青藏高原西部措勤县中新世布嘎寺组钾质火山岩成因

通常认为青藏高原新生代钾质、超钾质岩浆源于地幔,但最近的一些研究显示一些钾质火山岩也可以起源于下地壳.青藏高原西部措勤县中新世布嘎寺组火山岩是一套钾质到超钾质的岩石,根据化学组成可以将它们分成中酸性和中基性两组火山岩,它们都属于钾玄岩系列.其中中酸性组火山岩具有一些类似于埃达克质熔体的成分特征,它们可能是拉萨地块下地壳相对富钾的镁铁质物质部分熔融的产物;中基性组火山岩可能起源于一个含金云母的地幔源区,或者是来自该地幔的基性岩浆的分异产物.对中酸性组火山岩高精度的氩-氩同位素定年获得其坪年龄为15.5Ma,证实布嘎寺组火山岩喷发在晚中新世.结合布嘎寺组火山岩的年龄、化学组成和区域构造以及岩浆组合,我们初步认为布嘎寺组火山岩可能与15～20Ma左右构造伸展活动产生的南北向地堑系统有关.     

东天山莫哲巴依萨依环状基性超基性杂岩体研究

本文对莫哲巴依萨依环状基性超基性杂岩体的岩石学、岩石地球化学特征进行了较全面的论述。它们属铁质基性、超基性岩,为同源岩浆分异而成,其成因类似于阿拉斯加型同心环状超镁铁质杂岩。形成时代为晚石炭世—早二叠世。     

南秦岭东段耀岭河群、陨西群、武当山群火山岩和基性岩墙群岩石成因

南秦岭东段新元古代中-晚期(676～833 Ma)耀岭河群、陨西群、武当群火山岩和基性岩墙群产生于大陆板内裂谷环境.根据岩石地球化学数据,南秦岭东段新元古代中-晚期裂谷基性熔岩和基性岩墙总体上属于低Ti/Y(<500)岩浆类型.元素和同位素数据表明,南秦岭东段新元古代中-晚期裂谷基性熔岩和基性岩墙的化学变化不是由一个共同的母岩浆结晶分异作用所产生,它们极有可能是源于地幔柱源(εNd(t)≈ 5,Mg#≈0.7,La/Nb≈0.7).大陆地壳或大陆岩石圈混染作用对于南秦岭东段新元古代中-晚期裂谷基性熔岩和基性岩墙的形成有重要贡献.我们的研究揭示,南秦岭东段新元古代中-晚期火山岩和基性岩墙存在空间上的地球化学变化.它们总体上是产生于幔源石榴子石稳定区.而西北部镇安地区耀岭河群基性熔岩的母岩浆则是形成于幔源尖晶石-石榴子石过渡带.碱性熔岩是产生于部分熔融程度较低(<10%)的条件下,拉斑玄武质熔岩是产生于部分熔融程度较高(10%～30%)的条件下.武当山地区的武当山群和耀岭河群基性熔岩的母岩浆经受了浅层位辉长岩质(cpx plag ± ol)分离作用,而其他地区基性熔岩和基性岩墙的化学演化则是受控于单斜辉石(cpx)±橄榄石(ol)分离作用.     

珂吾拉勒山西段下二叠统钾质基性火山岩的地球化学特征

阿吾拉勒山位于中国新疆伊犁地区,是中亚造山带的重要组成部分。本文对阿吾拉勒山西段琼布拉克、卡查可让和托巴斯萨依等地出露的下二叠统基性火山岩的主元素、微量元素和同位素地球化学特征进行了研究。阿吾拉勒山西段琼布拉克、卡查可让、托巴斯萨依等地出露的基性火山岩为钾质基性火山岩（属橄榄玄粗岩系的橄辉玄粗岩）,其镁铁指数从23．3变化到64．1,表明它们经历了相当程度的分异演化;微量元素地球化学特征显示,该类钾质基性火山岩形成于后碰撞弧环境,暗示该地区在早二叠世地球动力学性质由挤压转换为伸展。La／Yb和Nb／Y比值显示,由于源区受到与俯冲有关的流体交代影响,岩石明显富集大离子亲石元素并亏损Nb、Ta和Ti等高场强元素。微量元素地球化学特征还显示,该类钾质基性火山岩的源区除了含有尖晶石、辉石、橄榄石和少量的石榴子石外,还含有一定数量的角闪石或金云母等含水矿物,该类岩石原始岩浆形成于深度大于70km的尖晶石橄榄岩与石榴子石橄榄岩的过渡区;微量元素地球化学特征显示,阿吾拉勒山西段南北两地钾质基性火山岩的源区组成有明显差异：南部的托巴斯萨依钾质基性火山岩较北部的卡查可让和琼布拉克钾质基性火山岩的源区更加富水,受到俯冲物质的影响更强烈,但源区石榴子石含量相对较少;同位素地球化学特征也显示,琼布拉克和卡查可让等地的钾质基性火山岩sNd（f）值比托巴斯萨依的钾质基性火山岩更低,（87Sr／86Sr）i比值比托巴斯萨依的钾质基性火山岩略高,暗示它们源区的富集程度更高,也表明托巴斯萨依的钾质基性火山岩受软流圈的影响更为强烈。     

北大巴山碱质基性—超基性潜火山杂岩的辉石矿物研究

北大巴山碱质基性-超基性潜火山杂岩中有7种岩石含有新鲜的单斜辉石,它们分属于透辉石、普通辉石及霓辉石。单斜辉石可划分为5种成因类型:(1)斑晶、微斑晶及微晶;(2)深源捕虏晶;(3)半同源捕虏晶;(4)异源捕虏晶;(5)地幔型捕虏晶,本文涉及前4类辉石。单斜辉石的研究表明:(1)7种含辉石的岩石为同源岩浆结晶分异作用的产物,源岩浆为碱性-过碱性幔源岩浆。(2)初始岩浆形成于77km以下深度,上升过程中岩浆曾在3个不同深度储积。(3)岩浆上升至近地表处,在冷凝固结前曾有多次潜火山隐爆活动发生。(4)霓辉石捕虏晶的出现代表区内存在另一种碱基性岩浆活动。(5)辉石成分指示碱质基性-超基性次火山杂岩形成于陆边板内裂陷带。     

对超基性—基性岩中锆石成因、来源及其U- Pb年龄的探讨——以江南造山带西段为例

对超基性—基性岩中锆石成因及其来源的解释直接关系到岩石成岩时代的准确厘定。江南造山带西段（包括桂北、黔东和湘西地区）的新元古代变质地层中分布有大量的超基性—基性火山岩和侵入岩,过去的研究认为它们都形成于新元古代,是四堡造山阶段和造山后裂谷阶段的产物。对前人近年发表相关岩石的锆石U- Pb测年数据的分析,结合笔者等对该地区多件基性岩中锆石的LA- ICP- MS测年结果,发现部分超基性—基性岩中普遍存在少量古生代,甚至中、新生代的年轻锆石。通过锆石形态及阴极发光特征分析,认为这些年轻锆石并不能一概用后期热液改造或挑样过程中混入来解释。本文抛砖引玉,旨在引起国内同行对超基性—基性岩真实成岩年龄解释的探讨。如果以往对这些超基性—基性岩中锆石成因及成岩时代的解释存在问题,将区域上多期岩浆热事件混为一谈,那么对江南造山带西段的构造演化历史需要重新解读。     

甘肃宕昌好梯碱性超基性火山岩:一种含上地幔包体和巨晶的钾质超镁铁煌斑岩

甘肃宕昌好梯含上地幔包体和巨晶的碱性超基性火山岩为新生代火山作用的产物。该火山岩的岩相学、矿物学、岩石化学和地球化学特征显示了从碱性基性岩(霞石碱玄岩-碧玄岩)-超基性岩(苦橄岩-玻基辉橄岩)-钾镁煌斑岩之过渡类型岩石的特征。表明好榜火山岩是一种煌斑岩。根据火山岩的岩相学、矿物学、岩石化学和地球化学特征,火山岩的镁铁指数>90,特别是岩石中含一定数量的金云母以及含白榴石、原生方解石、碱性角闪石和碱性辉石的球状分异物等特征,将该火山岩命名为钾质超镁铁煌斑岩。本文还提出该钾质超镁铁煌斑岩代表一种原生煌斑岩浆的标志。     

湘西隘口新元古代基性-超基性岩墙年代学和地球化学特征:岩石成因及其构造意义

湘西隘口地区基性-超基性岩墙锆石LA-ICP-MSU-Pb年龄为831.6±9.7Ma,与桂北、赣东北基性岩墙具有相似的形成时代(约830～825Ma),组成了扬子陆块南缘新元古代呈带状断续分布的基性岩墙群。隘口地区的基性-超基性岩墙化学成分上属于碱性系列,超基性岩具有比基性岩明显高的MgO、Cr和Ni含量,所有样品都展示出相似的稀土和微量元素配分模式,部分样品具有轻微的Nb的负异常和明显的P、Ti的负异常,表明岩浆在演化的过程中遭受过不同程度的地壳的混染。该区基性-超基性样品具有明显高的相似于软流圈地幔的εNd(t)值,则暗示其母岩浆来源于长期亏损的软流圈地幔。结合其微量元素及其对应的比值和εNd(t)值与板内裂谷碱性玄武岩和洋岛玄武岩非常相似的特征,以及扬子周缘大规模相同时代岩浆作用的特点,我们认为这些新元古代火成岩是地幔柱有关的裂谷岩浆作用的产物,地幔柱或超级地幔柱的作用导致了Rodinia超大陆最终的裂解。     

藏北若拉岗日C-P1裂谷带的发现及构造意义

若拉岗日裂谷带位于拉竹龙-西金乌兰-金沙江结合带的中段,该带作为一条重要的大地构造分界线已被地学界所注目.在西金乌兰地区发现了蛇绿混杂岩带,在金沙江、甘孜理塘等地保留有较完整的洋壳残片(蛇绿混杂岩套)和岛弧火山岩建造,其西延的若拉岗日一带,没有见到这些地质体.基性岩(脉)和少量超基性岩脉是三叠纪热侵位的产物,地球化学等特征表明,它们不是MORB型基性岩,更多地体现板内裂谷特征;石炭系—下二叠统基性火山岩以碱性系列玄武岩为主,具裂谷型双峰式特征,岩石地球化学等特征表明,它们形成于板内或板内裂谷;酸性花岗岩类侵入岩极不发育,构造岩浆带不发育.     

青藏高原西南部查孜地区中新世钾质火山岩地球化学及其成因

通常认为青藏高原的钾质-超钾质火山岩的形成多与地幔有着紧密的联系,然而最近对青藏高原的一些钾质-超钾质火山岩的研究显示一些钾质火山岩也可以起源于下地壳.青藏高原西南部查孜地区中新世火山岩是形成于13～11 Ma左右的一套钾质-超钾质岩石,根据岩石化学组成将其分为中基性火山岩组、中性火山岩组和流纹质火山岩.其中中基性火山岩组可能源于一个富含金云母的富集地幔源区;中性火山岩组可能是富钾的镁铁质下地壳部分熔融的产物;流纹质火山岩可能是拉萨地块在中新世时期的伸展构造运动而导致中上地壳因减压而发生部分熔融的产物.结合查孜地区及其邻近火山岩的年龄、化学组成以及岩浆组合,初步认为查孜地区火山岩可能与高原在中新世发生伸展活动而产生的南北向地堑系统有关.     

滇西盈江地区上新世双峰式火山岩的地球化学特征及其构造意义

盈江地区上新世火山岩是腾冲火山岩的重要组成部分,但以往研究极少涉及。通过对该火山岩进行岩石地球化学和KAr年代学研究,同时与腾冲火山岩东侧的龙江河谷地区的上新世火山岩对比,认为盈江和腾冲地区上新世火山岩是大陆构造背景下造山带造山后伸展作用下形成的火山岩,具有高Al_2O_3(15.54%~17.44%)、高K_2O(0.94%~3.50%)的岩石化学特点,为高钾钙碱性系列火山岩,形成于拉张环境,为双峰式火山岩(玄武岩DI=33~50,英安岩DI=62~76)。造山带裂谷火山岩常具弧火山岩的岩石化学特点,但其形成于造山带造山后的拉张环境,与板块俯冲作用没有直接关系。造山带裂谷火山岩发育在早期造山带,是造山带发展过程中一定阶段的岩浆作用的产物。     

The Redistribution of Phosphorus in Basic Volcanic Rocks

This work presents data on phosphorus content in the central and peripheral sectors of primary jointing blocks in olivine basalts of the Baikal rift zone (Khamar-Daban Range), as well as basaltic andesite flows and dolerite sills on the Karabakh Highland of the Lesser Caucasus. The P₂O₅ content decrease near cracks in volcanic rocks of the Baikal rift zone is caused by leaching of phosphorus during humid weathering. Estimates of the amount of mobilized phosphorus suggest that alkaline basic volcanic rocks can serve as the continental source for the formation of phosphates.     

松辽盆地含CO_2火山岩气藏的形成和分布

松辽盆地特有的深部构造背景和裂谷演化特征,造成盆地内含CO_2火山岩气藏的形成和富集。松辽裂谷盆地中新生代火山岩浆活动发育,总体上具有多期喷发、分布广泛和储集条件良好的特点。火山活动以中心式喷发为主,主要发育中基性-酸性火山岩,发育流纹岩、凝灰岩等多种岩石类型,爆发相和溢流相2种火山岩相。中生代火山岩在盆地内分布广泛,营域组构成深层有利储层,新生代火山岩在盆地外围出露较多,而在盆内出露较少。盆地高含量的二氧化碳为无机幔源成因,由青山口期和新生代幔源岩浆脱气形成。含CO_2火山岩气藏的形成主要受深部构造背景、深大断裂和中新生代火山岩控制。已发现含CO_2火山岩气藏主要分布于古中央隆起带及其两侧断陷的营城组火山岩中,具有点状、带状分布,局部富集的特点。根据主控因素分析,预测了5个CO_2富集区带。     

南秦岭元古宙板内火山作用特征及构造意义

南秦岭元古宙火山岩主要由两大类岩石构成，一类为SiO245%-57%的基性火山岩系，另一类为SiO267%-78%的酸性火山岩系，主要岩石类型为细碧岩、玄武岩和石英角班岩、流纹岩。基性火山岩整体上属拉斑玄武岩系列，酸性火山岩属钙碱系列。火山岩强烈富集稀土元素，尤其是轻稀土元素，酸性火山岩和基性火山岩有相似的稀土元素特征，显示了源区特征的不同。基性火山岩富集强不相容元素，相对亏损Nb和Ti, 成于大陆裂谷环境，具有大陆拉斑玄武岩的特征。同位素特征表明基性火山作用与地幔柱活动密切相关。南秦岭的中、晚元古代大陆拉张及由古地幔柱活动所引发的陆裂火山岩浆活动是古秦岭洋打开的先兆。     

北京西山——一个早中生代拗拉谷的一部分

华北地台北部的燕辽带在晚元古代时为一拗陷带,蓟县地区的整个层系厚度在10,000m以上。中生代时发生强烈的岩浆活动和形变。其构造性质与地台的含义并不相符,前人对该区有沉降带、台褶带等提法。     

华北中—新元古代火山岩及其对成矿作用的制约——以河北洞子沟银多金属矿床为例

华北地区中—新元古代发育有大红峪期、串岭沟期等多期火山岩,产出的主要岩石类型为碱性基性岩,包括响质碱玄岩、碱玄质响岩、响岩、副长岩、粗面岩、粗面玄武岩和粗面安山岩。该岩石为碱性,Ti含量高,微量元素表现为富集大离子亲石元素而贫高场强元素,显示其构造环境属拉张环境;微量元素比值和同位素分析显示岩浆为幔源,但受到大陆地壳的强烈影响,属裂谷环境。在该区发育有洞子沟、将军关、银冶岭、罗选厂、翟庄等一系列银多金属矿床(点)。这些矿床(点)在时间上和火山岩的形成时代基本一致,在空间上相互关联,许多矿体直接产于火山岩或火山机构中,矿石中发育与火山活动关系密切的低温硫化物矿物黝铜矿、自然铜、碲银矿等,从而证明中—新元古代火山作用对该区银多金属矿床的形成具有重要的作用。     

Catalysis and hydrogenation: volcanic activity and hydrocarbon generation in rift basins,eastern China

Major oil reserves in rift basins in eastern China are correlated with high quality source rocks. The high quality source rocks and their hydrocarbon generation are often related to volcanic activity in the basins. Three kinds of volcanic rocks in source rocks have been defined in the Songliao, Bohaiwan and North Jiangsu basins. Some of the volcanic rocks were formed in lacustrine environments during the deposition of source rocks. It is remarkable that a part of volcanic-derived materials serves as a source of nutrients for lacustrine organisms which resulted in the formation of the organic matter in source rocks with high organic C contents. Besides hydrothermal alteration, the volcanic minerals contributed catalysis and H₂ to thermal alteration of organic matter into hydrocarbons during burial and diagenesis of source rocks and volcanics. A series of thermal laboratory simulations were performed with various combinations of immature source rocks and natural mineral assemblages. Results indicate that a significant volume of H₂ was produced from the source rock mixed with olivine and zeolite; moreover, this combination provided a 3-fold increase in hydrocarbons. It is proposed that catalysis and hydrogenation by the volcanic minerals promote hydrocarbon generation, although organic matter type is significantly variable. Hydrocarbons are generated at a lower degree of thermal stress when the reaction mixture contains volcanic minerals, and have a heavier C isotopic composition, compared to the control set of experiments.     

Geochronology,geochemistry and tectonic significance of the late Mesozoic volcanic sequences in the northern Wuyi Mountain volcanic belt of South China

The widespread occurrence of late Mesozoic volcanic rocks in the Gan-Hang Belt in South China is associated with similarly widespread mineralization, but many important questions surrounding these volcanic rocks have not been clearly answered. The Tianhuashan basin located in the northern Wuyi Mountain volcanic belt is one of the most important volcanic basins in the Gan-Hang Belt, and it is primarily composed of the Daguding and Ehuling Formations and their intrusive counterparts. LA-ICP-MS zircon U–Pb dating shows that the Daguding Formation erupted in the Late Jurassic (152–160 Ma), whereas the Ehuling Formation erupted in the Early Cretaceous (131–139 Ma) in the Tianhuashan basin. Volcanic rocks are rhyolite and share similar trace and rare earth element patterns with an enrichment of LREEs and a depletion in Sr, Ba, Nb, Ta, P, Eu and Ti. They are also characterized by negative whole rock ε_Nd(t) and zircon ε_Hf(t) values with Paleoproterozoic t_2DM ages, suggesting that they were derived primarily from the remelting of ancient crustal materials. Daguding volcanic rocks are strongly peraluminous and show a higher Mg# than pure crustal melts, implying that they were likely derived from Paleoproterozoic metasedimentary basement materials. However, Ehuling volcanic rocks are weakly peraluminous and have a pronounced A₂-type geochemical signature. Detailed elemental and isotopic data suggest that they were formed by the partial melting of the Paleoproterozoic metamorphic basement (including metasedimentary and metaigneous rocks) at a high temperature (~ 840 °C), followed by fractional crystallization. These results imply that during the Late Jurassic, South China on the Gan-Hang Belt was a continental arc coupled with the subduction of the Paleo-Pacific plate. Since the beginning of the Early Cretaceous, an intra-arc rift has formed along the Gan-Hang Belt as a consequence of slab rollback. These results also indicate that the extension in the Gan-Hang Belt began later than the southwestern part of the Shi-Hang Zone and lasted from 139 Ma to 122 Ma.     

Emanation-Sedimentary Metallogenic Series and Models of the Proterozoic Rift in the Kangdian Axis

The Kangdian axis basement can be divided into two tectonic layers. The lower tectonic layer is the crystalline basement which is made up of the Archaean Dibadu Formation and early Proterozoic Dahongshan Group. The former is a kata-metamorphic basic volcano-sedimentary formation of the old geosyncline (old continental nucleus), and the latter is a medium-grade metamorphosed alkali-rich basic volcanic (emanation)-sedimentary formation of the Yuanjiang-Dahongshan marginal rift. They are in disconformable contact. The upper tectonic layer is the folded basement, and made up of the middle-late Proterozoic Kunyang Group. It is the result of Dongchuan-Yuanjiang intercontinental rifting with discordant contract with the underlying and overlying strata. Along with the evolution of Proterozoic from early to late, four types of emanation-sedimentary deposits in the Kangdian axis rift were formed in turn: (1) emanation-sedimentary iron-copper-gold deposits related to basic volcanic rocks in the Yuanmou-Dahongshan     

Geochemistry of volcanic rocks from transform margins: Evidence from the Alchan basin,northwestern Primorie

Geological, petrochemical, and geochemical data are reported for volcanic rocks of a Cretaceous pull-apart basin in the Tan Lu strike-slip system, Asian continental margin. A comparison of these volcanic rocks with magmatic rocks from typical Cenozoic transform margins in western North America and rift zones of Korea made it possible to distinguish some indicator features of transform-margin volcanic rocks. Magmatic rocks from strike-slip extension zones bear island-arc, within-plate, and, occasionally, depleted MORB geochemical signatures. In addition to calc-alkaline rocks, there are bimodal volcanic series. The rocks are characterized by high K₂O, MgO, and TiO₂ contents. They show variable enrichment in LILE relative to HFSE, which is typical of island-arc magmas. At the same time, they are rich in compatible transition elements, which is a characteristic of within-plate magmas. The trace-element distribution patterns normalized to MORB or primitive mantle usually display a negative Ta-Nb anomaly typical of suprasubduction settings. Their Ta/Nb ratio is lower, whereas Ba/Nb, Ba/La, and La/Yb are higher than those of some MORB and OIB. In terms of trace-element systematics, for example, Ta-Th-Hf, Ba/La-(Ba/La)_n, (La/Sm)_n-La/Hf, and others, they fall within the area of mixing of magmas from several sources (island arc, within plate, and depleted reservoirs). The magmatic rocks of transform settings display a sigmoidal chondrite-normalized REE distribution pattern, with a negative slope of LREE, depletion in MREE, and an enriched or flat HREE pattern. The magmas with mixed geochemical characteristics presumably originated in a transform margin setting in local extension zones under the influence of mantle diapirs, which caused metasomatism and melting of the lithosphere at different levels, and mixing of melts from different sources in variable proportions. Original Russian Text ? V.P. Simanenko, V.V. Golozubov, V.G. Sakhno, 2006, published in Geokhimiya, 2006, No. 12, pp. 1251–1265.