Asbestiform and non-asbestiform morphologies in a talc and vermiculite mine from the province of Córdoba (Argentina): a case study

In this work, a talc and vermiculite mine from the province of Córdoba (Argentina) was investigated with special emphasis on the occurrence of asbestiform and non-asbestiform phases. The meta-ultramafic rock was studied by a multimethodological approach, complementing field studies with petrographic-mineralogical, compositional and morphological analyses. Samples were examined by stereomicroscopy, polarizing light microscopy, SEM–EDS, XRD, DSC-TGA and FTIR. Complementary, compositional and textural analyses were performed with FE-SEM–EDS and EPMA. Talc-rich veins with a laminar and fibrous appearance were at first recognized. However, the fibrous morphology observed both in the field and by microscopy is due to an apparent habit because of the sample orientation. To avoid erroneous interpretations, studies by secondary electron images (SEM) are fundamental to carrying out this type of analysis. Tremolite was identified in different zones of the outcrop; however, only ~40% of the crystals located in the vermiculite zone have dimensions to be considered as asbestiform fibres in the range of respirable particles. In these types of complex deposits affected by superimposed metamorphic, igneous and deformational events, multimethodological approaches are necessary to develop models of occurrence of asbestiform morphologies that may be applicable to other with similar characteristics.     

First Lower Cretaceous record of Podocarpaceae wood associated with dinosaur remains from Patagonia,Neuquén Province,Argentina

The first Podocarpaceae wood record is described from the Mulichinco Formation (Valanginian, Lower Cretaceous), Neuquén Basin, Argentina. The specimen was directly associated with a middle caudal vertebra of a diplodocid sauropod dinosaur. A new species – Podocarpoxylon prumnopityoides – is proposed based on features that include the presence of abietinean wood type (tracheid radial pitting), plus podocarpoid (cupressoid type) and some dacrydioid (taxodioid type) cross-field pits, diffuse axial parenchyma and low rays. This combination of anatomical characters is comparable to both Prumnopitys and Podocarpus, whereas the type of pits in the cross-fields resembles some members of the extant Prumnopitys. This is the first unequivocal record of the Family Podocarpaceae in the Valanginian of South America and confirms the hypothesis that the divergence between the “Podocarpoid-Dacrydioid” and “Prumnopityoid” clades occurred earlier than the Early Cretaceous.     

Hydrochemistry and nutrients dynamic in the Suquía River urban catchment’s,Córdoba,Argentina

Suquía River is a medium-sized hydrological system (basin area of ~7,700 km²) that supplies fresh water to Córdoba city, a town of ~1,500,000 inhabitants in central Argentina. This paper examines the present-day hydrochemistry of Suquía River urban catchment analyzing its major and minor dissolved components, and the nutrients variability by means of QUAL-2K modeling software. The Suquía River has bicarbonate-type waters upstream the city and sulfate-type waters right downstream, whereas they exhibit a mixed-to-alkali-type cationic composition. The seasonal analysis of its major dissolved constituents clearly showed a dilution process during the wet season (i.e. austral summer). In the last 20 years, the Suquía River has modified its anionic composition, now showing higher relative concentrations of SO₄ ²⁻ as a consequence of urban activities. However, trace elements dissolved concentrations do not evidence a strong pollution effect. Nutrients [nitrogen species, total phosphorous (TP)] and related parameters, such as biochemical oxygen demand (BOD), and dissolved oxygen (DO), evidence a clear influence of human activities. The QUAL-2K model was used to evaluate the spatial behavior of selected nutrients and associated variables, (i.e. TP, N–NH₄ ⁺, N–NO₃ ⁻, DO, BOD). Nutrient concentrations are affected by point sources of contaminants, particularly domestic waste and sewage, as well as by diffuse agricultural pollution. A calibrated QUAL-2K modeling exercise clearly shows the impact of the Córdoba city’s municipal wastewater treatment plant on the Suquía River water quality.     

Fault gouge analyses: K–Ar illite dating,clay mineralogy and tectonic significance—a study from the Sierras Pampeanas,Argentina

We introduce a method for the detailed interpretation of K–Ar illite fine-fraction ages of fault gouges from non-sedimentary host rocks. Ages are cross-evaluated with several independent parameters, e.g. illite crystallinity, illite polytype quantification, grain size, mineralogical observations, K–Ar muscovite and biotite host-rock cooling ages as well as low-temperature thermochronological data (AFT, AHe, ZHe). This interpretation approach is applied to a regional study in order to constrain the ‘deformation path’ of the Eastern Sierras Pampeanas in NW Argentina. In the course of this study, a large number of gouge-bearing fault zones were systematically sampled and analysed. Obtained K–Ar illite fine-fraction ages range from Devonian to Cretaceous times, documenting a long-lasting brittle fault activity in this region. Ages >320 Ma are synchronous with a period of intra-Carboniferous compressional tectonism, whereas Permo-Triassic ages are contemporaneous to a flat-slab subduction episode of the Farallon plate beneath the South American plate. Middle to Late Permian and Early Triassic ages as well as Early Jurassic to Middle Cretaceous ages correlate with extensional tectonics in this region. Additionally, K–Ar illite ages reveal a propagation of brittle deformation from north to south in the Sierras de Córdoba and San Luis. Data integrity and consistency with other chronometers and geological evidence show that the here suggested interpretation is valid and can provide a powerful tool to evaluate cooling and deformation histories. Despite of that, we could show that the reliability of fault gouge data strongly depends on the regional cooling.     

Tracing metamorphism,exhumation and topographic evolution in orogenic belts by multiple thermochronology: a case study from the Nízke Tatry Mts., Western Carpathians

A combination of four thermochronometers [zircon fission track (ZFT), zircon (U–Th)/He (ZHe), apatite fission track (AFT) and apatite (U–Th–[Sm])/He (AHe) dating methods] applied to a valley to ridge transect is used to resolve the issues of metamorphic, exhumation and topographic evolution of the Nízke Tatry Mts. in the Western Carpathians. The ZFT ages of 132.1 ± 8.3, 155.1 ± 12.9, 146.8 ± 8.6 and 144.9 ± 11.0 Ma show that Variscan crystalline basement of the Nízke Tatry Mts. was heated to temperatures >210°C during the Mesozoic and experienced a low-grade Alpine metamorphic overprint. ZHe and AFT ages, clustering at ~55–40 and ~45–40 Ma, respectively, revealed a rapid Eocene cooling event, documenting erosional and/or tectonic exhumation related to the collapse of the Carpathian orogenic wedge. This is the first evidence that exhumation of crystalline cores in the Western Carpathians took place in the Eocene and not in the Cretaceous as traditionally believed. Bimodal AFT length distributions, Early Miocene AHe ages and thermal modelling results suggest that the samples were heated to temperatures of ~55–90°C during Oligocene–Miocene times. This thermal event may be related either to the Oligocene/Miocene sedimentary burial, or Miocene magmatic activity and increased heat flow. This finding supports the concept of thermal instability of the Carpathian crystalline bodies during the post-Eocene period.     

Pareto’s law and sample size: a case study of China’s urban system 1984–2008

While Pareto’s law has been widely supported by empirical evidence in urban studies, past studies have focused on finding best fits for city rank-size distribution. A main concern with Pareto’s law is the truncation of sample selection, for which few studies have examined it directly. This study tests three existing threshold methods (number threshold, size threshold, and urban population percentage threshold) using China’s city system as a case study. In addition, this study proposes a new method based upon the percentage threshold of the total number of cities. A systematic analysis is applied to examine the relationship between Pareto exponent and sample size using different threshold methods. The results show that Pareto exponent is sensitive to sample size and the truncation point. Including only large cities is problematic because a slight change in the truncation point will yield quite different results of Pareto exponent. In addition, the new method, the percentage threshold of the total number of cities method, presents an advantage over previous methods, in that this method yields a consistent set of results over a wide range of thresholds. Finally, when using this new method with China’s city system, the Pareto exponent presents a turning point in 1996, representing China’s transition from a planned economy to a more market oriented economy during that period.     

Pseudo- and real-inverted metamorphism caused by the superposition and extrusion of a stack of nappes: a case study of the Southern Brasília Orogen,Brazil

International Journal of Earth Sciences - The Southern Brasília Orogen is a Neoproterozoic belt that occurs along the southernmost border of the São Francisco Craton where the...     

Pingüino In-bearing polymetallic vein deposit,Deseado Massif,Patagonia, Argentina: characteristics of mineralization and ore-forming fluids

The Pingüino deposit, located in the low sulfidation epithermal metallogenetical province of the Deseado Massif, Patagonia, Argentina, represents a distinct deposit type in the region. It evolved through two different mineralization events: an early In-bearing polymetallic event that introduced In, Zn, Pb, Ag, Cd, Au, As, Cu, Sn, W and Bi represented by complex sulfide mineralogy, and a late Ag–Au quartz-rich vein type that crosscut and overprints the early polymetallic mineralization. The indium-bearing polymetallic mineralization developed in three stages: an early Cu–Au–In–As–Sn–W–Bi stage (Ps₁), a Zn–Pb–Ag–In–Cd–Sb stage (Ps₂) and a late Zn–In–Cd (Ps₃). Indium concentrations in the polymetallic veins show a wide range (3.4 to 1,184 ppm In). The highest indium values (up to 1,184 ppm) relate to the Ps₂ mineralization stage, and are associated with Fe-rich sphalerites, although significant In enrichment (up to 159 ppm) is also present in the Ps₁ paragenesis associated with Sn-minerals (ferrokesterite and cassiterite). The hydrothermal alteration associated with the polymetallic mineralization is characterized by advanced argillic alteration within the immediate vein zone, and sericitic alteration enveloping the vein zone. Fluid inclusion studies indicate homogenisation temperatures of 308.2–327°C for Ps₁ and 255–312.4°C for Ps₂, and low to moderate salinities (2 to 5 eq.wt.% NaCl and 4 to 9 eq.wt.% NaCl, respectively). δ³⁴S values of sulfide minerals (+0.76‰ to +3.61‰) indicate a possible magmatic source for the sulfur in the polymetallic mineralization while Pb isotope ratios for the sulfides and magmatic rocks (²⁰⁶Pb/²⁰⁴Pb, ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios of 17.379 to 18.502; 15.588 to 15.730 and 38.234 to 38.756, respectively) are consistent with the possibility that the Pb reservoirs for both had the same crustal source. Spatial relationships, hydrothermal alteration styles, S and Pb isotopic data suggest a probable genetic relation between the polymetallic mineralization and dioritic intrusions that could have been the source of metals and hydrothermal fluids. Mineralization paragenesis, alteration mineralogy, geochemical signatures, fluid inclusion data and isotopic data, confirm that the In-bearing polymetallic mineralization from Pingüino deposit is a distinct type, in comparison with the well-known epithermal low sulfidation mineralization from the Deseado Massif.     

Palaeoflood discharge estimation using dendrogeomorphic methods,rainfall-runoff and hydraulic modelling—a case study from southern Crete

Natural Hazards - This study represents the first palaeoflood discharge estimation using dendrogeomorphic evidence from two ungauged catchments in southern Crete. Dendrogeomorphological methods,...     

The impact of faults on the geomorphology of the Earth’s crust: case study of faults impacts on the geomorphology of Lar Valley,Northeast of Tehran (Iran)

The geomorphology of the Lar Valley in the Northeast of Tehran, the Capital of Iran, is under the geological influence of the Central Alborz, in which the different geological formations are folded and thrust, time and again over each other by faults, creating the heights. The Damavand volcano is located to the east of Lar Valley, appearing in the heights of Alborz at the point of deviation in the structural strike of Alborz chain and along the faults during the quaternary period. The physiographic, landslide phenomenon, rock fall, valleys, water courses and alluvial fans in the Lar Valley were reviewed and studied according to aerial photographs, satellite images and field observations from the aspect of their susceptibility to the impact of faults. The results indicate that 80% of the peaks and high mountains in Lar Valley are created and influenced by the action of overthrust faults. Ninety percent of the land and rock sinking are located in the intermediate regions between the faults, and they are believed to be the results of fault impacts. Seven out of the nine cases of landslide in Lar are located on or in the margin of the faults depicting the latter’s influence. The floor ratios of eight valleys were calculated and it was determined that in addition to the impacts of faults on creating the valleys, the situation of most of these along the margins of the faults as well as seven valleys are influenced by faults. The slope of rivulets and auxiliary rivers and their angles in relation to each other and the main river were calculated. The results showed that seven rivulets were under the influence of faults. Fifty-nine percent of the alluvial fans in Lar Valley were greatly influenced by faults, whereas 49% were under their normal impact. The supposition in this study is that the results can be used to identify faults and their characteristics.     

Vertebrate tracks from the Paso Córdoba fossiliferous site (Anacleto and Allen formations,Upper Cretaceous), Northern Patagonia,Argentina: Preservational,environmental and palaeobiological implications

The Paso Córdoba fossiliferous site (Río Negro, Northern Patagonia) is one of the first Mesozoic fossiliferous localities studied in Argentina. There, turtle, crocodile and dinosaur remains as well as dinosaur and bird tracks have been recorded. Recently, a new locality with vertebrate tracks, the Cañadón del Desvío, has been discovered in Paso Córdoba. Six track-bearing layers were located in outcrops belonging to the Anacleto (lower to middle Campanian, Neuquén Group) and Allen (middle Campanian-lower Maastrichtian, Malargüe Group) formations. The Cañadón del Desvío locality reveals that vertebrate trace fossils are distributed in two distinct environments, floodplains of a meandering fluvial to shallow lacustrine system and a wet interdune deposit that is associated to an aeolian setting. Also, in the logged section several soft sediment deformation structures were found. In regard of this, a sedimentary facies analysis is provided in order to assess the palaeoenvironmental implications of this new record. The analysed tracks are preserved in cross-sections, on bedding-planes and as natural casts. When it is possible, the tracking surface, true tracks, undertracks and overtracks/natural casts have been identified and the track preservation and the formation history of the tracksite are discussed. Only two tracks preserve enough anatomical details to relate them with their trackmakers, in this case hadrosaurid dinosaurs. The stratigraphical, facial and palaeoenvironmental data of this study support the idea of a transitional passage between the Anacleto and Allen Formation in Paso Córdoba. The presence of hadrosaurid dinosaur tracks suggests that the upper part of the log, where this kind of tracks were found, likely belong to Allen Formation due to this dinosaurs appear in the Southern Hemisphere in this epoch. The sum of osteological and ichnological remains improve the Paso Córdoba palaeofaunistic knowledge. The presence of six different levels in which the trackmakers walked reflects the abundance of vertebrates in the transition between Anacleto and Allen formations.     

Influence of Shannon’s entropy on landslide-causing parameters for vulnerability study and zonation—a case study in Sikkim, India

Landslide is a common hazard in the hilly regions, which causes heavy losses to life and properties every year. Since 1980, various researches and analyses have been carried out in the geographic information systems (GIS) environment to identify factors responsible for causing landslides. The important conditioning factors identified by the researchers are slope, geological, geomorphologic structures, and land use coupled with triggering factors like rainfall and a few of the anthropogenic activities. Almost all landslides vulnerability studies carried out so far used parameters of landslide events of the past as essential inputs and advanced methods like information value, regression analysis, fuzzy logic, etc. The present research is an attempt to investigate the landslide vulnerabilities in different slope areas with simple and realistic method of assignments of weights to the parameters based on experts?? opinion and generic logic, without using the parameters of past landslide events as inputs. The identified factors were assigned appropriate weights based on experts?? opinion and these weights were further balanced with respect to the Shannon??s entropy of their occurrences within the study area. The study area was finally classified into three zones namely least vulnerable zone, moderately vulnerable zone, and most vulnerable zone. When compared with the actual landslide history of the past, it was found that Shannon??s entropy applied zonation model matched to real landslide events with higher value of landslide density as compared to the model developed without Shannon??s entropy.     

Retrograde alterations of phyllosilicates in low-grade metapelite: a case study from the Szendr? Paleozoic, NE-Hungary

Frequently, at temperatures lower than the metamorphic peak conditions, slates undergo mineral transformations, usually mediated by fluids. We have studied core material of an epizonal slate series (Szendr? Mountains, NE-Hungary) to reconstruct the post-metamorphic lower-T hydrothermal alterations using petrographic, X-ray diffraction, electron microprobe methods, and transmission electron microscopy. The borehole crosscuts an upper part of the ca. 600?C800?m Lower-Carboniferous flysch-like Szendr? Phyllite Formation. The samples were metamorphosed reaching epizonal conditions with a mineral assemblage characterized by quartz, muscovite, chlorite and albite. Even in the freshest samples, break-up and loosening of the regional metamorphic structure was observed, with cracks parallel to or crossing the cleavage. In the upper part, chlorite and albite are almost absent, while the presence of paragonite, mixed Na?CK mica, and mixed-layered minerals with smectitic component are characteristic. Goethite, halloysite, and subordinate kaolinite are present in the most altered sample (13.0?m in the profile) which may indicate the position of the fissures in which the circulation of the post-metamorphic fluids was the most intense. Muscovite is the only mica from the lower part of the profile and chlorite becomes a significant constituent, whereas paragonite, halloysite, and kaolinite are missing. Discrete smectite is present in all the samples in spite of being incompatible with the prograde evolution of the sequence. The interleaved smectite layers in chlorite and muscovite/chlorite mixed-layers show at the lattice level textural characteristics indicative of a later alteration process. After the metamorphic peak at epizonal conditions, the introduction of hot fluids through the fractures gave rise to the crystallization of Na?CK white micas and muscovite/chlorite under anchizonal conditions. In a final stage of the hydrothermal process, the cooling of the circulating fluids favored the formation of halloysite and kaolinite in the areas near to the fissures, smectites in the samples far away from the fractures, and locally, goethite. The Fe₂O₃ content increasing upwards indicates oxidizing conditions in the late stage of hydrothermal activity and/or eventually, an influence of a younger near-surface weathering.     

Terrain characteristics and longitudinal,land use and land cover profiles behavior—a case study from Vamanapuram river basin,southern Kerala,India

The morphology of Vamanapuram river basin (VRB), southern Kerala, India has been studied by preparing longitudinal profiles from the source of VRB at Chemmunji Mottai (1,717 m) to its mouth at Muthalapallipozhy (Lakshadweep Sea). Survey of India topographical maps, Geocoded Satellite Imageries, Microsoft Excel and GIS software ILWIS 2.1 are used in this study. The morphometric analysis reveals that there are 1,489, 347, 79, 21, 6, 2 and 1 first-, second-, third-, fourth-, fifth-, sixth- and seventh-order streams, respectively, in VRB, which are responsible for the present-day landform genesis. The mean bifurcation value of VRB is 3.49. The Ponmudi hills receive the highest rainfall in VRB in the Western Ghats Region and Attingal, the lowest in the Coastal Strand Plain. The six land use and land cover profile sections show the distribution of land use–land cover with respect to elevation and depth to water level. The study reveals that mid and high lands generally occupy lower order streams up to fourth order and generally originate from linear ridge, hill crest, rocky slope (scarp face), side slope (S3)/slope 10–15° and hilly terrain.     

Assessing the vulnerability of social–environmental system from the perspective of hazard,sensitivity, and resilience: a case study of Beijing,China

Despite a recent increase in the number of vulnerability analyses there has been relatively little discussion of vulnerability assessment of social–environment system, especially when they face multiple hazards. In this study, we developed an applicable and convenient method to assess vulnerability of social–environment system at a regional scale. Vulnerability is quantified by measuring three critical elements (i.e. hazards, sensitivity, and resilience) through some key variables. The results showed that vulnerability is high in Miaofeng Mountain in Mengtougou District, the hills of Pinggu County and the riparian zones of the lower courses of the Beiyun and Yongding Rivers; but low in the city of Beijing and the southwestern part of the Fangshan District. Areas of very high, high, medium, and low-vulnerability account for 6.19, 25.48, 33.06, and 35.27% of the total area, respectively. The degree of vulnerability decreases in a northwest direction in mountainous areas and declines from watercourses to riparian zones along a lateral direction in the plain. Some adaptive strategies are also proposed.     

Trace elements and their correlations in hand-dug wells in a laterite environment in a semi-arid region: case study of Tikaré, Northern Burkina Faso

In many regions of the world and especially in arid and semi-arid areas, groundwater is the major source of drinking water for most of the rural population. The main reason is probably its accessibility through hand-dug wells. However, the resource is supplied in most of the cases to the population as raw water because groundwater is assumed to be safe. In that situation, the water chemistry and quality is usually not well known. Therefore, a study in Tikaré, northern Burkina Faso (West Africa) was carried out analysing fourteen trace elements to characterise their concentration patterns and correlations. The assessment of the quality and the chemistry of water resources is also done in order to forecast if any danger to the population might exist regarding the trace elements. The samples analysed were from 22 wells, 2 boreholes and 1 surface water location (small dam) in a laterite environment. This dam is recharging water to the underlying aquifer during and short after the rainy season. It was found that the most dominated trace elements are Fe and Mn. In summary, nearly all the studied trace elements were below the recommended limit in the drinking water guidelines of the WHO (Guidelines from Drinking Water Standards, 1984). The main source of the trace elements in groundwater seems to be the bedrock dominated by volcano-sedimentary schist and basalt. At least for the analysed area, with only limited traditional mining activities close to the sampling zone, there is no danger for humans to consume the extracted water regarding the analysed trace elements. Some good relationships were also found between some trace elements and major ions.