An urban geomonumental route focusing on the petrological and decay features of traditional building stones used in Madrid, Spain

The stone traditionally used to build cities contributes to their personality and attests to the geological substrate on which they stand. While stone decay in the built heritage can be attributed to a number of causes, anthropic activity has a particularly significant impact. The geomonumental routes project is one of the initiatives proposed in recent years for urban routes that convey geological fundamentals by observing the rocks present in heritage structures. Its innovative approach addresses traditional stone properties, original quarrying sites and mechanisms of decay. Madrid’s Royal Palace is a fine example of the use of traditional building stone in the centre of the Iberian Peninsula. In the geomonumental route proposed, the building doubles as an in situ laboratory that affords an overview of the main petrological properties of the two traditional stones most commonly used in the city’s built heritage, the forms of decay they are subject and the factors underlying such alterations. This route constitutes a tool for showing the main petrological features and decay forms in traditional building stones found in urban heritage façades, with a special focus on anthropic impact, primarily air pollution and the use of conservation treatments that time has proven to be unsuitable.     

Quality assessment of replacement stones for the Cologne Cathedral: mineralogical and petrophysical requirements

Owing to its long building history, different types of building stones comprised the construction of the Cologne Cathedral. Severe damage is observed on the different stones, e.g., sandstones, carbonate, and volcanic rocks, especially when the different stone materials neighbor the medieval “Drachenfels trachyte” from the “Siebengebirge”. The question arises, “Is the insufficient compatibility of the implemented building materials causatively related to the strong decay of the Drachenfels trachyte?” The present investigations focus on the petrography and mineralogical composition of eight different stones from the Cologne Cathedral. Petrophysical data, i.e., phase content, moisture and thermal characteristics as well as strength properties are determined and discussed in correlation to each other, showing that not only in terms of lithology great differences exist, but also the petrophysical properties strongly diverge. The ascertained parameters are discussed in view of the deterioration behavior and decay mechanisms of the different stones. To evaluate the compatibility of original, replacement and modern building materials, the properties of the investigated stones are compared to those of Drachenfels trachyte by means of constraints given in the literature. Besides optical properties, petrophysical criteria are also defined as well as strength values. It could be shown that primarily moisture properties, i.e., capillary and sorptive water uptake, water saturation, drying processes and moisture dilatation can be addressed to the deterioration processes.     

Research on limestone decay in a polluting environment, I˙stanbul-Turkey

 I˙stanbul, the capital of the east Roman, Byzantine and Ottoman Empires embraces two continents, one arm reaching out to Asia, the other to Europe. It is therefore, a rich city in terms of monuments and historical cites. Shell limestones of Upper Miocene age are used as building stone in the majority of the monuments in I˙stanbul because of their attractiveness, availability and workability. The durability characteristics of the limestones are examined, and those factors that are responsible for atmospheric weathering are discussed, in a humid and marine environment with important problems of urban pollution, specifically due to traffic. In the present study weathering of the building stones were first examined in situ by macroscopic observations. The weathering that developed as a result of environmental effects since this limestone was first used in historical monuments has been affected 0.1–1.5 cm deep from the surface. The weathered facing stone of Şehzade Mehmed Mosque in I˙stanbul is undergoing a program of progressive replacement. During this study, samples were taken from this monument where the shell limestone was used. The stone surface was principally examined by means of Scanning Electron Microscopy (SEM). Petrographical and mineralogical analyses were made by using optical microscopy and X-ray diffraction method. The physico-chemical properties of these rocks control their weathering behaviour and reactivity. Major and trace element analyses and the effect of deterioration on the physical properties of the limestones (unit weight, porosity and water absorption) have also been investigated. Studies on the samples implies that weathering on the stone surface caused important variations on the physical characteristics of the rock. Received: 11 February 1998 · Accepted: 18 August 1998     

The effect of cubic specimen size on uniaxial compressive strength of carbonate rocks from Western Turkey

One of the most important quality and design parameters of natural rock materials is uniaxial compressive strength (UCS). UCS value of a building stone determines its application area such as cladding, roofing, facing, and coverings. In rock mechanics and engineering practice determination of UCS values of rock materials is suggested on core specimens whereas in construction and building stone sector, cubic specimens are suggested. In this experimental study, the effect of cubic specimen size on UCS values of some carbonate rocks which are being used as dimension stones are investigated. A total of 299 cubic specimens at five different edge sizes (3, 5, 7, 9, and 11 cm) from limestone, marble, and travertine are prepared. Chemical, petrographic analyses and physical properties of specimens are determined and after that UCS tests are carried out. It is observed that as the specimen sizes increase from 3 to 11 cm, average UCS values decrease about 7% for the tested carbonate rocks. In the light of this finding, results of UCS tests could be interpreted considering cubic specimen sizes for the same rock types in various fields.     

Changing climate, changing process: implications for salt transportation and weathering within building sandstones in the UK

Salt weathering is a crucial process that brings about a change in stone, from the scale of landscapes to stone outcrops and natural building stone façades. It is acknowledged that salt weathering is controlled by fluctuations in temperature and moisture, where repeated oscillations in these parameters can cause re-crystallisation, hydration/de-hydration of salts, bringing about stone surface loss in the form of, for example, granular disaggregation, scaling, and multiple flaking. However, this ‘traditional’ view of how salt weathering proceeds may need to be re-evaluated in the light of current and future climatic trends. Indeed, there is considerable scope for the investigation of consequences of climate change on geomorphological processes in general. Building on contemporary research on the ‘deep wetting’ of natural building stones, it is proposed that (as stone may be wetter for longer), ion diffusion may become a more prominent mechanism for the mixing of molecular constituents, and a shift in focus from physical damage to chemical change is suggested. Data from ion diffusion cell experiments are presented for three different sandstone types, demonstrating that salts may diffuse through porous stone relatively rapidly (in comparison to, for example, dense concrete). Pore water from stones undergoing diffusion experiments was extracted and analysed. Factors controlling ion diffusion relating to ‘time of wetness’ within stones are discussed, (continued saturation, connectivity of pores, mineralogy, behaviour of salts, sedimentary structure), and potential changes in system dynamics as a result of climate change are addressed. System inputs may change in terms of increased moisture input, translating into a greater depth of wetting front. Salts are likely to be ‘stored’ differently in stones, with salt being in solution for longer periods (during prolonged winter wetness). This has myriad implications in terms of the movement of ions by diffusion and the potential for chemical change in the stone (especially in more mobile constituents), leading to a weakening of the stone matrix/grain boundary cementing. The ‘output’ may be mobilisation and precipitation of elements leading to, for example, uneven cementing in the stone. This reduced strength of the stone, or compromised ability of the stone to absorb stress, is likely to make crystallisation a more efficacious mechanism of decay when it does occur. Thus, a delay in the onset of crystallisation while stonework is wet does not preclude exaggerated or accelerated material loss when it finally happens.     

Potential for rock-polishing enterprises in southwestern Nigeria

Various igneous and metamorphic rocks constitute the basement complex in much of southwestern Nigeria. They are composed of felsic to mafic constitutions, and textural characteristics are wide ranging. Based on petrographic and physical parameters, these rocks hold promise to be utilized for polished items. However, industrial exploitation may be constrained by a number of factors, in some cases by huge financial outlay, environmental pollution and insincerity from government agencies. A sustainable, viable project in ornament stones would demand further geological appraisals, technical facilities, adequate capital and relevant manpower. As in most developing countries, in Nigeria deposits of stones or high-grade geomaterials are commonly blasted indiscriminately, and especially in the southwest, thus there needs to be an awareness and concern for their conservation and environmental protection. Mining of rocks commonly results in environmental degradation; consequently, there is a need to design adequate monitoring and conservation strategies for effective exploitation.     

Origin of salts in stone monument degradation using sulphur and oxygen isotopes: First results of the Bourges cathedral (France)

The crystallisation of soluble sulphate salts is one of the most important factors of stone monument degradation. The origin of these salts is variable: marine, air pollution, building or restoration material. The lack of certainty about these sources represents a problem for restoration campaigns. The use of sulphur and oxygen isotopic tracers allows to discriminate the origins of materials and some stone deterioration patterns like black crusts (e.g. [Šrámek J., 1988. Sulfur Isotopes in the revealing corrosion mechanism of stones. 6th International Congress on Deterioration and Conservation of Stone,. Proceedings, ed. J. Ciabach. Nicholas Copernicus University, Torun, Poland, 341–345.]). First results obtained on the Bourges cathedral (France) show that the sulphur and oxygen isotopic composition of sulphates from external (atmospheric pollution) and internal (mortars, plasters and sulphates coming from stone sulphide oxidation) origins constitute well differentiated poles. The isotopic composition of sulphates implied in different stone deterioration patterns is well explained by a combination of these poles. The present study will be extended to other French monuments located in different lithological and hydroclimatic settings where contributions of sea salts and ancient chemical treatments are suspected.     

Dry and wet laboratory tests and thermal fatigue of rocks

Investigation of the weathering and weatherability of three types of igneous rocks (granite, nepheline syenite and lamprophyric-minette dyke) was carried out by means of laboratory tests.For this purpose an experimental device was developed to obtain hot conditions alternating with room temperature and also with wet conditions, by immersion in two types of liquids (distilled water and a solution simulating “seawater”).Beyond qualitative effects emphasized in the text and in a photographic documentary, some quantitative determinations were made (weight loss and chemical decay of main cations of rock-minerals), which enable the authors to present an attempt at an alterability index for classification of the rocks. The research-program outlined on quantitative determinations is suitable for application in problems of engineering geology such as in determining suitability of rocks for use as breakwater stone or riprap for dams or in the stone deterioration measurements of the deterioration of stone used for buildings and ornamental facing stones.     

A comparison of the properties and salt weathering susceptibility of natural and reconstituted stones of the Orval Abbey (Belgium)

The Orval Abbey, a major monument of southern Wallonia, Belgium, was partly destroyed and rebuilt several times between the Middle Ages and the present time. The oldest parts are made of natural stones of local origin (Bajocian and Sinemurian limestones) and the most recent parts are mostly made of reconstituted stone. The process of reconstituted stone making is not known. Although confronting the same environmental conditions, the reconstituted stone is much more susceptible to weathering than the natural limestones, especially to salt crystallisation. The present study compared the mineralogical and petrophysical properties of these building materials to gather information on the making of the reconstituted stone and to understand the difference in salt susceptibility between natural and reconstituted stones. Microscopic observations and petrophysical measurements showed that the reconstituted stone is composed of debris of Sinemurian and Bajocian limestone and cement, and the salt efflorescences were thenardite. Within the cement, amorphous grains were found that may correspond to grains of clinker, which have not reacted during stone making. Although its porosity and water transfer properties were close to that of the Bajocian limestone, its pore access distribution was centred around 0.1 μm. Furthermore, the details of the pore size distribution allowed calculating salt susceptibility indices that were very high in the case of the reconstituted stone. Thus, the composition of the cement and the pore size distribution are likely the two factors explaining a high susceptibility of the reconstituted stone to salt weathering.     

Determination of deterioration of the main facade of the Ferit Paşa Cistern by non-destructive techniques (Konya,Turkey)

Building stones have long been one of the most widely used construction materials in the world. Building stones used in historical monuments are deteriorated partly or completely depending on the environmental and atmospheric effects. In recent years, non-destructive test methods have been used to assess deterioration of building stones used in historical monuments. Gödene stone is one of the building stones being widely used in the historical buildings in the Konya region, Central Anatolia. The most deterioration effects are observed in the Ferit Pa?a Cistern among the historical structures built with Gödene stone in the region. The aim of this study is to assess the deteriorating effects in the street façade of the Ferit Pa?a Cistern via non-destructive testing methods (Schmidt hardness rebound value, P-wave velocity, humidity measurement and thermal imaging) and create maps of deteriorated features. Turkey’s historic places are integrated to Turkish culture, efforts are made to conserve heritage through rehabilitation. Therefore, this study will help developers and federal managers during the project planning stage by providing technical data.     

Modified permeability apparatus to determine the permeability of natural building stones

Natural building stones are commonly used for a broad variety of purposes in the construction of many different types of buildings. Knowledge of the permeability of natural building stones, which are widely used in interiors, exteriors, flooring, veneering, landscaping, and walkway laying, is important for correctly determining their lifetime as well as their areas of use. The current study proposes a new test method to determine the air permeability of natural building stones, based on a previously developed method used to assess the permeability values of concrete samples. In this context, the air permeability index values of 96 natural building stone samples, belonging to 16 different types of natural stones classified into five groups, were determined using a new air permeability testing apparatus. The obtained permeability values were compared with the water absorption, open porosity, and apparent density properties of the natural building stones. Strong correlations were identified between the air permeability values of natural building stones and the open porosity and water absorption values. In contrast to other types of tests, the designed apparatus allowed information to be obtained concerning the porosity of natural building stones within a time period as short as 6 h. Based on the obtained results, the air permeability values of the natural building stones were classified into three groups as permeable, semi-permeable, and non-permeable. The study results indicated that the air permeability index can be effectively used to measure the air permeability of natural building stones within a short a period of time and by using a simple test apparatus.     

Influence of physico-mechanical properties of Indian dimension stones on cutting rate of diamond wire saw

Cutting performance of diamond wire saw is a key factor influencing mine planning, production scheduling, and equipment selection for dimension stone quarries. It is normally measured in terms of cutting rate. Rock samples collected from various granite and marble quarries in India were tested in laboratory to determine their physico-mechanical properties. Cutting rate of diamond wire saw was measured in the field studies during the actual cutting process in quarries. Using these laboratory determined properties and the cutting rate, a multiple linear regression model has been developed to predict the cutting rate of diamond wire saw. Physico-mechanical properties of rocks determined in laboratory are used as independent variables and cutting rate as predictor variable in the regression model. The study indicates that the cutting rate increases with a decrease in most of the hardness and strength parameters of rock. The final model is tested for its goodness of fit indicating a significant linear relation between cutting rate and physico-mechanical properties, namely tensile strength, slake durability index, and Cerchar hardness index with regression coefficient of 94%. The resulting model can be used suitably for different types of hard to medium hard and soft dimension stones. The generalized model for estimating the cutting rate becomes a handy tool for mining engineers to work out operating efficiency, expenses, planning etc. of the dimension stone block cutting.     

British decorative stones: finding the UK top ten

British geology reveals many good looking rocks, both ‘soft’ and ‘hard’, some of which were once highly prized for their polished decorative uses. They were quarried, cut, shaped and finished in a locally‐based British decorative stone industry that flourished twice, first in the Middle Ages, based largely on Purbeck marble from Dorset and also alabaster from Derbyshire, and then again in the nineteenth century when diverse sources of coloured and textured stone were pursued to the far corners of the British Isles. Today only the finished products survive; the pillars, panels and pavement adorning some fine but dusty architecture, but the stones commonly languish unrecognized and unappreciated. This anonymity is quite out of line with the heritage status of their settings and it will take a bit more geological awareness to put that right. A recent project aimed at rediscovering just one regional category of British decorative stones, the Devonshire marbles, has revealed how diverse and extensively‐used the fuller range of British decorative stones actually is. Not only do they embellish buildings from the merely modest to some of our finest, they were latterly chosen, specified, designed and coordinated by some of our greatest architects. Much work needs to be done to recognize British decorative stones in architectural settings and to restore them to their proper place in our national heritage. It is hoped that this article will throw light on the task ahead.     

The use of local stone in the buildings of the Isle of Wight

The charm of the Isle of Wight, so much appreciated by visitors and the local population alike, is very much a combination of its delightful scenery and unique assemblage of vernacular buildings. These buildings range from isolated farmhouses to elaborate manor houses, castles and churches all constructed using the indigenous stone resources of the island. Today, these stone buildings, many of which date back to medieval times, are increasingly in need of conservation repair to maintain them for future generations. Essential to such conservation work is the safeguarding of the island's indigenous building stone sources as many of the stones used are unique to the island and no longer quarried. Protecting these stone sources could also provide stone for new building projects which would help to further enhance the character of the island's towns and villages.     

The effect of welding degree on geotechnical properties of an ignimbrite flow unit: the Bitlis castle case (eastern Turkey)

Ignimbrites are associated with nearly most of the world’s volcanoes and are defined as a deposit from pyroclastic density currents. They consist predominantly of pumiceous lapilli and blocks, and glass shards, which shows evidence of having been emplaced as a concentrated hot and dry particulate flow. These rocks are widely used as building stone especially in ancient buildings. Bitlis valley is covered by ignimbritic products, derived from Nemrut stratovolcano, one of the significant volcanic centers in Eastern Anatolia. The Bitlis ignimbrite is separated into lower level (LL), middle level (ML) and upper level (UL) according to color, welding degree and structural features. All three levels were used extensively in many parts of the Bitlis castle as masonry materials. Studies were carried out on mineralogical and geochemical composition and on physical and mechanical properties of the ignimbrites. In addition, a freeze–thaw cycle test was executed. There are no considerable differences in mineralogical composition among the levels of ignimbrite. All levels contain plagioclase, sanidine, pyroxene, and opaque mineral. In addition, anorthoclase and quartz are seen. In general, the LL of ignimbrite shows relic perlitic and eutaxitic texture, whereas eutaxitic and vesicular texture are commonly developed in the ML and UL, respectively. Lower, middle, and upper level ignimbrite samples display similar and limited compositional spread in terms of major oxide elements. They have trachyte composition. Building stones can be classified according to mineralogy, mechanical and physical properties and processing types. Mechanical and physical properties are very important with respect to stone quality/durability. The mechanical and physical properties of the ignimbrites are controlled by the welding degree. It was found that increasing welding degree from UL to LL correlates with increasing density, compressive strength and slake durability index and with decreasing porosity. The Bitlis ignimbrites have turned out as susceptible to freeze–thaw cycles.     

A methodology for locating the original quarries used for constructing historical buildings: application to Málaga Cathedral, Spain

It is often necessary to locate the original quarry which supplied the stone for a particular historical building. This stones could be used for future restoration work and for testing in the laboratory (artificial aging tests, physical properties determination, control of the efficacy of conservation treatments, etc.). Generally, reviewing historical documentation gives information about the geographical setting of quarries and location of the stones in the monument, but this information needs to be proved by field and laboratory studies. The comparative study of stone from quarries and monuments should basically include the following: (1) mineralogical and petrographical studies; (2) the chemical analysis of major, minor and trace elements; (3)stable isotopes determinations; (4) physical properties of quarry materials and unweathered building stone (water absorption, ultrasound transmission velocity, porosity and porous system, density, bulk density, compressive strength, etc.). This methodology was applied to Málaga Cathedral stones represented in the main façade, towers, and the western zone of the terrace, which, according to historical literature, came from Almayate (Miocene–Pliocene limestones) and Cerro Coronado (Permotriassic sandstone) in Málaga. The conclusion of the comparative study carried out on quarries and building stones was consistent with the information available from the historical documentation.     

Environmental impact on the Roman monuments of Tarragona,Spain

The extant remains of the Roman monuments of Tarragona, Spain are made of different types of Miocenic rocks from the quarries surrounding the city, which vary from calcarenite to bioclastic limestones, showing different degrees of dolomitization, depending on their diagenetic evolution. The decay of these monuments is highly dependent on the mineralogy and the fabric of the stone as well as on the environmental conditions to which the monument subjected. As a consequence, different forms of decay are observed on these monuments, namely, granular disintegration, differential erosion between sparitic and micritic areas of the rock, and development of black crust and orange patinas, some of them attributed to a sulfation process. A number of processes have been established as being responsible for the decay forms observed: sulfation on sheltered areas of the building in the urban environment; differential dilatation because of the NaCl of the marine spray that crystallizes inside the porosity; hydric and thermal expansion of the stone, both related to the amount and crystallinity of the clay minerals forming the rock matrix; and biocolonization on the stone surface. An empirical model is proposed to explain the decay forms studied in relation to these factors (rock and environment).     

Building stones and geological environment in three ancient cities of Aegean Thrace,Greece

The type, use, and size of the structural stones employed in three ancient cities of the Aegean Thrace are considered Abdera, Maroneia, and Mesimbria. The impact of the geological environment on the choice of these materials also is examined. From the results obtained it is implied that despite the great variety of rocks exposed in the area, the rocks used in construction in these cities are mostly types of sandstone and limestone, rocks with moderate technical properties and easily obtained from the area. The quarries were within a radius of less than 10 km and the size distribution of the building stones in all towns is discussed.     

The use of X-ray tomography in the study of water repellents and consolidants

To reduce the weathering rate of natural building stones, a wide variety of water repellents and consolidants are commercially available. Although a lot of research is performed on these products, it remains difficult to determine which product is appropriate to use for a certain type of building stone. Each type of building stone has its own petrographic characteristics (mineralogy, texture, …), leading to typical physical and technical properties which influence its rate of decay. The localisation of the products inside a stone type is not only depending on the properties of the products themselves, but also linked to the texture and structure of the stone. The impregnation depth of the products strongly influences their efficiency and is therefore a key issue in the determination if a product is functional for a certain type of stone. X-ray micro-CT has recently been introduced as a non-destructive material evaluation technique for engineering and geology purposes. The fact that micro-CT can provide information about the internal structure and properties of natural building stones, is a major advantage in the study of their conservation. Firmly linked with more classical research techniques, this non-destructive technique offers an extra dimension to the cultural heritage research.In this paper, non-destructive X-ray computed micro-tomography (micro-CT) turns out to be a powerful tool as it can visualise the presence of water repellents and consolidants inside the stone and can help to detect the influence that these treatments exert on porosity and pore-size distribution. For the visualization of the product its atomic number and density and the amount of product inside the natural building stone is crucial. Besides the contrast in attenuation, the resolution of the micro-CT also needs to be taken into account to obtain a good contrast between stone and product. By doping with 3-bromopropyltrimethoxysilane, more contrast occurs between the stone material and the conservation product. When the amount of product inside the samples is very low and the product is homogeneously spread inside the sample, the doped product is difficult to distinguish from the stone material due to the resolution of the micro-CT. When the amount of doped product inside the stone material reaches a certain threshold value, the dope will appear in the 2D cross-sections derived from micro-CT, creating a good visualization of the products inside the stone samples.