing.     

Quartz microstructures developed during non-steady state plastic flow at rapidly decaying stress and strain rate

Synseismic loading to very high stresses (>0.5 GPa) and subsequent creep during stress relaxation in the uppermost plastosphere at temperatures of ca. 300–350 °C, near the lower tip of an inferred once seismically active crustal scale fault, was proposed based on peculiar microstructures identified in rocks exposed over >100 km² in the Sesia Zone, European Western Alps. Here we discuss the conspicuous and highly heterogeneous microstructural record of quartz in disseminated small-scale shear zones. Sub-basal deformation lamellae and arrays of elongate subgrains on the TEM-scale indicate an early stage of glide-controlled deformation at high stresses. Distributed brittle failure is indicated by healed microcracks. Very fine-grained recrystallised aggregates with a pronounced crystallographic preferred orientation reflect intense plastic flow by dislocation creep. Locally, a fine-grained foam microstructure indicates a final stage of static grain growth at low differential stress. For the previously inferred peak stresses of about 0.5 GPa and given temperatures, initial strain rates on the order of 10⁻¹⁰ s⁻¹ are predicted by available flow laws for dislocation creep of quartz. We emphasise the importance of short-term non-steady state deformation in the uppermost plastosphere underlying seismically active upper crust. The related heterogeneous record of quartz is governed by the local stress history at constant temperature.