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1.
The component composition and specific features of the structure of smectite-bearing clays in the Middle Eocene Kievskaya Formation of the Russian Plate were studied by the scanning electron microscopic, X-ray phase analysis, and complete chemical analysis methods. The clays are characterized by metastable (unstable) state of material expressed as abundance of the semidissolved clasts of felsic volcanic ashes and radiolarian skeletons, as well as colloidal segregations of siliceous, aluminosiliceous (Al-Si) and ferroaluminosiliceous (Fe-Al-Si) gel-type materials and newly formed smectite. Three stages of the diagenetic alteration of Middle Eocene dacite ashes are identified. Mechanism of the further transformation of rocks into smectite clays with siliceous nodules is proposed. The viewpoint suggesting the volcanosedimentary origin of clays of the Kievskaya Formation is confirmed. Sources of the pyroclastic material (suppliers of material for clays) in the Kievskaya Formation could be related to active explosions in the Caucasian volcanic arc in the Middle Eocene.  相似文献   

2.
Wadi Queih basin hosts a ~2,500-m thick Neoproterozoic volcanoclastic successions that unconformably lie over the oldest Precambrian basement. These successions were deposited in alluvial fan, fluviatile, lacustrine, and aeolian depositional environments. Diagenetic minerals from these volcaniclastic successions were studied by X-ray diffractometry, scanning electron microscopy, and analytical electron microscopy. The diagenetic processes recognized include mechanical compaction, cementation, and dissolution. Based on the framework grain–cement relationships, precipitation of the early calcite cement was either accompanied or followed by the development of part of the pore-lining and pore-filling clay cements. Secondary porosity development occurred due to partial to complete dissolution of early calcite cement and feldspar grains. In addition to calcite, several different clay minerals including kaolinite, illite, and chlorite with minor smectite occur as pore-filling and pore-lining cements. Chlorite coating grains helps to retain primary porosity by retarding the envelopment of quartz overgrowths. Clay minerals and their diagenetic assemblages has been distinguished between primary volcaniclastics directly produced by pyroclastic eruptions and epiclastic volcaniclastics derived from erosion of the pre-existing volcanic rocks. Phyllosilicates of the epiclastic rocks display wider compositional variations owing to wide variations in the mineralogical and chemical compositions of the parent material. Most of the phyllosilicates (kaolinite, illite, chlorite, mica, and smectite) are inherited minerals derived from the erosion of the volcanic basement complex, which had undergone hydrothermal alteration. Smectites of the epiclastic rocks are beidellite–montmorillonite derived from the altered volcanic materials of the sedimentary environment. Conversely, phyllosilicate minerals of the pyroclastic rocks are dominated by kaolinite, illite, and mica, which were formed by pedogenetic processes through the hydrothermal influence.  相似文献   

3.
The pioneer compositional analysis carried out for clayey sediments from most regional Miocene stages of the Taman trough made it possible to define the main types of clays and trace their variability through the section. It is established that the composition of these clays is largely controlled by the sedimentary rather than postsedimentary lithogenetic factors. The maximal hydromica (hereafter, illite) concentrations (up to 73%) are recorded in sediments deposited during orogenesis activation and major regressions (terminal Tarkhanian, Sarmatian, and early Pontian). The dominant role and elevated concentration of the smectite component are characteristic of sediments corresponding to transgressive phases of the basin development. The shallow-water sediments, which show a notable facies heterogeneity, differ from their deepwater counterparts by a higher diversity in the clay composition. These regularities in the distribution of clay minerals may be used for the lithostratigraphic subdivision of the sequences with a lower content of the fossil mollusc assemblages.  相似文献   

4.
The Paleogene succession of the Himalayan foreland basin is immensely important as it preserves evidence of India-Asia collision and related records of the Himalayan orogenesis. In this paper, the depositional regime of the Paleogene succession of the Himalayan foreland basin and variations in composition of the hinterland at different stages of the basin developments are presented. The Paleogene succession of the western Himalayan foreland basin developed in two stages, i.e. syn-collisional stage and post-collisional stage. At the onset, chert breccia containing fragments derived from the hanging walls of faults and reworked bauxite developed as a result of erosion of the forebulge. The overlying early Eocene succession possibly deposited in a coastal system, where carbonates represent barriers and shales represent lagoons. Up-section, the middle Eocene marl beds likely deposited on a tidal flat. The late Eocene/Oligocene basal Murree beds, containing tidal bundles, indicate that a mixed or semi-diurnal tidal system deposited the sediments and the sedimentation took place in a tide-dominated estuary. In the higher-up, the succession likely deposited in a river-dominated estuary or in meandering rivers. In the beginning of the basin evolution, the sediments were derived from the Precambrian basement or from the metasediments/volcanic rocks possessing terrains of the south. The early and middle Eocene (54.7–41.3 Ma) succession of the embryonic foreland possibly developed from the sediments derived from the Trans-Himalayan schists and phyllites and Indus ophiolite of the north during syn-collisional stage. The detrital minerals especially the lithic fragments and the heavy minerals suggest the provenance for the late Eocene/Oligocene sequences to be from the recycled orogenic belt of the Higher Himalaya, Tethyan Himalaya and the Indus-suture zone from the north during post-collisional stage. This is also supported by the paleocurrent measurements those suggest main flows directed towards southeast, south and east with minor variations. This implies that the river system stabilized later than 41 Ma and the Higher Himalaya attained sufficient height around this time. The chemical composition of the sandstones and mudstones occurring in the early foreland basin sequences are intermediate between the active and passive continental margins and/or same as the passive continental margins. The sedimentary succession of this basin has sustained a temperature of about 200 °C and undergone a burial depth of about 6 km.  相似文献   

5.
Najman  Bickle  & Chapman 《地学学报》2000,12(1):28-34
Nd- and Sr-isotopic compositions of Palaeogene foreland basin sediments are used to provide insights into early Himalayan evolution, particularly the timing of exposure of high 87Sr/86Sr units, erosion of which may have caused the late Tertiary increase in oceanic Sr-isotopic ratios. During the late Palaeocene–early Eocene, erosion was from mixed sources including suture zone rocks. Exhumation of the High Himalaya was occurring by the time of deposition of alluvial sediments after mid-Oligocene times and this source has dominated Himalayan sediments from at least this time until the present day. The transition is interpreted to reflect exhumation of 'basement rocks' of the Indian plate, when the High Himalaya became a sufficient topographic barrier to separate suture zone rocks from the foreland basin. The marked rise in seawater 87Sr/86Sr from 40 Ma is consistent with the erosion of a Himalayan source with a high 87Sr/86Sr ratio.  相似文献   

6.
The geology and former climate of northern Oman favoured the formation of smectite clay minerals in certain materials which are implicated in ground heave problems. Investigations have shown that the smectite content of these expansive materials was developed in Oligocene, Miocene and Pliocene times. No evidence of a significant content of smectite was found in pre Eocene strata or in Quaternary strata, except for Desert Fill. It is shown that the main types of expansive materials in northern Oman are bentonitic mudstones, marls and silty mudstones, argillaceous dolomitic limestone, altered conglomerates and the desert fill derived from these. These swelling materials exist as impersistent bands within the bedrock Tertiary conglomerates and limestones. A geotechnical testing program was carried out on undisturbed samples from Sultan Qaboos University staff housing areas where building damage had occurred, to evaluate mineralogical composition, cation content and swelling characteristics. The test results characterized these soils/rocks as highly expansive type with Na-smectite as the dominant clay mineral.  相似文献   

7.
Early Jurassic climate is characterized by alternating cold and warm periods highlighted by studies based notably on oxygen isotopes measured on belemnite guards and other marine invertebrate shells. These climatic changes include changes in the hydrological cycle, and consequently weathering and runoff conditions. In order to clarify the erosion and weathering conditions during the Pliensbachian, this study determined the mineralogical composition of the clay fraction of 132 samples taken from the entire stage drilled in the Llanbedr (Mochras Farm) borehole (Cardigan Bay Basin). The clay mineral assemblages are composed of various proportions of chlorite, illite, illite/smectite mixed‐layers (R1 I–S), smectite and kaolinite, with possibly occasional traces of berthierine. The occurrence of abundant smectite indicates that the maximum burial temperature never exceeded 70°C. Consequently, clay minerals are considered mainly detrital, and their fluctuations likely reflect environmental changes. The variations in the proportions of smectite and kaolinite are opposite to each other. Kaolinite is particularly abundant at the base of the jamesoni Zone, in part coinciding with the δ13C negative excursion corresponding to the Sinemurian/Pliensbachian Boundary Event, and through the davoei Zone, whilst smectite is abundant in the upper part of jamesoni and base of ibex zones and through the subnodosus/gibbosus subzones of the margaritatus Zone. The kaolinite‐rich intervals reflect an intensification of hydrolysis and an acceleration of the hydrological cycle, while the smectite‐rich intervals indicate a more arid climate. The spinatum Zone is characterized by a distinct clay assemblage with abundant primary minerals, R1 I–S, kaolinite reworked from previously deposited sediments or from Palaeozoic rocks, and probably berthierine originating from contemporaneous ironstone‐generating environments of shallower waters. This mineralogical change by the end of the Pliensbachian likely reflects a transition from a dominant chemical weathering to a deeper physical erosion of the continent, probably related to a significant sea‐level fall consistent with a glacio‐eustatic origin.  相似文献   

8.
青藏高原东缘新生代构造层序与构造事件   总被引:28,自引:7,他引:28       下载免费PDF全文
新生代龙门山前盆地和盐源盆地是青藏高原东缘龙门山-锦屏山冲断带内及前缘地区发育和保存最好的新生代沉积盆地,本次以地层不整合面和ESR测年资料为主要依据,将该区新生代构造地层序列划分为5个构造层序,即TS1(65-55Ma)、TS2(40-50Ma)、TS3(23-16Ma)、TS4(4.7-1.6Ma)和TS5(0.74-0Ma),据此将青藏高原东缘新生代构造变形和隆升事件划分为5期,其中TS1与喜马拉雅地体和拉萨地体拼合事件相关,TS2与印亚碰撞事件相关,TS3与青藏高原第一次隆升事件相关,TS4与青藏高原第二次隆升事件相关,TS5与青藏高原第三次隆升事件相关。  相似文献   

9.
The cereal soils of the Northwest of Tunisia derive most of the time, from alluvial deposits or altered remains of carbonated and clayey rocks. Extraction of the clayey fraction permitted to reveal the presence of the following clayey minerals: kaolinite, illite, smectite, chlorite, as well as an illite–smectite interstratified layer, which is present in the deep horizons of the vertisol and in the isohumic soil. The presence of such types of clays shows that the evolution mechanism of soils is weathering of primary minerals inherited from the sedimentary rocks of the Northwest of Tunisia. These clays ensure to soils most of their cationic exchange capacity. Thanks to these clays, which have Ca++, Mg++ and K+ as exchangeable cations, the chemical fertility of these soils is ensured. It may be improved by increasing contents of organic matter, which is naturally few abundant in these soils. To cite this article: H. Ben Hassine, C. R. Geoscience 338 (2006).  相似文献   

10.
The bar-top sediments at the Tons river deposited mainly from the suspension current during waning stage condition of river are collected to study their provenance on the basis of clay mineralogy, heavy minerals and magnetic properties. The clay mineral assemblages in samples predominantly consist of illite, with minor amounts of kaolinite, smectite and chlorite. The clay minerals are contributed due to (i) weathering and decomposition of shales, argillaceous limestones and pyroclastic deposits of upper Vindhyan Groups and (ii) weathering and erosion of Banda plain of Gangetic alluvium. The low ZTR index for the studied samples indicates poor sediment maturity, rapid erosion in the source region and short transportation of detritus. The transparent heavy mineral assemblages in the sediment samples predominantly consist of garnet, with minor amounts of tourmaline, zircon, hornblende, enstatite, hypersthene, rutile, tremolite, kyanite, sillimanite, andalusite, chlorite, epidote, wollastonite, and staurolite. The heavy minerals are dominantly angular to sub-angular with some rounded to sub-rounded grains. The rounded grains indicate multicyclicity and derivation fromVindhyan sandstones. The angular grains are either contributed due to erosion of primary rocks of Bundelkhand gneissic complex and or various Gangetic alluviums. The magnetic properties from sediment samples indicate that the antiferromagnetic minerals (illite, chlorite and smectite) are more concentrated in clay sized particles and it also indicated mixed source rocks for the bar-top sediment of Tons river.  相似文献   

11.
四川盆地白垩系粘土矿物特征及古气候探讨   总被引:3,自引:0,他引:3  
曹珂  李祥辉  王成善 《地质学报》2008,82(1):115-123
四川盆地是中国白垩纪最具代表性的陆相沉积盆地之一,主要发育一套广布的红色碎屑岩沉积,且膏盐、沙漠相沉积发育。本文在前人地层古生物学研究的基础上,借助粘土矿物气候指标、结合沉积物碎屑成分,着重讨论了中侏罗世—古近纪早期四川盆地及周边地区的气候状况及演变过程。碎屑组份统计分析认为盆地北部边缘早白垩世早期构造因子起主导作用,而盆地南部白垩纪气候因子起主导作用,说明构造活动对沉积物影响不大。粘土矿物组份主要以蒙脱石和伊利石为主。多数样品蒙脱石和伊利石同时出现,指示沉积物源区为干冷与暖湿交替的气候环境;局部层段只有伊利石,指示干冷气候。同时,所有样品伊利石化学指数值均大于0.5,说明粘土矿物经历了强烈的化学风化作用,盆地内部为暖湿气候。  相似文献   

12.
通过X射线衍射系统分析了杭州湾地区SE2孔全新世沉积物的黏土矿物组成,结果显示研究层段黏土矿物主要由伊利石、绿泥石、高岭石和蒙脱石组成;伊利石结晶度较好,化学风化指数普遍大于0.5,表明以化学风化为主,且风化趋势自下而上呈递减趋势。通过对比中国东南部主要河流沉积物的黏土矿物组成,认为钱塘江下切河谷全新世沉积物的黏土矿物组成具有较好的物源指示意义: 全新世 Ⅰ 段(即古河口湾和河漫滩)沉积物主要来自钱塘江上游,特征黏土矿物为高岭石,河口外物质贡献不大;Ⅱ 段(即现代河口湾和近岸浅海)沉积物包含较多蒙脱石,表明不仅包括钱塘江上游物质,河口外长江物质也开始进入钱塘江河口。黏土矿物中,高岭石对气候有较好的指示作用:中全新世高岭石含量达到最高值,反映气候最为湿热,化学风化程度最高;晚全新世含量逐渐降低,反映气候逐渐回冷,化学风化强度降低。  相似文献   

13.
通过X射线衍射系统分析了杭州湾地区SE2孔全新世沉积物的黏土矿物组成,结果显示研究层段黏土矿物主要由伊利石、绿泥石、高岭石和蒙脱石组成;伊利石结晶度较好,化学风化指数普遍大于0.5,表明以化学风化为主,且风化趋势自下而上呈递减趋势。通过对比中国东南部主要河流沉积物的黏土矿物组成,认为钱塘江下切河谷全新世沉积物的黏土矿物组成具有较好的物源指示意义: 全新世 Ⅰ 段(即古河口湾和河漫滩)沉积物主要来自钱塘江上游,特征黏土矿物为高岭石,河口外物质贡献不大;Ⅱ 段(即现代河口湾和近岸浅海)沉积物包含较多蒙脱石,表明不仅包括钱塘江上游物质,河口外长江物质也开始进入钱塘江河口。黏土矿物中,高岭石对气候有较好的指示作用:中全新世高岭石含量达到最高值,反映气候最为湿热,化学风化程度最高;晚全新世含量逐渐降低,反映气候逐渐回冷,化学风化强度降低。  相似文献   

14.
Clay minerals of about 600 samples from drill cores in the Tertiary shales of the Rhinegraben, were analysed by X-ray diffraction methods. It was found that the abundance of smectite decreases with increasing amounts of mixed layer clays and illites, suggesting a diagenetic alteration of smectite with increasing temperatures of the sediments as was also observed in other sedimentary basins. As for the relation between smectite alteration and temperatures as measured in sample depths, in the marine Graue Schichtenfolge (Middle Oligocene) when temperatures reach 70°C and over, smectite no longer is to be found. In the limnic Bunte Niederröderner Schichten (Upper Oligocene) the maximum temperature of smectite occurrence is about 80°C. These temperatures also fit the results of former field studies of the thermal stability of smectite. In the brackish to limnic Obere and Untere Hydrobienschichten (Lower Miocene) however, smectite seems to have disappeared already at a temperature of over 30°C. Although the smectite distribution in the latter formations may depend partly on its inhomogenous deposition there is also evidence for the diagenetic alteration of smectite in these formations. The rapid disappearance of smectite in these formations was possibly caused by a greater availability of potassium ions since high permeability of these strata provide extraordinarily good mobility of the pore solutions. In the older Lymnäenmergel formation (Upper Eocene) a more advanced stage of smectite alteration is found as compared to the other formations at corresponding temperatures. This is considered to be the consequence of the longer duration of diagenesis and the rock salt inclusions of this saline formation which might have enriched the pore solutions with potassium ions.  相似文献   

15.
The clay mineralogy of the Newark Supergroup (Upper Triassic/Lower Jurassic) in the Connecticut Valley was studied by X-ray diffraction analysis. Clay minerals identified in 126 samples are illite, chlorite, smectite, kaolinite, vermiculite, expandable chlorite, mixed-layer illite/smectite, mixed-layer chlorite/smectite, and mixed-layer chlorite/vermiculite. In general, the rocks are illitic with subordinate amounts of chlorite. However, the various lithofacies in the Newark Supergroup are characterized by distinct clay-mineral assemblages. Red beds of floodplain origin contain clays mainly of detrital nature with 2M illite most abundant. Subordinate amounts of chlorite, smectite, vermiculite, kaolinite and mixed-layer illite/smectite are also present. An interstratified chlorite/vermiculite occurs in red mudstone underlying basalt flows. Lacustrine gray beds are generally characterized by the clay-mineral assemblage 1Md illite + chlorite with minor amounts of smectite ane expandable chlorite. An interstratified chlorite/smectite predominates in gray mudstone associated with perennial lake cycles in the East Berlin Formation. Black shales of deeper lacustrine origin contain the assemblage 1Md ifillite + trioctahedral smectite and traces of chlorite. Illite and smectite also occur as mixed-layer phases.In many respects, the distribution of clay minerals in the Connecticut Valley can be likened to the general scheme proposed for the Permo-Triassic basins of Europe and Africa. These display both vertical and horizontal variations in clay-mineral assemblages that reflect the chemical and spatiotemporal evolution of intrabasin depositional and diagenetic environments. Chemical data indicate that magnesium, especially, was concentrated in the black muds of large perennial lakes that intermittently occupied the Connecticut rift valley. Pore waters derived from these sediments played an important role in the development of Mg-rich 2 : 1 and interstratified clay minerals during early diagenesis.  相似文献   

16.
张德玉 《沉积学报》1993,11(1):111-120
根据三个沉积岩芯的研究,马里亚纳海槽和西菲律宾海盆更新世以来的沉积物中粘土矿物明显不同:前者以海槽内基性火山物质蚀变形成的蒙皂石为主,伴随少量铁镁绿泥石和伊利石;后者以来自海盆以西陆上岩石风化形成的伊利石为主,其次为蒙皂石、普通绿泥石和高岭石。这种差别除与物源有关外,主要与两个海盆中的火山活动有关。海槽内粘土矿物也有差异,迷可能与海底热液活动的影响有关。古气候对粘土矿物也有影响,但在海槽则被频繁的火山活动所掩盖。  相似文献   

17.
The Middle Muschelkalk (Middle Triassic) of the Catalan Coastal Range (north-east Spain) comprises sandstone, mudstone, anhydrite and minor carbonate layers. Interbedded sandstones and mudstones which are dominant in the north-eastern parts of the basin are terminal alluvial fan deposits. South-westward in the basin, the rocks become dominated by interbedded evaporites and mudstones deposited in sabkha/mudflat environments. The diagenetic and pore water evolution patterns of the Middle Muschelkalk suggest a strong facies control. During eodiagenesis, formation of microdolomite, anhydrite, baryte, magnesite, K-feldspar and mixed-layer chlorite/smectite was favoured within and adjacent to the sabkha/mudflat facies, whereas calcite, haematite, mixed-layer illite/smectite and quartz formed mainly in the alluvial facies. Low δ18OSMOW values for microdolomite (+23.7 to +28.4%) and K-feldspar overgrowths (+17.3 to +17.7%) suggest either low-temperature, isotopic disequilibrium or precipitation from low-18O porewaters. Low-18O waters might have developed, at least in part, during low-temperature alteration of volcanic rock fragments. During mesodiagenesis, precipitation of quartz overgrowths and coarse dolomite occurred in the alluvial sandstones, whereas recrystallization of microdolomite was dominant in the sabkha/mudflat facies. The isotopic compositions of these mesogenetic phases reflect increasing temperature during burial. Upon uplift and erosion, telogenetic calcite and trace haematite precipitated in fractures and replaced dolomite. The isotopic composition of the calcite (δ18OSMOW=+21.5 to +25.6%o; δ13C= 7.7 to - 5.6%o) and presence of haematite indicate infiltration of meteoric waters.  相似文献   

18.
我国中新生代陆相沉积,特别是咸化湖泊沉积中普遍发现属于“海源陆生”的沟鞭藻化石,由于其良好的生油特性,被认为是我国白垩纪—第三纪陆相油气资源的重要来源。柴达木盆地第三系始新统下干柴沟组是该地区最主要的烃源岩,生油岩及原油中富含公认的沟鞭藻生物标志物4 甲基甾烷和甲藻甾烷,但迄今该地区尚未发现可靠的沟鞭藻化石。本次研究在柴达木盆地北缘昆2井下干柴沟组发现了类型单调但化石丰富的以Subtilisphaera为主的沟鞭藻化石组合,为肯定柴达木盆地第三系原油沟鞭藻的贡献提供了直接化石证据。研究表明,沟鞭藻发育的第三系中始新统可能是本地区最有利的生油层,形成于湿热气候所控制的陆相咸水湖泊。  相似文献   

19.
《International Geology Review》2012,54(12):1829-1838
Arguments are presented here to the effect that the parent rocks of the red kaolinitic weathered crust on the Adzharian shore of the Black Sea are not the Middle and Upper Eocene volcanogenic hard rocks, but montmorillonitic clays over dense lavas, of hydrothermal origin and with relict structures of hyaloclastites, tuffs, and porous lavas of basaltic or trachytic composition. The erosion of clayey metasomatites and the development of their eluvium and soils begins in Middle Pleistocene, it appears (together with the post-Bakunian orogenic phase), and is continuing even now. -- Author  相似文献   

20.
黏土矿物古气候意义研究的现状与展望   总被引:6,自引:1,他引:5  
系统地分析了利用海洋沉积物、古土壤、湖盆沉积物中黏土矿物进行古气候环境研究的现状、存在问题和发展趋势。海洋沉积物的物源范围广,影响因素复杂,其中的碎屑黏土矿物所指示的古气候参数只能用于解释母源区的气候变化,而只有自生黏土矿物才能指示沉积区的气候;古土壤形成于特定的地质背景条件下,尤其是发育于火山物质母岩之上的风化自生黏土矿物,可以准确地指示该区的古气候条件;湖盆沉积物的物源范围小,沉积物中的黏土矿物可以更有效地运用于古气候环境的分析。对于沉积物中黏土矿物来源的分析,可以借助晶体中cv空位和tv空位的精细结构特征进行判断;在风化改造的红土剖面研究中,因强烈的化学风化、淋滤和迁移,黏土矿物方法具有独特的优势。风化过程中形成的一些亚种或过渡性黏土矿物,以及同生沉积过程中形成的黏土矿物,对气候环境的变化更加敏感,应加强这方面的研究。此外,在造山带的气候环境演化研究中,自生黏土矿物稳定同位素可以更可靠地指示气候环境的变化。  相似文献   

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